data_vic1325 _audit_creation_method SHELXL-97 _chemical_name_systematic ; ? ; _chemical_name_common ? _chemical_melting_point ? _chemical_formula_moiety 'C18 H28 P2 Sb, C F3 O3 S' _chemical_formula_sum 'C19 H28 F3 O3 P2 S Sb' _chemical_formula_weight 577.16 loop_ _atom_type_symbol _atom_type_description _atom_type_scat_dispersion_real _atom_type_scat_dispersion_imag _atom_type_scat_source 'C' 'C' 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' 'H' 'H' 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' 'O' 'O' 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' 'F' 'F' 0.0171 0.0103 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' 'P' 'P' 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' 'S' 'S' 0.1246 0.1234 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' 'Sb' 'Sb' -0.5866 1.5461 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' _symmetry_cell_setting Monoclinic _symmetry_space_group_name_H-M 'P 21/c' _symmetry_space_group_name_Hall '-P 2ybc' loop_ _symmetry_equiv_pos_as_xyz 'x, y, z' '-x, y+1/2, -z+1/2' '-x, -y, -z' 'x, -y-1/2, z-1/2' _cell_length_a 8.2974(3) _cell_length_b 11.1805(4) _cell_length_c 26.4962(9) _cell_angle_alpha 90.00 _cell_angle_beta 93.3876(4) _cell_angle_gamma 90.00 _cell_volume 2453.73(15) _cell_formula_units_Z 4 _cell_measurement_temperature 173(2) _cell_measurement_reflns_used 9656 _cell_measurement_theta_min 2.39 _cell_measurement_theta_max 27.40 _exptl_crystal_description fragment _exptl_crystal_colour colorless _exptl_crystal_size_max 0.36 _exptl_crystal_size_mid 0.35 _exptl_crystal_size_min 0.24 _exptl_crystal_density_meas ? _exptl_crystal_density_diffrn 1.562 _exptl_crystal_density_method 'not measured' _exptl_crystal_F_000 1160 _exptl_absorpt_coefficient_mu 1.379 _exptl_absorpt_correction_type integration _exptl_absorpt_correction_T_min 0.6359 _exptl_absorpt_correction_T_max 0.7349 _exptl_absorpt_process_details 'SADABS (Sheldrick, 2008)' _exptl_special_details ; ? ; _diffrn_ambient_temperature 173(2) _diffrn_radiation_wavelength 0.71073 _diffrn_radiation_type MoK\a _diffrn_radiation_source 'fine-focus sealed tube' _diffrn_radiation_monochromator graphite _diffrn_measurement_device_type 'Bruker APEX-II CCD' _diffrn_measurement_method '\w scans' _diffrn_detector_area_resol_mean ? _diffrn_reflns_number 21436 _diffrn_reflns_av_R_equivalents 0.0131 _diffrn_reflns_av_unetI/netI 0.0106 _diffrn_reflns_limit_h_min -10 _diffrn_reflns_limit_h_max 10 _diffrn_reflns_limit_k_min -14 _diffrn_reflns_limit_k_max 14 _diffrn_reflns_limit_l_min -34 _diffrn_reflns_limit_l_max 34 _diffrn_reflns_theta_min 1.54 _diffrn_reflns_theta_max 27.44 _reflns_number_total 5589 _reflns_number_gt 5272 _reflns_threshold_expression I>2\s(I) _computing_data_collection 'Bruker APEX2' _computing_cell_refinement 'Bruker SAINT' _computing_data_reduction 'Bruker SAINT' _computing_structure_solution 'DIRDIF-2008 (Beurskens et al., 2008)' _computing_structure_refinement 'SHELXL-97 (Sheldrick, 2008)' _computing_molecular_graphics 'Bruker SHELXTL' _computing_publication_material 'Bruker SHELXTL' _refine_special_details ; Refinement of F^2^ against ALL reflections. The weighted R-factor wR and goodness of fit S are based on F^2^, conventional R-factors R are based on F, with F set to zero for negative F^2^. The threshold expression of F^2^ > 2sigma(F^2^) is used only for calculating R-factors(gt) etc. and is not relevant to the choice of reflections for refinement. R-factors based on F^2^ are statistically about twice as large as those based on F, and R- factors based on ALL data will be even larger. ; _refine_ls_structure_factor_coef Fsqd _refine_ls_matrix_type full _refine_ls_weighting_scheme calc _refine_ls_weighting_details 'calc w=1/[\s^2^(Fo^2^)+(0.0226P)^2^+2.0116P] where P=(Fo^2^+2Fc^2^)/3' _atom_sites_solution_primary direct _atom_sites_solution_secondary difmap _atom_sites_solution_hydrogens geom _refine_ls_hydrogen_treatment constr _refine_ls_extinction_method none _refine_ls_extinction_coef ? _refine_ls_number_reflns 5589 _refine_ls_number_parameters 268 _refine_ls_number_restraints 0 _refine_ls_R_factor_all 0.0215 _refine_ls_R_factor_gt 0.0201 _refine_ls_wR_factor_ref 0.0506 _refine_ls_wR_factor_gt 0.0497 _refine_ls_goodness_of_fit_ref 1.050 _refine_ls_restrained_S_all 1.050 _refine_ls_shift/su_max 0.002 _refine_ls_shift/su_mean 0.000 loop_ _atom_site_label _atom_site_type_symbol _atom_site_fract_x _atom_site_fract_y _atom_site_fract_z _atom_site_U_iso_or_equiv _atom_site_adp_type _atom_site_occupancy _atom_site_symmetry_multiplicity _atom_site_calc_flag _atom_site_refinement_flags _atom_site_disorder_assembly _atom_site_disorder_group Sb Sb 0.075982(13) 0.396706(10) 0.112994(4) 0.02135(4) Uani 1 1 d . . . P1 P -0.11671(5) 0.47012(4) 0.190708(16) 0.02379(9) Uani 1 1 d . . . P2 P 0.25562(5) 0.31469(4) 0.035902(16) 0.02415(9) Uani 1 1 d . . . C1 C -0.1378(3) 0.4068(2) 0.25284(8) 0.0398(5) Uani 1 1 d . . . H1A H -0.2079 0.4581 0.2720 0.048 Uiso 1 1 calc R . . H1B H -0.0313 0.4011 0.2708 0.048 Uiso 1 1 calc R . . H1C H -0.1855 0.3268 0.2494 0.048 Uiso 1 1 calc R . . C2 C -0.0689(3) 0.62598(18) 0.20327(9) 0.0430(5) Uani 1 1 d . . . H2A H -0.1481 0.6598 0.2253 0.052 Uiso 1 1 calc R . . H2B H -0.0722 0.6704 0.1713 0.052 Uiso 1 1 calc R . . H2C H 0.0393 0.6320 0.2200 0.052 Uiso 1 1 calc R . . C3 C -0.3211(2) 0.4741(2) 0.16291(8) 0.0389(5) Uani 1 1 d . . . H3A H -0.3219 0.5126 0.1296 0.047 Uiso 1 1 calc R . . H3B H -0.3895 0.5197 0.1849 0.047 Uiso 1 1 calc R . . H3C H -0.3625 0.3924 0.1591 0.047 Uiso 1 1 calc R . . C4 C 0.1784(3) 0.39362(19) -0.02014(7) 0.0369(4) Uani 1 1 d . . . H4A H 0.2444 0.3741 -0.0485 0.044 Uiso 1 1 calc R . . H4B H 0.1827 0.4800 -0.0139 0.044 Uiso 1 1 calc R . . H4C H 0.0664 0.3695 -0.0284 0.044 Uiso 1 1 calc R . . C5 C 0.2694(3) 0.16071(19) 0.01562(9) 0.0460(5) Uani 1 1 d . . . H5A H 0.3248 0.1134 0.0425 0.055 Uiso 1 1 calc R . . H5B H 0.3302 0.1567 -0.0149 0.055 Uiso 1 1 calc R . . H5C H 0.1606 0.1286 0.0083 0.055 Uiso 1 1 calc R . . C6 C 0.4623(2) 0.36435(19) 0.04487(8) 0.0336(4) Uani 1 1 d . . . H6A H 0.5180 0.3508 0.0138 0.040 Uiso 1 1 calc R . . H6B H 0.5167 0.3194 0.0727 0.040 Uiso 1 1 calc R . . H6C H 0.4644 0.4499 0.0530 0.040 Uiso 1 1 calc R . . C11 C -0.0689(2) 0.23617(15) 0.10879(6) 0.0236(3) Uani 1 1 d . . . C12 C -0.0807(2) 0.16078(18) 0.15021(7) 0.0315(4) Uani 1 1 d . . . H12 H -0.0193 0.1776 0.1808 0.038 Uiso 1 1 calc R . . C13 C -0.1811(2) 0.06143(19) 0.14746(8) 0.0372(4) Uani 1 1 d . . . H13 H -0.1880 0.0110 0.1761 0.045 Uiso 1 1 calc R . . C14 C -0.2710(2) 0.03541(18) 0.10328(8) 0.0375(4) Uani 1 1 d . . . H14 H -0.3392 -0.0329 0.1013 0.045 Uiso 1 1 calc R . . C15 C -0.2609(2) 0.10975(18) 0.06194(8) 0.0364(4) Uani 1 1 d . . . H15 H -0.3227 0.0925 0.0315 0.044 Uiso 1 1 calc R . . C16 C -0.1608(2) 0.20961(17) 0.06455(7) 0.0290(4) Uani 1 1 d . . . H16 H -0.1551 0.2602 0.0359 0.035 Uiso 1 1 calc R . . C21 C 0.25141(19) 0.32747(15) 0.16877(6) 0.0225(3) Uani 1 1 d . . . C22 C 0.2957(2) 0.39289(16) 0.21226(7) 0.0271(4) Uani 1 1 d . . . H22 H 0.2527 0.4708 0.2164 0.033 Uiso 1 1 calc R . . C23 C 0.4019(2) 0.34523(19) 0.24953(7) 0.0327(4) Uani 1 1 d . . . H23 H 0.4286 0.3899 0.2794 0.039 Uiso 1 1 calc R . . C24 C 0.4691(2) 0.23345(19) 0.24354(8) 0.0344(4) Uani 1 1 d . . . H24 H 0.5418 0.2012 0.2690 0.041 Uiso 1 1 calc R . . C25 C 0.4290(2) 0.16898(18) 0.19993(8) 0.0338(4) Uani 1 1 d . . . H25 H 0.4766 0.0929 0.1951 0.041 Uiso 1 1 calc R . . C26 C 0.3196(2) 0.21482(16) 0.16320(7) 0.0292(4) Uani 1 1 d . . . H26 H 0.2910 0.1687 0.1339 0.035 Uiso 1 1 calc R . . S S 0.34101(6) 0.70184(5) 0.09863(2) 0.03914(12) Uani 1 1 d . . . F1 F 0.2214(5) 0.89676(16) 0.05815(8) 0.1441(14) Uani 1 1 d . . . F2 F 0.2847(4) 0.91176(17) 0.13642(8) 0.1228(11) Uani 1 1 d . . . F3 F 0.0723(3) 0.8158(2) 0.11099(9) 0.1113(9) Uani 1 1 d . . . O1 O 0.3125(2) 0.64641(17) 0.14623(6) 0.0545(4) Uani 1 1 d . . . O2 O 0.2665(2) 0.64279(15) 0.05512(6) 0.0538(4) Uani 1 1 d . . . O3 O 0.5013(3) 0.7420(3) 0.09210(11) 0.1020(9) Uani 1 1 d . . . C30 C 0.2223(5) 0.8377(2) 0.10055(9) 0.0685(9) Uani 1 1 d . . . loop_ _atom_site_aniso_label _atom_site_aniso_U_11 _atom_site_aniso_U_22 _atom_site_aniso_U_33 _atom_site_aniso_U_23 _atom_site_aniso_U_13 _atom_site_aniso_U_12 Sb 0.02291(6) 0.02168(6) 0.01954(6) 0.00201(4) 0.00197(4) 0.00056(4) P1 0.0222(2) 0.0266(2) 0.0230(2) -0.00282(16) 0.00466(16) 0.00067(16) P2 0.0282(2) 0.0249(2) 0.01984(19) -0.00072(16) 0.00566(16) 0.00005(17) C1 0.0408(11) 0.0496(12) 0.0292(10) 0.0062(9) 0.0043(8) 0.0021(9) C2 0.0458(12) 0.0291(10) 0.0559(13) -0.0113(9) 0.0175(10) -0.0035(9) C3 0.0268(9) 0.0530(13) 0.0367(10) 0.0044(9) 0.0000(8) 0.0026(9) C4 0.0405(11) 0.0460(12) 0.0240(9) 0.0043(8) 0.0009(8) 0.0028(9) C5 0.0643(15) 0.0284(10) 0.0465(12) -0.0091(9) 0.0145(11) -0.0046(10) C6 0.0289(9) 0.0384(10) 0.0339(10) -0.0015(8) 0.0049(7) -0.0003(8) C11 0.0224(8) 0.0250(8) 0.0235(8) -0.0010(6) 0.0028(6) 0.0004(6) C12 0.0319(9) 0.0358(10) 0.0266(9) 0.0044(7) -0.0013(7) -0.0059(8) C13 0.0372(10) 0.0353(10) 0.0393(11) 0.0082(8) 0.0050(8) -0.0072(8) C14 0.0321(10) 0.0323(10) 0.0487(12) -0.0076(9) 0.0063(8) -0.0086(8) C15 0.0337(10) 0.0413(11) 0.0337(10) -0.0120(8) -0.0019(8) -0.0046(8) C16 0.0300(9) 0.0327(9) 0.0243(8) -0.0015(7) 0.0006(7) 0.0008(7) C21 0.0205(7) 0.0250(8) 0.0220(7) 0.0032(6) 0.0027(6) -0.0021(6) C22 0.0240(8) 0.0278(9) 0.0295(9) -0.0013(7) 0.0019(7) -0.0039(7) C23 0.0280(9) 0.0415(11) 0.0279(9) 0.0015(8) -0.0034(7) -0.0099(8) C24 0.0239(9) 0.0423(11) 0.0364(10) 0.0154(8) -0.0036(7) -0.0055(8) C25 0.0303(9) 0.0295(9) 0.0418(11) 0.0091(8) 0.0032(8) 0.0049(7) C26 0.0316(9) 0.0281(9) 0.0279(9) 0.0011(7) 0.0024(7) 0.0015(7) S 0.0393(3) 0.0376(3) 0.0415(3) -0.0024(2) 0.0105(2) -0.0081(2) F1 0.329(4) 0.0467(11) 0.0620(12) 0.0303(9) 0.0590(18) 0.0417(16) F2 0.241(3) 0.0544(11) 0.0794(14) -0.0418(10) 0.0599(17) -0.0347(14) F3 0.1035(17) 0.0990(17) 0.134(2) 0.0270(14) 0.0348(15) 0.0595(14) O1 0.0629(11) 0.0563(10) 0.0429(9) 0.0163(8) -0.0088(8) -0.0017(9) O2 0.0836(13) 0.0384(8) 0.0401(9) -0.0117(7) 0.0112(8) -0.0096(8) O3 0.0577(13) 0.130(2) 0.122(2) -0.0201(18) 0.0342(14) -0.0427(14) C30 0.143(3) 0.0278(11) 0.0386(13) 0.0024(9) 0.0366(16) 0.0026(14) _geom_special_details ; All esds (except the esd in the dihedral angle between two l.s. planes) are estimated using the full covariance matrix. The cell esds are taken into account individually in the estimation of esds in distances, angles and torsion angles; correlations between esds in cell parameters are only used when they are defined by crystal symmetry. An approximate (isotropic) treatment of cell esds is used for estimating esds involving l.s. planes. ; loop_ _geom_bond_atom_site_label_1 _geom_bond_atom_site_label_2 _geom_bond_distance _geom_bond_site_symmetry_2 _geom_bond_publ_flag Sb C21 2.1558(16) . ? Sb C11 2.1594(17) . ? Sb P2 2.7559(4) . ? Sb P1 2.8034(4) . ? Sb O1 3.4951(19) . ? Sb O2 3.5647(17) . ? P1 C3 1.8089(19) . ? P1 C1 1.810(2) . ? P1 C2 1.814(2) . ? P2 C6 1.8047(19) . ? P2 C5 1.809(2) . ? P2 C4 1.812(2) . ? C11 C16 1.392(2) . ? C11 C12 1.392(2) . ? C12 C13 1.388(3) . ? C13 C14 1.381(3) . ? C14 C15 1.382(3) . ? C15 C16 1.391(3) . ? C21 C26 1.392(2) . ? C21 C22 1.396(2) . ? C22 C23 1.391(3) . ? C23 C24 1.381(3) . ? C24 C25 1.386(3) . ? C25 C26 1.389(3) . ? S O3 1.424(2) . ? S O2 1.4365(17) . ? S O1 1.4372(17) . ? S C30 1.813(3) . ? F1 C30 1.303(3) . ? F2 C30 1.341(4) . ? F3 C30 1.314(4) . ? loop_ _geom_angle_atom_site_label_1 _geom_angle_atom_site_label_2 _geom_angle_atom_site_label_3 _geom_angle _geom_angle_site_symmetry_1 _geom_angle_site_symmetry_3 _geom_angle_publ_flag C21 Sb C11 95.06(6) . . ? C21 Sb P2 90.90(4) . . ? C11 Sb P2 90.51(4) . . ? C21 Sb P1 89.60(4) . . ? C11 Sb P1 86.64(4) . . ? P2 Sb P1 177.142(13) . . ? C21 Sb O1 76.58(5) . . ? C11 Sb O1 168.37(5) . . ? P2 Sb O1 97.60(3) . . ? P1 Sb O1 85.25(3) . . ? C21 Sb O2 105.87(5) . . ? C11 Sb O2 151.52(5) . . ? P2 Sb O2 70.42(3) . . ? P1 Sb O2 112.13(3) . . ? O1 Sb O2 40.11(4) . . ? C3 P1 C1 103.97(10) . . ? C3 P1 C2 103.91(11) . . ? C1 P1 C2 103.94(11) . . ? C3 P1 Sb 105.65(7) . . ? C1 P1 Sb 130.04(7) . . ? C2 P1 Sb 106.75(7) . . ? C6 P2 C5 104.82(11) . . ? C6 P2 C4 104.20(10) . . ? C5 P2 C4 104.21(11) . . ? C6 P2 Sb 110.57(7) . . ? C5 P2 Sb 125.68(8) . . ? C4 P2 Sb 105.36(7) . . ? C16 C11 C12 118.30(16) . . ? C16 C11 Sb 119.76(13) . . ? C12 C11 Sb 121.84(13) . . ? C13 C12 C11 120.89(17) . . ? C14 C13 C12 120.37(19) . . ? C13 C14 C15 119.33(18) . . ? C14 C15 C16 120.52(18) . . ? C15 C16 C11 120.59(18) . . ? C26 C21 C22 118.22(16) . . ? C26 C21 Sb 120.96(13) . . ? C22 C21 Sb 120.79(12) . . ? C23 C22 C21 120.69(17) . . ? C24 C23 C22 120.54(18) . . ? C23 C24 C25 119.21(17) . . ? C24 C25 C26 120.47(18) . . ? C25 C26 C21 120.83(17) . . ? O3 S O2 114.10(14) . . ? O3 S O1 116.49(15) . . ? O2 S O1 114.88(11) . . ? O3 S C30 104.57(17) . . ? O2 S C30 101.47(13) . . ? O1 S C30 102.65(11) . . ? S O1 Sb 104.03(9) . . ? S O2 Sb 100.96(8) . . ? F1 C30 F3 108.6(4) . . ? F1 C30 F2 106.3(2) . . ? F3 C30 F2 107.2(2) . . ? F1 C30 S 112.1(2) . . ? F3 C30 S 111.87(19) . . ? F2 C30 S 110.5(3) . . ? loop_ _geom_torsion_atom_site_label_1 _geom_torsion_atom_site_label_2 _geom_torsion_atom_site_label_3 _geom_torsion_atom_site_label_4 _geom_torsion _geom_torsion_site_symmetry_1 _geom_torsion_site_symmetry_2 _geom_torsion_site_symmetry_3 _geom_torsion_site_symmetry_4 _geom_torsion_publ_flag C21 Sb P1 C3 -154.44(9) . . . . ? C11 Sb P1 C3 -59.35(9) . . . . ? P2 Sb P1 C3 -54.4(3) . . . . ? O1 Sb P1 C3 129.00(8) . . . . ? O2 Sb P1 C3 98.56(9) . . . . ? C21 Sb P1 C1 -30.18(11) . . . . ? C11 Sb P1 C1 64.92(11) . . . . ? P2 Sb P1 C1 69.8(3) . . . . ? O1 Sb P1 C1 -106.74(10) . . . . ? O2 Sb P1 C1 -137.17(10) . . . . ? C21 Sb P1 C2 95.38(10) . . . . ? C11 Sb P1 C2 -169.53(10) . . . . ? P2 Sb P1 C2 -164.6(3) . . . . ? O1 Sb P1 C2 18.82(9) . . . . ? O2 Sb P1 C2 -11.62(9) . . . . ? C21 Sb P2 C6 -51.47(9) . . . . ? C11 Sb P2 C6 -146.54(9) . . . . ? P1 Sb P2 C6 -151.5(3) . . . . ? O1 Sb P2 C6 25.10(8) . . . . ? O2 Sb P2 C6 55.07(8) . . . . ? C21 Sb P2 C5 75.81(12) . . . . ? C11 Sb P2 C5 -19.26(12) . . . . ? P1 Sb P2 C5 -24.2(3) . . . . ? O1 Sb P2 C5 152.38(11) . . . . ? O2 Sb P2 C5 -177.66(11) . . . . ? C21 Sb P2 C4 -163.48(9) . . . . ? C11 Sb P2 C4 101.45(9) . . . . ? P1 Sb P2 C4 96.5(3) . . . . ? O1 Sb P2 C4 -86.91(8) . . . . ? O2 Sb P2 C4 -56.94(8) . . . . ? C21 Sb C11 C16 -153.05(14) . . . . ? P2 Sb C11 C16 -62.10(13) . . . . ? P1 Sb C11 C16 117.65(13) . . . . ? O1 Sb C11 C16 163.5(2) . . . . ? O2 Sb C11 C16 -15.4(2) . . . . ? C21 Sb C11 C12 30.62(15) . . . . ? P2 Sb C11 C12 121.57(14) . . . . ? P1 Sb C11 C12 -58.67(14) . . . . ? O1 Sb C11 C12 -12.8(4) . . . . ? O2 Sb C11 C12 168.25(12) . . . . ? C16 C11 C12 C13 0.2(3) . . . . ? Sb C11 C12 C13 176.62(15) . . . . ? C11 C12 C13 C14 0.2(3) . . . . ? C12 C13 C14 C15 -0.4(3) . . . . ? C13 C14 C15 C16 0.2(3) . . . . ? C14 C15 C16 C11 0.2(3) . . . . ? C12 C11 C16 C15 -0.4(3) . . . . ? Sb C11 C16 C15 -176.87(14) . . . . ? C11 Sb C21 C26 47.76(14) . . . . ? P2 Sb C21 C26 -42.84(13) . . . . ? P1 Sb C21 C26 134.35(13) . . . . ? O1 Sb C21 C26 -140.44(14) . . . . ? O2 Sb C21 C26 -112.72(13) . . . . ? C11 Sb C21 C22 -130.13(13) . . . . ? P2 Sb C21 C22 139.27(13) . . . . ? P1 Sb C21 C22 -43.54(13) . . . . ? O1 Sb C21 C22 41.67(13) . . . . ? O2 Sb C21 C22 69.38(14) . . . . ? C26 C21 C22 C23 -1.6(3) . . . . ? Sb C21 C22 C23 176.35(13) . . . . ? C21 C22 C23 C24 1.8(3) . . . . ? C22 C23 C24 C25 -0.2(3) . . . . ? C23 C24 C25 C26 -1.5(3) . . . . ? C24 C25 C26 C21 1.7(3) . . . . ? C22 C21 C26 C25 -0.1(3) . . . . ? Sb C21 C26 C25 -178.05(14) . . . . ? O3 S O1 Sb -136.30(14) . . . . ? O2 S O1 Sb 0.93(13) . . . . ? C30 S O1 Sb 110.12(13) . . . . ? C21 Sb O1 S 135.50(10) . . . . ? C11 Sb O1 S -179.7(2) . . . . ? P2 Sb O1 S 46.39(9) . . . . ? P1 Sb O1 S -133.78(9) . . . . ? O2 Sb O1 S -0.53(7) . . . . ? O3 S O2 Sb 137.36(15) . . . . ? O1 S O2 Sb -0.90(12) . . . . ? C30 S O2 Sb -110.80(10) . . . . ? C21 Sb O2 S -44.08(10) . . . . ? C11 Sb O2 S -179.82(10) . . . . ? P2 Sb O2 S -129.28(10) . . . . ? P1 Sb O2 S 52.10(10) . . . . ? O1 Sb O2 S 0.52(7) . . . . ? O3 S C30 F1 63.4(3) . . . . ? O2 S C30 F1 -55.5(3) . . . . ? O1 S C30 F1 -174.5(3) . . . . ? O3 S C30 F3 -174.3(2) . . . . ? O2 S C30 F3 66.8(2) . . . . ? O1 S C30 F3 -52.3(2) . . . . ? O3 S C30 F2 -55.0(2) . . . . ? O2 S C30 F2 -173.86(19) . . . . ? O1 S C30 F2 67.1(2) . . . . ? _diffrn_measured_fraction_theta_max 0.999 _diffrn_reflns_theta_full 27.44 _diffrn_measured_fraction_theta_full 0.999 _refine_diff_density_max 0.725 _refine_diff_density_min -0.587 _refine_diff_density_rms 0.055