data_dflbr _audit_creation_method SHELXL-97 _chemical_name_systematic ; Tetrakis(1,3-Diphenyl-1,3-propanediono)-(mu!2$-4,4'-bipyridyl)-di-zinc(II), clathrate with Fluorobenzene (1:2/3) ; _chemical_name_common Tetrakis(Dibenzoylmethanato)-(mu!2$-4,4'-bipyridyl)-di-zinc(II), clathrate with Fluorobenzene (1:2/3) _chemical_formula_moiety [Zn2(4,4'-biPy)(DBM)4]*2/3(Fluorobenzene) _chemical_formula_sum 'C74 H55.33 F0.67 N2 O8 Zn2' _chemical_formula_weight 1243.94 loop_ _atom_type_symbol _atom_type_description _atom_type_scat_dispersion_real _atom_type_scat_dispersion_imag _atom_type_scat_source 'C' 'C' 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' 'H' 'H' 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' 'N' 'N' 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' 'O' 'O' 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' 'F' 'F' 0.0171 0.0103 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' 'Zn' 'Zn' 0.2839 1.4301 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' _symmetry_cell_setting Triclinic _symmetry_space_group_name_H-M P-1 (no.2) loop_ _symmetry_equiv_pos_as_xyz 'x, y, z' '-x, -y, -z' _cell_length_a 12.371(3) _cell_length_b 13.676(3) _cell_length_c 27.386(7) _cell_angle_alpha 80.90(3) _cell_angle_beta 87.01(2) _cell_angle_gamma 88.29(2) _cell_volume 4568(2) _cell_formula_units_Z 3 _cell_measurement_temperature 295(2) _cell_measurement_reflns_used 247 _cell_measurement_theta_min 1.5 _cell_measurement_theta_max 29 _exptl_crystal_description block _exptl_crystal_colour white _exptl_crystal_size_max 0.4 _exptl_crystal_size_mid 0.3 _exptl_crystal_size_min 0.1 _exptl_crystal_density_meas ? _exptl_crystal_density_diffrn 1.357 _exptl_crystal_density_method 'not measured' _exptl_crystal_F_000 1930 _exptl_absorpt_coefficient_mu 0.850 _exptl_absorpt_correction_type ? _exptl_absorpt_correction_T_min ? _exptl_absorpt_correction_T_max ? _exptl_special_details ; ? ; _diffrn_ambient_temperature 295(2) _diffrn_radiation_wavelength 0.71073 _diffrn_radiation_type MoK\a _diffrn_radiation_source 'fine-focus sealed tube' _diffrn_radiation_monochromator graphite _diffrn_measurement_device_type Smart CCD