High Accuracy Measurements of OH Reaction Rate Constants and IR Absorption Spectra: Substituted 2-Propanols.

Vladimir L. Orkin*, Victor G. Khamaganov, and Michael J. Kurylo 

National Institute of Standards and Technology, Gaithersburg, Maryland 20899


UV absorption cross-sections (a.c.s) of (CF3)3COH   (1,1,1,3,3,3-hexafluoro-2-(trifluoromethyl)-2-propanol, perfluoro-tert-butanol)

T = 298 K

UV absorption cross sections

nm               a.c.s. (cm^2/molecule)    

163		1.1e-19
164		8.9e-20
165		7.1e-20
166		5.7e-20
167		4.4e-20
168		3.5e-20
169		2.7e-20
170		2.2e-20
171		1.7e-20
172		1.4e-20
173		1.1e-20
174		8.6e-21
175		6.9e-21
176		5.4e-21
177		4.4e-21
178		3.5e-21
179		2.8e-21
180		2.1e-21
181		1.7e-21
182		1.3e-21
183		1.1e-21