data_2 _audit_creation_method SHELXL-97 _chemical_name_systematic ; ? ; _chemical_name_common ? _chemical_melting_point ? _chemical_formula_moiety ? _chemical_formula_sum 'C32 H35 Eu2 N5 O18' _chemical_formula_weight 1081.57 loop_ _atom_type_symbol _atom_type_description _atom_type_scat_dispersion_real _atom_type_scat_dispersion_imag _atom_type_scat_source 'C' 'C' 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' 'H' 'H' 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' 'Eu' 'Eu' -0.1578 3.6682 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' 'N' 'N' 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' 'O' 'O' 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' _symmetry_cell_setting Triclinic _symmetry_space_group_name_H-M P-1 loop_ _symmetry_equiv_pos_as_xyz 'x, y, z' '-x, -y, -z' _cell_length_a 10.944(2) _cell_length_b 11.129(2) _cell_length_c 15.998(3) _cell_angle_alpha 75.57(3) _cell_angle_beta 82.96(3) _cell_angle_gamma 75.56(3) _cell_volume 1823.7(6) _cell_formula_units_Z 2 _cell_measurement_temperature 293(2) _cell_measurement_reflns_used 4997 _cell_measurement_theta_min 1.32 _cell_measurement_theta_max 25.01 _exptl_crystal_description 'block' _exptl_crystal_colour 'orange' _exptl_crystal_size_max 0.21 _exptl_crystal_size_mid 0.16 _exptl_crystal_size_min 0.12 _exptl_crystal_density_meas none _exptl_crystal_density_diffrn 1.970 _exptl_crystal_density_method 'not measured' _exptl_crystal_F_000 1064 _exptl_absorpt_coefficient_mu 3.495 _exptl_absorpt_correction_type multi-scan _exptl_absorpt_correction_T_min 0.516 _exptl_absorpt_correction_T_max 0.657 _exptl_absorpt_process_details SADABS _exptl_special_details ; ? ; _diffrn_ambient_temperature 293(2) _diffrn_radiation_wavelength 0.71073 _diffrn_radiation_type MoK\a _diffrn_radiation_source 'fine-focus sealed tube' _diffrn_radiation_monochromator graphite _diffrn_measurement_device_type 'Bruker Smart Apex CCD area detector' _diffrn_measurement_method ? _diffrn_detector_area_resol_mean ? _diffrn_standards_number ? _diffrn_standards_interval_count ? _diffrn_standards_interval_time ? _diffrn_standards_decay_% ? _diffrn_reflns_number 11019 _diffrn_reflns_av_R_equivalents 0.0458 _diffrn_reflns_av_sigmaI/netI 0.0796 _diffrn_reflns_limit_h_min -13 _diffrn_reflns_limit_h_max 11 _diffrn_reflns_limit_k_min -13 _diffrn_reflns_limit_k_max 11 _diffrn_reflns_limit_l_min -19 _diffrn_reflns_limit_l_max 18 _diffrn_reflns_theta_min 1.32 _diffrn_reflns_theta_max 25.01 _reflns_number_total 6308 _reflns_number_gt 4772 _reflns_threshold_expression >2sigma(I) _computing_data_collection 'SMART (Bruker, 2000)' _computing_cell_refinement 'SMART' _computing_data_reduction 'SAINT (Bruker, 2000)' _computing_structure_solution 'SHELXS-97 (Sheldrick, 1990)' _computing_structure_refinement 'SHELXL-97 (Sheldrick, 1997)' _computing_molecular_graphics 'SHELXTL' _computing_publication_material 'SHELXTL' _refine_special_details ; Refinement of F^2^ against ALL reflections. The weighted R-factor wR and goodness of fit S are based on F^2^, conventional R-factors R are based on F, with F set to zero for negative F^2^. The threshold expression of F^2^ > 2sigma(F^2^) is used only for calculating R-factors(gt) etc. and is not relevant to the choice of reflections for refinement. R-factors based on F^2^ are statistically about twice as large as those based on F, and R- factors based on ALL data will be even larger. ; _refine_ls_structure_factor_coef Fsqd _refine_ls_matrix_type full _refine_ls_weighting_scheme calc _refine_ls_weighting_details 'calc w=1/[\s^2^(Fo^2^)+(0.1500P)^2^+0.0000P] where P=(Fo^2^+2Fc^2^)/3' _atom_sites_solution_primary direct _atom_sites_solution_secondary difmap _atom_sites_solution_hydrogens geom _refine_ls_hydrogen_treatment mixed _refine_ls_extinction_method none _refine_ls_extinction_coef ? _refine_ls_number_reflns 6308 _refine_ls_number_parameters 526 _refine_ls_number_restraints 0 _refine_ls_R_factor_all 0.0766 _refine_ls_R_factor_gt 0.0638 _refine_ls_wR_factor_ref 0.2088 _refine_ls_wR_factor_gt 0.1941 _refine_ls_goodness_of_fit_ref 1.019 _refine_ls_restrained_S_all 1.019 _refine_ls_shift/su_max 0.000 _refine_ls_shift/su_mean 0.000 loop_ _atom_site_label _atom_site_type_symbol _atom_site_fract_x _atom_site_fract_y _atom_site_fract_z _atom_site_U_iso_or_equiv _atom_site_adp_type _atom_site_occupancy _atom_site_symmetry_multiplicity _atom_site_calc_flag _atom_site_refinement_flags _atom_site_disorder_assembly _atom_site_disorder_group O11 O 0.3596(7) 0.2866(8) 0.7270(5) 0.0162(17) Uani 1 1 d . . . O8 O 0.5739(7) 0.9960(7) 0.2435(5) 0.0138(17) Uani 1 1 d . . . O5 O -0.0205(7) 1.0737(7) 0.0845(4) 0.0102(16) Uani 1 1 d . . . O6 O 0.1475(7) 1.0697(7) -0.0077(5) 0.0129(16) Uani 1 1 d . . . C9 C 0.0935(10) 1.0746(10) 0.0652(7) 0.011(2) Uani 1 1 d . . . O12 O 0.2264(7) 0.2020(7) 0.8262(5) 0.0140(17) Uani 1 1 d . . . O7 O 0.5714(7) 1.0200(8) 0.1037(5) 0.0198(19) Uani 1 1 d . . . C16 C 0.5144(11) 1.0233(11) 0.1748(8) 0.017(3) Uani 1 1 d . . . C12 C 0.3740(10) 1.0625(11) 0.1831(7) 0.015(2) Uani 1 1 d . . . C11 C 0.3026(11) 1.0598(11) 0.1192(7) 0.014(2) Uani 1 1 d . . . H11 H 0.3408 1.0426 0.0670 0.017 Uiso 1 1 calc R . . C24 C 0.2772(10) 0.2909(11) 0.7874(7) 0.012(2) Uani 1 1 d . . . C20 C 0.2351(11) 0.4141(12) 0.8165(7) 0.018(3) Uani 1 1 d . . . C19 C 0.2777(10) 0.5219(11) 0.7724(7) 0.017(2) Uani 1 1 d . . . H19 H 0.3327 0.5184 0.7234 0.021 Uiso 1 1 calc R . . O4 O -0.3892(7) 1.1174(8) 0.5418(5) 0.0190(18) Uani 1 1 d . . . O3 O -0.3798(7) 1.1832(8) 0.6582(5) 0.0164(17) Uani 1 1 d . . . C8 C -0.3293(10) 1.1571(11) 0.5896(7) 0.016(2) Uani 1 1 d . . . C4 C -0.1959(10) 1.1629(11) 0.5637(7) 0.014(2) Uani 1 1 d . . . C5 C -0.1493(11) 1.1639(11) 0.4798(7) 0.016(2) Uani 1 1 d . . . H5 H -0.2029 1.1669 0.4381 0.019 Uiso 1 1 calc R . . Eu1 Eu 0.41255(5) 1.16000(5) 0.62672(3) 0.0098(2) Uani 1 1 d . . . Eu2 Eu 0.20768(4) 0.99481(5) 0.86643(3) 0.0088(2) Uani 1 1 d . . . O2 O 0.0683(7) 1.0952(8) 0.7493(5) 0.0177(18) Uani 1 1 d . . . O16 O 0.3617(7) 1.1944(7) 0.4756(4) 0.0137(16) Uani 1 1 d . . . H16A H 0.3751 1.1229 0.4619 0.021 Uiso 1 1 d R . . H16B H 0.2844 1.2321 0.4702 0.021 Uiso 1 1 d R . . O15 O 0.4171(8) 1.3751(8) 0.5546(5) 0.0203(18) Uani 1 1 d . . . H1B H 0.4402 1.3785 0.5015 0.030 Uiso 1 1 d R . . H1A H 0.3436 1.4225 0.5589 0.030 Uiso 1 1 d R . . O9 O 0.2448(8) 0.8472(8) 0.7843(5) 0.0200(18) Uani 1 1 d . . . N1 N 0.0198(9) 1.1544(10) 0.3698(6) 0.018(2) Uani 1 1 d . . . O14 O 0.4200(7) 0.9558(8) 0.5984(5) 0.0179(18) Uani 1 1 d . . . H1C H 0.4338 0.8985 0.6447 0.027 Uiso 1 1 d R . . H1D H 0.3498 0.9569 0.5803 0.027 Uiso 1 1 d R . . O10 O 0.3579(9) 0.7460(8) 0.6899(6) 0.027(2) Uani 1 1 d . . . C17 C 0.2853(11) 0.7476(11) 0.7553(7) 0.013(2) Uani 1 1 d . . . O13 O 0.2791(8) 0.8048(8) 0.9722(5) 0.025(2) Uani 1 1 d . . . N2 N 0.1364(8) 1.1390(10) 0.3558(6) 0.019(2) Uani 1 1 d . . . C23 C 0.1563(12) 0.6378(12) 0.8734(7) 0.021(3) Uani 1 1 d . . . H23 H 0.1302 0.7123 0.8936 0.025 Uiso 1 1 calc R . . C18 C 0.2404(10) 0.6320(11) 0.7998(7) 0.017(2) Uani 1 1 d . . . C2 C 0.0103(10) 1.1553(11) 0.6038(7) 0.014(2) Uani 1 1 d . . . O1 O 0.2034(7) 1.1661(9) 0.6468(5) 0.0191(19) Uani 1 1 d . . . C14 C 0.1828(10) 1.1219(12) 0.2713(7) 0.019(3) Uani 1 1 d . . . N3 N 0.0268(12) 0.5454(11) 0.9855(8) 0.033(3) Uani 1 1 d . . . C15 C 0.1135(11) 1.1107(12) 0.2084(7) 0.017(2) Uani 1 1 d . . . H15 H 0.0262 1.1222 0.2176 0.020 Uiso 1 1 calc R . . C7 C 0.0596(10) 1.1580(11) 0.5211(7) 0.015(2) Uani 1 1 d . . . H7 H 0.1445 1.1583 0.5064 0.018 Uiso 1 1 calc R . . C1 C 0.1002(10) 1.1389(11) 0.6727(7) 0.015(2) Uani 1 1 d . . . C3 C -0.1175(11) 1.1594(11) 0.6248(7) 0.017(2) Uani 1 1 d . . . H3 H -0.1501 1.1597 0.6813 0.020 Uiso 1 1 calc R . . C21 C 0.1537(11) 0.4168(11) 0.8879(7) 0.018(2) Uani 1 1 d . . . H21 H 0.1259 0.3444 0.9177 0.022 Uiso 1 1 calc R . . C6 C -0.0224(10) 1.1603(11) 0.4576(7) 0.014(2) Uani 1 1 d . . . C10 C 0.1704(10) 1.0836(11) 0.1344(7) 0.016(2) Uani 1 1 d . . . C13 C 0.3145(10) 1.0960(11) 0.2599(7) 0.017(2) Uani 1 1 d . . . H13 H 0.3625 1.1007 0.3026 0.020 Uiso 1 1 calc R . . C22 C 0.1135(12) 0.5293(12) 0.9151(8) 0.025(3) Uani 1 1 d . . . C25 C 0.1471(16) 0.7619(17) 1.1059(11) 0.050(4) Uani 1 1 d . . . H25A H 0.0958 0.8471 1.0972 0.075 Uiso 1 1 calc R . . H25B H 0.1601 0.7287 1.1664 0.075 Uiso 1 1 calc R . . H25C H 0.1052 0.7091 1.0859 0.075 Uiso 1 1 calc R . . N4 N 0.3751(14) 0.7203(14) 1.0990(9) 0.050(4) Uani 1 1 d . . . C26 C 0.2724(17) 0.7633(17) 1.0562(11) 0.050(4) Uani 1 1 d . . . C28 C 0.4991(16) 0.7296(17) 1.0497(11) 0.050(4) Uani 1 1 d . . . H28A H 0.5122 0.6824 1.0054 0.075 Uiso 1 1 calc R . . H28B H 0.5661 0.6950 1.0884 0.075 Uiso 1 1 calc R . . H28C H 0.4985 0.8173 1.0237 0.075 Uiso 1 1 calc R . . C27 C 0.3694(16) 0.7008(17) 1.1882(10) 0.050(4) Uani 1 1 d . . . H27A H 0.3316 0.7799 1.2046 0.075 Uiso 1 1 calc R . . H27B H 0.4533 0.6693 1.2080 0.075 Uiso 1 1 calc R . . H27C H 0.3193 0.6397 1.2138 0.075 Uiso 1 1 calc R . . C30 C 0.2221(17) 1.4194(17) 0.2731(11) 0.050(4) Uani 1 1 d . . . O17 O 0.2619(11) 1.4114(11) 0.3527(7) 0.050(3) Uani 1 1 d . . . C29 C 0.0756(16) 1.4557(17) 0.2810(11) 0.050(4) Uani 1 1 d . . . H29A H 0.0448 1.3912 0.3242 0.075 Uiso 1 1 calc R . . H29B H 0.0437 1.4623 0.2264 0.075 Uiso 1 1 calc R . . H29C H 0.0476 1.5360 0.2973 0.075 Uiso 1 1 calc R . . N5 N 0.2814(14) 1.4101(14) 0.1956(9) 0.050(4) Uani 1 1 d . . . C32 C 0.4157(16) 1.3757(17) 0.1842(11) 0.050(4) Uani 1 1 d . . . H32A H 0.4510 1.4370 0.2001 0.075 Uiso 1 1 calc R . . H32B H 0.4402 1.3741 0.1247 0.075 Uiso 1 1 calc R . . H32C H 0.4464 1.2929 0.2201 0.075 Uiso 1 1 calc R . . C31 C 0.2202(16) 1.4242(17) 0.1178(10) 0.050(4) Uani 1 1 d . . . H31A H 0.1712 1.3610 0.1267 0.075 Uiso 1 1 calc R . . H31B H 0.2830 1.4133 0.0712 0.075 Uiso 1 1 calc R . . H31C H 0.1656 1.5076 0.1037 0.075 Uiso 1 1 calc R . . O18 O 0.4953(12) 1.4393(12) 0.3877(8) 0.050(3) Uani 1 1 d G . . H18A H 0.5408 1.3818 0.3636 0.075 Uiso 1 1 d G . . H18B H 0.4241 1.4308 0.3770 0.075 Uiso 1 1 d G . . loop_ _atom_site_aniso_label _atom_site_aniso_U_11 _atom_site_aniso_U_22 _atom_site_aniso_U_33 _atom_site_aniso_U_23 _atom_site_aniso_U_13 _atom_site_aniso_U_12 O11 0.020(4) 0.016(4) 0.016(4) -0.009(3) 0.010(3) -0.010(3) O8 0.013(4) 0.018(4) 0.013(4) -0.002(3) -0.004(3) -0.006(3) O5 0.008(4) 0.018(4) 0.007(4) -0.003(3) 0.002(3) -0.009(3) O6 0.012(4) 0.015(4) 0.013(4) -0.008(3) 0.005(3) -0.006(3) C9 0.015(6) 0.011(6) 0.012(5) -0.005(4) 0.001(5) -0.008(4) O12 0.017(4) 0.015(4) 0.011(4) -0.005(3) 0.004(3) -0.007(3) O7 0.014(4) 0.032(5) 0.012(4) -0.002(4) 0.002(3) -0.008(3) C16 0.010(6) 0.012(6) 0.032(7) -0.009(5) 0.004(5) -0.006(4) C12 0.006(5) 0.020(7) 0.018(6) -0.001(5) 0.005(4) -0.008(4) C11 0.023(6) 0.015(6) 0.006(5) -0.003(4) 0.002(4) -0.007(5) C24 0.011(5) 0.019(6) 0.009(5) -0.007(4) 0.000(4) -0.003(4) C20 0.018(6) 0.023(7) 0.010(5) 0.000(5) 0.003(5) -0.007(5) C19 0.014(6) 0.025(7) 0.018(6) -0.013(5) 0.006(5) -0.009(5) O4 0.012(4) 0.035(5) 0.014(4) -0.014(4) 0.002(3) -0.007(3) O3 0.012(4) 0.026(5) 0.015(4) -0.010(3) 0.004(3) -0.009(3) C8 0.011(6) 0.018(6) 0.021(6) -0.004(5) 0.003(5) -0.011(5) C4 0.005(5) 0.017(6) 0.022(6) -0.009(5) 0.002(4) -0.001(4) C5 0.017(6) 0.021(7) 0.013(5) -0.008(5) -0.008(5) -0.003(5) Eu1 0.0060(3) 0.0154(4) 0.0096(3) -0.0053(2) 0.0031(2) -0.0047(2) Eu2 0.0066(3) 0.0122(3) 0.0088(3) -0.0033(2) 0.0017(2) -0.0043(2) O2 0.012(4) 0.029(5) 0.012(4) -0.005(3) 0.005(3) -0.008(3) O16 0.011(4) 0.017(4) 0.014(4) -0.004(3) -0.007(3) -0.002(3) O15 0.032(5) 0.015(5) 0.018(4) -0.009(3) 0.004(4) -0.010(3) O9 0.021(4) 0.022(5) 0.019(4) -0.007(4) 0.007(3) -0.010(4) N1 0.015(5) 0.027(6) 0.015(5) -0.007(4) 0.003(4) -0.012(4) O14 0.013(4) 0.029(5) 0.015(4) -0.005(4) 0.001(3) -0.012(3) O10 0.037(5) 0.012(5) 0.032(5) -0.013(4) 0.025(4) -0.013(4) C17 0.020(6) 0.010(6) 0.016(6) -0.008(4) 0.001(5) -0.009(4) O13 0.031(5) 0.017(5) 0.020(4) 0.011(4) -0.006(4) -0.005(4) N2 0.009(5) 0.033(6) 0.016(5) -0.009(4) -0.001(4) -0.004(4) C23 0.028(7) 0.015(7) 0.017(6) -0.003(5) 0.006(5) -0.005(5) C18 0.014(6) 0.013(6) 0.020(6) -0.003(5) 0.012(5) -0.006(4) C2 0.011(5) 0.022(7) 0.015(5) -0.010(5) -0.002(4) -0.010(4) O1 0.007(4) 0.041(6) 0.018(4) -0.018(4) 0.001(3) -0.009(3) C14 0.004(5) 0.034(8) 0.017(6) -0.007(5) 0.005(4) -0.006(5) N3 0.040(7) 0.019(6) 0.042(7) -0.017(5) 0.030(5) -0.018(5) C15 0.014(6) 0.023(7) 0.014(6) -0.003(5) 0.002(5) -0.009(5) C7 0.011(5) 0.017(6) 0.016(6) -0.003(5) 0.001(4) -0.003(4) C1 0.011(6) 0.013(6) 0.018(6) -0.004(5) 0.002(5) 0.001(4) C3 0.014(6) 0.020(7) 0.017(6) -0.007(5) 0.003(5) -0.002(4) C21 0.028(7) 0.011(6) 0.016(6) -0.006(5) 0.011(5) -0.010(5) C6 0.015(6) 0.018(6) 0.012(5) -0.007(4) 0.002(4) -0.009(4) C10 0.013(6) 0.012(6) 0.024(6) -0.002(5) 0.000(5) -0.008(4) C13 0.015(6) 0.023(7) 0.012(5) -0.003(5) -0.002(5) -0.002(5) C22 0.030(7) 0.016(7) 0.029(7) -0.012(6) 0.020(6) -0.010(5) C25 0.050(10) 0.050(11) 0.050(10) -0.011(8) -0.003(8) -0.011(8) N4 0.050(9) 0.050(9) 0.050(8) -0.011(7) -0.003(7) -0.011(7) C26 0.050(11) 0.050(11) 0.050(10) -0.011(8) -0.003(8) -0.011(8) C28 0.050(10) 0.050(11) 0.050(10) -0.011(8) -0.003(8) -0.011(8) C27 0.050(10) 0.050(11) 0.050(10) -0.011(8) -0.003(8) -0.011(8) C30 0.050(10) 0.050(12) 0.050(10) -0.011(8) -0.003(9) -0.011(8) O17 0.050(7) 0.050(8) 0.050(7) -0.011(6) -0.003(6) -0.011(6) C29 0.050(11) 0.050(11) 0.050(10) -0.011(8) -0.003(8) -0.011(8) N5 0.050(9) 0.050(10) 0.050(8) -0.011(7) -0.003(7) -0.011(7) C32 0.050(10) 0.050(12) 0.050(10) -0.011(8) -0.003(8) -0.011(8) C31 0.050(10) 0.050(12) 0.050(10) -0.011(8) -0.003(8) -0.011(8) O18 0.050(7) 0.050(8) 0.050(7) -0.011(6) -0.003(6) -0.011(6) _geom_special_details ; All esds (except the esd in the dihedral angle between two l.s. planes) are estimated using the full covariance matrix. The cell esds are taken into account individually in the estimation of esds in distances, angles and torsion angles; correlations between esds in cell parameters are only used when they are defined by crystal symmetry. An approximate (isotropic) treatment of cell esds is used for estimating esds involving l.s. planes. ; loop_ _geom_bond_atom_site_label_1 _geom_bond_atom_site_label_2 _geom_bond_distance _geom_bond_site_symmetry_2 _geom_bond_publ_flag O11 C24 1.240(13) . ? O11 Eu1 2.321(8) 1_545 ? O8 C16 1.278(14) . ? O8 Eu1 2.345(7) 2_676 ? O8 Eu2 2.796(8) 2_676 ? O5 C9 1.250(13) . ? O5 Eu2 2.341(7) 2_576 ? O6 C9 1.248(13) . ? O6 Eu2 2.327(7) 1_554 ? C9 C10 1.507(15) . ? O12 C24 1.248(14) . ? O12 Eu2 2.288(8) 1_545 ? O7 C16 1.233(15) . ? O7 Eu2 2.479(8) 2_676 ? C16 C12 1.488(15) . ? C16 Eu2 2.999(11) 2_676 ? C12 C11 1.369(16) . ? C12 C13 1.408(16) . ? C11 C10 1.406(16) . ? C24 C20 1.503(16) . ? C20 C21 1.362(16) . ? C20 C19 1.389(16) . ? C19 C18 1.354(17) . ? O4 C8 1.282(14) . ? O4 Eu1 2.421(8) 1_455 ? O3 C8 1.235(14) . ? O3 Eu1 2.474(7) 1_455 ? C8 C4 1.480(15) . ? C8 Eu1 2.809(11) 1_455 ? C4 C3 1.365(16) . ? C4 C5 1.375(16) . ? C5 C6 1.385(16) . ? Eu1 O1 2.258(8) . ? Eu1 O11 2.321(8) 1_565 ? Eu1 O8 2.345(7) 2_676 ? Eu1 O15 2.394(8) . ? Eu1 O14 2.405(8) . ? Eu1 O4 2.421(8) 1_655 ? Eu1 O16 2.463(7) . ? Eu1 O3 2.474(7) 1_655 ? Eu1 C8 2.809(11) 1_655 ? Eu1 Eu2 4.4211(16) . ? Eu2 O9 2.280(8) . ? Eu2 O12 2.288(8) 1_565 ? Eu2 O6 2.327(7) 1_556 ? Eu2 O5 2.341(7) 2_576 ? Eu2 O13 2.380(8) . ? Eu2 O2 2.428(8) . ? Eu2 O7 2.479(8) 2_676 ? Eu2 O8 2.796(8) 2_676 ? Eu2 C16 2.999(11) 2_676 ? O2 C1 1.241(13) . ? O9 C17 1.265(14) . ? N1 N2 1.243(13) . ? N1 C6 1.436(14) . ? O10 C17 1.234(14) . ? C17 C18 1.476(15) . ? O13 C26 1.306(18) . ? N2 C14 1.426(15) . ? C23 C22 1.389(17) . ? C23 C18 1.407(16) . ? C2 C7 1.362(15) . ? C2 C3 1.391(15) . ? C2 C1 1.515(15) . ? O1 C1 1.238(14) . ? C14 C15 1.378(16) . ? C14 C13 1.396(15) . ? N3 N3 1.26(2) 2_567 ? N3 C22 1.397(16) . ? C15 C10 1.336(16) . ? C7 C6 1.427(15) . ? C21 C22 1.378(17) . ? C25 C26 1.50(2) . ? N4 C26 1.31(2) . ? N4 C27 1.38(2) . ? N4 C28 1.50(2) . ? C30 N5 1.34(2) . ? C30 O17 1.37(2) . ? C30 C29 1.55(2) . ? N5 C32 1.42(2) . ? N5 C31 1.44(2) . ? loop_ _geom_angle_atom_site_label_1 _geom_angle_atom_site_label_2 _geom_angle_atom_site_label_3 _geom_angle _geom_angle_site_symmetry_1 _geom_angle_site_symmetry_3 _geom_angle_publ_flag C24 O11 Eu1 132.0(7) . 1_545 ? C16 O8 Eu1 136.2(7) . 2_676 ? C16 O8 Eu2 86.4(6) . 2_676 ? Eu1 O8 Eu2 118.4(3) 2_676 2_676 ? C9 O5 Eu2 162.5(7) . 2_576 ? C9 O6 Eu2 157.3(7) . 1_554 ? O6 C9 O5 124.4(10) . . ? O6 C9 C10 117.9(10) . . ? O5 C9 C10 117.6(9) . . ? C24 O12 Eu2 155.1(7) . 1_545 ? C16 O7 Eu2 102.6(7) . 2_676 ? O7 C16 O8 121.2(10) . . ? O7 C16 C12 120.9(11) . . ? O8 C16 C12 117.9(11) . . ? O7 C16 Eu2 53.8(6) . 2_676 ? O8 C16 Eu2 68.5(6) . 2_676 ? C12 C16 Eu2 166.8(8) . 2_676 ? C11 C12 C13 120.1(10) . . ? C11 C12 C16 120.9(11) . . ? C13 C12 C16 118.9(10) . . ? C12 C11 C10 118.6(10) . . ? O11 C24 O12 125.8(11) . . ? O11 C24 C20 116.9(10) . . ? O12 C24 C20 117.2(9) . . ? C21 C20 C19 120.8(11) . . ? C21 C20 C24 117.7(10) . . ? C19 C20 C24 121.5(10) . . ? C18 C19 C20 120.9(11) . . ? C8 O4 Eu1 93.6(7) . 1_455 ? C8 O3 Eu1 92.3(6) . 1_455 ? O3 C8 O4 120.5(10) . . ? O3 C8 C4 120.7(10) . . ? O4 C8 C4 118.7(10) . . ? O3 C8 Eu1 61.6(6) . 1_455 ? O4 C8 Eu1 59.3(5) . 1_455 ? C4 C8 Eu1 175.6(8) . 1_455 ? C3 C4 C5 120.2(10) . . ? C3 C4 C8 119.5(10) . . ? C5 C4 C8 120.2(10) . . ? C4 C5 C6 119.8(10) . . ? O1 Eu1 O11 81.3(3) . 1_565 ? O1 Eu1 O8 84.3(3) . 2_676 ? O11 Eu1 O8 79.2(3) 1_565 2_676 ? O1 Eu1 O15 102.7(3) . . ? O11 Eu1 O15 71.0(3) 1_565 . ? O8 Eu1 O15 147.7(3) 2_676 . ? O1 Eu1 O14 82.1(3) . . ? O11 Eu1 O14 146.2(3) 1_565 . ? O8 Eu1 O14 70.0(3) 2_676 . ? O15 Eu1 O14 141.7(3) . . ? O1 Eu1 O4 149.7(3) . 1_655 ? O11 Eu1 O4 127.4(3) 1_565 1_655 ? O8 Eu1 O4 108.1(3) 2_676 1_655 ? O15 Eu1 O4 81.7(3) . 1_655 ? O14 Eu1 O4 76.9(3) . 1_655 ? O1 Eu1 O16 80.2(3) . . ? O11 Eu1 O16 133.1(3) 1_565 . ? O8 Eu1 O16 140.5(3) 2_676 . ? O15 Eu1 O16 71.6(3) . . ? O14 Eu1 O16 71.9(3) . . ? O4 Eu1 O16 72.7(2) 1_655 . ? O1 Eu1 O3 157.3(3) . 1_655 ? O11 Eu1 O3 76.8(3) 1_565 1_655 ? O8 Eu1 O3 85.4(3) 2_676 1_655 ? O15 Eu1 O3 76.2(3) . 1_655 ? O14 Eu1 O3 113.2(3) . 1_655 ? O4 Eu1 O3 53.0(3) 1_655 1_655 ? O16 Eu1 O3 119.7(2) . 1_655 ? O1 Eu1 C8 176.1(3) . 1_655 ? O11 Eu1 C8 101.1(3) 1_565 1_655 ? O8 Eu1 C8 99.0(3) 2_676 1_655 ? O15 Eu1 C8 75.5(3) . 1_655 ? O14 Eu1 C8 97.2(3) . 1_655 ? O4 Eu1 C8 27.1(3) 1_655 1_655 ? O16 Eu1 C8 95.9(3) . 1_655 ? O3 Eu1 C8 26.1(3) 1_655 1_655 ? O1 Eu1 Eu2 53.0(2) . . ? O11 Eu1 Eu2 65.62(19) 1_565 . ? O8 Eu1 Eu2 33.81(18) 2_676 . ? O15 Eu1 Eu2 132.4(2) . . ? O14 Eu1 Eu2 80.87(18) . . ? O4 Eu1 Eu2 141.4(2) 1_655 . ? O16 Eu1 Eu2 128.71(17) . . ? O3 Eu1 Eu2 110.78(18) 1_655 . ? C8 Eu1 Eu2 130.7(2) 1_655 . ? O9 Eu2 O12 128.8(3) . 1_565 ? O9 Eu2 O6 155.1(3) . 1_556 ? O12 Eu2 O6 76.1(3) 1_565 1_556 ? O9 Eu2 O5 85.2(3) . 2_576 ? O12 Eu2 O5 125.9(3) 1_565 2_576 ? O6 Eu2 O5 77.2(3) 1_556 2_576 ? O9 Eu2 O13 79.5(3) . . ? O12 Eu2 O13 140.0(3) 1_565 . ? O6 Eu2 O13 79.7(3) 1_556 . ? O5 Eu2 O13 77.7(3) 2_576 . ? O9 Eu2 O2 76.4(3) . . ? O12 Eu2 O2 74.7(3) 1_565 . ? O6 Eu2 O2 115.0(3) 1_556 . ? O5 Eu2 O2 75.5(3) 2_576 . ? O13 Eu2 O2 145.2(3) . . ? O9 Eu2 O7 99.1(3) . 2_676 ? O12 Eu2 O7 76.6(3) 1_565 2_676 ? O6 Eu2 O7 86.7(3) 1_556 2_676 ? O5 Eu2 O7 146.5(2) 2_576 2_676 ? O13 Eu2 O7 70.5(3) . 2_676 ? O2 Eu2 O7 137.9(3) . 2_676 ? O9 Eu2 O8 68.3(3) . 2_676 ? O12 Eu2 O8 72.0(3) 1_565 2_676 ? O6 Eu2 O8 129.4(2) 1_556 2_676 ? O5 Eu2 O8 153.1(2) 2_576 2_676 ? O13 Eu2 O8 101.0(3) . 2_676 ? O2 Eu2 O8 93.1(2) . 2_676 ? O7 Eu2 O8 48.5(2) 2_676 2_676 ? O9 Eu2 C16 81.8(3) . 2_676 ? O12 Eu2 C16 75.5(3) 1_565 2_676 ? O6 Eu2 C16 109.0(3) 1_556 2_676 ? O5 Eu2 C16 158.4(3) 2_576 2_676 ? O13 Eu2 C16 83.0(3) . 2_676 ? O2 Eu2 C16 117.5(3) . 2_676 ? O7 Eu2 C16 23.7(3) 2_676 2_676 ? O8 Eu2 C16 25.2(3) 2_676 2_676 ? O9 Eu2 Eu1 75.0(2) . . ? O12 Eu2 Eu1 55.18(19) 1_565 . ? O6 Eu2 Eu1 129.27(19) 1_556 . ? O5 Eu2 Eu1 141.52(17) 2_576 . ? O13 Eu2 Eu1 128.5(2) . . ? O2 Eu2 Eu1 67.98(18) . . ? O7 Eu2 Eu1 70.42(18) 2_676 . ? O8 Eu2 Eu1 27.82(15) 2_676 . ? C16 Eu2 Eu1 49.9(2) 2_676 . ? C1 O2 Eu2 126.7(7) . . ? C17 O9 Eu2 164.1(8) . . ? N2 N1 C6 113.3(9) . . ? O10 C17 O9 121.9(10) . . ? O10 C17 C18 119.6(10) . . ? O9 C17 C18 118.4(10) . . ? C26 O13 Eu2 139.1(10) . . ? N1 N2 C14 114.8(9) . . ? C22 C23 C18 118.1(11) . . ? C19 C18 C23 119.7(11) . . ? C19 C18 C17 122.3(10) . . ? C23 C18 C17 118.1(11) . . ? C7 C2 C3 120.7(10) . . ? C7 C2 C1 118.1(10) . . ? C3 C2 C1 121.1(10) . . ? C1 O1 Eu1 163.0(8) . . ? C15 C14 C13 119.5(11) . . ? C15 C14 N2 126.6(10) . . ? C13 C14 N2 113.2(10) . . ? N3 N3 C22 114.1(14) 2_567 . ? C10 C15 C14 120.7(11) . . ? C2 C7 C6 118.2(10) . . ? O1 C1 O2 125.0(10) . . ? O1 C1 C2 116.1(10) . . ? O2 C1 C2 118.8(10) . . ? C4 C3 C2 120.9(11) . . ? C20 C21 C22 118.5(11) . . ? C5 C6 C7 120.2(10) . . ? C5 C6 N1 116.1(9) . . ? C7 C6 N1 123.6(10) . . ? C15 C10 C11 121.7(10) . . ? C15 C10 C9 120.3(10) . . ? C11 C10 C9 118.0(10) . . ? C14 C13 C12 119.3(11) . . ? C21 C22 C23 122.0(11) . . ? C21 C22 N3 123.9(11) . . ? C23 C22 N3 114.1(11) . . ? C26 N4 C27 121.3(16) . . ? C26 N4 C28 117.9(14) . . ? C27 N4 C28 118.4(14) . . ? O13 C26 N4 120.8(16) . . ? O13 C26 C25 120.8(14) . . ? N4 C26 C25 118.3(15) . . ? N5 C30 O17 134.2(16) . . ? N5 C30 C29 118.9(16) . . ? O17 C30 C29 106.7(14) . . ? C30 N5 C32 121.7(15) . . ? C30 N5 C31 125.4(15) . . ? C32 N5 C31 112.8(14) . . ? _diffrn_measured_fraction_theta_max 0.981 _diffrn_reflns_theta_full 25.01 _diffrn_measured_fraction_theta_full 0.981 _refine_diff_density_max 3.373 _refine_diff_density_min -2.999 _refine_diff_density_rms 0.302