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Ligand-Exchange-Ready CuInS2/ZnS Quantum Dots via Surface-Ligand Composition Control for Film-Type Display Devices
journal contribution
posted on 2019-08-23, 17:35 authored by Jinyoung Choi, Wonseok Choi, Duk Young JeonQuantum
dots (QDs) are promising material that regularly requires
ligand exchange for application in film-type display devices. However,
the photoluminescence quantum yield (PLQY) and ligand exchangeability
of the QDs are often incompatible with each other because strongly
bonded ligands, which easily grant high PLQY, require more energy
to be changed to other ligands. Here we present CuInS2/ZnS
QDs comprising both high ligand exchangeability and PLQY through a
simple mixed-ligand synthesis approach to control the composition
of the surface ligands. The QDs were able to maintain both beneficial
traits of thiol- and amine-based ligands, which are high PLQY and
ligand exchangeability, respectively. The analysis showed that the
resulting QDs that contain combined ligand composition have PLQYs
reaching up to 90% of the QDs with only the thiol-based ligand while
maintaining a certain portion of the amine-based ligand as intended
to comprise facile ligand exchangeability. Furthermore, it was found
that the PLQY of the QDs was able to be augmented even further by
the ligand exchange. These findings are expected to greatly simplify
the fabrication of efficient film-type display devices.