syn Additions to 4α-Epoxypyranosides: 
Synthesis of l-Idopyranosides

Cheng, Gang; Fan, Renhua; Hernández-Torres, Jesús M.; Boulineau, Fabien P.; Wei, Alexander

doi:10.1021/ol702185y.s002

ol702185y_si_002.pdf (965.91 kB)

syn Additions to 4α-Epoxypyranosides: Synthesis of l-Idopyranosides

journal contribution

posted on 2007-11-08, 00:00 authored by Gang Cheng, Renhua Fan, Jesús M. Hernández-Torres, Fabien P. Boulineau, Alexander Wei

The syn-selective addition of organozinc compounds to 4α-epoxypyranosides (4α-EPs), generated from methyl β-d-glucoside or aminoglucoside, provides an efficient route to pyranosides with α-l-ido configurations, including l-iduronic acid, neosamine B, and higher monosaccharide derivatives.

syn Additions to 4α-Epoxypyranosides: Synthesis of l-Idopyranosides

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