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Cobalt Nanoparticles Embedded in N‑Doped Carbon Nanotubes on Reduced Graphene Oxide as Efficient Oxygen Catalysts for Zn-Air Batteries
journal contribution
posted on 2020-07-02, 12:09 authored by Xiaomin Peng, Licheng Wei, Yiyi Liu, Tianlun Cen, Zhifeng Ye, Zhaogen Zhu, Zhaotong Ni, Dingsheng YuanThe key point to developing green
and environmentally friendly
zinc-air batteries is exploring efficient bifunctional electrocatalysts
for oxygen reduction and evolution reactions (ORR and OER) on an air
electrode. Herein, we reported a facile and green method for fabricating
a bifunctional electrocatalyst of Co@N-CNT/rGO, which is composed
of cobalt nanoparticles wrapped into nitrogen-doped carbon nanotubes
growing on reduced graphene oxide. It is obtained by pyrolyzing a
GO-wrapped two-dimension leaf-like zeolitic imidazolate framework.
The Co@N-CNT/rGO-0.1 exhibits efficient catalytic activities for ORR
and OER with a small Tafel slope. It benefits from the synergistic
effect of the Co nanoparticle and N-CNT, the high conductivity of
reduced graphene oxide and highly graphitizing carbon nanotubes, the
great specific surface area, and suitable aperture size. Moreover,
the Co@N-CNT/rGO-0.1 catalyst assembled primary zinc-air battery shows
a high open-circuit voltage (1.43 V), a large peak power density (122
mW cm–2), and an excellent specific capacity (855
mA h gZn–1). In addition, the Co@N-CNT/rGO-0.1
assembly rechargeable zinc-air battery also displays an excellent
cycling durability of 120 h at 5 mA cm–2. According
to the above results, our work provides a cost-effective strategy
to scale-up and commercialize the bifunctional electrocatalysts for
zinc-air battery application.