Palladium-Catalyzed Aerobic Intramolecular Aminoacetoxylation of Alkenes Enabled by Catalytic Nitrate
2016-10-18T19:07:30Z (GMT)
by
A mild aerobic intramolecular
aminoacetoxylation method for the
synthesis of pyrrolidine and indoline derivatives was achieved using
molecular oxygen as the oxidant. A catalytic NOx species acts as an electron transfer mediator to access a
high-valent palladium intermediate as the presumed active oxidant.
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