data_publication_text _publ_requested_journal organ _publ_contact_author_name 'Prof. Cauzzi Daniele Alessandro' _publ_contact_author_address ;Dipartimento di Chimica "GIAF", Universit\`a di Parma, Parma, Italy ; _publ_contact_author_email cauzzi@unipr.it _publ_contact_author_phone '(+39) 0521 90 54 67' _publ_contact_author_fax '(+39) 0521 90 55 57' loop_ _publ_author_name _publ_author_address 'Cauzzi, Daniele Alessandro' ;Dipartimento di Chimica "GIAF, Universit\`a di Parma, Parma, Italy ; 'Delferro, Massimiliano' ;Dipartimento di Chimica "GIAF", Universit\`a di Parma, Parma, Italy ; 'Tegoni, Matteo' ;Dipartimento di Chimica "GIAF", Universit\`a di Parma, Parma, Italy ; 'Verdolino, Vincenzo' ;Dipartimento di Chimica "GIAF", Universit\`a di Parma, Parma, Italy ; 'Graiff, Claudia' ;Dipartimento di Chimica "GIAF", Universit\`a di Parma, Parma, Italy ; 'Tiripicchio, Antonio' ;Dipartimento di Chimica "GIAF", Universit\`a di Parma, Parma, Italy ; data_sad _audit_creation_method SHELXL-97 _chemical_name_systematic ; ? ; _chemical_name_common ? _chemical_melting_point ? _chemical_formula_moiety ? _chemical_formula_sum 'C32 H33 I N3 O P2 Rh S2' _chemical_formula_weight 831.48 loop_ _atom_type_symbol _atom_type_description _atom_type_scat_dispersion_real _atom_type_scat_dispersion_imag _atom_type_scat_source 'C' 'C' 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' 'H' 'H' 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' 'I' 'I' -0.4742 1.8119 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' 'N' 'N' 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' 'P' 'P' 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' 'Rh' 'Rh' -1.1178 0.9187 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' 'S' 'S' 0.1246 0.1234 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' 'O' 'O' 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' _symmetry_cell_setting monoclinic _symmetry_space_group_name_H-M 'P21/n' loop_ _symmetry_equiv_pos_as_xyz 'x, y, z' '-x+1/2, y+1/2, -z+1/2' '-x, -y, -z' 'x-1/2, -y-1/2, z-1/2' _cell_length_a 10.2202(10) _cell_length_b 17.1021(17) _cell_length_c 19.943(2) _cell_angle_alpha 90.00 _cell_angle_beta 99.151(2) _cell_angle_gamma 90.00 _cell_volume 3441.5(6) _cell_formula_units_Z 4 _cell_measurement_temperature 293(2) _cell_measurement_reflns_used 711 _cell_measurement_theta_min 2.25 _cell_measurement_theta_max 21 _exptl_crystal_description prism _exptl_crystal_colour red _exptl_crystal_size_max 0.10 _exptl_crystal_size_mid 0.10 _exptl_crystal_size_min 0.10 _exptl_crystal_density_meas ? _exptl_crystal_density_diffrn 1.605 _exptl_crystal_density_method 'not measured' _exptl_crystal_F_000 1656 _exptl_absorpt_coefficient_mu 1.637 _exptl_absorpt_correction_type 'multi-scan' _exptl_absorpt_correction_T_min 0.839 _exptl_absorpt_correction_T_max 1.000 _exptl_absorpt_process_details 'sadabs Bruker' _exptl_special_details ; ? ; _diffrn_ambient_temperature 293(2) _diffrn_radiation_wavelength 0.71073 _diffrn_radiation_type MoK\a _diffrn_radiation_source 'fine-focus sealed tube' _diffrn_radiation_monochromator graphite _diffrn_measurement_device_type 'Bruker AXS Smart 1000' _diffrn_measurement_method 'omega scan' _diffrn_detector_area_resol_mean ? _diffrn_standards_number ? _diffrn_standards_interval_count ? _diffrn_standards_interval_time ? _diffrn_standards_decay_% ? _diffrn_reflns_number 42555 _diffrn_reflns_av_R_equivalents 0.0459 _diffrn_reflns_av_sigmaI/netI 0.0444 _diffrn_reflns_limit_h_min -13 _diffrn_reflns_limit_h_max 13 _diffrn_reflns_limit_k_min -22 _diffrn_reflns_limit_k_max 22 _diffrn_reflns_limit_l_min -26 _diffrn_reflns_limit_l_max 26 _diffrn_reflns_theta_min 1.58 _diffrn_reflns_theta_max 28.03 _reflns_number_total 8298 _reflns_number_gt 5383 _reflns_threshold_expression >2sigma(I) _computing_data_collection 'Software Bruker' _computing_cell_refinement 'Software Bruker' _computing_data_reduction 'saint' _computing_structure_solution 'SHELXS' _computing_structure_refinement 'SHELXL-97 (Sheldrick, 1997)' _computing_molecular_graphics ? _computing_publication_material ? _refine_special_details ; Refinement of F^2^ against ALL reflections. The weighted R-factor wR and goodness of fit S are based on F^2^, conventional R-factors R are based on F, with F set to zero for negative F^2^. The threshold expression of F^2^ > 2sigma(F^2^) is used only for calculating R-factors(gt) etc. and is not relevant to the choice of reflections for refinement. R-factors based on F^2^ are statistically about twice as large as those based on F, and R- factors based on ALL data will be even larger. ; _refine_ls_structure_factor_coef Fsqd _refine_ls_matrix_type full _refine_ls_weighting_scheme calc _refine_ls_weighting_details 'calc w=1/[\s^2^(Fo^2^)+(0.0556P)^2^+0.0000P] where P=(Fo^2^+2Fc^2^)/3' _atom_sites_solution_primary direct _atom_sites_solution_secondary difmap _atom_sites_solution_hydrogens geom _refine_ls_hydrogen_treatment constr _refine_ls_extinction_method none _refine_ls_extinction_coef ? _refine_ls_number_reflns 8298 _refine_ls_number_parameters 379 _refine_ls_number_restraints 0 _refine_ls_R_factor_all 0.0670 _refine_ls_R_factor_gt 0.0372 _refine_ls_wR_factor_ref 0.0998 _refine_ls_wR_factor_gt 0.0902 _refine_ls_goodness_of_fit_ref 0.910 _refine_ls_restrained_S_all 0.910 _refine_ls_shift/su_max 0.001 _refine_ls_shift/su_mean 0.000 loop_ _atom_site_label _atom_site_type_symbol _atom_site_fract_x _atom_site_fract_y _atom_site_fract_z _atom_site_U_iso_or_equiv _atom_site_adp_type _atom_site_occupancy _atom_site_symmetry_multiplicity _atom_site_calc_flag _atom_site_refinement_flags _atom_site_disorder_assembly _atom_site_disorder_group C1 C 0.9929(3) 0.1827(2) 0.43436(17) 0.0456(8) Uani 1 1 d . . . C2 C 0.8908(4) 0.3432(2) 0.19565(18) 0.0499(9) Uani 1 1 d . . . C3 C 0.9623(5) 0.1112(3) 0.5340(3) 0.0854(15) Uani 1 1 d . . . H3A H 0.9662 0.1617 0.5564 0.102 Uiso 1 1 calc R . . H3B H 1.0174 0.0748 0.5633 0.102 Uiso 1 1 calc R . . C4 C 0.8283(6) 0.0836(4) 0.5208(3) 0.120(2) Uani 1 1 d . . . H4A H 0.7944 0.0791 0.5629 0.179 Uiso 1 1 calc R . . H4B H 0.8258 0.0333 0.4992 0.179 Uiso 1 1 calc R . . H4C H 0.7749 0.1198 0.4915 0.179 Uiso 1 1 calc R . . C5 C 0.8577(6) 0.4286(3) 0.1021(3) 0.0934(17) Uani 1 1 d . . . H5A H 0.7904 0.4222 0.0623 0.112 Uiso 1 1 calc R . . H5B H 0.8209 0.4610 0.1344 0.112 Uiso 1 1 calc R . . C6 C 0.9695(7) 0.4660(5) 0.0833(5) 0.180(4) Uani 1 1 d . . . H6A H 0.9438 0.5160 0.0635 0.270 Uiso 1 1 calc R . . H6B H 1.0052 0.4343 0.0508 0.270 Uiso 1 1 calc R . . H6C H 1.0355 0.4733 0.1228 0.270 Uiso 1 1 calc R . . C7 C 1.0968(3) 0.0964(2) 0.32476(17) 0.0439(8) Uani 1 1 d . . . C8 C 0.9923(4) 0.0443(2) 0.3124(2) 0.0568(10) Uani 1 1 d . . . H8 H 0.9105 0.0575 0.3240 0.068 Uiso 1 1 calc R . . C9 C 1.0093(5) -0.0270(3) 0.2827(2) 0.0759(13) Uani 1 1 d . . . H9 H 0.9387 -0.0618 0.2741 0.091 Uiso 1 1 calc R . . C10 C 1.1299(5) -0.0467(3) 0.2659(3) 0.0865(15) Uani 1 1 d . . . H10 H 1.1413 -0.0951 0.2462 0.104 Uiso 1 1 calc R . . C11 C 1.2338(5) 0.0049(3) 0.2780(3) 0.0832(15) Uani 1 1 d . . . H11 H 1.3152 -0.0082 0.2658 0.100 Uiso 1 1 calc R . . C12 C 1.2187(4) 0.0746(2) 0.3074(2) 0.0597(10) Uani 1 1 d . . . H12 H 1.2904 0.1085 0.3162 0.072 Uiso 1 1 calc R . . C13 C 1.2368(3) 0.2295(2) 0.39040(16) 0.0442(8) Uani 1 1 d . . . C14 C 1.3123(4) 0.2627(2) 0.34582(19) 0.0603(11) Uani 1 1 d . . . H14 H 1.2760 0.2695 0.3004 0.072 Uiso 1 1 calc R . . C15 C 1.4414(4) 0.2860(3) 0.3688(2) 0.0725(13) Uani 1 1 d . . . H15 H 1.4923 0.3071 0.3385 0.087 Uiso 1 1 calc R . . C16 C 1.4935(4) 0.2781(3) 0.4347(2) 0.0822(15) Uani 1 1 d . . . H16 H 1.5796 0.2950 0.4500 0.099 Uiso 1 1 calc R . . C17 C 1.4210(5) 0.2455(3) 0.4792(2) 0.0875(16) Uani 1 1 d . . . H17 H 1.4579 0.2398 0.5247 0.105 Uiso 1 1 calc R . . C18 C 1.2935(4) 0.2210(3) 0.45687(19) 0.0682(12) Uani 1 1 d . . . H18 H 1.2450 0.1982 0.4874 0.082 Uiso 1 1 calc R . . C19 C 0.7669(3) 0.1953(2) 0.21609(18) 0.0455(8) Uani 1 1 d . . . C20 C 0.7113(4) 0.1729(2) 0.2722(2) 0.0560(10) Uani 1 1 d . . . H20 H 0.7565 0.1821 0.3158 0.067 Uiso 1 1 calc R . . C21 C 0.5882(4) 0.1369(3) 0.2632(2) 0.0705(12) Uani 1 1 d . . . H21 H 0.5506 0.1217 0.3006 0.085 Uiso 1 1 calc R . . C22 C 0.5221(4) 0.1238(3) 0.1989(3) 0.0776(14) Uani 1 1 d . . . H22 H 0.4410 0.0981 0.1932 0.093 Uiso 1 1 calc R . . C23 C 0.5729(4) 0.1477(3) 0.1433(2) 0.0763(14) Uani 1 1 d . . . H23 H 0.5256 0.1397 0.1001 0.092 Uiso 1 1 calc R . . C24 C 0.6958(4) 0.1840(3) 0.1516(2) 0.0635(11) Uani 1 1 d . . . H24 H 0.7307 0.2008 0.1138 0.076 Uiso 1 1 calc R . . C25 C 1.0295(3) 0.1981(2) 0.17482(16) 0.0440(8) Uani 1 1 d . . . C26 C 1.1372(4) 0.2406(2) 0.15917(18) 0.0538(9) Uani 1 1 d . . . H26 H 1.1549 0.2905 0.1768 0.065 Uiso 1 1 calc R . . C27 C 1.2172(4) 0.2077(3) 0.1172(2) 0.0701(13) Uani 1 1 d . . . H27 H 1.2886 0.2358 0.1060 0.084 Uiso 1 1 calc R . . C28 C 1.1923(5) 0.1346(4) 0.0921(2) 0.0791(15) Uani 1 1 d . . . H28 H 1.2472 0.1130 0.0640 0.095 Uiso 1 1 calc R . . C29 C 1.0889(5) 0.0926(3) 0.1072(2) 0.0769(14) Uani 1 1 d . . . H29 H 1.0729 0.0427 0.0893 0.092 Uiso 1 1 calc R . . C30 C 1.0061(4) 0.1238(2) 0.14955(19) 0.0589(10) Uani 1 1 d . . . H30 H 0.9358 0.0946 0.1606 0.071 Uiso 1 1 calc R . . C31 C 1.0711(4) 0.3993(2) 0.3722(2) 0.0643(11) Uani 1 1 d . . . C32 C 1.1126(5) 0.4309(3) 0.4412(3) 0.0970(18) Uani 1 1 d . . . H32A H 1.0466 0.4188 0.4689 0.146 Uiso 1 1 calc R . . H32B H 1.1226 0.4866 0.4387 0.146 Uiso 1 1 calc R . . H32C H 1.1955 0.4078 0.4607 0.146 Uiso 1 1 calc R . . I1 I 0.75481(3) 0.445595(16) 0.406388(15) 0.06635(11) Uani 1 1 d . . . N1 N 1.0105(4) 0.1180(2) 0.46659(18) 0.0676(10) Uani 1 1 d . . . N2 N 0.8930(4) 0.3515(2) 0.13253(17) 0.0709(10) Uani 1 1 d . . . N3 N 0.9882(3) 0.24977(16) 0.30706(13) 0.0414(6) Uani 1 1 d . . . P1 P 1.07527(8) 0.19062(5) 0.36003(4) 0.0391(2) Uani 1 1 d . . . P2 P 0.92462(9) 0.24388(5) 0.22713(4) 0.0408(2) Uani 1 1 d . . . Rh1 Rh 0.90268(3) 0.343484(16) 0.355372(13) 0.04391(9) Uani 1 1 d . . . S1 S 0.91471(11) 0.26832(6) 0.45418(5) 0.0563(3) Uani 1 1 d . . . S2 S 0.84142(14) 0.40798(7) 0.25270(5) 0.0743(3) Uani 1 1 d . . . O1 O 1.1369(3) 0.4063(2) 0.32827(19) 0.0950(11) Uani 1 1 d . . . loop_ _atom_site_aniso_label _atom_site_aniso_U_11 _atom_site_aniso_U_22 _atom_site_aniso_U_33 _atom_site_aniso_U_23 _atom_site_aniso_U_13 _atom_site_aniso_U_12 C1 0.049(2) 0.050(2) 0.0409(19) 0.0005(16) 0.0180(16) -0.0021(17) C2 0.049(2) 0.054(2) 0.048(2) 0.0001(17) 0.0106(17) 0.0060(17) C3 0.100(4) 0.074(3) 0.096(4) 0.027(3) 0.056(3) 0.005(3) C4 0.119(5) 0.125(5) 0.125(5) 0.003(4) 0.049(4) -0.003(4) C5 0.132(5) 0.091(4) 0.061(3) 0.026(3) 0.025(3) 0.027(4) C6 0.108(6) 0.149(7) 0.283(12) 0.116(7) 0.029(6) 0.001(5) C7 0.0413(19) 0.050(2) 0.0403(19) -0.0025(16) 0.0068(15) 0.0035(16) C8 0.052(2) 0.049(2) 0.070(3) -0.0069(19) 0.011(2) 0.0012(18) C9 0.073(3) 0.059(3) 0.092(3) -0.017(2) 0.002(3) -0.011(2) C10 0.081(4) 0.069(3) 0.109(4) -0.036(3) 0.012(3) 0.011(3) C11 0.067(3) 0.097(4) 0.088(3) -0.030(3) 0.020(3) 0.018(3) C12 0.047(2) 0.068(3) 0.065(3) -0.016(2) 0.0141(19) -0.0004(19) C13 0.045(2) 0.050(2) 0.0371(18) 0.0015(15) 0.0036(15) -0.0043(16) C14 0.054(2) 0.080(3) 0.046(2) 0.015(2) 0.0035(18) -0.013(2) C15 0.052(2) 0.095(3) 0.069(3) 0.022(3) 0.004(2) -0.021(2) C16 0.054(3) 0.117(4) 0.069(3) 0.011(3) -0.010(2) -0.027(3) C17 0.066(3) 0.142(5) 0.046(2) 0.011(3) -0.016(2) -0.024(3) C18 0.064(3) 0.098(3) 0.041(2) 0.011(2) 0.0051(19) -0.018(2) C19 0.0370(19) 0.054(2) 0.045(2) -0.0046(17) 0.0064(16) 0.0005(16) C20 0.046(2) 0.067(3) 0.056(2) -0.0004(19) 0.0099(18) -0.0030(19) C21 0.047(2) 0.091(3) 0.076(3) 0.014(3) 0.019(2) -0.004(2) C22 0.040(2) 0.085(3) 0.104(4) 0.004(3) -0.001(3) -0.007(2) C23 0.048(3) 0.106(4) 0.071(3) -0.010(3) -0.004(2) -0.006(2) C24 0.050(2) 0.089(3) 0.051(2) -0.005(2) 0.0061(19) -0.004(2) C25 0.0401(19) 0.060(2) 0.0332(17) 0.0006(16) 0.0099(14) 0.0053(16) C26 0.045(2) 0.071(3) 0.046(2) 0.0053(19) 0.0077(17) 0.0030(19) C27 0.050(2) 0.108(4) 0.056(3) 0.012(3) 0.018(2) 0.008(2) C28 0.063(3) 0.126(5) 0.052(3) -0.005(3) 0.020(2) 0.035(3) C29 0.077(3) 0.086(3) 0.067(3) -0.030(3) 0.009(2) 0.017(3) C30 0.057(2) 0.069(3) 0.051(2) -0.015(2) 0.0094(19) 0.003(2) C31 0.071(3) 0.048(2) 0.078(3) 0.002(2) 0.025(2) -0.003(2) C32 0.080(4) 0.105(4) 0.104(4) -0.042(3) 0.007(3) -0.036(3) I1 0.0809(2) 0.05574(17) 0.06900(19) -0.00673(13) 0.03218(15) 0.00850(14) N1 0.090(3) 0.059(2) 0.063(2) 0.0103(18) 0.0401(19) 0.0078(19) N2 0.101(3) 0.067(2) 0.0467(19) 0.0094(17) 0.0201(19) 0.016(2) N3 0.0447(16) 0.0473(16) 0.0328(14) -0.0035(12) 0.0076(12) 0.0030(13) P1 0.0394(5) 0.0445(5) 0.0346(4) -0.0008(4) 0.0096(4) -0.0030(4) P2 0.0392(5) 0.0501(5) 0.0339(4) -0.0036(4) 0.0085(4) 0.0007(4) Rh1 0.05151(17) 0.04293(16) 0.03977(15) -0.00422(12) 0.01490(12) -0.00057(13) S1 0.0762(7) 0.0523(6) 0.0475(5) 0.0005(4) 0.0315(5) 0.0032(5) S2 0.1093(10) 0.0647(7) 0.0496(6) 0.0031(5) 0.0153(6) 0.0357(7) O1 0.085(2) 0.097(3) 0.113(3) 0.021(2) 0.045(2) -0.017(2) _geom_special_details ; All esds (except the esd in the dihedral angle between two l.s. planes) are estimated using the full covariance matrix. The cell esds are taken into account individually in the estimation of esds in distances, angles and torsion angles; correlations between esds in cell parameters are only used when they are defined by crystal symmetry. An approximate (isotropic) treatment of cell esds is used for estimating esds involving l.s. planes. ; loop_ _geom_bond_atom_site_label_1 _geom_bond_atom_site_label_2 _geom_bond_distance _geom_bond_site_symmetry_2 _geom_bond_publ_flag C1 N1 1.278(5) . ? C1 S1 1.743(4) . ? C1 P1 1.822(3) . ? C2 N2 1.271(5) . ? C2 S2 1.721(4) . ? C2 P2 1.824(4) . ? C3 N1 1.508(5) . ? C3 C4 1.433(7) . ? C5 C6 1.412(8) . ? C5 N2 1.472(6) . ? C7 C8 1.382(5) . ? C7 C12 1.396(5) . ? C7 P1 1.786(4) . ? C8 C9 1.379(6) . ? C9 C10 1.370(6) . ? C10 C11 1.374(7) . ? C11 C12 1.347(6) . ? C13 C18 1.368(5) . ? C13 C14 1.388(5) . ? C13 P1 1.793(3) . ? C14 C15 1.384(5) . ? C15 C16 1.345(6) . ? C16 C17 1.363(6) . ? C17 C18 1.374(6) . ? C19 C24 1.386(5) . ? C19 C20 1.387(5) . ? C19 P2 1.796(3) . ? C20 C21 1.387(5) . ? C21 C22 1.369(6) . ? C22 C23 1.359(6) . ? C23 C24 1.388(6) . ? C25 C30 1.374(5) . ? C25 C26 1.396(5) . ? C25 P2 1.791(3) . ? C26 C27 1.380(5) . ? C27 C28 1.356(7) . ? C28 C29 1.350(7) . ? C29 C30 1.393(6) . ? C31 O1 1.194(5) . ? C31 C32 1.475(6) . ? C31 Rh1 1.950(4) . ? I1 Rh1 2.6187(4) . ? N3 P2 1.626(3) . ? N3 P1 1.622(3) . ? N3 Rh1 2.128(3) . ? Rh1 S2 2.3224(11) . ? Rh1 S1 2.3396(10) . ? loop_ _geom_angle_atom_site_label_1 _geom_angle_atom_site_label_2 _geom_angle_atom_site_label_3 _geom_angle _geom_angle_site_symmetry_1 _geom_angle_site_symmetry_3 _geom_angle_publ_flag N1 C1 S1 130.3(3) . . ? N1 C1 P1 115.3(3) . . ? S1 C1 P1 114.2(2) . . ? N2 C2 S2 129.5(3) . . ? N2 C2 P2 114.4(3) . . ? S2 C2 P2 115.6(2) . . ? N1 C3 C4 107.5(5) . . ? C6 C5 N2 111.1(5) . . ? C8 C7 C12 118.6(3) . . ? C8 C7 P1 120.7(3) . . ? C12 C7 P1 120.6(3) . . ? C9 C8 C7 120.0(4) . . ? C8 C9 C10 120.2(4) . . ? C11 C10 C9 120.0(4) . . ? C10 C11 C12 120.4(4) . . ? C11 C12 C7 120.9(4) . . ? C18 C13 C14 118.1(3) . . ? C18 C13 P1 120.9(3) . . ? C14 C13 P1 120.7(3) . . ? C15 C14 C13 120.2(4) . . ? C16 C15 C14 120.2(4) . . ? C15 C16 C17 120.5(4) . . ? C16 C17 C18 119.9(4) . . ? C13 C18 C17 121.1(4) . . ? C24 C19 C20 119.3(3) . . ? C24 C19 P2 120.4(3) . . ? C20 C19 P2 120.2(3) . . ? C19 C20 C21 119.8(4) . . ? C22 C21 C20 119.8(4) . . ? C23 C22 C21 121.3(4) . . ? C22 C23 C24 119.5(4) . . ? C19 C24 C23 120.3(4) . . ? C30 C25 C26 119.8(3) . . ? C30 C25 P2 122.2(3) . . ? C26 C25 P2 118.0(3) . . ? C27 C26 C25 119.2(4) . . ? C28 C27 C26 120.3(4) . . ? C27 C28 C29 121.1(4) . . ? C28 C29 C30 120.2(5) . . ? C25 C30 C29 119.3(4) . . ? O1 C31 C32 122.4(4) . . ? O1 C31 Rh1 120.5(4) . . ? C32 C31 Rh1 117.1(3) . . ? C1 N1 C3 118.4(3) . . ? C2 N2 C5 117.9(4) . . ? P2 N3 P1 133.79(18) . . ? P2 N3 Rh1 111.19(14) . . ? P1 N3 Rh1 113.39(14) . . ? N3 P1 C7 113.30(15) . . ? N3 P1 C13 111.65(16) . . ? C7 P1 C13 107.63(17) . . ? N3 P1 C1 107.43(16) . . ? C7 P1 C1 110.80(17) . . ? C13 P1 C1 105.79(16) . . ? N3 P2 C25 114.54(15) . . ? N3 P2 C19 111.09(15) . . ? C25 P2 C19 109.58(17) . . ? N3 P2 C2 107.70(16) . . ? C25 P2 C2 107.75(16) . . ? C19 P2 C2 105.74(17) . . ? C31 Rh1 N3 91.83(14) . . ? C31 Rh1 S2 91.51(14) . . ? N3 Rh1 S2 91.78(8) . . ? C31 Rh1 S1 101.36(14) . . ? N3 Rh1 S1 89.84(8) . . ? S2 Rh1 S1 166.97(5) . . ? C31 Rh1 I1 98.89(12) . . ? N3 Rh1 I1 169.14(7) . . ? S2 Rh1 I1 86.25(3) . . ? S1 Rh1 I1 89.74(3) . . ? C1 S1 Rh1 103.60(12) . . ? C2 S2 Rh1 102.16(13) . . ? _diffrn_measured_fraction_theta_max 0.994 _diffrn_reflns_theta_full 28.03 _diffrn_measured_fraction_theta_full 0.994 _refine_diff_density_max 1.193 _refine_diff_density_min -0.739 _refine_diff_density_rms 0.081