data_global _audit_creation_date 10-05-05 _publ_contact_author_name ; 'Franck Camerel' ; _publ_contact_author_address ; Laboratoire de Chimie Universit\'e Louis Pasteur, d'Electronique et de Photonique Moleculaires ECPM, 1 rue Blaise Pascal Strasbourg F-67008 FRANCE ; _publ_contact_author_phone '0390241593' _publ_contact_author_fax '0390241232' _publ_contact_author_email fcamerel@chimie.u-strasbg.fr _publ_requested_journal '?????' _publ_contact_letter ; ; _publ_section_title ; Routes to ................ .......................... .......................... ; loop_ _publ_author_name _publ_author_address 'CAMEREL Franck' ; Laboratoire de Chimie Mol\'eculaire, Ecole de Chimie, Polym\`eres, Mat\'eriaux (ECPM), Universite Louis Pasteur (ULP), 25 rue Becquerel 67087 Strasbourg Cedex 02 France ; 'RETAILLEAU Pascal' ; ICSN-CNRS 1 avenue de la Terrasse 91198 Gif sur Yvette France ; 'ZIESSEL Raymond' ; Laboratoire de Chimie Mol\'eculaire, Ecole de Chimie, Polym\`eres, Mat\'eriaux (ECPM), Universite Louis Pasteur (ULP), 25 rue Becquerel 67087 Strasbourg Cedex 02 France ; data_RIS1009A _audit_creation_method SHELXL-97 _chemical_name_systematic ; ? ; _chemical_name_common ? _chemical_melting_point ? _chemical_formula_moiety 'C35 H50 N3 Pt Si, C6 H12, B F4' _chemical_formula_sum 'C41 H62 B F4 N3 Pt Si' _chemical_formula_weight 906.93 loop_ _atom_type_symbol _atom_type_description _atom_type_scat_dispersion_real _atom_type_scat_dispersion_imag _atom_type_scat_source 'C' 'C' 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' 'H' 'H' 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' 'B' 'B' 0.0013 0.0007 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' 'F' 'F' 0.0171 0.0103 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' 'N' 'N' 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' 'Pt' 'Pt' -1.7033 8.3905 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' 'Si' 'Si' 0.0817 0.0704 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' _symmetry_cell_setting triclinic _symmetry_space_group_name_H-M 'P -1' _symmetry_space_group_name_Hall '-P 1' loop_ _symmetry_equiv_pos_as_xyz 'x, y, z' '-x, -y, -z' _cell_length_a 10.379(3) _cell_length_b 12.700(3) _cell_length_c 17.441(3) _cell_angle_alpha 89.340(2) _cell_angle_beta 87.933(2) _cell_angle_gamma 75.752(2) _cell_volume 2226.8(9) _cell_formula_units_Z 2 _cell_measurement_temperature 293(2) _cell_measurement_reflns_used 4298 _cell_measurement_theta_min 0.998 _cell_measurement_theta_max 23.257 _exptl_crystal_description prism _exptl_crystal_colour 'dark yellow' _exptl_crystal_size_max 0.40 _exptl_crystal_size_mid 0.20 _exptl_crystal_size_min 0.20 _exptl_crystal_density_meas ? _exptl_crystal_density_diffrn 1.353 _exptl_crystal_density_method 'not measured' _exptl_crystal_F_000 924 _exptl_absorpt_coefficient_mu 3.224 _exptl_absorpt_correction_type multi-scan _exptl_absorpt_correction_T_min 0.328 _exptl_absorpt_correction_T_max 0.526 _exptl_absorpt_process_details 'HKL SCALEPACK, Blessing' _exptl_special_details ; ? ; _diffrn_ambient_temperature 293(2) _diffrn_radiation_wavelength 0.71073 _diffrn_radiation_type MoK\a _diffrn_radiation_source 'Enraf Nonius FR590' _diffrn_radiation_monochromator 'horizontally mounted graphite crystal' _diffrn_measurement_device_type '95mm CCD camera on \k-goniostat' _diffrn_measurement_method 'CCD rotation images, thick slices' _diffrn_detector_area_resol_mean 9 _diffrn_standards_number ? _diffrn_standards_interval_count ? _diffrn_standards_interval_time ? _diffrn_standards_decay_% ? _diffrn_reflns_number 16005 _diffrn_reflns_av_R_equivalents 0.0290 _diffrn_reflns_av_sigmaI/netI 0.0478 _diffrn_reflns_limit_h_min -11 _diffrn_reflns_limit_h_max 11 _diffrn_reflns_limit_k_min -14 _diffrn_reflns_limit_k_max 13 _diffrn_reflns_limit_l_min -19 _diffrn_reflns_limit_l_max 18 _diffrn_reflns_theta_min 2.02 _diffrn_reflns_theta_max 23.33 _reflns_number_total 6419 _reflns_number_gt 5480 _reflns_threshold_expression >2sigma(I) _computing_data_collection 'Collect (Nonius BV, 1997-2000)' _computing_cell_refinement 'HKL Scalepack (Otwinowski & Minor 1997)' _computing_data_reduction 'HKL Denzo and Scalepack (Otwinowski & Minor 1997)' _computing_structure_solution 'DIRDIF99 (Beurskens et al, 1999)' _computing_structure_refinement 'SHELXL-97 (Sheldrick, 1997)' _computing_molecular_graphics 'PLATON (Spek, 1980-2004)' _computing_publication_material 'SHELXL-97 (Sheldrick, 1997)' _refine_special_details ; Refinement of F^2^ against ALL reflectionsi except two reflections truncated by the beamstop. The weighted R-factor wR and goodness of fit S are based on F^2^, conventional R-factors R are based on F, with F set to zero for negative F^2^. The threshold expression of F^2^ > 2sigma(F^2^) is used only for calculating R-factors(gt) etc. and is not relevant to the choice of reflections for refinement. R-factors based on F^2^ are statistically about twice as large as those based on F, and R- factors based on ALL data will be even larger. ; _refine_ls_structure_factor_coef Fsqd _refine_ls_matrix_type full _refine_ls_weighting_scheme calc _refine_ls_weighting_details 'calc w=1/[\s^2^(Fo^2^)+(0.0591P)^2^+1.5933P] where P=(Fo^2^+2Fc^2^)/3' _atom_sites_solution_primary direct _atom_sites_solution_secondary difmap _atom_sites_solution_hydrogens geom _refine_ls_hydrogen_treatment constr _refine_ls_extinction_method none _refine_ls_extinction_coef ? _refine_ls_number_reflns 6419 _refine_ls_number_parameters 541 _refine_ls_number_restraints 338 _refine_ls_R_factor_all 0.0518 _refine_ls_R_factor_gt 0.0396 _refine_ls_wR_factor_ref 0.1028 _refine_ls_wR_factor_gt 0.0958 _refine_ls_goodness_of_fit_ref 1.043 _refine_ls_restrained_S_all 1.035 _refine_ls_shift/su_max 0.009 _refine_ls_shift/su_mean 0.000 loop_ _atom_site_label _atom_site_type_symbol _atom_site_fract_x _atom_site_fract_y _atom_site_fract_z _atom_site_U_iso_or_equiv _atom_site_adp_type _atom_site_occupancy _atom_site_symmetry_multiplicity _atom_site_calc_flag _atom_site_refinement_flags _atom_site_disorder_assembly _atom_site_disorder_group Pt Pt 0.06397(2) 0.078526(19) 0.356888(14) 0.05473(12) Uani 1 1 d . . . N1 N -0.0555(5) 0.1947(4) 0.2939(3) 0.0585(13) Uani 1 1 d . . . N2 N -0.0008(5) 0.1894(4) 0.4360(3) 0.0502(12) Uani 1 1 d . . . N3 N 0.1672(5) 0.0023(4) 0.4458(3) 0.0556(13) Uani 1 1 d . . . C1 C -0.1165(6) 0.2862(5) 0.3344(4) 0.0579(16) Uani 1 1 d . . . C2 C -0.1967(6) 0.3734(5) 0.2988(4) 0.0629(17) Uani 1 1 d . . . H2 H -0.2360 0.4354 0.3270 0.076 Uiso 1 1 calc R . . C3 C -0.2202(7) 0.3707(6) 0.2211(4) 0.0678(18) Uani 1 1 d . . . C4 C -0.1591(7) 0.2773(6) 0.1819(4) 0.077(2) Uani 1 1 d . . . H4 H -0.1723 0.2721 0.1298 0.092 Uiso 1 1 calc R . . C5 C -0.0788(7) 0.1916(6) 0.2195(4) 0.0667(18) Uani 1 1 d . . . H5 H -0.0391 0.1290 0.1920 0.080 Uiso 1 1 calc R . . C16 C -0.3110(8) 0.4702(7) 0.1823(5) 0.081(2) Uani 1 1 d . . . C17 C -0.3382(11) 0.4458(8) 0.1007(5) 0.122(4) Uani 1 1 d . . . H17A H -0.2565 0.4303 0.0707 0.182 Uiso 1 1 calc R . . H17B H -0.3994 0.5076 0.0795 0.182 Uiso 1 1 calc R . . H17C H -0.3760 0.3840 0.1002 0.182 Uiso 1 1 calc R . . C18 C -0.4431(8) 0.5012(8) 0.2267(6) 0.116(3) Uani 1 1 d . . . H18A H -0.4763 0.4376 0.2352 0.173 Uiso 1 1 calc R . . H18B H -0.5057 0.5535 0.1978 0.173 Uiso 1 1 calc R . . H18C H -0.4311 0.5319 0.2751 0.173 Uiso 1 1 calc R . . C19 C -0.2442(9) 0.5640(7) 0.1830(6) 0.107(3) Uani 1 1 d . . . H19A H -0.2242 0.5776 0.2348 0.160 Uiso 1 1 calc R . . H19B H -0.3028 0.6279 0.1626 0.160 Uiso 1 1 calc R . . H19C H -0.1633 0.5458 0.1522 0.160 Uiso 1 1 calc R . . C6 C -0.0879(6) 0.2814(5) 0.4170(4) 0.0540(15) Uani 1 1 d . . . C7 C -0.1414(6) 0.3567(5) 0.4723(4) 0.0600(16) Uani 1 1 d . . . H7 H -0.2033 0.4203 0.4598 0.072 Uiso 1 1 calc R . . C8 C -0.1017(6) 0.3366(5) 0.5475(4) 0.0624(17) Uani 1 1 d . A . C9 C -0.0068(6) 0.2412(6) 0.5650(4) 0.0638(17) Uani 1 1 d . . . H9 H 0.0216 0.2277 0.6150 0.077 Uiso 1 1 calc R . . C10 C 0.0441(6) 0.1676(5) 0.5076(4) 0.0547(15) Uani 1 1 d . . . C20 C -0.1613(8) 0.4203(6) 0.6114(4) 0.081(2) Uani 1 1 d DU . . C21A C -0.1107(15) 0.5212(10) 0.5970(8) 0.100(4) Uani 0.67 1 d PDU A 1 H21A H -0.1321 0.5479 0.5461 0.150 Uiso 0.67 1 calc PR A 1 H21B H -0.0160 0.5037 0.6021 0.150 Uiso 0.67 1 calc PR A 1 H21C H -0.1520 0.5761 0.6337 0.150 Uiso 0.67 1 calc PR A 1 C22A C -0.3143(10) 0.4537(14) 0.6025(9) 0.123(5) Uani 0.67 1 d PDU A 1 H22A H -0.3339 0.4808 0.5516 0.185 Uiso 0.67 1 calc PR A 1 H22B H -0.3536 0.5093 0.6391 0.185 Uiso 0.67 1 calc PR A 1 H22C H -0.3502 0.3916 0.6115 0.185 Uiso 0.67 1 calc PR A 1 C23A C -0.128(2) 0.3762(12) 0.6909(7) 0.142(6) Uani 0.67 1 d PDU A 1 H23A H -0.1602 0.3123 0.6991 0.212 Uiso 0.67 1 calc PR A 1 H23B H -0.1687 0.4301 0.7283 0.212 Uiso 0.67 1 calc PR A 1 H23C H -0.0330 0.3581 0.6959 0.212 Uiso 0.67 1 calc PR A 1 C21B C -0.050(2) 0.456(3) 0.6542(19) 0.145(10) Uani 0.33 1 d PDU A 2 H21D H -0.0033 0.4929 0.6192 0.218 Uiso 0.33 1 calc PR A 2 H21E H 0.0106 0.3924 0.6740 0.218 Uiso 0.33 1 calc PR A 2 H21F H -0.0893 0.5030 0.6957 0.218 Uiso 0.33 1 calc PR A 2 C22B C -0.235(3) 0.364(2) 0.6695(16) 0.114(9) Uani 0.33 1 d PDU A 2 H22D H -0.1753 0.2990 0.6880 0.170 Uiso 0.33 1 calc PR A 2 H22E H -0.3079 0.3447 0.6452 0.170 Uiso 0.33 1 calc PR A 2 H22F H -0.2687 0.4116 0.7117 0.170 Uiso 0.33 1 calc PR A 2 C23B C -0.259(4) 0.525(2) 0.5863(17) 0.178(14) Uani 0.33 1 d PDU A 2 H23D H -0.2157 0.5626 0.5492 0.267 Uiso 0.33 1 calc PR A 2 H23E H -0.2884 0.5712 0.6301 0.267 Uiso 0.33 1 calc PR A 2 H23F H -0.3344 0.5080 0.5638 0.267 Uiso 0.33 1 calc PR A 2 C11 C 0.1454(6) 0.0632(5) 0.5121(4) 0.0556(15) Uani 1 1 d . . . C12 C 0.2205(6) 0.0294(5) 0.5760(4) 0.0654(17) Uani 1 1 d . . . H12 H 0.2046 0.0721 0.6199 0.078 Uiso 1 1 calc R . . C13 C 0.3187(6) -0.0667(6) 0.5757(4) 0.0661(18) Uani 1 1 d . . . C14 C 0.3330(6) -0.1279(6) 0.5100(5) 0.0691(19) Uani 1 1 d . . . H14 H 0.3944 -0.1950 0.5084 0.083 Uiso 1 1 calc R . . C15 C 0.2585(6) -0.0925(5) 0.4457(4) 0.0647(18) Uani 1 1 d . . . H15 H 0.2724 -0.1356 0.4020 0.078 Uiso 1 1 calc R . . C24 C 0.4118(7) -0.0990(6) 0.6413(4) 0.077(2) Uani 1 1 d . . . C25 C 0.4611(10) -0.2229(8) 0.6486(6) 0.125(4) Uani 1 1 d . . . H25A H 0.5031 -0.2523 0.6009 0.187 Uiso 1 1 calc R . . H25B H 0.3870 -0.2535 0.6607 0.187 Uiso 1 1 calc R . . H25C H 0.5239 -0.2402 0.6886 0.187 Uiso 1 1 calc R . . C26 C 0.5313(8) -0.0523(8) 0.6236(5) 0.098(3) Uani 1 1 d . . . H26A H 0.5737 -0.0815 0.5760 0.147 Uiso 1 1 calc R . . H26B H 0.5932 -0.0713 0.6641 0.147 Uiso 1 1 calc R . . H26C H 0.5023 0.0254 0.6196 0.147 Uiso 1 1 calc R . . C27 C 0.3463(9) -0.0542(10) 0.7165(5) 0.122(4) Uani 1 1 d . . . H27A H 0.4079 -0.0758 0.7569 0.183 Uiso 1 1 calc R . . H27B H 0.2694 -0.0820 0.7269 0.183 Uiso 1 1 calc R . . H27C H 0.3199 0.0236 0.7136 0.183 Uiso 1 1 calc R . . C1' C 0.1259(7) -0.0291(6) 0.2750(4) 0.0684(18) Uani 1 1 d . . . C2' C 0.1611(9) -0.0816(7) 0.2182(5) 0.094(3) Uani 1 1 d . . . Si Si 0.2266(4) -0.1501(2) 0.12794(15) 0.1217(11) Uani 1 1 d DU . . C3' C 0.1863(13) -0.0478(8) 0.0497(5) 0.144(4) Uani 1 1 d DU . . H3'1 H 0.0903 -0.0213 0.0485 0.173 Uiso 1 1 calc R . . H3'2 H 0.2225 0.0133 0.0617 0.173 Uiso 1 1 calc R . . C4' C 0.4101(12) -0.2043(11) 0.1357(8) 0.185(5) Uani 1 1 d DU . . H4'1 H 0.4262 -0.2570 0.1772 0.222 Uiso 1 1 calc R . . H4'2 H 0.4453 -0.2421 0.0886 0.222 Uiso 1 1 calc R . . C5' C 0.160(2) -0.2670(12) 0.1123(9) 0.223(7) Uani 1 1 d DU . . H5'1 H 0.1915 -0.2975 0.0624 0.267 Uiso 1 1 calc R . . H5'2 H 0.1940 -0.3218 0.1507 0.267 Uiso 1 1 calc R . . C6' C 0.239(2) -0.0893(14) -0.0307(7) 0.253(9) Uani 1 1 d DU . . H6'1 H 0.2131 -0.0317 -0.0674 0.379 Uiso 1 1 calc R . . H6'2 H 0.2020 -0.1488 -0.0440 0.379 Uiso 1 1 calc R . . H6'3 H 0.3340 -0.1135 -0.0309 0.379 Uiso 1 1 calc R . . C7' C 0.4869(16) -0.1176(16) 0.1504(12) 0.259(10) Uani 1 1 d DU . . H7'1 H 0.5799 -0.1519 0.1541 0.389 Uiso 1 1 calc R . . H7'2 H 0.4543 -0.0805 0.1975 0.389 Uiso 1 1 calc R . . H7'3 H 0.4745 -0.0663 0.1088 0.389 Uiso 1 1 calc R . . C8' C 0.010(2) -0.2395(18) 0.1164(13) 0.300(12) Uani 1 1 d DU . . H8'1 H -0.0197 -0.3039 0.1075 0.450 Uiso 1 1 calc R . . H8'2 H -0.0236 -0.1861 0.0779 0.450 Uiso 1 1 calc R . . H8'3 H -0.0211 -0.2110 0.1662 0.450 Uiso 1 1 calc R . . B B 0.3374(10) 0.2998(8) 0.6007(7) 0.108(3) Uani 1 1 d DU . . F1 F 0.3261(7) 0.2529(5) 0.5341(4) 0.158(2) Uani 1 1 d DU . . F2 F 0.2921(9) 0.4055(5) 0.6015(4) 0.191(3) Uani 1 1 d DU . . F3 F 0.2682(9) 0.2533(7) 0.6553(4) 0.180(3) Uani 1 1 d DU . . F4 F 0.4636(7) 0.2717(7) 0.6233(6) 0.209(4) Uani 1 1 d DU . . C28A C 0.235(3) 0.4009(19) 0.0661(14) 0.198(9) Uani 0.60 1 d PDU B 1 H28A H 0.2903 0.4514 0.0716 0.237 Uiso 0.60 1 calc PR B 1 H28B H 0.1759 0.4266 0.0242 0.237 Uiso 0.60 1 calc PR B 1 C29A C 0.153(3) 0.402(2) 0.1376(14) 0.185(8) Uani 0.60 1 d PDU B 1 H29A H 0.0702 0.3849 0.1253 0.222 Uiso 0.60 1 calc PR B 1 H29B H 0.1326 0.4739 0.1595 0.222 Uiso 0.60 1 calc PR B 1 C30A C 0.224(3) 0.3185(19) 0.1986(10) 0.153(6) Uani 0.60 1 d PDU B 1 H30A H 0.3046 0.3368 0.2144 0.184 Uiso 0.60 1 calc PR B 1 H30B H 0.1659 0.3193 0.2435 0.184 Uiso 0.60 1 calc PR B 1 C31A C 0.257(3) 0.2091(19) 0.1617(15) 0.184(8) Uani 0.60 1 d PDU B 1 H31A H 0.1897 0.1987 0.1274 0.221 Uiso 0.60 1 calc PR B 1 H31B H 0.2793 0.1495 0.1980 0.221 Uiso 0.60 1 calc PR B 1 C32A C 0.380(2) 0.234(2) 0.1193(15) 0.192(9) Uani 0.60 1 d PDU B 1 H32A H 0.4184 0.2819 0.1493 0.230 Uiso 0.60 1 calc PR B 1 H32B H 0.4480 0.1678 0.1084 0.230 Uiso 0.60 1 calc PR B 1 C33A C 0.324(3) 0.290(2) 0.0450(12) 0.195(9) Uani 0.60 1 d PDU B 1 H33A H 0.3952 0.2977 0.0099 0.234 Uiso 0.60 1 calc PR B 1 H33B H 0.2722 0.2463 0.0201 0.234 Uiso 0.60 1 calc PR B 1 C28B C 0.212(4) 0.291(3) 0.0333(16) 0.195(11) Uani 0.40 1 d PDU C 2 H28C H 0.2470 0.3279 -0.0087 0.234 Uiso 0.40 1 calc PR C 2 H28D H 0.1603 0.2462 0.0108 0.234 Uiso 0.40 1 calc PR C 2 C29B C 0.120(3) 0.375(3) 0.0810(19) 0.176(10) Uani 0.40 1 d PDU C 2 H29C H 0.0293 0.3684 0.0762 0.212 Uiso 0.40 1 calc PR C 2 H29D H 0.1235 0.4470 0.0627 0.212 Uiso 0.40 1 calc PR C 2 C30B C 0.158(3) 0.363(4) 0.1672(17) 0.177(9) Uani 0.40 1 d PDU C 2 H30C H 0.1063 0.4231 0.1978 0.212 Uiso 0.40 1 calc PR C 2 H30D H 0.1457 0.2951 0.1888 0.212 Uiso 0.40 1 calc PR C 2 C31B C 0.303(3) 0.364(3) 0.161(2) 0.194(9) Uani 0.40 1 d PDU C 2 H31C H 0.3362 0.3913 0.2059 0.233 Uiso 0.40 1 calc PR C 2 H31D H 0.3283 0.3980 0.1143 0.233 Uiso 0.40 1 calc PR C 2 C32B C 0.332(5) 0.238(3) 0.157(2) 0.188(10) Uani 0.40 1 d PDU C 2 H32C H 0.4175 0.2040 0.1776 0.225 Uiso 0.40 1 calc PR C 2 H32D H 0.2632 0.2119 0.1848 0.225 Uiso 0.40 1 calc PR C 2 C33B C 0.331(4) 0.215(3) 0.070(2) 0.184(10) Uani 0.40 1 d PDU C 2 H33C H 0.4124 0.2242 0.0458 0.221 Uiso 0.40 1 calc PR C 2 H33D H 0.3265 0.1403 0.0631 0.221 Uiso 0.40 1 calc PR C 2 loop_ _atom_site_aniso_label _atom_site_aniso_U_11 _atom_site_aniso_U_22 _atom_site_aniso_U_33 _atom_site_aniso_U_23 _atom_site_aniso_U_13 _atom_site_aniso_U_12 Pt 0.05622(16) 0.04563(17) 0.06242(19) -0.01241(11) 0.00381(11) -0.01298(11) N1 0.067(3) 0.052(3) 0.056(3) -0.008(3) 0.001(2) -0.013(3) N2 0.053(3) 0.045(3) 0.053(3) -0.009(2) -0.002(2) -0.013(2) N3 0.056(3) 0.047(3) 0.067(4) -0.003(3) 0.005(2) -0.018(2) C1 0.062(4) 0.044(4) 0.066(4) -0.010(3) 0.009(3) -0.011(3) C2 0.062(4) 0.048(4) 0.074(5) -0.007(3) 0.010(3) -0.006(3) C3 0.070(4) 0.062(5) 0.070(5) 0.006(4) 0.002(3) -0.016(3) C4 0.092(5) 0.076(5) 0.062(5) -0.004(4) -0.003(4) -0.020(4) C5 0.077(4) 0.064(5) 0.056(4) -0.015(3) -0.001(3) -0.011(4) C16 0.087(5) 0.074(5) 0.077(5) 0.012(4) -0.004(4) -0.009(4) C17 0.148(8) 0.105(8) 0.091(7) 0.026(6) -0.021(6) 0.009(6) C18 0.086(6) 0.120(8) 0.120(8) 0.024(6) 0.001(5) 0.013(5) C19 0.116(7) 0.073(6) 0.125(8) 0.023(5) 0.011(6) -0.015(5) C6 0.055(3) 0.045(4) 0.062(4) -0.009(3) 0.009(3) -0.016(3) C7 0.069(4) 0.045(4) 0.064(4) -0.008(3) 0.013(3) -0.012(3) C8 0.070(4) 0.045(4) 0.072(5) -0.014(3) 0.024(3) -0.019(3) C9 0.076(4) 0.067(5) 0.053(4) -0.005(3) 0.009(3) -0.026(4) C10 0.054(3) 0.053(4) 0.062(4) -0.008(3) 0.008(3) -0.022(3) C20 0.112(5) 0.060(4) 0.070(4) -0.020(3) 0.027(4) -0.019(4) C21A 0.144(11) 0.072(8) 0.091(9) -0.037(6) 0.039(8) -0.046(8) C22A 0.104(7) 0.140(15) 0.125(12) -0.064(10) 0.064(7) -0.036(8) C23A 0.265(19) 0.077(9) 0.063(7) -0.021(6) 0.028(10) -0.010(12) C21B 0.15(2) 0.15(3) 0.15(3) -0.09(2) 0.035(15) -0.070(17) C22B 0.12(2) 0.12(2) 0.09(2) -0.036(14) 0.069(16) -0.032(16) C23B 0.25(3) 0.12(2) 0.09(2) -0.020(16) 0.03(2) 0.09(2) C11 0.059(3) 0.051(4) 0.061(4) -0.001(3) 0.001(3) -0.022(3) C12 0.073(4) 0.058(4) 0.071(5) -0.002(3) 0.001(4) -0.027(4) C13 0.065(4) 0.058(4) 0.082(5) 0.008(4) -0.001(4) -0.028(3) C14 0.062(4) 0.050(4) 0.095(6) 0.005(4) -0.001(4) -0.014(3) C15 0.062(4) 0.050(4) 0.083(5) -0.009(4) 0.004(4) -0.015(3) C24 0.073(4) 0.087(6) 0.080(5) 0.020(4) -0.017(4) -0.034(4) C25 0.132(8) 0.099(7) 0.155(10) 0.063(7) -0.065(7) -0.045(6) C26 0.076(5) 0.113(7) 0.117(7) 0.026(6) -0.022(5) -0.045(5) C27 0.103(6) 0.181(11) 0.080(6) 0.029(7) -0.019(5) -0.031(7) C1' 0.078(4) 0.056(4) 0.061(4) -0.021(4) -0.013(3) 0.006(3) C2' 0.117(6) 0.065(5) 0.088(6) -0.015(5) -0.023(5) 0.004(5) Si 0.202(3) 0.0719(17) 0.0728(16) -0.0247(13) -0.0102(18) 0.0040(18) C3' 0.222(12) 0.109(8) 0.092(6) 0.003(5) -0.030(7) -0.022(8) C4' 0.211(9) 0.144(12) 0.130(10) -0.031(9) 0.018(9) 0.089(7) C5' 0.44(2) 0.130(11) 0.127(11) -0.028(8) -0.014(17) -0.115(16) C6' 0.42(3) 0.238(19) 0.081(7) -0.010(9) 0.007(12) -0.055(19) C7' 0.152(9) 0.28(2) 0.30(2) -0.08(2) -0.004(14) 0.036(10) C8' 0.43(2) 0.28(2) 0.27(2) 0.022(19) -0.14(3) -0.23(2) B 0.098(6) 0.070(6) 0.150(9) -0.045(6) 0.016(6) -0.013(5) F1 0.190(6) 0.129(5) 0.156(5) -0.054(4) 0.021(4) -0.043(5) F2 0.291(9) 0.079(4) 0.168(6) -0.018(4) -0.016(6) 0.025(5) F3 0.222(7) 0.179(7) 0.165(6) -0.010(5) 0.000(5) -0.100(6) F4 0.127(5) 0.181(7) 0.304(11) -0.078(7) -0.023(5) -0.005(5) C28A 0.227(18) 0.172(15) 0.175(15) 0.062(12) 0.040(13) -0.023(14) C29A 0.179(15) 0.191(15) 0.150(16) -0.007(12) 0.020(11) 0.020(13) C30A 0.147(14) 0.209(16) 0.099(12) -0.010(10) 0.003(10) -0.037(13) C31A 0.225(19) 0.170(14) 0.154(16) 0.029(11) 0.015(15) -0.045(16) C32A 0.194(17) 0.200(17) 0.146(16) 0.015(14) 0.038(12) 0.012(13) C33A 0.199(18) 0.230(18) 0.124(13) 0.016(13) 0.060(12) -0.002(16) C28B 0.21(2) 0.22(2) 0.135(14) -0.023(15) -0.004(15) 0.003(19) C29B 0.169(17) 0.20(2) 0.138(17) -0.005(16) -0.003(14) 0.003(15) C30B 0.175(16) 0.21(2) 0.148(16) -0.054(17) -0.019(16) -0.043(15) C31B 0.180(16) 0.222(17) 0.180(19) -0.042(17) -0.012(16) -0.047(19) C32B 0.191(19) 0.212(17) 0.150(16) -0.013(17) -0.018(16) -0.028(16) C33B 0.203(19) 0.180(19) 0.137(16) -0.007(15) 0.024(17) 0.011(16) _geom_special_details ; All esds (except the esd in the dihedral angle between two l.s. planes) are estimated using the full covariance matrix. The cell esds are taken into account individually in the estimation of esds in distances, angles and torsion angles; correlations between esds in cell parameters are only used when they are defined by crystal symmetry. An approximate (isotropic) treatment of cell esds is used for estimating esds involving l.s. planes. ; loop_ _geom_bond_atom_site_label_1 _geom_bond_atom_site_label_2 _geom_bond_distance _geom_bond_site_symmetry_2 _geom_bond_publ_flag Pt N2 1.962(5) . ? Pt C1' 1.967(7) . ? Pt N3 2.016(5) . ? Pt N1 2.020(5) . ? N1 C5 1.330(8) . ? N1 C1 1.370(8) . ? N2 C6 1.337(8) . ? N2 C10 1.350(8) . ? N3 C15 1.337(8) . ? N3 C11 1.378(8) . ? C1 C2 1.369(9) . ? C1 C6 1.478(9) . ? C2 C3 1.387(9) . ? C2 H2 0.9300 . ? C3 C4 1.376(10) . ? C3 C16 1.544(10) . ? C4 C5 1.373(10) . ? C4 H4 0.9300 . ? C5 H5 0.9300 . ? C16 C17 1.511(12) . ? C16 C18 1.517(11) . ? C16 C19 1.519(11) . ? C17 H17A 0.9600 . ? C17 H17B 0.9600 . ? C17 H17C 0.9600 . ? C18 H18A 0.9600 . ? C18 H18B 0.9600 . ? C18 H18C 0.9600 . ? C19 H19A 0.9600 . ? C19 H19B 0.9600 . ? C19 H19C 0.9600 . ? C6 C7 1.369(8) . ? C7 C8 1.390(9) . ? C7 H7 0.9300 . ? C8 C9 1.399(9) . ? C8 C20 1.552(9) . ? C9 C10 1.377(9) . ? C9 H9 0.9300 . ? C10 C11 1.479(9) . ? C20 C23A 1.510(11) . ? C20 C21A 1.515(11) . ? C20 C22B 1.526(15) . ? C20 C23B 1.534(16) . ? C20 C21B 1.551(16) . ? C20 C22A 1.553(12) . ? C21A H21A 0.9600 . ? C21A H21B 0.9600 . ? C21A H21C 0.9600 . ? C22A H22A 0.9600 . ? C22A H22B 0.9600 . ? C22A H22C 0.9600 . ? C23A H23A 0.9600 . ? C23A H23B 0.9600 . ? C23A H23C 0.9600 . ? C21B H21D 0.9600 . ? C21B H21E 0.9600 . ? C21B H21F 0.9600 . ? C22B H22D 0.9600 . ? C22B H22E 0.9600 . ? C22B H22F 0.9600 . ? C23B H23D 0.9600 . ? C23B H23E 0.9600 . ? C23B H23F 0.9600 . ? C11 C12 1.386(9) . ? C12 C13 1.384(9) . ? C12 H12 0.9300 . ? C13 C14 1.375(10) . ? C13 C24 1.511(10) . ? C14 C15 1.391(10) . ? C14 H14 0.9300 . ? C15 H15 0.9300 . ? C24 C27 1.506(12) . ? C24 C26 1.521(9) . ? C24 C25 1.536(12) . ? C25 H25A 0.9600 . ? C25 H25B 0.9600 . ? C25 H25C 0.9600 . ? C26 H26A 0.9600 . ? C26 H26B 0.9600 . ? C26 H26C 0.9600 . ? C27 H27A 0.9600 . ? C27 H27B 0.9600 . ? C27 H27C 0.9600 . ? C1' C2' 1.195(10) . ? C2' Si 1.833(10) . ? Si C5' 1.810(13) . ? Si C3' 1.860(9) . ? Si C4' 1.868(12) . ? C3' C6' 1.536(13) . ? C3' H3'1 0.9700 . ? C3' H3'2 0.9700 . ? C4' C7' 1.538(15) . ? C4' H4'1 0.9700 . ? C4' H4'2 0.9700 . ? C5' C8' 1.509(16) . ? C5' H5'1 0.9700 . ? C5' H5'2 0.9700 . ? C6' H6'1 0.9600 . ? C6' H6'2 0.9600 . ? C6' H6'3 0.9600 . ? C7' H7'1 0.9600 . ? C7' H7'2 0.9600 . ? C7' H7'3 0.9600 . ? C8' H8'1 0.9600 . ? C8' H8'2 0.9600 . ? C8' H8'3 0.9600 . ? B F2 1.309(10) . ? B F1 1.334(11) . ? B F4 1.343(11) . ? B F3 1.384(11) . ? C28A C29A 1.480(15) . ? C28A C33A 1.525(15) . ? C28A H28A 0.9700 . ? C28A H28B 0.9700 . ? C29A C30A 1.559(15) . ? C29A H29A 0.9700 . ? C29A H29B 0.9700 . ? C30A C31A 1.494(15) . ? C30A H30A 0.9700 . ? C30A H30B 0.9700 . ? C31A C32A 1.553(15) . ? C31A H31A 0.9700 . ? C31A H31B 0.9700 . ? C32A C33A 1.535(15) . ? C32A H32A 0.9700 . ? C32A H32B 0.9700 . ? C33A H33A 0.9700 . ? C33A H33B 0.9700 . ? C28B C29B 1.491(15) . ? C28B C33B 1.522(16) . ? C28B H28C 0.9700 . ? C28B H28D 0.9700 . ? C29B C30B 1.564(16) . ? C29B H29C 0.9700 . ? C29B H29D 0.9700 . ? C30B C31B 1.515(16) . ? C30B H30C 0.9700 . ? C30B H30D 0.9700 . ? C31B C32B 1.558(16) . ? C31B H31C 0.9700 . ? C31B H31D 0.9700 . ? C32B C33B 1.538(15) . ? C32B H32C 0.9700 . ? C32B H32D 0.9700 . ? C33B H33C 0.9700 . ? C33B H33D 0.9700 . ? loop_ _geom_angle_atom_site_label_1 _geom_angle_atom_site_label_2 _geom_angle_atom_site_label_3 _geom_angle _geom_angle_site_symmetry_1 _geom_angle_site_symmetry_3 _geom_angle_publ_flag N2 Pt C1' 178.1(2) . . ? N2 Pt N3 81.0(2) . . ? C1' Pt N3 100.8(2) . . ? N2 Pt N1 80.0(2) . . ? C1' Pt N1 98.1(2) . . ? N3 Pt N1 160.9(2) . . ? C5 N1 C1 118.4(6) . . ? C5 N1 Pt 127.5(5) . . ? C1 N1 Pt 114.1(4) . . ? C6 N2 C10 123.3(5) . . ? C6 N2 Pt 118.8(4) . . ? C10 N2 Pt 117.8(4) . . ? C15 N3 C11 118.4(6) . . ? C15 N3 Pt 128.2(5) . . ? C11 N3 Pt 113.2(4) . . ? C2 C1 N1 120.7(6) . . ? C2 C1 C6 124.6(6) . . ? N1 C1 C6 114.8(5) . . ? C1 C2 C3 121.0(6) . . ? C1 C2 H2 119.5 . . ? C3 C2 H2 119.5 . . ? C4 C3 C2 117.2(6) . . ? C4 C3 C16 122.9(7) . . ? C2 C3 C16 119.9(7) . . ? C5 C4 C3 120.3(7) . . ? C5 C4 H4 119.9 . . ? C3 C4 H4 119.9 . . ? N1 C5 C4 122.5(7) . . ? N1 C5 H5 118.8 . . ? C4 C5 H5 118.8 . . ? C17 C16 C18 107.9(8) . . ? C17 C16 C19 109.7(7) . . ? C18 C16 C19 109.7(8) . . ? C17 C16 C3 111.6(7) . . ? C18 C16 C3 109.1(6) . . ? C19 C16 C3 108.8(6) . . ? C16 C17 H17A 109.5 . . ? C16 C17 H17B 109.5 . . ? H17A C17 H17B 109.5 . . ? C16 C17 H17C 109.5 . . ? H17A C17 H17C 109.5 . . ? H17B C17 H17C 109.5 . . ? C16 C18 H18A 109.5 . . ? C16 C18 H18B 109.5 . . ? H18A C18 H18B 109.5 . . ? C16 C18 H18C 109.5 . . ? H18A C18 H18C 109.5 . . ? H18B C18 H18C 109.5 . . ? C16 C19 H19A 109.5 . . ? C16 C19 H19B 109.5 . . ? H19A C19 H19B 109.5 . . ? C16 C19 H19C 109.5 . . ? H19A C19 H19C 109.5 . . ? H19B C19 H19C 109.5 . . ? N2 C6 C7 119.8(6) . . ? N2 C6 C1 112.3(5) . . ? C7 C6 C1 127.9(6) . . ? C6 C7 C8 119.1(6) . . ? C6 C7 H7 120.5 . . ? C8 C7 H7 120.5 . . ? C7 C8 C9 119.7(6) . . ? C7 C8 C20 120.1(6) . . ? C9 C8 C20 120.2(6) . . ? C10 C9 C8 119.3(6) . . ? C10 C9 H9 120.4 . . ? C8 C9 H9 120.4 . . ? N2 C10 C9 118.7(6) . . ? N2 C10 C11 112.4(5) . . ? C9 C10 C11 128.9(6) . . ? C23A C20 C21A 110.5(9) . . ? C23A C20 C22B 48.0(11) . . ? C21A C20 C22B 144.0(13) . . ? C23A C20 C23B 129.9(14) . . ? C21A C20 C23B 60.9(15) . . ? C22B C20 C23B 107.5(13) . . ? C23A C20 C21B 61.0(13) . . ? C21A C20 C21B 52.7(14) . . ? C22B C20 C21B 107.6(13) . . ? C23B C20 C21B 106.4(13) . . ? C23A C20 C8 112.7(8) . . ? C21A C20 C8 108.4(7) . . ? C22B C20 C8 107.1(11) . . ? C23B C20 C8 116.7(13) . . ? C21B C20 C8 111.2(13) . . ? C23A C20 C22A 110.6(9) . . ? C21A C20 C22A 107.1(9) . . ? C22B C20 C22A 67.4(12) . . ? C23B C20 C22A 46.3(15) . . ? C21B C20 C22A 140.4(14) . . ? C8 C20 C22A 107.5(8) . . ? C20 C21A H21A 109.5 . . ? C20 C21A H21B 109.5 . . ? H21A C21A H21B 109.5 . . ? C20 C21A H21C 109.5 . . ? H21A C21A H21C 109.5 . . ? H21B C21A H21C 109.5 . . ? C20 C22A H22A 109.5 . . ? C20 C22A H22B 109.5 . . ? H22A C22A H22B 109.5 . . ? C20 C22A H22C 109.5 . . ? H22A C22A H22C 109.5 . . ? H22B C22A H22C 109.5 . . ? C20 C23A H23A 109.5 . . ? C20 C23A H23B 109.5 . . ? H23A C23A H23B 109.5 . . ? C20 C23A H23C 109.5 . . ? H23A C23A H23C 109.5 . . ? H23B C23A H23C 109.5 . . ? C20 C21B H21D 109.5 . . ? C20 C21B H21E 109.5 . . ? H21D C21B H21E 109.5 . . ? C20 C21B H21F 109.5 . . ? H21D C21B H21F 109.5 . . ? H21E C21B H21F 109.5 . . ? C20 C22B H22D 109.5 . . ? C20 C22B H22E 109.5 . . ? H22D C22B H22E 109.5 . . ? C20 C22B H22F 109.5 . . ? H22D C22B H22F 109.5 . . ? H22E C22B H22F 109.5 . . ? C20 C23B H23D 109.5 . . ? C20 C23B H23E 109.5 . . ? H23D C23B H23E 109.5 . . ? C20 C23B H23F 109.5 . . ? H23D C23B H23F 109.5 . . ? H23E C23B H23F 109.5 . . ? N3 C11 C12 120.9(6) . . ? N3 C11 C10 115.3(5) . . ? C12 C11 C10 123.7(6) . . ? C13 C12 C11 121.3(7) . . ? C13 C12 H12 119.4 . . ? C11 C12 H12 119.4 . . ? C14 C13 C12 116.1(6) . . ? C14 C13 C24 121.6(7) . . ? C12 C13 C24 122.1(7) . . ? C13 C14 C15 122.1(7) . . ? C13 C14 H14 119.0 . . ? C15 C14 H14 119.0 . . ? N3 C15 C14 121.1(7) . . ? N3 C15 H15 119.5 . . ? C14 C15 H15 119.5 . . ? C27 C24 C13 111.5(6) . . ? C27 C24 C26 109.4(8) . . ? C13 C24 C26 106.9(6) . . ? C27 C24 C25 108.7(7) . . ? C13 C24 C25 111.8(7) . . ? C26 C24 C25 108.4(7) . . ? C24 C25 H25A 109.5 . . ? C24 C25 H25B 109.5 . . ? H25A C25 H25B 109.5 . . ? C24 C25 H25C 109.5 . . ? H25A C25 H25C 109.5 . . ? H25B C25 H25C 109.5 . . ? C24 C26 H26A 109.5 . . ? C24 C26 H26B 109.5 . . ? H26A C26 H26B 109.5 . . ? C24 C26 H26C 109.5 . . ? H26A C26 H26C 109.5 . . ? H26B C26 H26C 109.5 . . ? C24 C27 H27A 109.5 . . ? C24 C27 H27B 109.5 . . ? H27A C27 H27B 109.5 . . ? C24 C27 H27C 109.5 . . ? H27A C27 H27C 109.5 . . ? H27B C27 H27C 109.5 . . ? C2' C1' Pt 170.3(7) . . ? C1' C2' Si 173.1(9) . . ? C5' Si C2' 111.5(7) . . ? C5' Si C3' 112.3(7) . . ? C2' Si C3' 107.4(4) . . ? C5' Si C4' 105.9(8) . . ? C2' Si C4' 108.1(5) . . ? C3' Si C4' 111.6(7) . . ? C6' C3' Si 115.1(9) . . ? C6' C3' H3'1 108.5 . . ? Si C3' H3'1 108.5 . . ? C6' C3' H3'2 108.5 . . ? Si C3' H3'2 108.5 . . ? H3'1 C3' H3'2 107.5 . . ? C7' C4' Si 114.6(10) . . ? C7' C4' H4'1 108.6 . . ? Si C4' H4'1 108.6 . . ? C7' C4' H4'2 108.6 . . ? Si C4' H4'2 108.6 . . ? H4'1 C4' H4'2 107.6 . . ? C8' C5' Si 112.7(13) . . ? C8' C5' H5'1 109.0 . . ? Si C5' H5'1 109.0 . . ? C8' C5' H5'2 109.0 . . ? Si C5' H5'2 109.0 . . ? H5'1 C5' H5'2 107.8 . . ? C3' C6' H6'1 109.5 . . ? C3' C6' H6'2 109.5 . . ? H6'1 C6' H6'2 109.5 . . ? C3' C6' H6'3 109.5 . . ? H6'1 C6' H6'3 109.5 . . ? H6'2 C6' H6'3 109.5 . . ? C4' C7' H7'1 109.5 . . ? C4' C7' H7'2 109.5 . . ? H7'1 C7' H7'2 109.5 . . ? C4' C7' H7'3 109.5 . . ? H7'1 C7' H7'3 109.5 . . ? H7'2 C7' H7'3 109.5 . . ? C5' C8' H8'1 109.5 . . ? C5' C8' H8'2 109.5 . . ? H8'1 C8' H8'2 109.5 . . ? C5' C8' H8'3 109.5 . . ? H8'1 C8' H8'3 109.5 . . ? H8'2 C8' H8'3 109.5 . . ? F2 B F1 114.6(10) . . ? F2 B F4 110.5(9) . . ? F1 B F4 110.8(9) . . ? F2 B F3 109.8(9) . . ? F1 B F3 106.4(9) . . ? F4 B F3 104.1(10) . . ? C29A C28A C33A 114.1(17) . . ? C29A C28A H28A 108.7 . . ? C33A C28A H28A 108.7 . . ? C29A C28A H28B 108.7 . . ? C33A C28A H28B 108.7 . . ? H28A C28A H28B 107.6 . . ? C28A C29A C30A 113.1(17) . . ? C28A C29A H29A 109.0 . . ? C30A C29A H29A 109.0 . . ? C28A C29A H29B 109.0 . . ? C30A C29A H29B 109.0 . . ? H29A C29A H29B 107.8 . . ? C31A C30A C29A 107(2) . . ? C31A C30A H30A 110.3 . . ? C29A C30A H30A 110.3 . . ? C31A C30A H30B 110.3 . . ? C29A C30A H30B 110.3 . . ? H30A C30A H30B 108.6 . . ? C30A C31A C32A 90.8(18) . . ? C30A C31A H31A 113.5 . . ? C32A C31A H31A 113.5 . . ? C30A C31A H31B 113.5 . . ? C32A C31A H31B 113.5 . . ? H31A C31A H31B 110.8 . . ? C33A C32A C31A 103.3(19) . . ? C33A C32A H32A 111.1 . . ? C31A C32A H32A 111.1 . . ? C33A C32A H32B 111.1 . . ? C31A C32A H32B 111.1 . . ? H32A C32A H32B 109.1 . . ? C28A C33A C32A 107.8(19) . . ? C28A C33A H33A 110.1 . . ? C32A C33A H33A 110.1 . . ? C28A C33A H33B 110.1 . . ? C32A C33A H33B 110.1 . . ? H33A C33A H33B 108.5 . . ? C29B C28B C33B 119(2) . . ? C29B C28B H28C 107.5 . . ? C33B C28B H28C 107.5 . . ? C29B C28B H28D 107.5 . . ? C33B C28B H28D 107.5 . . ? H28C C28B H28D 107.0 . . ? C28B C29B C30B 111(2) . . ? C28B C29B H29C 109.5 . . ? C30B C29B H29C 109.5 . . ? C28B C29B H29D 109.6 . . ? C30B C29B H29D 109.5 . . ? H29C C29B H29D 108.1 . . ? C31B C30B C29B 101(2) . . ? C31B C30B H30C 111.6 . . ? C29B C30B H30C 111.6 . . ? C31B C30B H30D 111.6 . . ? C29B C30B H30D 111.6 . . ? H30C C30B H30D 109.4 . . ? C30B C31B C32B 86(2) . . ? C30B C31B H31C 114.3 . . ? C32B C31B H31C 114.3 . . ? C30B C31B H31D 114.3 . . ? C32B C31B H31D 114.3 . . ? H31C C31B H31D 111.5 . . ? C33B C32B C31B 104(2) . . ? C33B C32B H32C 111.0 . . ? C31B C32B H32C 111.0 . . ? C33B C32B H32D 111.1 . . ? C31B C32B H32D 111.0 . . ? H32C C32B H32D 109.0 . . ? C28B C33B C32B 111(2) . . ? C28B C33B H33C 109.4 . . ? C32B C33B H33C 109.4 . . ? C28B C33B H33D 109.4 . . ? C32B C33B H33D 109.4 . . ? H33C C33B H33D 108.0 . . ? loop_ _geom_torsion_atom_site_label_1 _geom_torsion_atom_site_label_2 _geom_torsion_atom_site_label_3 _geom_torsion_atom_site_label_4 _geom_torsion _geom_torsion_site_symmetry_1 _geom_torsion_site_symmetry_2 _geom_torsion_site_symmetry_3 _geom_torsion_site_symmetry_4 _geom_torsion_publ_flag N2 Pt N1 C5 179.8(6) . . . . ? C1' Pt N1 C5 0.0(6) . . . . ? N3 Pt N1 C5 173.4(5) . . . . ? N2 Pt N1 C1 0.6(4) . . . . ? C1' Pt N1 C1 -179.2(4) . . . . ? N3 Pt N1 C1 -5.8(8) . . . . ? C1' Pt N2 C6 8(7) . . . . ? N3 Pt N2 C6 179.4(4) . . . . ? N1 Pt N2 C6 1.5(4) . . . . ? C1' Pt N2 C10 -173(7) . . . . ? N3 Pt N2 C10 -1.5(4) . . . . ? N1 Pt N2 C10 -179.4(4) . . . . ? N2 Pt N3 C15 -176.0(5) . . . . ? C1' Pt N3 C15 3.7(6) . . . . ? N1 Pt N3 C15 -169.6(5) . . . . ? N2 Pt N3 C11 -1.8(4) . . . . ? C1' Pt N3 C11 177.9(4) . . . . ? N1 Pt N3 C11 4.6(8) . . . . ? C5 N1 C1 C2 -1.6(9) . . . . ? Pt N1 C1 C2 177.7(5) . . . . ? C5 N1 C1 C6 178.4(5) . . . . ? Pt N1 C1 C6 -2.3(6) . . . . ? N1 C1 C2 C3 1.1(9) . . . . ? C6 C1 C2 C3 -178.9(6) . . . . ? C1 C2 C3 C4 -0.3(10) . . . . ? C1 C2 C3 C16 -180.0(6) . . . . ? C2 C3 C4 C5 0.0(10) . . . . ? C16 C3 C4 C5 179.7(7) . . . . ? C1 N1 C5 C4 1.3(10) . . . . ? Pt N1 C5 C4 -177.8(5) . . . . ? C3 C4 C5 N1 -0.5(11) . . . . ? C4 C3 C16 C17 7.8(11) . . . . ? C2 C3 C16 C17 -172.5(7) . . . . ? C4 C3 C16 C18 126.9(8) . . . . ? C2 C3 C16 C18 -53.4(10) . . . . ? C4 C3 C16 C19 -113.4(8) . . . . ? C2 C3 C16 C19 66.3(9) . . . . ? C10 N2 C6 C7 -3.5(8) . . . . ? Pt N2 C6 C7 175.5(4) . . . . ? C10 N2 C6 C1 177.9(5) . . . . ? Pt N2 C6 C1 -3.1(6) . . . . ? C2 C1 C6 N2 -176.5(6) . . . . ? N1 C1 C6 N2 3.5(7) . . . . ? C2 C1 C6 C7 5.0(10) . . . . ? N1 C1 C6 C7 -175.0(6) . . . . ? N2 C6 C7 C8 1.2(9) . . . . ? C1 C6 C7 C8 179.6(6) . . . . ? C6 C7 C8 C9 1.0(9) . . . . ? C6 C7 C8 C20 -179.7(6) . . . . ? C7 C8 C9 C10 -1.2(9) . . . . ? C20 C8 C9 C10 179.5(6) . . . . ? C6 N2 C10 C9 3.3(8) . . . . ? Pt N2 C10 C9 -175.8(4) . . . . ? C6 N2 C10 C11 -176.7(5) . . . . ? Pt N2 C10 C11 4.2(6) . . . . ? C8 C9 C10 N2 -0.9(8) . . . . ? C8 C9 C10 C11 179.1(6) . . . . ? C7 C8 C20 C23A 168.9(10) . . . . ? C9 C8 C20 C23A -11.8(12) . . . . ? C7 C8 C20 C21A -68.5(10) . . . . ? C9 C8 C20 C21A 110.8(9) . . . . ? C7 C8 C20 C22B 117.9(15) . . . . ? C9 C8 C20 C22B -62.8(15) . . . . ? C7 C8 C20 C23B -2(2) . . . . ? C9 C8 C20 C23B 176.8(19) . . . . ? C7 C8 C20 C21B -124.7(17) . . . . ? C9 C8 C20 C21B 54.6(17) . . . . ? C7 C8 C20 C22A 46.9(10) . . . . ? C9 C8 C20 C22A -133.8(9) . . . . ? C15 N3 C11 C12 3.0(8) . . . . ? Pt N3 C11 C12 -171.8(4) . . . . ? C15 N3 C11 C10 179.3(5) . . . . ? Pt N3 C11 C10 4.6(6) . . . . ? N2 C10 C11 N3 -5.7(7) . . . . ? C9 C10 C11 N3 174.3(6) . . . . ? N2 C10 C11 C12 170.5(5) . . . . ? C9 C10 C11 C12 -9.5(10) . . . . ? N3 C11 C12 C13 -0.6(9) . . . . ? C10 C11 C12 C13 -176.7(5) . . . . ? C11 C12 C13 C14 -2.6(9) . . . . ? C11 C12 C13 C24 173.1(6) . . . . ? C12 C13 C14 C15 3.6(9) . . . . ? C24 C13 C14 C15 -172.1(6) . . . . ? C11 N3 C15 C14 -2.0(8) . . . . ? Pt N3 C15 C14 171.9(4) . . . . ? C13 C14 C15 N3 -1.3(10) . . . . ? C14 C13 C24 C27 -154.5(7) . . . . ? C12 C13 C24 C27 30.1(9) . . . . ? C14 C13 C24 C26 85.9(8) . . . . ? C12 C13 C24 C26 -89.5(8) . . . . ? C14 C13 C24 C25 -32.6(9) . . . . ? C12 C13 C24 C25 152.0(7) . . . . ? N2 Pt C1' C2' 24(10) . . . . ? N3 Pt C1' C2' -148(4) . . . . ? N1 Pt C1' C2' 30(4) . . . . ? Pt C1' C2' Si 43(9) . . . . ? C1' C2' Si C5' -178(6) . . . . ? C1' C2' Si C3' -54(6) . . . . ? C1' C2' Si C4' 66(6) . . . . ? C5' Si C3' C6' -59.5(14) . . . . ? C2' Si C3' C6' 177.6(11) . . . . ? C4' Si C3' C6' 59.3(13) . . . . ? C5' Si C4' C7' -179.2(13) . . . . ? C2' Si C4' C7' -59.6(14) . . . . ? C3' Si C4' C7' 58.3(14) . . . . ? C2' Si C5' C8' 54.2(17) . . . . ? C3' Si C5' C8' -66.4(17) . . . . ? C4' Si C5' C8' 171.5(15) . . . . ? C33A C28A C29A C30A 33(4) . . . . ? C28A C29A C30A C31A -57(3) . . . . ? C29A C30A C31A C32A 79(2) . . . . ? C30A C31A C32A C33A -88(2) . . . . ? C29A C28A C33A C32A -40(4) . . . . ? C31A C32A C33A C28A 70(3) . . . . ? C33B C28B C29B C30B -5(6) . . . . ? C28B C29B C30B C31B 53(4) . . . . ? C29B C30B C31B C32B -93(3) . . . . ? C30B C31B C32B C33B 90(3) . . . . ? C29B C28B C33B C32B 2(6) . . . . ? C31B C32B C33B C28B -46(4) . . . . ? _diffrn_measured_fraction_theta_max 0.995 _diffrn_reflns_theta_full 23.33 _diffrn_measured_fraction_theta_full 0.995 _refine_diff_density_max 0.692 _refine_diff_density_min -0.843 _refine_diff_density_rms 0.097