data_nol118m _audit_creation_method SHELXL-97 _chemical_name_systematic ; ? ; _chemical_name_common ? _chemical_melting_point ? _chemical_formula_moiety ? _chemical_formula_sum 'C22 H38 Cl N4 Rh' _chemical_formula_weight 496.92 loop_ _atom_type_symbol _atom_type_description _atom_type_scat_dispersion_real _atom_type_scat_dispersion_imag _atom_type_scat_source 'C' 'C' 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' 'H' 'H' 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' 'N' 'N' 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' 'Cl' 'Cl' 0.1484 0.1585 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' 'Rh' 'Rh' -1.1178 0.9187 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' _symmetry_cell_setting Triclinic _symmetry_space_group_name_H-M P-1 loop_ _symmetry_equiv_pos_as_xyz 'x, y, z' '-x, -y, -z' _cell_length_a 9.0969(4) _cell_length_b 10.1843(5) _cell_length_c 14.2497(7) _cell_angle_alpha 93.0260(10) _cell_angle_beta 98.2820(10) _cell_angle_gamma 110.9590(10) _cell_volume 1212.17(10) _cell_formula_units_Z 2 _cell_measurement_temperature 150(2) _cell_measurement_reflns_used 13569 _cell_measurement_theta_min 2.155 _cell_measurement_theta_max 28.853 _exptl_crystal_description needle _exptl_crystal_colour red _exptl_crystal_size_max 0.3 _exptl_crystal_size_mid 0.4 _exptl_crystal_size_min 0.5 _exptl_crystal_density_meas ? _exptl_crystal_density_diffrn 1.361 _exptl_crystal_density_method 'not measured' _exptl_crystal_F_000 520 _exptl_absorpt_coefficient_mu 0.829 _exptl_absorpt_correction_type empirical _exptl_absorpt_correction_T_min 0.626178 _exptl_absorpt_correction_T_max 0.745775 _exptl_absorpt_process_details ? _exptl_special_details ; ? ; _diffrn_ambient_temperature 150(2) _diffrn_radiation_wavelength 0.71073 _diffrn_radiation_type MoK\a _diffrn_radiation_source 'fine-focus sealed tube' _diffrn_radiation_monochromator graphite _diffrn_measurement_device_type 'CCD area detector' _diffrn_measurement_method 'phi and omega scans' _diffrn_detector_area_resol_mean ? _diffrn_standards_number ? _diffrn_standards_interval_count ? _diffrn_standards_interval_time ? _diffrn_standards_decay_% ? _diffrn_reflns_number 14860 _diffrn_reflns_av_R_equivalents 0.0160 _diffrn_reflns_av_sigmaI/netI 0.0162 _diffrn_reflns_limit_h_min -11 _diffrn_reflns_limit_h_max 12 _diffrn_reflns_limit_k_min -13 _diffrn_reflns_limit_k_max 13 _diffrn_reflns_limit_l_min -18 _diffrn_reflns_limit_l_max 19 _diffrn_reflns_theta_min 2.16 _diffrn_reflns_theta_max 28.85 _reflns_number_total 5824 _reflns_number_gt 5517 _reflns_threshold_expression >2sigma(I) _computing_data_collection 'Bruker SMART' _computing_cell_refinement 'Bruker SMART' _computing_data_reduction 'Bruker SHELXTL' _computing_structure_solution 'SHELXS-97 (Sheldrick, 1990)' _computing_structure_refinement 'SHELXL-97 (Sheldrick, 1997)' _computing_molecular_graphics 'Bruker SHELXTL' _computing_publication_material 'Bruker SHELXTL' _refine_special_details ; Refinement of F^2^ against ALL reflections. The weighted R-factor wR and goodness of fit S are based on F^2^, conventional R-factors R are based on F, with F set to zero for negative F^2^. The threshold expression of F^2^ > 2sigma(F^2^) is used only for calculating R-factors(gt) etc. and is not relevant to the choice of reflections for refinement. R-factors based on F^2^ are statistically about twice as large as those based on F, and R- factors based on ALL data will be even larger. ; _refine_ls_structure_factor_coef Fsqd _refine_ls_matrix_type full _refine_ls_weighting_scheme calc _refine_ls_weighting_details 'calc w=1/[\s^2^(Fo^2^)+(0.0194P)^2^+0.6479P] where P=(Fo^2^+2Fc^2^)/3' _atom_sites_solution_primary direct _atom_sites_solution_secondary difmap _atom_sites_solution_hydrogens geom _refine_ls_hydrogen_treatment mixed _refine_ls_extinction_method SHELXL _refine_ls_extinction_coef 0.0132(5) _refine_ls_extinction_expression 'Fc^*^=kFc[1+0.001xFc^2^\l^3^/sin(2\q)]^-1/4^' _refine_ls_number_reflns 5824 _refine_ls_number_parameters 406 _refine_ls_number_restraints 245 _refine_ls_R_factor_all 0.0218 _refine_ls_R_factor_gt 0.0201 _refine_ls_wR_factor_ref 0.0466 _refine_ls_wR_factor_gt 0.0459 _refine_ls_goodness_of_fit_ref 1.057 _refine_ls_restrained_S_all 1.036 _refine_ls_shift/su_max 0.003 _refine_ls_shift/su_mean 0.000 loop_ _atom_site_label _atom_site_type_symbol _atom_site_fract_x _atom_site_fract_y _atom_site_fract_z _atom_site_U_iso_or_equiv _atom_site_adp_type _atom_site_occupancy _atom_site_symmetry_multiplicity _atom_site_calc_flag _atom_site_refinement_flags _atom_site_disorder_assembly _atom_site_disorder_group Rh1 Rh 0.358846(12) 0.147149(11) 0.272512(7) 0.01722(4) Uani 1 1 d U . . Cl1 Cl 0.52039(4) -0.00880(4) 0.27217(2) 0.02451(7) Uani 1 1 d U . . C1 C 0.55144(16) 0.31141(14) 0.33943(10) 0.0199(3) Uani 1 1 d U . . N1 N 0.61759(14) 0.41693(13) 0.28639(8) 0.0227(2) Uani 1 1 d U . . N2 N 0.63729(14) 0.35790(12) 0.42937(8) 0.0221(2) Uani 1 1 d U . . C2 C 0.74505(19) 0.52715(16) 0.34075(12) 0.0303(3) Uani 1 1 d U . . H2 H 0.803(2) 0.608(2) 0.3134(14) 0.037(5) Uiso 1 1 d . . . N3 N 0.01147(13) 0.04233(12) 0.22628(8) 0.0206(2) Uani 1 1 d U . . C3 C 0.75773(19) 0.48993(16) 0.43016(12) 0.0297(3) Uani 1 1 d U . . H3 H 0.828(2) 0.537(2) 0.4839(14) 0.032(5) Uiso 1 1 d . . . N4 N 0.05448(14) -0.10711(12) 0.13172(8) 0.0209(2) Uani 1 1 d U . . C4 C 0.55026(17) 0.40430(15) 0.18401(10) 0.0220(3) Uani 1 1 d U . . C5 C 0.41542(19) 0.25581(16) 0.15899(10) 0.0259(3) Uani 1 1 d U . . H5A H 0.323(2) 0.266(2) 0.1236(14) 0.039(5) Uiso 1 1 d . . . H5B H 0.454(2) 0.195(2) 0.1225(14) 0.036(5) Uiso 1 1 d . . . C6 C 0.4873(2) 0.52353(19) 0.16743(13) 0.0341(4) Uani 1 1 d U . . H6A H 0.447(3) 0.518(2) 0.1005(16) 0.045(6) Uiso 1 1 d . . . H6B H 0.569(3) 0.615(2) 0.1848(15) 0.041(5) Uiso 1 1 d . . . H6C H 0.400(3) 0.517(2) 0.2039(15) 0.045(6) Uiso 1 1 d . . . C7 C 0.6828(2) 0.4171(2) 0.12619(13) 0.0335(3) Uani 1 1 d U . . H7A H 0.641(2) 0.408(2) 0.0584(16) 0.043(6) Uiso 1 1 d . . . H7B H 0.720(2) 0.349(2) 0.1384(15) 0.041(6) Uiso 1 1 d . . . H7C H 0.773(3) 0.510(2) 0.1426(16) 0.051(6) Uiso 1 1 d . . . C8 C 0.61750(17) 0.27681(14) 0.51401(10) 0.0218(3) Uani 1 1 d U . . C9 C 0.45195(19) 0.16014(17) 0.49645(11) 0.0268(3) Uani 1 1 d U . . H9A H 0.372(2) 0.204(2) 0.4878(14) 0.037(5) Uiso 1 1 d . . . H9B H 0.441(2) 0.111(2) 0.5506(14) 0.036(5) Uiso 1 1 d . . . H9C H 0.436(2) 0.094(2) 0.4420(15) 0.037(5) Uiso 1 1 d . . . C10 C 0.6315(2) 0.37624(18) 0.60217(12) 0.0328(3) Uani 1 1 d U . . H10A H 0.557(2) 0.425(2) 0.5913(15) 0.042(5) Uiso 1 1 d . . . H10C H 0.741(3) 0.447(2) 0.6211(15) 0.044(6) Uiso 1 1 d . . . H10A H 0.608(3) 0.318(2) 0.6545(16) 0.047(6) Uiso 1 1 d . . . C11 C 0.7491(2) 0.21570(18) 0.52876(13) 0.0304(3) Uani 1 1 d U . . H11A H 0.742(2) 0.166(2) 0.5856(14) 0.038(5) Uiso 1 1 d . . . H11B H 0.856(3) 0.293(2) 0.5385(14) 0.040(5) Uiso 1 1 d . . . H11C H 0.740(2) 0.149(2) 0.4742(15) 0.039(5) Uiso 1 1 d . . . C12 C 0.13313(16) 0.00799(14) 0.19933(9) 0.0194(2) Uani 1 1 d U . . C13 C -0.13734(17) -0.04943(17) 0.18106(11) 0.0269(3) Uani 1 1 d U . . H13 H -0.232(2) -0.0437(19) 0.1934(13) 0.031(5) Uiso 1 1 d . . . C14 C -0.11070(17) -0.14254(17) 0.12141(11) 0.0267(3) Uani 1 1 d U . . H14 H -0.182(2) -0.217(2) 0.0775(13) 0.031(5) Uiso 1 1 d . . . C15 C 0.04734(16) 0.15884(14) 0.30324(10) 0.0209(3) Uani 1 1 d U . . C16 C 0.21957(17) 0.25790(15) 0.30192(11) 0.0228(3) Uani 1 1 d U . . H16A H 0.263(2) 0.315(2) 0.3629(14) 0.035(5) Uiso 1 1 d . . . H16B H 0.2127(18) 0.3189(16) 0.2569(11) 0.013(4) Uiso 1 1 d . . . C17 C 0.0278(2) 0.09196(18) 0.39683(11) 0.0285(3) Uani 1 1 d U . . H17A H 0.098(2) 0.037(2) 0.4096(14) 0.040(5) Uiso 1 1 d . . . H17B H 0.055(2) 0.167(2) 0.4499(14) 0.038(5) Uiso 1 1 d . . . H17C H -0.083(2) 0.027(2) 0.3932(13) 0.035(5) Uiso 1 1 d . . . C18 C -0.06850(19) 0.23660(18) 0.28304(13) 0.0289(3) Uani 1 1 d U . . H18B H -0.037(2) 0.317(2) 0.3312(14) 0.038(5) Uiso 1 1 d . . . H18C H -0.176(2) 0.178(2) 0.2847(14) 0.039(5) Uiso 1 1 d . . . H18A H -0.064(2) 0.269(2) 0.2209(14) 0.033(5) Uiso 1 1 d . . . C19 C 0.12767(17) -0.19435(15) 0.08072(10) 0.0234(3) Uani 1 1 d U . . C20 C 0.0068(2) -0.2839(2) -0.00654(12) 0.0331(3) Uani 1 1 d U . . H20A H -0.090(2) -0.354(2) 0.0090(13) 0.032(5) Uiso 1 1 d . . . H20B H -0.026(2) -0.228(2) -0.0476(14) 0.034(5) Uiso 1 1 d . . . H20C H 0.059(2) -0.331(2) -0.0414(15) 0.042(5) Uiso 1 1 d . . . C21 C 0.27685(19) -0.09616(17) 0.04652(11) 0.0278(3) Uani 1 1 d U . . H21A H 0.319(2) -0.155(2) 0.0085(15) 0.043(5) Uiso 1 1 d . . . H21B H 0.249(2) -0.033(2) 0.0054(15) 0.040(5) Uiso 1 1 d . . . H21C H 0.358(2) -0.0414(19) 0.0994(13) 0.028(4) Uiso 1 1 d . . . C22 C 0.1690(2) -0.29095(17) 0.14973(13) 0.0308(3) Uani 1 1 d U . . H22A H 0.214(2) -0.351(2) 0.1167(14) 0.038(5) Uiso 1 1 d . . . H22B H 0.240(2) -0.238(2) 0.2023(14) 0.030(5) Uiso 1 1 d . . . H22C H 0.069(3) -0.354(2) 0.1727(15) 0.045(6) Uiso 1 1 d . . . loop_ _atom_site_aniso_label _atom_site_aniso_U_11 _atom_site_aniso_U_22 _atom_site_aniso_U_33 _atom_site_aniso_U_23 _atom_site_aniso_U_13 _atom_site_aniso_U_12 Rh1 0.01609(6) 0.01794(6) 0.01767(6) 0.00174(4) 0.00342(4) 0.00622(4) Cl1 0.02078(15) 0.02815(17) 0.02661(16) -0.00048(13) 0.00259(12) 0.01253(13) C1 0.0205(6) 0.0202(6) 0.0195(6) 0.0031(5) 0.0044(5) 0.0077(5) N1 0.0219(6) 0.0215(6) 0.0219(6) 0.0040(5) 0.0036(5) 0.0046(5) N2 0.0226(6) 0.0188(5) 0.0211(6) 0.0012(4) 0.0011(4) 0.0044(5) C2 0.0292(8) 0.0222(7) 0.0312(8) 0.0048(6) 0.0029(6) 0.0001(6) N3 0.0178(5) 0.0225(6) 0.0221(6) 0.0004(4) 0.0045(4) 0.0079(4) C3 0.0283(7) 0.0215(7) 0.0292(8) 0.0005(6) -0.0006(6) -0.0003(6) N4 0.0183(5) 0.0231(6) 0.0211(5) -0.0010(4) 0.0027(4) 0.0080(5) C4 0.0228(6) 0.0249(7) 0.0197(6) 0.0058(5) 0.0055(5) 0.0095(5) C5 0.0267(7) 0.0278(7) 0.0194(7) 0.0052(6) 0.0032(6) 0.0055(6) C6 0.0421(9) 0.0309(8) 0.0348(9) 0.0089(7) 0.0054(7) 0.0198(8) C7 0.0279(8) 0.0449(10) 0.0298(8) 0.0077(7) 0.0108(7) 0.0133(8) C8 0.0263(7) 0.0198(6) 0.0186(6) 0.0018(5) 0.0022(5) 0.0083(5) C9 0.0276(7) 0.0271(7) 0.0227(7) 0.0063(6) 0.0047(6) 0.0060(6) C10 0.0497(10) 0.0260(8) 0.0229(7) -0.0012(6) 0.0035(7) 0.0159(8) C11 0.0282(8) 0.0274(8) 0.0375(9) 0.0065(7) 0.0047(7) 0.0124(6) C12 0.0191(6) 0.0212(6) 0.0183(6) 0.0019(5) 0.0041(5) 0.0079(5) C13 0.0172(6) 0.0305(7) 0.0318(8) -0.0005(6) 0.0044(6) 0.0078(6) C14 0.0179(6) 0.0296(7) 0.0288(7) -0.0036(6) 0.0012(6) 0.0063(6) C15 0.0211(6) 0.0207(6) 0.0231(6) 0.0009(5) 0.0063(5) 0.0095(5) C16 0.0209(6) 0.0194(6) 0.0282(7) 0.0010(6) 0.0058(5) 0.0074(5) C17 0.0318(8) 0.0299(8) 0.0254(7) 0.0037(6) 0.0102(6) 0.0112(7) C18 0.0243(7) 0.0299(8) 0.0366(9) 0.0010(7) 0.0072(6) 0.0146(6) C19 0.0225(7) 0.0252(7) 0.0229(7) -0.0031(5) 0.0032(5) 0.0105(6) C20 0.0275(8) 0.0382(9) 0.0297(8) -0.0106(7) 0.0012(6) 0.0110(7) C21 0.0262(7) 0.0318(8) 0.0254(7) -0.0014(6) 0.0075(6) 0.0102(6) C22 0.0297(8) 0.0269(8) 0.0368(9) 0.0028(7) 0.0027(7) 0.0129(7) _geom_special_details ; All esds (except the esd in the dihedral angle between two l.s. planes) are estimated using the full covariance matrix. The cell esds are taken into account individually in the estimation of esds in distances, angles and torsion angles; correlations between esds in cell parameters are only used when they are defined by crystal symmetry. An approximate (isotropic) treatment of cell esds is used for estimating esds involving l.s. planes. ; loop_ _geom_bond_atom_site_label_1 _geom_bond_atom_site_label_2 _geom_bond_distance _geom_bond_site_symmetry_2 _geom_bond_publ_flag Rh1 C1 2.0077(14) . ? Rh1 C5 2.0316(14) . ? Rh1 C16 2.0442(14) . ? Rh1 C12 2.1113(13) . ? Rh1 Cl1 2.5205(4) . ? C1 N1 1.3574(18) . ? C1 N2 1.3637(18) . ? N1 C2 1.3866(19) . ? N1 C4 1.4786(18) . ? N2 C3 1.3963(18) . ? N2 C8 1.4934(18) . ? C2 C3 1.349(2) . ? N3 C12 1.3710(17) . ? N3 C13 1.3788(18) . ? N3 C15 1.4831(17) . ? N4 C12 1.3771(17) . ? N4 C14 1.3974(18) . ? N4 C19 1.5017(17) . ? C4 C7 1.528(2) . ? C4 C6 1.532(2) . ? C4 C5 1.552(2) . ? C8 C9 1.524(2) . ? C8 C11 1.529(2) . ? C8 C10 1.532(2) . ? C13 C14 1.349(2) . ? C15 C17 1.533(2) . ? C15 C16 1.5338(19) . ? C15 C18 1.534(2) . ? C19 C22 1.528(2) . ? C19 C21 1.533(2) . ? C19 C20 1.535(2) . ? loop_ _geom_angle_atom_site_label_1 _geom_angle_atom_site_label_2 _geom_angle_atom_site_label_3 _geom_angle _geom_angle_site_symmetry_1 _geom_angle_site_symmetry_3 _geom_angle_publ_flag C1 Rh1 C5 81.06(6) . . ? C1 Rh1 C16 88.71(6) . . ? C5 Rh1 C16 90.58(6) . . ? C1 Rh1 C12 167.43(5) . . ? C5 Rh1 C12 94.36(6) . . ? C16 Rh1 C12 79.60(5) . . ? C1 Rh1 Cl1 91.03(4) . . ? C5 Rh1 Cl1 102.12(5) . . ? C16 Rh1 Cl1 167.10(4) . . ? C12 Rh1 Cl1 101.40(4) . . ? N1 C1 N2 104.77(12) . . ? N1 C1 Rh1 116.56(10) . . ? N2 C1 Rh1 138.50(10) . . ? C1 N1 C2 111.54(12) . . ? C1 N1 C4 119.76(12) . . ? C2 N1 C4 128.69(12) . . ? C1 N2 C3 109.98(12) . . ? C1 N2 C8 126.05(11) . . ? C3 N2 C8 123.77(12) . . ? C3 C2 N1 106.15(13) . . ? C12 N3 C13 112.60(12) . . ? C12 N3 C15 119.99(11) . . ? C13 N3 C15 127.15(12) . . ? C2 C3 N2 107.53(13) . . ? C12 N4 C14 110.25(11) . . ? C12 N4 C19 127.00(11) . . ? C14 N4 C19 122.54(12) . . ? N1 C4 C7 108.47(12) . . ? N1 C4 C6 108.79(12) . . ? C7 C4 C6 110.18(13) . . ? N1 C4 C5 106.98(11) . . ? C7 C4 C5 110.21(13) . . ? C6 C4 C5 112.08(13) . . ? C4 C5 Rh1 114.98(10) . . ? N2 C8 C9 109.22(11) . . ? N2 C8 C11 108.16(12) . . ? C9 C8 C11 111.35(12) . . ? N2 C8 C10 109.39(12) . . ? C9 C8 C10 108.50(13) . . ? C11 C8 C10 110.20(13) . . ? N3 C12 N4 103.33(11) . . ? N3 C12 Rh1 111.64(9) . . ? N4 C12 Rh1 145.02(10) . . ? C14 C13 N3 105.92(13) . . ? C13 C14 N4 107.86(13) . . ? N3 C15 C17 107.20(11) . . ? N3 C15 C16 105.32(11) . . ? C17 C15 C16 112.97(12) . . ? N3 C15 C18 110.24(12) . . ? C17 C15 C18 110.24(12) . . ? C16 C15 C18 110.70(12) . . ? C15 C16 Rh1 111.50(9) . . ? N4 C19 C22 108.19(12) . . ? N4 C19 C21 109.45(12) . . ? C22 C19 C21 111.35(13) . . ? N4 C19 C20 109.26(12) . . ? C22 C19 C20 109.86(13) . . ? C21 C19 C20 108.70(13) . . ? loop_ _geom_torsion_atom_site_label_1 _geom_torsion_atom_site_label_2 _geom_torsion_atom_site_label_3 _geom_torsion_atom_site_label_4 _geom_torsion _geom_torsion_site_symmetry_1 _geom_torsion_site_symmetry_2 _geom_torsion_site_symmetry_3 _geom_torsion_site_symmetry_4 _geom_torsion_publ_flag C5 Rh1 C1 N1 5.33(11) . . . . ? C16 Rh1 C1 N1 -85.46(11) . . . . ? C12 Rh1 C1 N1 -64.1(3) . . . . ? Cl1 Rh1 C1 N1 107.44(10) . . . . ? C5 Rh1 C1 N2 179.74(16) . . . . ? C16 Rh1 C1 N2 88.95(16) . . . . ? C12 Rh1 C1 N2 110.3(3) . . . . ? Cl1 Rh1 C1 N2 -78.15(15) . . . . ? N2 C1 N1 C2 1.23(16) . . . . ? Rh1 C1 N1 C2 177.41(10) . . . . ? N2 C1 N1 C4 -178.20(12) . . . . ? Rh1 C1 N1 C4 -2.02(16) . . . . ? N1 C1 N2 C3 -1.43(16) . . . . ? Rh1 C1 N2 C3 -176.26(13) . . . . ? N1 C1 N2 C8 -176.51(12) . . . . ? Rh1 C1 N2 C8 8.7(2) . . . . ? C1 N1 C2 C3 -0.56(18) . . . . ? C4 N1 C2 C3 178.80(14) . . . . ? N1 C2 C3 N2 -0.35(19) . . . . ? C1 N2 C3 C2 1.14(18) . . . . ? C8 N2 C3 C2 176.35(13) . . . . ? C1 N1 C4 C7 -122.79(14) . . . . ? C2 N1 C4 C7 57.9(2) . . . . ? C1 N1 C4 C6 117.36(15) . . . . ? C2 N1 C4 C6 -61.96(19) . . . . ? C1 N1 C4 C5 -3.92(17) . . . . ? C2 N1 C4 C5 176.76(15) . . . . ? N1 C4 C5 Rh1 8.05(15) . . . . ? C7 C4 C5 Rh1 125.78(12) . . . . ? C6 C4 C5 Rh1 -111.12(13) . . . . ? C1 Rh1 C5 C4 -7.43(11) . . . . ? C16 Rh1 C5 C4 81.17(11) . . . . ? C12 Rh1 C5 C4 160.78(11) . . . . ? Cl1 Rh1 C5 C4 -96.57(11) . . . . ? C1 N2 C8 C9 -20.89(19) . . . . ? C3 N2 C8 C9 164.67(14) . . . . ? C1 N2 C8 C11 100.45(16) . . . . ? C3 N2 C8 C11 -73.98(17) . . . . ? C1 N2 C8 C10 -139.51(15) . . . . ? C3 N2 C8 C10 46.06(19) . . . . ? C13 N3 C12 N4 2.32(16) . . . . ? C15 N3 C12 N4 176.81(11) . . . . ? C13 N3 C12 Rh1 -178.48(10) . . . . ? C15 N3 C12 Rh1 -3.98(15) . . . . ? C14 N4 C12 N3 -1.89(15) . . . . ? C19 N4 C12 N3 -176.61(13) . . . . ? C14 N4 C12 Rh1 179.40(14) . . . . ? C19 N4 C12 Rh1 4.7(3) . . . . ? C1 Rh1 C12 N3 -36.1(3) . . . . ? C5 Rh1 C12 N3 -104.14(10) . . . . ? C16 Rh1 C12 N3 -14.35(10) . . . . ? Cl1 Rh1 C12 N3 152.55(9) . . . . ? C1 Rh1 C12 N4 142.5(2) . . . . ? C5 Rh1 C12 N4 74.51(18) . . . . ? C16 Rh1 C12 N4 164.30(18) . . . . ? Cl1 Rh1 C12 N4 -28.80(18) . . . . ? C12 N3 C13 C14 -1.87(18) . . . . ? C15 N3 C13 C14 -175.88(13) . . . . ? N3 C13 C14 N4 0.58(18) . . . . ? C12 N4 C14 C13 0.86(18) . . . . ? C19 N4 C14 C13 175.85(13) . . . . ? C12 N3 C15 C17 -94.08(15) . . . . ? C13 N3 C15 C17 79.54(17) . . . . ? C12 N3 C15 C16 26.48(16) . . . . ? C13 N3 C15 C16 -159.91(14) . . . . ? C12 N3 C15 C18 145.92(13) . . . . ? C13 N3 C15 C18 -40.46(19) . . . . ? N3 C15 C16 Rh1 -36.99(13) . . . . ? C17 C15 C16 Rh1 79.70(13) . . . . ? C18 C15 C16 Rh1 -156.13(10) . . . . ? C1 Rh1 C16 C15 -155.71(11) . . . . ? C5 Rh1 C16 C15 123.24(11) . . . . ? C12 Rh1 C16 C15 28.92(10) . . . . ? Cl1 Rh1 C16 C15 -66.7(2) . . . . ? C12 N4 C19 C22 75.92(17) . . . . ? C14 N4 C19 C22 -98.20(16) . . . . ? C12 N4 C19 C21 -45.57(18) . . . . ? C14 N4 C19 C21 140.30(14) . . . . ? C12 N4 C19 C20 -164.49(14) . . . . ? C14 N4 C19 C20 21.38(19) . . . . ? _diffrn_measured_fraction_theta_max 0.915 _diffrn_reflns_theta_full 28.85 _diffrn_measured_fraction_theta_full 0.915 _refine_diff_density_max 0.591 _refine_diff_density_min -0.519 _refine_diff_density_rms 0.057