ol8011875_si_001.pdf (773.51 kB)
Ruthenium-Catalyzed Hydroarylations of Methylenecyclopropanes: Mild C−H Bond Functionalizations with Conservation of Cyclopropane Rings
journal contribution
posted on 2008-08-21, 00:00 authored by Sergei I. Kozhushkov, Dmitry S. Yufit, Lutz AckermannRing conservation was observed in the first catalytic intermolecular hydroarylation of methylenecyclopropanes via C−H bond functionalization, a remarkable reactivity mode for a transformation proceeding through (cyclopropylcarbinyl)metal intermediates.