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Synthesis and Characterization of Hierarchically Ordered Porous Silica Materials
journal contribution
posted on 2004-06-01, 00:00 authored by T. Sen, G. J. T. Tiddy, J. L. Casci, M. W. AndersonA series of hierarchically ordered porous silica composites were synthesized using anionic
(SO4-2) polystyrene spheres and triblock copolymers Pluronic F127 (EO107PO70EO107) and
P123 (EO20PO70EO20) as templates in the presence of cosurfactants (n-alcohols) in an acidic
medium. The silica materials were characterized by XRD, SEM, TEM, Hg porosimetry, N2
adsorption, solid-state NMR, and TG-DTA. At least three distinct pore sizes are observed in
these materials. The composites consist of three-dimensional ordered macrospheres (200−800 nm) with interconnecting uniform-sized (70−130 nm) windows. The walls of these
macrospheres consist of mesostructured pores (3−8 nm). Nitrogen adsorption indicates the
presence of microporosity (<2 nm). Here, we report the detailed synthesis and characterization of such hierarchically ordered porous silica composites (Sen et al. U.K. Patent, GB
0201951.1; Angew. Chem., Int. Ed. 2003, 42, 4649) with macro−meso−microporous structure
and a three-dimensional interconnectivity. These materials could be useful as potential
supports for heterogeneous catalysis for bulkier molecules where diffusion of reactant
molecules could be facilitated.