 
data_complex_1
 
_audit_creation_method            'SHELXL-2016/6'
_shelx_SHELXL_version_number      '2016/6'
_chemical_name_systematic         ?
_chemical_name_common             ?
_chemical_melting_point           ?
_chemical_formula_moiety          ?
_chemical_formula_sum
 'C98 H96 Au2 Cl4 F6 O6 P6 Pt S2' 
_chemical_formula_weight          2464.51

loop_
 _atom_type_symbol
 _atom_type_description
 _atom_type_scat_dispersion_real
 _atom_type_scat_dispersion_imag
 _atom_type_scat_source
 'C'  'C'   0.0033   0.0016
 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
 'H'  'H'   0.0000   0.0000
 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
 'O'  'O'   0.0106   0.0060
 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
 'F'  'F'   0.0171   0.0103
 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
 'P'  'P'   0.1023   0.0942
 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
 'S'  'S'   0.1246   0.1234
 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
 'Cl'  'Cl'   0.1484   0.1585
 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
 'Pt'  'Pt'  -1.7033   8.3905
 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
 'Au'  'Au'  -2.0133   8.8022
 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
 
_space_group_crystal_system       triclinic
_space_group_IT_number            2
_space_group_name_H-M_alt         'P -1'
_space_group_name_Hall            '-P 1'
 
_shelx_space_group_comment
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
 
loop_
 _space_group_symop_operation_xyz
 'x, y, z'
 '-x, -y, -z'
 
_cell_length_a                    12.5423(6)
_cell_length_b                    14.0963(7)
_cell_length_c                    14.8713(7)
_cell_angle_alpha                 113.020(2)
_cell_angle_beta                  90.361(2)
_cell_angle_gamma                 95.260(2)
_cell_volume                      2407.1(2)
_cell_formula_units_Z             1
_cell_measurement_temperature     150(2)
_cell_measurement_reflns_used     9920
_cell_measurement_theta_min       2.56
_cell_measurement_theta_max      25.41
 
_exptl_crystal_description        plate
_exptl_crystal_colour             yellowish
_exptl_crystal_density_meas       ?
_exptl_crystal_density_method     ?
_exptl_crystal_density_diffrn     1.700          
_exptl_crystal_F_000              1212
_exptl_transmission_factor_min    ?
_exptl_transmission_factor_max    ?
_exptl_crystal_size_max           0.120
_exptl_crystal_size_mid           0.100
_exptl_crystal_size_min           0.030
_exptl_absorpt_coefficient_mu     4.808
_shelx_estimated_absorpt_T_min    0.596
_shelx_estimated_absorpt_T_max    0.869
_exptl_absorpt_correction_type    multi-scan
_exptl_absorpt_correction_T_min   0.5240
_exptl_absorpt_correction_T_max   0.7452
_exptl_absorpt_process_details    ?
_exptl_absorpt_special_details    ?
_diffrn_ambient_temperature       150(2)
_diffrn_radiation_wavelength      0.71073
_diffrn_radiation_type            MoK\a
_diffrn_source                    ?
_diffrn_measurement_device_type   'Bruker APEX-II CCD'
_diffrn_measurement_method         'φ and ω scans'
_diffrn_detector_area_resol_mean  ?
_diffrn_reflns_number             21323
_diffrn_reflns_av_unetI/netI      0.0367
_diffrn_reflns_av_R_equivalents   0.0287
_diffrn_reflns_limit_h_min        -15
_diffrn_reflns_limit_h_max        15
_diffrn_reflns_limit_k_min        -16
_diffrn_reflns_limit_k_max        17
_diffrn_reflns_limit_l_min        -17
_diffrn_reflns_limit_l_max        17
_diffrn_reflns_theta_min          2.260
_diffrn_reflns_theta_max          25.416
_diffrn_reflns_theta_full         25.242
_diffrn_measured_fraction_theta_max   0.983
_diffrn_measured_fraction_theta_full  0.987
_diffrn_reflns_Laue_measured_fraction_max    0.983
_diffrn_reflns_Laue_measured_fraction_full   0.987
_diffrn_reflns_point_group_measured_fraction_max   0.983
_diffrn_reflns_point_group_measured_fraction_full  0.987
_reflns_number_total              8732
_reflns_number_gt                 7956
_reflns_threshold_expression      'I > 2σ(I)'
_reflns_Friedel_coverage          0.000
_reflns_Friedel_fraction_max      .
_reflns_Friedel_fraction_full     .
 
_reflns_special_details
;
 Reflections were merged by SHELXL according to the crystal
 class for the calculation of statistics and refinement.
 
 _reflns_Friedel_fraction is defined as the number of unique
 Friedel pairs measured divided by the number that would be
 possible theoretically, ignoring centric projections and
 systematic absences.
;
 
_computing_data_collection        ?
_computing_cell_refinement        ?
_computing_data_reduction         ?
_computing_structure_solution     'SHELXT 2014/5 (Sheldrick, 2014)'
_computing_structure_refinement 'SHELXL-2016/6 (Sheldrick, 2016)'
_computing_molecular_graphics     ?
_computing_publication_material   ?
_refine_special_details           ?
_refine_ls_structure_factor_coef  Fsqd
_refine_ls_matrix_type            full
_refine_ls_weighting_scheme       calc
_refine_ls_weighting_details
'w=1/[σ²(Fo²)+(0.0472P)²+1.9181P] where P=(Fo²+2Fc²)/3'
_atom_sites_solution_primary      ?
_atom_sites_solution_secondary    ?
_atom_sites_solution_hydrogens    geom
_refine_ls_hydrogen_treatment     constr
_refine_ls_extinction_method      none
_refine_ls_extinction_coef        .
_refine_ls_number_reflns          8732
_refine_ls_number_parameters      671
_refine_ls_number_restraints      231
_refine_ls_R_factor_all           0.0338
_refine_ls_R_factor_gt            0.0300
_refine_ls_wR_factor_ref          0.0876
_refine_ls_wR_factor_gt           0.0811
_refine_ls_goodness_of_fit_ref    1.137
_refine_ls_restrained_S_all       1.135
_refine_ls_shift/su_max           0.001
_refine_ls_shift/su_mean          0.000
 
loop_
 _atom_site_label
 _atom_site_type_symbol
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_U_iso_or_equiv
 _atom_site_adp_type
 _atom_site_occupancy
 _atom_site_site_symmetry_order  
 _atom_site_calc_flag
 _atom_site_refinement_flags_posn
 _atom_site_refinement_flags_adp
 _atom_site_refinement_flags_occupancy
 _atom_site_disorder_assembly
 _atom_site_disorder_group
Au1 Au 0.32745(2) 0.95821(2) 0.35491(2) 0.02571(7) Uani 1 1 d . . . . .
Pt1 Pt 0.500000 1.000000 0.500000 0.02003(7) Uani 1 2 d DS . P . .
S1 S 0.76890(10) 0.29974(9) 0.30046(10) 0.0388(3) Uani 1 1 d . . . . .
P1 P 0.25211(10) 0.82204(10) 0.39217(10) 0.0307(3) Uani 1 1 d . . . . .
P2 P 0.45281(9) 0.84673(8) 0.51968(8) 0.0215(2) Uani 1 1 d . . . . .
P3 P 0.61669(9) 0.90924(8) 0.69613(8) 0.0227(2) Uani 1 1 d . . . . .
F1 F 0.9532(3) 0.3807(3) 0.2692(3) 0.0551(8) Uani 1 1 d . . . . .
F2 F 0.9176(3) 0.4291(3) 0.4199(3) 0.0635(10) Uani 1 1 d . . . . .
F3 F 0.8377(3) 0.4904(2) 0.3294(3) 0.0647(11) Uani 1 1 d . . . . .
O1 O 0.6944(3) 0.3401(3) 0.3766(3) 0.0579(11) Uani 1 1 d . . . . .
O2 O 0.8240(4) 0.2177(3) 0.3074(4) 0.0643(12) Uani 1 1 d . . . . .
O3 O 0.7308(4) 0.2876(4) 0.2053(3) 0.0734(14) Uani 1 1 d . . . . .
C1 C 0.3062(3) 0.8256(4) 0.5080(3) 0.0270(9) Uani 1 1 d . . . . .
H1A H 0.282619 0.759322 0.513723 0.032 Uiso 1 1 calc R U . . .
H1B H 0.276512 0.881802 0.562578 0.032 Uiso 1 1 calc R U . . .
C2 C 0.4808(3) 0.8548(3) 0.6452(3) 0.0242(9) Uani 1 1 d . . . . .
H2A H 0.429019 0.897592 0.689013 0.029 Uiso 1 1 calc R U . . .
H2B H 0.468034 0.784257 0.644787 0.029 Uiso 1 1 calc R U . . .
C3 C 0.1094(4) 0.8317(4) 0.4043(5) 0.0467(15) Uani 1 1 d . . . . .
C4 C 0.0454(5) 0.8165(5) 0.3198(5) 0.0546(17) Uani 1 1 d . . . . .
C5 C -0.0615(5) 0.8346(6) 0.3327(8) 0.081(3) Uani 1 1 d . . . . .
H5 H -0.105875 0.824131 0.276933 0.097 Uiso 1 1 calc R U . . .
C6 C -0.1052(5) 0.8666(7) 0.4216(8) 0.090(3) Uani 1 1 d . . . . .
H6 H -0.178227 0.880154 0.427637 0.108 Uiso 1 1 calc R U . . .
C7 C -0.0434(5) 0.8793(7) 0.5027(7) 0.087(3) Uani 1 1 d . . . . .
H7 H -0.074064 0.899777 0.564857 0.104 Uiso 1 1 calc R U . . .
C8 C 0.0641(5) 0.8622(6) 0.4937(6) 0.065(2) Uani 1 1 d . . . . .
H8 H 0.106816 0.871697 0.550163 0.078 Uiso 1 1 calc R U . . .
C9 C 0.0874(6) 0.7820(5) 0.2191(6) 0.073(2) Uani 1 1 d . . . . .
H9A H 0.032357 0.784930 0.173501 0.109 Uiso 1 1 calc R U . . .
H9B H 0.106128 0.710784 0.198391 0.109 Uiso 1 1 calc R U . . .
H9C H 0.151361 0.827799 0.219631 0.109 Uiso 1 1 calc R U . . .
C10 C 0.2756(4) 0.6957(4) 0.3018(4) 0.0413(13) Uani 1 1 d . . . . .
C11 C 0.2173(6) 0.6039(4) 0.2974(5) 0.0608(19) Uani 1 1 d . . . . .
C12 C 0.1287(6) 0.5989(6) 0.3605(7) 0.082(3) Uani 1 1 d . . . . .
H12A H 0.114794 0.527980 0.357125 0.124 Uiso 1 1 calc R U . . .
H12B H 0.064155 0.618998 0.338081 0.124 Uiso 1 1 calc R U . . .
H12C H 0.148340 0.646269 0.428129 0.124 Uiso 1 1 calc R U . . .
C13 C 0.2487(8) 0.5104(6) 0.2263(7) 0.092(3) Uani 1 1 d . . . . .
H13 H 0.211729 0.445802 0.219323 0.110 Uiso 1 1 calc R U . . .
C14 C 0.3335(8) 0.5127(6) 0.1667(6) 0.088(3) Uani 1 1 d . . . . .
H14 H 0.351804 0.449080 0.119105 0.105 Uiso 1 1 calc R U . . .
C15 C 0.3926(7) 0.6045(6) 0.1740(5) 0.077(2) Uani 1 1 d . . . . .
H15 H 0.451955 0.603979 0.134479 0.093 Uiso 1 1 calc R U . . .
C16 C 0.3615(6) 0.6953(5) 0.2405(4) 0.0545(16) Uani 1 1 d . . . . .
H16 H 0.398414 0.759236 0.245606 0.065 Uiso 1 1 calc R U . . .
C17 C 0.5035(3) 0.7268(3) 0.4417(3) 0.0257(9) Uani 1 1 d . . . . .
C18 C 0.4489(4) 0.6306(4) 0.4293(4) 0.0331(11) Uani 1 1 d . . . . .
H18 H 0.381978 0.627757 0.458182 0.040 Uiso 1 1 calc R U . . .
C19 C 0.4928(4) 0.5407(4) 0.3753(4) 0.0403(12) Uani 1 1 d . . . . .
H19 H 0.455603 0.475802 0.366932 0.048 Uiso 1 1 calc R U . . .
C20 C 0.5907(4) 0.5436(4) 0.3330(4) 0.0404(12) Uani 1 1 d . . . . .
H20 H 0.619765 0.480986 0.295076 0.048 Uiso 1 1 calc R U . . .
C21 C 0.6460(4) 0.6382(4) 0.3461(4) 0.0389(11) Uani 1 1 d . . . . .
H21 H 0.713700 0.640559 0.318242 0.047 Uiso 1 1 calc R U . . .
C22 C 0.6027(4) 0.7289(4) 0.3995(4) 0.0314(10) Uani 1 1 d . . . . .
H22 H 0.640522 0.793555 0.407856 0.038 Uiso 1 1 calc R U . . .
C23 C 0.6141(4) 0.9584(4) 0.8296(3) 0.0288(10) Uani 1 1 d . . . . .
C24 C 0.6000(4) 0.8938(4) 0.8819(3) 0.0323(10) Uani 1 1 d . . . . .
C25 C 0.6195(4) 0.9401(4) 0.9830(4) 0.0391(12) Uani 1 1 d . . . . .
H25 H 0.612782 0.897864 1.019564 0.047 Uiso 1 1 calc R U . . .
C26 C 0.6484(4) 1.0457(5) 1.0322(4) 0.0451(13) Uani 1 1 d . . . . .
H26 H 0.662135 1.074547 1.101058 0.054 Uiso 1 1 calc R U . . .
C27 C 0.6571(5) 1.1084(4) 0.9804(4) 0.0465(13) Uani 1 1 d . . . . .
H27 H 0.674415 1.181051 1.013534 0.056 Uiso 1 1 calc R U . . .
C28 C 0.6403(4) 1.0645(4) 0.8801(4) 0.0384(11) Uani 1 1 d . . . . .
H28 H 0.646918 1.107814 0.844572 0.046 Uiso 1 1 calc R U . . .
C29 C 0.5641(5) 0.7796(4) 0.8353(4) 0.0414(12) Uani 1 1 d . . . . .
H29A H 0.542818 0.754594 0.886152 0.062 Uiso 1 1 calc R U . . .
H29B H 0.623159 0.742325 0.800017 0.062 Uiso 1 1 calc R U . . .
H29C H 0.502965 0.767461 0.789480 0.062 Uiso 1 1 calc R U . . .
C30 C 0.7050(4) 0.8055(3) 0.6600(3) 0.0271(9) Uani 1 1 d . . . . .
C31 C 0.8142(4) 0.8297(4) 0.6879(4) 0.0347(11) Uani 1 1 d . . . . .
C32 C 0.8802(4) 0.7504(4) 0.6530(4) 0.0442(13) Uani 1 1 d . . . . .
H32 H 0.954593 0.765593 0.670901 0.053 Uiso 1 1 calc R U . . .
C33 C 0.8417(4) 0.6503(4) 0.5933(4) 0.0428(12) Uani 1 1 d . . . . .
H33 H 0.889485 0.598265 0.569425 0.051 Uiso 1 1 calc R U . . .
C34 C 0.7341(4) 0.6263(4) 0.5686(4) 0.0371(11) Uani 1 1 d . . . . .
H34 H 0.706589 0.557179 0.528873 0.045 Uiso 1 1 calc R U . . .
C35 C 0.6657(4) 0.7041(4) 0.6024(3) 0.0314(10) Uani 1 1 d . . . . .
H35 H 0.591146 0.687597 0.585797 0.038 Uiso 1 1 calc R U . . .
C36 C 0.8623(4) 0.9368(4) 0.7547(5) 0.0524(15) Uani 1 1 d . . . . .
H36A H 0.940508 0.938409 0.757805 0.079 Uiso 1 1 calc R U . . .
H36B H 0.835359 0.954000 0.820336 0.079 Uiso 1 1 calc R U . . .
H36C H 0.842107 0.987375 0.729137 0.079 Uiso 1 1 calc R U . . .
C37 C 0.5784(15) 0.9445(17) 0.3768(10) 0.017(3) Uani 0.5 1 d D U P A -1
C38 C 0.6297(10) 0.9158(13) 0.3033(7) 0.020(3) Uani 0.5 1 d D U P A -1
C39 C 0.7022(15) 0.8844(12) 0.2235(11) 0.022(2) Uani 0.5 1 d D U P A -1
C40 C 0.7021(11) 0.7786(10) 0.1628(9) 0.027(2) Uani 0.5 1 d D U P A -1
H40 H 0.653373 0.728580 0.173174 0.032 Uiso 0.5 1 calc R U P A -1
C41 C 0.7732(10) 0.7474(8) 0.0880(8) 0.027(2) Uani 0.5 1 d D U P A -1
H41 H 0.772342 0.675829 0.047541 0.033 Uiso 0.5 1 calc R U P A -1
C42 C 0.8458(9) 0.8187(7) 0.0709(8) 0.028(2) Uani 0.5 1 d D U P A -1
C43 C 0.8452(14) 0.9239(10) 0.1335(12) 0.024(2) Uani 0.5 1 d . U P A -1
H43 H 0.899077 0.972302 0.126641 0.029 Uiso 0.5 1 calc R U P A -1
C44 C 0.7692(15) 0.9622(17) 0.2059(14) 0.021(2) Uani 0.5 1 d . U P A -1
H44 H 0.763313 1.034068 0.240073 0.025 Uiso 0.5 1 calc R U P A -1
C45 C 0.9172(8) 0.7840(7) -0.0173(7) 0.037(2) Uani 0.5 1 d D U P A -1
C46 C 0.8540(10) 0.7779(10) -0.1081(6) 0.050(2) Uani 0.5 1 d D U P A -1
H46A H 0.901067 0.761378 -0.163386 0.076 Uiso 0.5 1 calc R U P A -1
H46B H 0.826581 0.844680 -0.095238 0.076 Uiso 0.5 1 calc R U P A -1
H46C H 0.793794 0.723673 -0.123875 0.076 Uiso 0.5 1 calc R U P A -1
C47 C 0.9539(9) 0.6782(7) -0.0365(7) 0.045(2) Uani 0.5 1 d D U P A -1
H47A H 0.997709 0.657245 -0.094120 0.067 Uiso 0.5 1 calc R U P A -1
H47B H 0.891220 0.627319 -0.048224 0.067 Uiso 0.5 1 calc R U P A -1
H47C H 0.996545 0.681844 0.020418 0.067 Uiso 0.5 1 calc R U P A -1
C48 C 1.0156(9) 0.8619(10) -0.0010(9) 0.062(3) Uani 0.5 1 d D U P A -1
H48A H 1.067491 0.831457 -0.050611 0.093 Uiso 0.5 1 calc R U P A -1
H48B H 1.048507 0.879507 0.064204 0.093 Uiso 0.5 1 calc R U P A -1
H48C H 0.994173 0.924745 -0.006225 0.093 Uiso 0.5 1 calc R U P A -1
C49 C 0.4180(18) 1.062(2) 0.6206(12) 0.033(4) Uani 0.5 1 d D U P A -2
C50 C 0.3643(10) 1.0858(13) 0.6927(8) 0.034(3) Uani 0.5 1 d D U P A -2
C51 C 0.3005(18) 1.1139(13) 0.7784(13) 0.035(3) Uani 0.5 1 d D U P A -2
C52 C 0.3000(14) 1.2143(12) 0.8495(10) 0.038(3) Uani 0.5 1 d D U P A -2
H52 H 0.348163 1.268664 0.845967 0.046 Uiso 0.5 1 calc R U P A -2
C53 C 0.2296(12) 1.2357(9) 0.9255(9) 0.038(3) Uani 0.5 1 d D U P A -2
H53 H 0.230028 1.304720 0.972411 0.046 Uiso 0.5 1 calc R U P A -2
C54 C 0.1590(11) 1.1582(8) 0.9340(9) 0.038(2) Uani 0.5 1 d D U P A -2
C55 C 0.1617(16) 1.0567(10) 0.8686(12) 0.036(3) Uani 0.5 1 d D U P A -2
H55 H 0.123591 1.000121 0.878040 0.043 Uiso 0.5 1 calc R U P A -2
C56 C 0.2233(19) 1.0430(19) 0.7887(16) 0.036(3) Uani 0.5 1 d D U P A -2
H56 H 0.211195 0.977868 0.735083 0.043 Uiso 0.5 1 calc R U P A -2
C57 C 0.0834(11) 1.1822(10) 1.0112(9) 0.051(3) Uani 0.5 1 d D U P A -2
C58 C 0.0162(11) 1.1953(13) 1.0709(10) 0.075(3) Uani 0.5 1 d D U P A -2
H58 H -0.037009 1.205610 1.118102 0.090 Uiso 0.5 1 calc R U P A -2
C59 C 0.8737(4) 0.4057(4) 0.3314(4) 0.0371(11) Uani 1 1 d . U . . .
Cl1 Cl 0.6371(5) 0.4542(5) 0.0792(3) 0.236(3) Uani 1 1 d . . . . .
Cl2 Cl 0.8617(7) 0.5253(5) 0.1097(7) 0.329(5) Uani 1 1 d . . . . .
C01 C 0.7646(10) 0.4150(8) 0.0414(12) 0.156(6) Uani 1 1 d . . . . .
H01A H 0.769746 0.396173 -0.029777 0.188 Uiso 1 1 calc R U . . .
H01B H 0.777910 0.354214 0.055998 0.188 Uiso 1 1 calc R U . . .
 
 
_geom_special_details
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;
 
loop_
 _geom_bond_atom_site_label_1
 _geom_bond_atom_site_label_2
 _geom_bond_distance
 _geom_bond_site_symmetry_2
 _geom_bond_publ_flag
Au1 P1 2.3218(12) . ?
Au1 P3 2.3310(11) 2_676 ?
Au1 Pt1 2.89821(19) . ?
Pt1 C37 1.995(6) . ?
Pt1 C49 2.000(7) . ?
Pt1 P2 2.3166(11) . ?
Pt1 P2 2.3166(11) 2_676 ?
S1 O3 1.431(4) . ?
S1 O2 1.437(4) . ?
S1 O1 1.445(4) . ?
S1 C59 1.807(5) . ?
P1 C3 1.813(5) . ?
P1 C10 1.815(6) . ?
P1 C1 1.828(5) . ?
P2 C17 1.812(5) . ?
P2 C1 1.831(4) . ?
P2 C2 1.854(4) . ?
P3 C30 1.829(5) . ?
P3 C23 1.830(5) . ?
P3 C2 1.833(4) . ?
F1 C59 1.339(6) . ?
F2 C59 1.328(6) . ?
F3 C59 1.325(6) . ?
C3 C8 1.371(10) . ?
C3 C4 1.419(8) . ?
C4 C5 1.388(10) . ?
C4 C9 1.498(11) . ?
C5 C6 1.356(13) . ?
C6 C7 1.371(12) . ?
C7 C8 1.390(9) . ?
C10 C11 1.405(8) . ?
C10 C16 1.415(9) . ?
C11 C13 1.422(12) . ?
C11 C12 1.473(11) . ?
C13 C14 1.394(13) . ?
C14 C15 1.396(12) . ?
C15 C16 1.369(9) . ?
C17 C22 1.399(6) . ?
C17 C18 1.405(6) . ?
C18 C19 1.375(7) . ?
C19 C20 1.389(8) . ?
C20 C21 1.387(7) . ?
C21 C22 1.378(7) . ?
C23 C28 1.391(7) . ?
C23 C24 1.412(6) . ?
C24 C25 1.395(7) . ?
C24 C29 1.505(7) . ?
C25 C26 1.389(8) . ?
C26 C27 1.378(8) . ?
C27 C28 1.380(7) . ?
C30 C35 1.388(6) . ?
C30 C31 1.400(6) . ?
C31 C32 1.388(7) . ?
C31 C36 1.510(7) . ?
C32 C33 1.379(8) . ?
C33 C34 1.373(7) . ?
C34 C35 1.393(7) . ?
C37 C38 1.217(6) . ?
C38 C39 1.452(7) . ?
C39 C40 1.409(8) . ?
C39 C44 1.426(15) . ?
C40 C41 1.389(9) . ?
C41 C42 1.392(9) . ?
C42 C43 1.410(13) . ?
C42 C45 1.535(8) . ?
C43 C44 1.419(18) . ?
C45 C47 1.521(9) . ?
C45 C48 1.526(9) . ?
C45 C46 1.531(9) . ?
C49 C50 1.219(6) . ?
C50 C51 1.448(8) . ?
C51 C56 1.380(10) . ?
C51 C52 1.397(7) . ?
C52 C53 1.393(7) . ?
C53 C54 1.388(7) . ?
C54 C55 1.384(9) . ?
C54 C57 1.449(7) . ?
C55 C56 1.380(10) . ?
C57 C58 1.201(8) . ?
Cl1 C01 1.763(13) . ?
Cl2 C01 1.826(13) . ?
 
loop_
 _geom_angle_atom_site_label_1
 _geom_angle_atom_site_label_2
 _geom_angle_atom_site_label_3
 _geom_angle
 _geom_angle_site_symmetry_1
 _geom_angle_site_symmetry_3
 _geom_angle_publ_flag
P1 Au1 P3 172.48(4) . 2_676 ?
P1 Au1 Pt1 90.43(3) . . ?
P3 Au1 Pt1 97.06(3) 2_676 . ?
C37 Pt1 P2 99.2(7) . . ?
C49 Pt1 P2 83.7(9) . . ?
C37 Pt1 P2 80.8(7) . 2_676 ?
P2 Pt1 P2 180.00(5) . 2_676 ?
C37 Pt1 Au1 79.1(7) . . ?
C49 Pt1 Au1 98.7(8) . . ?
P2 Pt1 Au1 92.55(3) . . ?
P2 Pt1 Au1 87.45(3) 2_676 . ?
C37 Pt1 Au1 100.9(7) . 2_676 ?
P2 Pt1 Au1 87.45(3) . 2_676 ?
P2 Pt1 Au1 92.55(3) 2_676 2_676 ?
Au1 Pt1 Au1 180.0 . 2_676 ?
O3 S1 O2 117.3(3) . . ?
O3 S1 O1 114.5(3) . . ?
O2 S1 O1 113.8(3) . . ?
O3 S1 C59 102.9(3) . . ?
O2 S1 C59 103.0(2) . . ?
O1 S1 C59 102.6(2) . . ?
C3 P1 C10 110.0(3) . . ?
C3 P1 C1 107.1(2) . . ?
C10 P1 C1 105.2(2) . . ?
C3 P1 Au1 108.58(16) . . ?
C10 P1 Au1 113.22(19) . . ?
C1 P1 Au1 112.58(15) . . ?
C17 P2 C1 107.5(2) . . ?
C17 P2 C2 103.9(2) . . ?
C1 P2 C2 102.4(2) . . ?
C17 P2 Pt1 121.28(15) . . ?
C1 P2 Pt1 106.29(14) . . ?
C2 P2 Pt1 113.89(14) . . ?
C30 P3 C23 106.1(2) . . ?
C30 P3 C2 109.2(2) . . ?
C23 P3 C2 108.3(2) . . ?
C30 P3 Au1 113.18(15) . 2_676 ?
C23 P3 Au1 110.96(15) . 2_676 ?
C2 P3 Au1 109.01(14) . 2_676 ?
P1 C1 P2 113.0(2) . . ?
P3 C2 P2 115.1(2) . . ?
C8 C3 C4 119.6(6) . . ?
C8 C3 P1 121.7(4) . . ?
C4 C3 P1 118.4(5) . . ?
C5 C4 C3 117.4(7) . . ?
C5 C4 C9 119.3(6) . . ?
C3 C4 C9 123.3(6) . . ?
C6 C5 C4 122.7(7) . . ?
C5 C6 C7 119.6(7) . . ?
C6 C7 C8 119.9(8) . . ?
C3 C8 C7 120.8(7) . . ?
C11 C10 C16 122.2(6) . . ?
C11 C10 P1 122.3(5) . . ?
C16 C10 P1 115.4(4) . . ?
C10 C11 C13 115.9(8) . . ?
C10 C11 C12 124.9(6) . . ?
C13 C11 C12 119.3(7) . . ?
C14 C13 C11 120.5(7) . . ?
C13 C14 C15 122.9(8) . . ?
C16 C15 C14 117.2(9) . . ?
C15 C16 C10 121.3(7) . . ?
C22 C17 C18 119.0(4) . . ?
C22 C17 P2 120.0(3) . . ?
C18 C17 P2 120.7(4) . . ?
C19 C18 C17 119.7(5) . . ?
C18 C19 C20 120.9(5) . . ?
C21 C20 C19 119.8(5) . . ?
C22 C21 C20 119.9(5) . . ?
C21 C22 C17 120.7(4) . . ?
C28 C23 C24 119.7(4) . . ?
C28 C23 P3 116.4(4) . . ?
C24 C23 P3 123.4(4) . . ?
C25 C24 C23 117.2(4) . . ?
C25 C24 C29 118.8(4) . . ?
C23 C24 C29 124.0(4) . . ?
C26 C25 C24 122.5(5) . . ?
C27 C26 C25 119.5(5) . . ?
C26 C27 C28 119.3(5) . . ?
C27 C28 C23 121.7(5) . . ?
C35 C30 C31 119.9(4) . . ?
C35 C30 P3 120.8(3) . . ?
C31 C30 P3 119.3(3) . . ?
C32 C31 C30 117.7(4) . . ?
C32 C31 C36 119.1(4) . . ?
C30 C31 C36 123.2(4) . . ?
C33 C32 C31 122.4(5) . . ?
C34 C33 C32 119.7(5) . . ?
C33 C34 C35 119.3(5) . . ?
C30 C35 C34 120.9(4) . . ?
C38 C37 Pt1 176.4(12) . . ?
C37 C38 C39 173.1(9) . . ?
C40 C39 C44 121.3(11) . . ?
C40 C39 C38 119.6(8) . . ?
C44 C39 C38 119.0(12) . . ?
C41 C40 C39 120.1(8) . . ?
C40 C41 C42 121.4(8) . . ?
C41 C42 C43 117.4(9) . . ?
C41 C42 C45 120.6(7) . . ?
C43 C42 C45 121.8(8) . . ?
C42 C43 C44 124.1(14) . . ?
C43 C44 C39 114.9(18) . . ?
C47 C45 C48 108.8(10) . . ?
C47 C45 C46 108.8(8) . . ?
C48 C45 C46 107.7(9) . . ?
C47 C45 C42 111.3(7) . . ?
C48 C45 C42 110.9(7) . . ?
C46 C45 C42 109.3(7) . . ?
C50 C49 Pt1 170.9(15) . . ?
C49 C50 C51 180.0(2) . . ?
C56 C51 C52 114.0(13) . . ?
C56 C51 C50 120.7(12) . . ?
C52 C51 C50 124.8(9) . . ?
C53 C52 C51 120.8(9) . . ?
C54 C53 C52 121.4(8) . . ?
C55 C54 C53 119.5(9) . . ?
C55 C54 C57 119.7(8) . . ?
C53 C54 C57 120.8(7) . . ?
C56 C55 C54 115.6(17) . . ?
C51 C56 C55 127(2) . . ?
C58 C57 C54 175.0(15) . . ?
F3 C59 F2 108.1(4) . . ?
F3 C59 F1 107.8(4) . . ?
F2 C59 F1 106.4(4) . . ?
F3 C59 S1 112.0(3) . . ?
F2 C59 S1 111.1(4) . . ?
F1 C59 S1 111.1(3) . . ?
Cl1 C01 Cl2 106.4(7) . . ?
 
_refine_diff_density_max    1.329
_refine_diff_density_min   -1.459
_refine_diff_density_rms    0.219



