data_wt1718 _audit_creation_method SHELXL-97 _chemical_name_systematic ; ? ; _chemical_name_common ? _chemical_melting_point ? _chemical_formula_moiety 'C27 H23 F6 N4 P Pt' _chemical_formula_sum 'C27 H23 F6 N4 P Pt' _chemical_formula_weight 743.55 loop_ _atom_type_symbol _atom_type_description _atom_type_scat_dispersion_real _atom_type_scat_dispersion_imag _atom_type_scat_source 'C' 'C' 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' 'H' 'H' 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' 'P' 'P' 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' 'Pt' 'Pt' -1.7033 8.3905 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' 'F' 'F' 0.0171 0.0103 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' 'N' 'N' 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' _symmetry_cell_setting triclinic _symmetry_space_group_name_H-M 'P -1' loop_ _symmetry_equiv_pos_as_xyz 'x, y, z' '-x, -y, -z' _cell_length_a 7.851(1) _cell_length_b 12.525(2) _cell_length_c 14.097(3) _cell_angle_alpha 84.75(2) _cell_angle_beta 85.48(2) _cell_angle_gamma 78.32(2) _cell_volume 1349.2(4) _cell_formula_units_Z 2 _cell_measurement_temperature 301(2) _cell_measurement_reflns_used 0 _cell_measurement_theta_min 0 _cell_measurement_theta_max 0 _exptl_crystal_description prism _exptl_crystal_colour yellow _exptl_crystal_size_max 0.4 _exptl_crystal_size_mid 0.1 _exptl_crystal_size_min 0.05 _exptl_crystal_density_meas ? _exptl_crystal_density_diffrn 1.830 _exptl_crystal_density_method 'not measured' _exptl_crystal_F_000 720 _exptl_absorpt_coefficient_mu 5.325 _exptl_absorpt_correction_type 'multi-scan' _exptl_absorpt_correction_T_min 0.91 _exptl_absorpt_correction_T_max 0.94 _exptl_absorpt_process_details 'SADABS' _exptl_special_details ; ? ; _diffrn_ambient_temperature 301(2) _diffrn_radiation_wavelength 0.71073 _diffrn_radiation_type MoK\a _diffrn_radiation_source 'fine-focus sealed tube' _diffrn_radiation_monochromator graphite _diffrn_measurement_device_type ? _diffrn_measurement_method ? _diffrn_detector_area_resol_mean ? _diffrn_standards_number ? _diffrn_standards_interval_count ? _diffrn_standards_interval_time ? _diffrn_standards_decay_% ? _diffrn_reflns_number 7963 _diffrn_reflns_av_R_equivalents 0.0204 _diffrn_reflns_av_sigmaI/netI 0.0322 _diffrn_reflns_limit_h_min -9 _diffrn_reflns_limit_h_max 9 _diffrn_reflns_limit_k_min -15 _diffrn_reflns_limit_k_max 15 _diffrn_reflns_limit_l_min -16 _diffrn_reflns_limit_l_max 17 _diffrn_reflns_theta_min 2.12 _diffrn_reflns_theta_max 25.68 _reflns_number_total 5001 _reflns_number_gt 4591 _reflns_threshold_expression >2sigma(I) _computing_data_collection ? _computing_cell_refinement ? _computing_data_reduction ? _computing_structure_solution 'SHELXS-97 (Sheldrick, 1997)' _computing_structure_refinement 'SHELXL-97 (Sheldrick, 1997)' _computing_molecular_graphics 'Ortep-3 for Windows (Farrugia, 1997)' _computing_publication_material 'WinGX publication routines (Farrugia, 1999)' _refine_special_details ; Refinement of F^2^ against ALL reflections. The weighted R-factor wR and goodness of fit S are based on F^2^, conventional R-factors R are based on F, with F set to zero for negative F^2^. The threshold expression of F^2^ > 2sigma(F^2^) is used only for calculating R-factors(gt) etc. and is not relevant to the choice of reflections for refinement. R-factors based on F^2^ are statistically about twice as large as those based on F, and R- factors based on ALL data will be even larger. ; _refine_ls_structure_factor_coef Fsqd _refine_ls_matrix_type full _refine_ls_weighting_scheme calc _refine_ls_weighting_details 'calc w=1/[\s^2^(Fo^2^)+(0.0686P)^2^+1.2686P] where P=(Fo^2^+2Fc^2^)/3' _atom_sites_solution_primary direct _atom_sites_solution_secondary difmap _atom_sites_solution_hydrogens geom _refine_ls_hydrogen_treatment constr _refine_ls_extinction_method none _refine_ls_extinction_coef ? _refine_ls_number_reflns 5001 _refine_ls_number_parameters 349 _refine_ls_number_restraints 198 _refine_ls_R_factor_all 0.0401 _refine_ls_R_factor_gt 0.0365 _refine_ls_wR_factor_ref 0.0996 _refine_ls_wR_factor_gt 0.0968 _refine_ls_goodness_of_fit_ref 1.025 _refine_ls_restrained_S_all 1.075 _refine_ls_shift/su_max 0.001 _refine_ls_shift/su_mean 0.000 loop_ _atom_site_label _atom_site_type_symbol _atom_site_fract_x _atom_site_fract_y _atom_site_fract_z _atom_site_U_iso_or_equiv _atom_site_adp_type _atom_site_occupancy _atom_site_symmetry_multiplicity _atom_site_calc_flag _atom_site_refinement_flags _atom_site_disorder_assembly _atom_site_disorder_group C1 C 0.0618(8) 0.4947(5) 0.2163(5) 0.0557(13) Uani 1 1 d . . . C2 C -0.0969(8) 0.4690(6) 0.3798(5) 0.0584(14) Uani 1 1 d . . . C3 C -0.2029(9) 0.5592(6) 0.4178(5) 0.0624(15) Uani 1 1 d . . . C4 C -0.2934(10) 0.5397(8) 0.5053(6) 0.081(2) Uani 1 1 d . . . H4 H -0.3654 0.5976 0.5344 0.097 Uiso 1 1 calc R . . C5 C -0.2759(12) 0.4342(9) 0.5487(6) 0.088(2) Uani 1 1 d . . . H5 H -0.3383 0.4220 0.6062 0.106 Uiso 1 1 calc R . . C6 C -0.1705(11) 0.3494(8) 0.5090(6) 0.080(2) Uani 1 1 d . . . H6 H -0.1612 0.2799 0.5400 0.096 Uiso 1 1 calc R . . C7 C -0.0744(9) 0.3624(6) 0.4225(5) 0.0666(16) Uani 1 1 d . . . C8 C -0.2244(12) 0.6719(7) 0.3681(6) 0.084(2) Uani 1 1 d . . . H8A H -0.1117 0.6884 0.3494 0.126 Uiso 1 1 calc R . . H8B H -0.2861 0.7242 0.4107 0.126 Uiso 1 1 calc R . . H8C H -0.2890 0.6752 0.3125 0.126 Uiso 1 1 calc R . . C9 C 0.0439(12) 0.2691(7) 0.3797(7) 0.087(2) Uani 1 1 d . . . H9A H 0.0067 0.2607 0.3180 0.131 Uiso 1 1 calc R . . H9B H 0.0413 0.2035 0.4202 0.131 Uiso 1 1 calc R . . H9C H 0.1605 0.2827 0.3731 0.131 Uiso 1 1 calc R . . C10 C 0.3423(9) 0.2754(5) 0.1392(6) 0.0672(16) Uani 1 1 d . . . H10 H 0.2855 0.2867 0.1989 0.081 Uiso 1 1 calc R . . C11 C 0.4471(11) 0.1746(6) 0.1241(7) 0.081(2) Uani 1 1 d . . . H11 H 0.4586 0.1186 0.1726 0.097 Uiso 1 1 calc R . . C12 C 0.5330(11) 0.1584(6) 0.0372(8) 0.087(2) Uani 1 1 d . . . H12 H 0.6025 0.0907 0.0259 0.104 Uiso 1 1 calc R . . C13 C 0.5170(9) 0.2415(6) -0.0334(6) 0.0745(19) Uani 1 1 d . . . H13 H 0.5778 0.2309 -0.0922 0.089 Uiso 1 1 calc R . . C14 C 0.4092(8) 0.3425(6) -0.0171(5) 0.0604(15) Uani 1 1 d . . . C15 C 0.3789(9) 0.4386(6) -0.0855(5) 0.0594(15) Uani 1 1 d . . . C16 C 0.2698(8) 0.5252(6) -0.0491(4) 0.0543(13) Uani 1 1 d . . . C17 C 0.2248(8) 0.6269(6) -0.0997(5) 0.0603(15) Uani 1 1 d . . . C18 C 0.2995(11) 0.6389(7) -0.1927(5) 0.075(2) Uani 1 1 d . . . H18 H 0.2747 0.7055 -0.2288 0.090 Uiso 1 1 calc R . . C19 C 0.4094(11) 0.5512(8) -0.2298(5) 0.080(2) Uani 1 1 d . . . H19 H 0.4577 0.5596 -0.2918 0.095 Uiso 1 1 calc R . . C20 C 0.4516(10) 0.4506(8) -0.1789(6) 0.076(2) Uani 1 1 d . . . H20 H 0.5264 0.3924 -0.2061 0.091 Uiso 1 1 calc R . . C21 C 0.1039(8) 0.7073(5) -0.0456(5) 0.0604(15) Uani 1 1 d . . . C22 C 0.0302(11) 0.8145(6) -0.0781(6) 0.078(2) Uani 1 1 d . . . H22 H 0.0568 0.8399 -0.1405 0.094 Uiso 1 1 calc R . . C23 C -0.0780(13) 0.8813(7) -0.0209(7) 0.088(3) Uani 1 1 d . . . H23 H -0.1267 0.9521 -0.0437 0.105 Uiso 1 1 calc R . . C24 C -0.1170(12) 0.8437(7) 0.0733(8) 0.087(3) Uani 1 1 d . . . H24 H -0.1892 0.8890 0.1149 0.104 Uiso 1 1 calc R . . C25 C -0.0445(10) 0.7368(6) 0.1023(6) 0.0724(18) Uani 1 1 d . . . H25 H -0.0718 0.7101 0.1642 0.087 Uiso 1 1 calc R . . C26 C 0.3875(19) -0.1184(12) -0.3958(9) 0.116(3) Uani 1 1 d . . . C27 C 0.292(2) -0.0094(13) -0.4148(11) 0.158(6) Uani 1 1 d . . . H27A H 0.2363 0.0180 -0.3564 0.236 Uiso 1 1 calc R . . H27B H 0.2055 -0.0097 -0.4591 0.236 Uiso 1 1 calc R . . H27C H 0.3705 0.0367 -0.4416 0.236 Uiso 1 1 calc R . . P1 P 0.7619(4) 0.08784(17) -0.27812(16) 0.0894(7) Uani 1 1 d D . . Pt1 Pt 0.17075(3) 0.510702(16) 0.081983(15) 0.05122(11) Uani 1 1 d . . . F1 F 0.7918(17) 0.2027(9) -0.2552(9) 0.130(4) Uiso 0.50 1 d PD A 1 F2 F 0.6640(16) 0.0684(9) -0.1792(7) 0.124(4) Uiso 0.50 1 d PD A 1 F3 F 0.9412(16) 0.0308(12) -0.2339(10) 0.195(8) Uiso 0.50 1 d PD A 1 F4 F 0.8727(14) 0.0962(8) -0.3783(6) 0.102(3) Uiso 0.50 1 d PD A 1 F5 F 0.5956(16) 0.1423(12) -0.3285(10) 0.203(8) Uiso 0.50 1 d PD A 1 F6 F 0.7347(16) -0.0294(8) -0.3034(8) 0.123(4) Uiso 0.50 1 d PD A 1 F7 F 0.5693(15) 0.0692(12) -0.2549(11) 0.195(8) Uiso 0.50 1 d PD A 2 F8 F 0.741(2) 0.0966(12) -0.3860(8) 0.198(8) Uiso 0.50 1 d PD A 2 F9 F 0.8373(15) -0.0364(7) -0.2733(8) 0.110(3) Uiso 0.50 1 d PD A 2 F10 F 0.7787(15) 0.0837(9) -0.1656(6) 0.110(3) Uiso 0.50 1 d PD A 2 F11 F 0.6798(15) 0.2167(7) -0.2768(8) 0.108(3) Uiso 0.50 1 d PD A 2 F12 F 0.9468(16) 0.1177(12) -0.2937(11) 0.201(8) Uiso 0.50 1 d PD A 2 N1 N -0.0065(7) 0.4856(4) 0.2907(4) 0.0594(12) Uani 1 1 d . . . N2 N 0.3206(7) 0.3570(4) 0.0703(4) 0.0555(12) Uani 1 1 d . . . N3 N 0.0629(7) 0.6703(4) 0.0455(4) 0.0555(12) Uani 1 1 d . . . N4 N 0.4651(19) -0.2051(11) -0.3805(9) 0.148(4) Uani 1 1 d . . . loop_ _atom_site_aniso_label _atom_site_aniso_U_11 _atom_site_aniso_U_22 _atom_site_aniso_U_33 _atom_site_aniso_U_23 _atom_site_aniso_U_13 _atom_site_aniso_U_12 C1 0.053(3) 0.049(3) 0.062(4) 0.002(3) -0.001(3) -0.007(2) C2 0.048(3) 0.074(4) 0.053(3) -0.001(3) 0.000(3) -0.016(3) C3 0.054(3) 0.067(4) 0.067(4) -0.012(3) -0.004(3) -0.011(3) C4 0.063(4) 0.105(6) 0.076(5) -0.026(4) 0.009(4) -0.018(4) C5 0.077(5) 0.120(7) 0.068(5) 0.000(5) 0.012(4) -0.031(5) C6 0.078(5) 0.093(5) 0.071(5) 0.007(4) 0.003(4) -0.031(4) C7 0.064(4) 0.072(4) 0.064(4) 0.005(3) -0.006(3) -0.016(3) C8 0.082(5) 0.075(5) 0.088(5) -0.012(4) -0.005(4) 0.004(4) C9 0.098(6) 0.070(4) 0.088(5) 0.010(4) -0.007(4) -0.009(4) C10 0.060(4) 0.061(4) 0.078(4) 0.003(3) 0.004(3) -0.012(3) C11 0.070(5) 0.054(4) 0.114(7) 0.007(4) -0.009(4) -0.007(3) C12 0.070(5) 0.058(4) 0.132(8) -0.026(5) -0.004(5) -0.003(3) C13 0.061(4) 0.070(4) 0.094(5) -0.026(4) 0.002(4) -0.009(3) C14 0.045(3) 0.068(4) 0.074(4) -0.023(3) 0.002(3) -0.019(3) C15 0.054(3) 0.069(4) 0.062(4) -0.013(3) -0.005(3) -0.021(3) C16 0.053(3) 0.066(3) 0.049(3) -0.001(3) -0.006(2) -0.025(3) C17 0.054(3) 0.075(4) 0.057(3) 0.004(3) -0.009(3) -0.026(3) C18 0.075(5) 0.094(5) 0.061(4) 0.005(4) -0.012(3) -0.029(4) C19 0.076(5) 0.113(7) 0.053(4) 0.001(4) 0.003(3) -0.031(5) C20 0.059(4) 0.106(6) 0.066(4) -0.027(4) 0.005(3) -0.019(4) C21 0.057(3) 0.061(3) 0.068(4) 0.008(3) -0.019(3) -0.023(3) C22 0.079(5) 0.072(4) 0.085(5) 0.018(4) -0.024(4) -0.020(4) C23 0.093(6) 0.056(4) 0.112(7) 0.006(4) -0.030(5) -0.007(4) C24 0.078(5) 0.064(4) 0.113(7) -0.014(4) -0.020(5) 0.005(4) C25 0.074(5) 0.065(4) 0.077(5) -0.009(3) -0.009(4) -0.008(3) C26 0.129(10) 0.121(9) 0.104(8) -0.006(7) 0.011(7) -0.045(8) C27 0.146(12) 0.163(13) 0.143(12) -0.060(10) -0.009(9) 0.039(10) P1 0.131(2) 0.0647(11) 0.0696(12) 0.0004(9) 0.0002(12) -0.0158(12) Pt1 0.04900(15) 0.04960(15) 0.05555(16) -0.00403(9) 0.00016(9) -0.01216(9) N1 0.057(3) 0.057(3) 0.062(3) 0.000(2) -0.002(2) -0.008(2) N2 0.051(3) 0.051(3) 0.065(3) -0.007(2) 0.001(2) -0.013(2) N3 0.052(3) 0.050(3) 0.066(3) -0.001(2) -0.010(2) -0.012(2) N4 0.172(11) 0.128(9) 0.144(10) 0.011(8) -0.012(8) -0.036(8) _geom_special_details ; All esds (except the esd in the dihedral angle between two l.s. planes) are estimated using the full covariance matrix. The cell esds are taken into account individually in the estimation of esds in distances, angles and torsion angles; correlations between esds in cell parameters are only used when they are defined by crystal symmetry. An approximate (isotropic) treatment of cell esds is used for estimating esds involving l.s. planes. ; loop_ _geom_bond_atom_site_label_1 _geom_bond_atom_site_label_2 _geom_bond_distance _geom_bond_site_symmetry_2 _geom_bond_publ_flag C1 N1 1.147(9) . ? C1 Pt1 2.025(7) . ? C2 C3 1.384(10) . ? C2 C7 1.396(10) . ? C2 N1 1.414(9) . ? C3 C4 1.401(11) . ? C3 C8 1.501(11) . ? C4 C5 1.390(13) . ? C5 C6 1.344(13) . ? C6 C7 1.396(11) . ? C7 C9 1.481(11) . ? C10 N2 1.339(9) . ? C10 C11 1.384(10) . ? C11 C12 1.362(13) . ? C12 C13 1.366(12) . ? C13 C14 1.400(10) . ? C14 N2 1.374(9) . ? C14 C15 1.464(10) . ? C15 C16 1.352(11) . ? C15 C20 1.402(10) . ? C16 C17 1.396(9) . ? C16 Pt1 1.955(6) . ? C17 C18 1.402(10) . ? C17 C21 1.461(10) . ? C18 C19 1.369(13) . ? C19 C20 1.384(13) . ? C21 N3 1.363(9) . ? C21 C22 1.400(10) . ? C22 C23 1.341(13) . ? C23 C24 1.400(14) . ? C24 C25 1.382(11) . ? C25 N3 1.333(10) . ? C26 N4 1.143(16) . ? C26 C27 1.431(19) . ? P1 F8 1.534(11) . ? P1 F5 1.540(11) . ? P1 F9 1.547(9) . ? P1 F2 1.562(10) . ? P1 F12 1.566(11) . ? P1 F1 1.570(10) . ? P1 F7 1.581(11) . ? P1 F3 1.590(11) . ? P1 F10 1.598(9) . ? P1 F6 1.601(9) . ? P1 F4 1.606(9) . ? P1 F11 1.614(9) . ? Pt1 N3 2.042(5) . ? Pt1 N2 2.056(5) . ? loop_ _geom_angle_atom_site_label_1 _geom_angle_atom_site_label_2 _geom_angle_atom_site_label_3 _geom_angle _geom_angle_site_symmetry_1 _geom_angle_site_symmetry_3 _geom_angle_publ_flag N1 C1 Pt1 177.1(6) . . ? C3 C2 C7 124.8(6) . . ? C3 C2 N1 117.7(6) . . ? C7 C2 N1 117.5(6) . . ? C2 C3 C4 116.3(7) . . ? C2 C3 C8 122.6(7) . . ? C4 C3 C8 121.1(7) . . ? C5 C4 C3 120.2(8) . . ? C6 C5 C4 121.1(8) . . ? C5 C6 C7 122.1(8) . . ? C2 C7 C6 115.5(7) . . ? C2 C7 C9 122.6(7) . . ? C6 C7 C9 121.9(7) . . ? N2 C10 C11 121.8(8) . . ? C12 C11 C10 119.2(8) . . ? C11 C12 C13 120.0(7) . . ? C12 C13 C14 119.9(8) . . ? N2 C14 C13 119.4(7) . . ? N2 C14 C15 114.4(6) . . ? C13 C14 C15 126.2(7) . . ? C16 C15 C20 118.8(7) . . ? C16 C15 C14 112.9(6) . . ? C20 C15 C14 128.2(7) . . ? C15 C16 C17 123.6(7) . . ? C15 C16 Pt1 119.4(5) . . ? C17 C16 Pt1 117.1(5) . . ? C16 C17 C18 117.4(7) . . ? C16 C17 C21 113.5(6) . . ? C18 C17 C21 129.1(7) . . ? C19 C18 C17 119.1(8) . . ? C18 C19 C20 122.7(7) . . ? C19 C20 C15 118.3(8) . . ? N3 C21 C22 119.0(7) . . ? N3 C21 C17 114.1(5) . . ? C22 C21 C17 126.9(7) . . ? C23 C22 C21 121.3(8) . . ? C22 C23 C24 119.5(7) . . ? C25 C24 C23 117.6(9) . . ? N3 C25 C24 122.9(8) . . ? N4 C26 C27 179.3(17) . . ? F8 P1 F5 54.3(7) . . ? F8 P1 F9 93.8(6) . . ? F5 P1 F9 123.8(7) . . ? F8 P1 F2 142.9(7) . . ? F5 P1 F2 94.6(6) . . ? F9 P1 F2 87.9(6) . . ? F8 P1 F12 91.6(7) . . ? F5 P1 F12 127.9(8) . . ? F9 P1 F12 92.8(6) . . ? F2 P1 F12 125.4(7) . . ? F8 P1 F1 105.5(7) . . ? F5 P1 F1 90.6(6) . . ? F9 P1 F1 145.5(6) . . ? F2 P1 F1 93.1(5) . . ? F12 P1 F1 59.1(7) . . ? F8 P1 F7 92.1(6) . . ? F5 P1 F7 51.3(7) . . ? F9 P1 F7 92.4(6) . . ? F2 P1 F7 50.7(6) . . ? F12 P1 F7 173.4(8) . . ? F1 P1 F7 114.6(7) . . ? F8 P1 F3 121.4(8) . . ? F5 P1 F3 175.6(7) . . ? F9 P1 F3 55.3(6) . . ? F2 P1 F3 89.7(6) . . ? F12 P1 F3 49.4(7) . . ? F1 P1 F3 90.2(6) . . ? F7 P1 F3 131.9(7) . . ? F8 P1 F10 177.7(7) . . ? F5 P1 F10 123.9(7) . . ? F9 P1 F10 88.5(5) . . ? F2 P1 F10 36.7(5) . . ? F12 P1 F10 88.7(6) . . ? F1 P1 F10 72.7(6) . . ? F7 P1 F10 87.3(6) . . ? F3 P1 F10 60.4(6) . . ? F8 P1 F6 73.7(7) . . ? F5 P1 F6 89.7(6) . . ? F9 P1 F6 34.1(5) . . ? F2 P1 F6 88.1(5) . . ? F12 P1 F6 119.9(7) . . ? F1 P1 F6 178.7(6) . . ? F7 P1 F6 66.5(7) . . ? F3 P1 F6 89.4(6) . . ? F10 P1 F6 108.1(6) . . ? F8 P1 F4 38.8(6) . . ? F5 P1 F4 89.3(6) . . ? F9 P1 F4 86.9(6) . . ? F2 P1 F4 174.6(6) . . ? F12 P1 F4 53.9(6) . . ? F1 P1 F4 90.7(5) . . ? F7 P1 F4 130.6(6) . . ? F3 P1 F4 86.4(6) . . ? F10 P1 F4 142.0(6) . . ? F6 P1 F4 88.1(5) . . ? F8 P1 F11 89.1(6) . . ? F5 P1 F11 57.3(6) . . ? F9 P1 F11 176.8(6) . . ? F2 P1 F11 89.0(6) . . ? F12 P1 F11 88.4(6) . . ? F1 P1 F11 34.0(5) . . ? F7 P1 F11 86.2(6) . . ? F3 P1 F11 124.0(6) . . ? F10 P1 F11 88.6(5) . . ? F6 P1 F11 146.5(6) . . ? F4 P1 F11 96.3(5) . . ? C16 Pt1 C1 178.3(2) . . ? C16 Pt1 N3 80.2(3) . . ? C1 Pt1 N3 99.7(2) . . ? C16 Pt1 N2 79.2(3) . . ? C1 Pt1 N2 101.0(2) . . ? N3 Pt1 N2 159.3(2) . . ? C1 N1 C2 175.9(7) . . ? C10 N2 C14 119.5(6) . . ? C10 N2 Pt1 126.3(5) . . ? C14 N2 Pt1 114.1(4) . . ? C25 N3 C21 119.6(6) . . ? C25 N3 Pt1 125.3(5) . . ? C21 N3 Pt1 115.1(4) . . ? _diffrn_measured_fraction_theta_max 0.974 _diffrn_reflns_theta_full 25.68 _diffrn_measured_fraction_theta_full 0.974 _refine_diff_density_max 1.424 _refine_diff_density_min -0.908 _refine_diff_density_rms 0.115