data_R_293K _audit_creation_method SHELXL-97 _chemical_name_systematic ; ? ; _chemical_name_common ? _chemical_melting_point ? _chemical_formula_moiety 'C16 H40 Bi2 Br12 N4 O4 Rb2' _chemical_formula_sum 'C16 H40 Bi2 Br12 N4 O4 Rb2' _chemical_formula_weight 1900.22 _chemical_absolute_configuration 'R' loop_ _atom_type_symbol _atom_type_description _atom_type_scat_dispersion_real _atom_type_scat_dispersion_imag _atom_type_scat_source 'C' 'C' 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' 'H' 'H' 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' 'N' 'N' 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' 'O' 'O' 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' 'Br' 'Br' -0.2901 2.4595 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' 'Rb' 'Rb' -0.9393 2.9676 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' 'Bi' 'Bi' -4.1077 10.2566 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' _symmetry_cell_setting 'triclinic' _symmetry_space_group_name_H-M 'P1' _symmetry_space_group_name_HALL 'P1' loop_ _symmetry_equiv_pos_as_xyz 'x, y, z' _cell_length_a 8.7893(4) _cell_length_b 14.0924(7) _cell_length_c 9.6968(5) _cell_angle_alpha 93.982(4) _cell_angle_beta 67.441(5) _cell_angle_gamma 92.837(4) _cell_volume 1106.15(10) _cell_formula_units_Z 1 _cell_measurement_temperature 293(2) _cell_measurement_reflns_used 5896 _cell_measurement_theta_min 2.28 _cell_measurement_theta_max 24.990 _exptl_crystal_description 'block' _exptl_crystal_colour 'light yellow' _exptl_crystal_size_max 0.200 _exptl_crystal_size_mid 0.200 _exptl_crystal_size_min 0.200 _exptl_crystal_density_meas ? _exptl_crystal_density_diffrn 2.853 _exptl_crystal_density_method 'not measured' _exptl_crystal_F_000 856 _exptl_absorpt_coefficient_mu 20.993 _exptl_absorpt_correction_type 'multi-scan' _exptl_absorpt_correction_T_min 0.015 _exptl_absorpt_correction_T_max 0.021 _exptl_absorpt_process_details 'CrysAlisPro 1.171.39.46 (Rigaku OD, 2018)' _exptl_special_details ; ? ; _diffrn_ambient_temperature 293(2) _diffrn_radiation_wavelength 0.71073 _diffrn_radiation_type MoK\a _diffrn_radiation_source 'fine-focus sealed tube' _diffrn_radiation_monochromator graphite _diffrn_measurement_device_type 'XtaLAB Synergy R, DW system, HyPix' _diffrn_measurement_method '\w scans' _diffrn_detector_area_resol_mean ? _diffrn_standards_number ? _diffrn_standards_interval_count ? _diffrn_standards_interval_time ? _diffrn_standards_decay_% ? _diffrn_reflns_number 15431 _diffrn_reflns_av_R_equivalents 0.0704 _diffrn_reflns_av_sigmaI/netI 0.1109 _diffrn_reflns_limit_h_min -10 _diffrn_reflns_limit_h_max 10 _diffrn_reflns_limit_k_min -16 _diffrn_reflns_limit_k_max 16 _diffrn_reflns_limit_l_min -11 _diffrn_reflns_limit_l_max 11 _diffrn_reflns_theta_min 2.28 _diffrn_reflns_theta_max 24.99 _reflns_number_total 7249 _reflns_number_gt 5896 _reflns_threshold_expression >2sigma(I) _computing_data_collection ? _computing_cell_refinement ? _computing_data_reduction ? _computing_structure_solution 'SHELXS-97 (Sheldrick, 1990)' _computing_structure_refinement 'SHELXL-97 (Sheldrick, 1997)' _computing_molecular_graphics ? _computing_publication_material ? _refine_special_details ; Refinement of F^2^ against ALL reflections. The weighted R-factor wR and goodness of fit S are based on F^2^, conventional R-factors R are based on F, with F set to zero for negative F^2^. The threshold expression of F^2^ > 2sigma(F^2^) is used only for calculating R-factors(gt) etc. and is not relevant to the choice of reflections for refinement. R-factors based on F^2^ are statistically about twice as large as those based on F, and R- factors based on ALL data will be even larger. ; _refine_ls_structure_factor_coef Fsqd _refine_ls_matrix_type full _refine_ls_weighting_scheme calc _refine_ls_weighting_details 'calc w=1/[\s^2^(Fo^2^)+(0.0904P)^2^+0.0000P] where P=(Fo^2^+2Fc^2^)/3' _atom_sites_solution_primary direct _atom_sites_solution_secondary difmap _atom_sites_solution_hydrogens geom _refine_ls_hydrogen_treatment mixed _refine_ls_extinction_method SHELXL _refine_ls_extinction_coef 0.00939(14) _refine_ls_extinction_expression 'Fc^*^=kFc[1+0.001xFc^2^\l^3^/sin(2\q)]^-1/4^' _refine_ls_abs_structure_details 'Flack H D (1983), Acta Cryst. A39, 876-881' _refine_ls_abs_structure_Flack -0.018(15) _refine_ls_number_reflns 7249 _refine_ls_number_parameters 356 _refine_ls_number_restraints 153 _refine_ls_R_factor_all 0.0865 _refine_ls_R_factor_gt 0.0686 _refine_ls_wR_factor_ref 0.1685 _refine_ls_wR_factor_gt 0.1603 _refine_ls_goodness_of_fit_ref 1.061 _refine_ls_restrained_S_all 1.051 _refine_ls_shift/su_max 0.001 _refine_ls_shift/su_mean 0.000 loop_ _atom_site_label _atom_site_type_symbol _atom_site_fract_x _atom_site_fract_y _atom_site_fract_z _atom_site_U_iso_or_equiv _atom_site_adp_type _atom_site_occupancy _atom_site_symmetry_multiplicity _atom_site_calc_flag _atom_site_refinement_flags _atom_site_disorder_assembly _atom_site_disorder_group Bi1 Bi 0.37817(4) 0.11645(3) 0.95881(3) 0.02507(9) Uani 1 1 d . . . Bi2 Bi 0.70944(4) -0.38872(3) 0.35979(3) 0.02653(9) Uani 1 1 d . . . Br3 Br 0.54273(13) -0.01274(8) 0.70161(11) 0.0438(4) Uani 1 1 d . . . Br4 Br 0.65742(12) 0.24120(8) 0.87602(10) 0.0392(3) Uani 1 1 d . . . Br5 Br 0.23949(11) 0.23508(7) 1.21724(10) 0.0364(3) Uani 1 1 d . . . Br6 Br 0.42561(12) -0.26968(7) 0.46114(10) 0.0369(3) Uani 1 1 d . . . Br7 Br 0.86228(12) -0.25591(7) 0.49425(11) 0.0457(3) Uani 1 1 d . . . Br8 Br 0.83851(12) -0.29205(8) 0.09047(11) 0.0405(3) Uani 1 1 d . . . Br9 Br 0.08615(13) -0.00327(8) 1.03402(11) 0.0470(4) Uani 1 1 d . . . Br10 Br 0.99128(13) -0.50478(8) 0.28195(12) 0.0489(4) Uani 1 1 d . . . Br11 Br 0.55926(17) -0.47560(8) 0.64292(12) 0.0562(4) Uani 1 1 d . . . Br12 Br 0.23518(13) 0.22204(8) 0.80970(12) 0.0497(3) Uani 1 1 d . . . Br14 Br 0.54718(14) -0.53024(8) 0.22457(12) 0.0547(4) Uani 1 1 d . . . Br16 Br 0.53285(13) 0.01036(7) 1.12426(11) 0.0506(3) Uani 1 1 d . . . Rb1 Rb 0.33419(13) 0.43162(7) 0.97674(11) 0.0461(4) Uani 1 1 d . . . Rb2 Rb 0.74776(14) -0.07579(8) 0.33069(11) 0.0480(4) Uani 1 1 d . . . N1 N 0.4690(10) 0.7554(6) 0.8059(9) 0.049(3) Uani 1 1 d U . . H1A H 0.4995 0.7025 0.7456 0.058 Uiso 1 1 calc R . . H1B H 0.4934 0.8061 0.7490 0.058 Uiso 1 1 calc R . . N2 N 0.6159(9) 0.2382(6) 0.2465(9) 0.048(3) Uani 1 1 d U . . H2D H 0.6021 0.1831 0.1993 0.057 Uiso 1 1 calc R . . H2C H 0.5784 0.2857 0.2115 0.057 Uiso 1 1 calc R . . C5 C 0.2873(13) 0.7507(9) 0.9006(12) 0.053(3) Uani 1 1 d U . . H5A H 0.2310 0.8017 0.8792 0.064 Uiso 1 1 calc R . . H5B H 0.2391 0.6904 0.8812 0.064 Uiso 1 1 calc R . . C3 C 0.8104(13) 0.2309(8) 0.3569(12) 0.055(3) Uani 1 1 d U . . H3 H 0.9015 0.2676 0.3711 0.066 Uiso 1 1 calc R . . C7 C 0.5549(12) 0.7641(8) 0.9122(10) 0.046(3) Uani 1 1 d U . . H7A H 0.6546 0.7275 0.8741 0.055 Uiso 1 1 calc R . . H7B H 0.5835 0.8300 0.9289 0.055 Uiso 1 1 calc R . . C2 C 0.6453(12) 0.2546(8) 0.4801(11) 0.052(3) Uani 1 1 d U . . H2A H 0.6233 0.2156 0.5646 0.063 Uiso 1 1 calc R . . H2B H 0.6432 0.3211 0.5140 0.063 Uiso 1 1 calc R . . C4 C 0.5237(13) 0.2337(9) 0.4112(11) 0.052(3) Uani 1 1 d U . . H4B H 0.4374 0.2802 0.4469 0.063 Uiso 1 1 calc R . . H4A H 0.4737 0.1710 0.4354 0.063 Uiso 1 1 calc R . . O1 O 0.4363(10) 0.6250(5) 1.0447(8) 0.071(3) Uani 1 1 d U . . H1C H 0.5260 0.6072 1.0392 0.107 Uiso 1 1 calc R . . O2 O 0.8315(9) 0.1319(5) 0.3518(8) 0.058(3) Uani 1 1 d U . . H2E H 0.9240 0.1182 0.2833 0.086 Uiso 1 1 d R . . N3 N 0.1456(13) 0.5367(7) 0.5549(10) 0.079(3) Uani 1 1 d U . . H3A H 0.1222 0.5450 0.4741 0.095 Uiso 1 1 calc R . . H3B H 0.2408 0.5683 0.5438 0.095 Uiso 1 1 calc R . . C12 C 0.0042(17) 0.5765(9) 0.6987(13) 0.076(4) Uani 1 1 d U . . H12A H 0.0416 0.6317 0.7436 0.091 Uiso 1 1 calc R . . H12B H -0.0899 0.5933 0.6773 0.091 Uiso 1 1 calc R . . C10 C 0.1632(16) 0.4330(9) 0.5684(14) 0.077(4) Uani 1 1 d U . . H10A H 0.2583 0.4221 0.5922 0.093 Uiso 1 1 calc R . . H10B H 0.1731 0.3964 0.4770 0.093 Uiso 1 1 calc R . . C9 C 0.4374(13) 0.7264(8) 1.0492(11) 0.048(3) Uani 1 1 d U . . H9 H 0.4608 0.7531 1.1353 0.057 Uiso 1 1 calc R . . C6 C 0.2735(13) 0.7605(10) 1.0575(13) 0.063(4) Uani 1 1 d U . . H6A H 0.1832 0.7213 1.1207 0.076 Uiso 1 1 calc R . . H6B H 0.2568 0.8262 1.0959 0.076 Uiso 1 1 calc R . . O3 O 0.0597(10) 0.5026(6) 0.8868(8) 0.073(3) Uani 1 1 d U . . H3C H 0.0377 0.5537 0.9419 0.110 Uiso 1 1 d R . . O4 O 1.0547(11) -0.0156(7) 0.4039(8) 0.078(3) Uani 1 1 d U . . H4E H 0.9951 0.0264 0.3921 0.117 Uiso 1 1 d R . . C16 C 0.9948(14) 0.0891(8) 0.6132(12) 0.061(4) Uani 1 1 d U . . H16A H 0.9105 0.1010 0.5753 0.073 Uiso 1 1 calc R . . H16B H 1.0487 0.1491 0.6252 0.073 Uiso 1 1 calc R . . C15 C 1.1145(15) 0.0212(10) 0.5127(13) 0.066(4) Uani 1 1 d U . . H15 H 1.2218 0.0533 0.4646 0.080 Uiso 1 1 calc R . . C13 C 0.0049(15) 0.4080(9) 0.6956(13) 0.067(4) Uani 1 1 d U . . H13A H -0.0818 0.3900 0.6595 0.080 Uiso 1 1 calc R . . H13B H 0.0202 0.3564 0.7498 0.080 Uiso 1 1 calc R . . C14 C -0.0342(14) 0.4986(9) 0.7919(12) 0.059(4) Uani 1 1 d U . . H14 H -0.1521 0.4985 0.8548 0.071 Uiso 1 1 calc R . . C19 C 0.9597(14) -0.0614(9) 0.7270(14) 0.068(4) Uani 1 1 d U . . H19B H 0.8823 -0.0962 0.6919 0.081 Uiso 1 1 calc R . . H19A H 0.9605 -0.0899 0.8149 0.081 Uiso 1 1 calc R . . N4 N 0.9235(12) 0.0416(8) 0.7558(10) 0.076(4) Uani 1 1 d U . . H4C H 0.8138 0.0494 0.7966 0.092 Uiso 1 1 calc R . . H4D H 0.9671 0.0675 0.8203 0.092 Uiso 1 1 calc R . . C20 C 1.1287(14) -0.0557(9) 0.6067(13) 0.070(4) Uani 1 1 d U . . H20A H 1.1572 -0.1157 0.5487 0.084 Uiso 1 1 calc R . . H20B H 1.2110 -0.0387 0.6486 0.084 Uiso 1 1 calc R . . C17 C 0.7891(14) 0.2548(9) 0.2199(14) 0.067(4) Uani 1 1 d U . . H17A H 0.8203 0.3209 0.1991 0.080 Uiso 1 1 calc R . . H17B H 0.8572 0.2150 0.1350 0.080 Uiso 1 1 calc R . . loop_ _atom_site_aniso_label _atom_site_aniso_U_11 _atom_site_aniso_U_22 _atom_site_aniso_U_33 _atom_site_aniso_U_23 _atom_site_aniso_U_13 _atom_site_aniso_U_12 Bi1 0.02105(14) 0.02915(16) 0.02071(14) -0.00191(13) -0.00355(11) 0.00241(13) Bi2 0.02569(15) 0.02658(16) 0.02060(14) -0.00450(13) -0.00217(12) 0.00210(13) Br3 0.0448(6) 0.0435(6) 0.0250(5) -0.0079(5) 0.0053(4) 0.0017(5) Br4 0.0329(5) 0.0475(6) 0.0292(5) 0.0027(5) -0.0044(4) -0.0105(5) Br5 0.0294(5) 0.0427(5) 0.0282(5) -0.0088(4) -0.0026(4) 0.0048(4) Br6 0.0343(5) 0.0408(5) 0.0311(5) -0.0036(4) -0.0068(4) 0.0127(4) Br7 0.0602(5) 0.0347(5) 0.0537(5) -0.0047(5) -0.0364(4) -0.0029(5) Br8 0.0351(5) 0.0535(6) 0.0260(5) 0.0051(5) -0.0035(4) 0.0018(5) Br9 0.0398(6) 0.0572(7) 0.0291(5) 0.0017(5) 0.0008(4) -0.0192(5) Br10 0.0407(6) 0.0520(6) 0.0453(6) -0.0131(5) -0.0066(5) 0.0231(5) Br11 0.0767(8) 0.0426(6) 0.0272(5) 0.0078(5) 0.0044(5) -0.0079(6) Br12 0.0601(6) 0.0462(6) 0.0545(5) 0.0058(5) -0.0334(4) 0.0090(5) Br14 0.0794(6) 0.0323(6) 0.0712(6) -0.0046(5) -0.0513(4) -0.0026(5) Br16 0.0763(6) 0.0339(5) 0.0633(5) -0.0069(5) -0.0507(4) 0.0152(5) Rb1 0.0551(6) 0.0420(6) 0.0316(5) 0.0050(5) -0.0056(4) -0.0003(5) Rb2 0.0604(6) 0.0434(6) 0.0277(5) 0.0059(5) -0.0019(5) 0.0050(5) N1 0.063(4) 0.046(5) 0.048(4) 0.010(4) -0.034(3) -0.006(4) N2 0.047(4) 0.049(5) 0.048(4) 0.012(4) -0.019(3) -0.014(4) C5 0.046(5) 0.063(6) 0.052(5) -0.010(5) -0.021(4) 0.015(5) C3 0.054(5) 0.062(6) 0.051(5) -0.006(5) -0.023(4) 0.011(5) C7 0.047(5) 0.060(6) 0.036(4) 0.008(5) -0.023(4) -0.013(5) C2 0.045(4) 0.063(5) 0.040(4) -0.014(4) -0.009(3) 0.001(4) C4 0.045(4) 0.063(5) 0.040(4) -0.014(4) -0.009(3) 0.001(4) O1 0.112(5) 0.044(4) 0.069(4) 0.028(4) -0.046(4) -0.011(4) O2 0.055(4) 0.043(4) 0.075(5) 0.004(4) -0.025(3) 0.006(4) N3 0.105(6) 0.086(6) 0.036(4) -0.006(5) -0.025(4) -0.055(5) C12 0.108(7) 0.063(7) 0.060(6) 0.009(6) -0.033(6) 0.012(6) C10 0.072(7) 0.084(7) 0.059(6) -0.036(6) -0.012(5) 0.003(6) C9 0.059(5) 0.057(5) 0.026(4) 0.009(4) -0.014(3) -0.001(4) C6 0.040(6) 0.083(7) 0.050(6) -0.005(6) 0.000(5) -0.003(6) O3 0.080(5) 0.084(5) 0.054(4) -0.019(4) -0.026(4) 0.025(5) O4 0.093(5) 0.098(6) 0.044(4) 0.001(4) -0.029(4) 0.004(5) C16 0.077(6) 0.052(6) 0.063(5) -0.024(5) -0.041(4) 0.012(5) C15 0.062(6) 0.079(6) 0.059(6) -0.002(6) -0.025(5) 0.002(6) C13 0.078(6) 0.062(6) 0.067(6) -0.012(6) -0.036(5) 0.000(6) C14 0.063(5) 0.071(6) 0.048(5) -0.002(5) -0.024(4) 0.014(5) C19 0.064(5) 0.076(7) 0.074(6) -0.020(6) -0.042(4) 0.001(6) N4 0.073(5) 0.096(7) 0.068(5) -0.016(5) -0.037(4) 0.018(5) C20 0.073(6) 0.083(7) 0.072(6) -0.020(6) -0.049(4) 0.019(6) C17 0.058(6) 0.058(6) 0.077(7) 0.004(6) -0.018(5) -0.004(6) _geom_special_details ; All esds (except the esd in the dihedral angle between two l.s. planes) are estimated using the full covariance matrix. The cell esds are taken into account individually in the estimation of esds in distances, angles and torsion angles; correlations between esds in cell parameters are only used when they are defined by crystal symmetry. An approximate (isotropic) treatment of cell esds is used for estimating esds involving l.s. planes. ; loop_ _geom_bond_atom_site_label_1 _geom_bond_atom_site_label_2 _geom_bond_distance _geom_bond_site_symmetry_2 _geom_bond_publ_flag Bi1 Br12 2.7862(13) . ? Bi1 Br5 2.7994(10) . ? Bi1 Br4 2.8313(10) . ? Bi1 Br9 2.8761(11) . ? Bi1 Br3 2.9136(10) . ? Bi1 Br16 2.9773(13) . ? Bi2 Br7 2.7863(12) . ? Bi2 Br8 2.8338(11) . ? Bi2 Br10 2.8595(11) . ? Bi2 Br11 2.8819(12) . ? Bi2 Br6 2.8822(10) . ? Bi2 Br14 2.9190(13) . ? Br4 Rb1 3.8063(15) . ? Br5 Rb1 3.6031(15) . ? Br6 Rb2 3.7482(15) . ? Br7 Rb2 3.4653(17) . ? Br8 Rb2 3.6303(15) . ? Br9 Rb2 3.4218(13) 1_456 ? Br10 Rb1 3.4207(13) 1_644 ? Br11 Rb1 3.3941(14) 1_545 ? Br12 Rb1 3.5024(16) . ? Br14 Rb1 3.5695(18) 1_544 ? Br16 Rb2 3.5376(18) 1_556 ? Rb1 O1 2.937(8) . ? Rb1 O3 3.092(10) . ? Rb1 Br11 3.3940(14) 1_565 ? Rb1 Br10 3.4207(13) 1_466 ? Rb1 Br14 3.5695(19) 1_566 ? Rb2 O2 2.996(7) . ? Rb2 O4 3.108(10) . ? Rb2 Br9 3.4218(13) 1_654 ? Rb2 Br16 3.5376(18) 1_554 ? N1 C7 1.489(15) . ? N1 C5 1.506(12) . ? N2 C17 1.453(15) . ? N2 C4 1.493(12) . ? C5 C6 1.476(17) . ? C3 O2 1.411(14) . ? C3 C17 1.474(19) . ? C3 C2 1.519(13) . ? C7 C9 1.451(13) . ? C2 C4 1.471(17) . ? O1 C9 1.428(13) . ? N3 C10 1.498(17) . ? N3 C12 1.560(14) . ? C12 C14 1.415(17) . ? C10 C13 1.508(16) . ? C9 C6 1.511(17) . ? O3 C14 1.449(16) . ? O4 C15 1.407(16) . ? C16 C15 1.469(16) . ? C16 N4 1.475(15) . ? C15 C20 1.504(19) . ? C13 C14 1.501(16) . ? C19 N4 1.486(16) . ? C19 C20 1.499(14) . ? loop_ _geom_angle_atom_site_label_1 _geom_angle_atom_site_label_2 _geom_angle_atom_site_label_3 _geom_angle _geom_angle_site_symmetry_1 _geom_angle_site_symmetry_3 _geom_angle_publ_flag Br12 Bi1 Br5 90.24(3) . . ? Br12 Bi1 Br4 90.68(3) . . ? Br5 Bi1 Br4 87.39(3) . . ? Br12 Bi1 Br9 85.90(4) . . ? Br5 Bi1 Br9 92.52(3) . . ? Br4 Bi1 Br9 176.59(4) . . ? Br12 Bi1 Br3 94.70(3) . . ? Br5 Bi1 Br3 174.82(4) . . ? Br4 Bi1 Br3 91.00(3) . . ? Br9 Bi1 Br3 89.38(3) . . ? Br12 Bi1 Br16 177.84(3) . . ? Br5 Bi1 Br16 87.99(3) . . ? Br4 Bi1 Br16 87.99(3) . . ? Br9 Bi1 Br16 95.42(3) . . ? Br3 Bi1 Br16 87.03(3) . . ? Br7 Bi2 Br8 90.65(3) . . ? Br7 Bi2 Br10 88.15(3) . . ? Br8 Bi2 Br10 93.94(3) . . ? Br7 Bi2 Br11 88.38(4) . . ? Br8 Bi2 Br11 175.52(4) . . ? Br10 Bi2 Br11 90.40(4) . . ? Br7 Bi2 Br6 88.80(3) . . ? Br8 Bi2 Br6 89.29(3) . . ? Br10 Bi2 Br6 175.57(4) . . ? Br11 Bi2 Br6 86.31(3) . . ? Br7 Bi2 Br14 178.78(4) . . ? Br8 Bi2 Br14 90.57(3) . . ? Br10 Bi2 Br14 91.64(3) . . ? Br11 Bi2 Br14 90.42(4) . . ? Br6 Bi2 Br14 91.35(3) . . ? Bi1 Br4 Rb1 83.11(3) . . ? Bi1 Br5 Rb1 87.44(3) . . ? Bi2 Br6 Rb2 82.65(3) . . ? Bi2 Br7 Rb2 89.47(4) . . ? Bi2 Br8 Rb2 85.49(3) . . ? Bi1 Br9 Rb2 142.44(4) . 1_456 ? Bi2 Br10 Rb1 139.62(5) . 1_644 ? Bi2 Br11 Rb1 172.41(6) . 1_545 ? Bi1 Br12 Rb1 89.67(4) . . ? Bi2 Br14 Rb1 145.09(4) . 1_544 ? Bi1 Br16 Rb2 169.78(4) . 1_556 ? O1 Rb1 O3 93.3(3) . . ? O1 Rb1 Br11 73.58(14) . 1_565 ? O3 Rb1 Br11 78.71(14) . 1_565 ? O1 Rb1 Br10 80.20(14) . 1_466 ? O3 Rb1 Br10 68.00(13) . 1_466 ? Br11 Rb1 Br10 135.93(5) 1_565 1_466 ? O1 Rb1 Br12 166.06(16) . . ? O3 Rb1 Br12 79.51(17) . . ? Br11 Rb1 Br12 93.18(4) 1_565 . ? Br10 Rb1 Br12 107.62(4) 1_466 . ? O1 Rb1 Br14 59.80(18) . 1_566 ? O3 Rb1 Br14 145.45(16) . 1_566 ? Br11 Rb1 Br14 110.01(4) 1_565 1_566 ? Br10 Rb1 Br14 85.13(4) 1_466 1_566 ? Br12 Rb1 Br14 131.14(4) . 1_566 ? O1 Rb1 Br5 126.16(16) . . ? O3 Rb1 Br5 118.38(16) . . ? Br11 Rb1 Br5 149.37(4) 1_565 . ? Br10 Rb1 Br5 74.30(3) 1_466 . ? Br12 Rb1 Br5 67.68(3) . . ? Br14 Rb1 Br5 71.32(3) 1_566 . ? O1 Rb1 Br4 116.45(18) . . ? O3 Rb1 Br4 142.14(16) . . ? Br11 Rb1 Br4 87.48(3) 1_565 . ? Br10 Rb1 Br4 136.33(4) 1_466 . ? Br12 Rb1 Br4 66.13(3) . . ? Br14 Rb1 Br4 72.42(3) 1_566 . ? Br5 Rb1 Br4 63.27(3) . . ? O2 Rb2 O4 61.4(2) . . ? O2 Rb2 Br9 66.33(13) . 1_654 ? O4 Rb2 Br9 64.74(14) . 1_654 ? O2 Rb2 Br7 126.52(18) . . ? O4 Rb2 Br7 68.60(18) . . ? Br9 Rb2 Br7 108.49(4) 1_654 . ? O2 Rb2 Br16 80.99(17) . 1_554 ? O4 Rb2 Br16 137.42(18) . 1_554 ? Br9 Rb2 Br16 82.96(4) 1_654 1_554 ? Br7 Rb2 Br16 152.41(4) . 1_554 ? O2 Rb2 Br8 144.88(13) . . ? O4 Rb2 Br8 108.72(16) . . ? Br9 Rb2 Br8 78.93(3) 1_654 . ? Br7 Rb2 Br8 68.52(3) . . ? Br16 Rb2 Br8 90.13(4) 1_554 . ? O2 Rb2 Br6 146.82(13) . . ? O4 Rb2 Br6 133.21(17) . . ? Br9 Rb2 Br6 143.99(4) 1_654 . ? Br7 Rb2 Br6 66.58(3) . . ? Br16 Rb2 Br6 89.20(4) 1_554 . ? Br8 Rb2 Br6 65.95(3) . . ? C7 N1 C5 106.1(7) . . ? C17 N2 C4 107.7(9) . . ? C6 C5 N1 106.1(9) . . ? O2 C3 C17 108.9(10) . . ? O2 C3 C2 108.1(9) . . ? C17 C3 C2 103.4(10) . . ? C9 C7 N1 104.9(9) . . ? C4 C2 C3 104.9(9) . . ? C2 C4 N2 106.3(8) . . ? C9 O1 Rb1 155.4(8) . . ? C3 O2 Rb2 157.4(7) . . ? C10 N3 C12 109.1(8) . . ? C14 C12 N3 102.2(10) . . ? N3 C10 C13 102.6(9) . . ? O1 C9 C7 112.1(8) . . ? O1 C9 C6 110.2(10) . . ? C7 C9 C6 103.7(10) . . ? C5 C6 C9 103.5(8) . . ? C14 O3 Rb1 152.1(6) . . ? C15 O4 Rb2 146.9(6) . . ? C15 C16 N4 103.9(10) . . ? O4 C15 C16 108.0(11) . . ? O4 C15 C20 111.4(11) . . ? C16 C15 C20 107.2(10) . . ? C14 C13 C10 103.2(10) . . ? C12 C14 O3 112.1(11) . . ? C12 C14 C13 108.8(10) . . ? O3 C14 C13 108.4(10) . . ? N4 C19 C20 99.6(9) . . ? C16 N4 C19 109.0(8) . . ? C19 C20 C15 103.2(10) . . ? N2 C17 C3 106.7(9) . . ? _diffrn_measured_fraction_theta_max 0.992 _diffrn_reflns_theta_full 24.99 _diffrn_measured_fraction_theta_full 0.992 _refine_diff_density_max 3.123 _refine_diff_density_min -2.801 _refine_diff_density_rms 0.301