####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_Co-HL
_database_code_depnum_ccdc_archive 'CCDC 1883438'
loop_
_audit_author_name
_audit_author_address
'Junling Chen'
;Dalian University of Technology
China
;
_audit_update_record             
;
2020-09-18 deposited with the CCDC.	2020-09-21 downloaded from the CCDC.
;
_audit_creation_date             2020-08-21
_audit_creation_method           
;
Olex2 1.2
(compiled 2018.05.29 svn.r3508 for OlexSys, GUI svn.r5506)
;
_shelx_SHELXL_version_number     2018/3
_audit_contact_author_address    ?
_audit_contact_author_email      ?
_audit_contact_author_phone      ?
_publ_contact_author_id_orcid    ?
_publ_section_references         
;
Dolomanov, O.V., Bourhis, L.J., Gildea, R.J, Howard, J.A.K. & Puschmann, H.
 (2009), J. Appl. Cryst. 42, 339-341.

Sheldrick, G.M. (2015). Acta Cryst. C71, 3-8.
;
_chemical_name_common            ?
_chemical_name_systematic        ?
_chemical_formula_moiety         'C23 H20 Co2 O17, 3(H2 O)'
_chemical_formula_sum            'C23 H26 Co2 O20'
_chemical_formula_weight         740.30
_chemical_melting_point          ?
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Co Co 0.3494 0.9721 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_shelx_space_group_comment       
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
_space_group_crystal_system      monoclinic
_space_group_IT_number           15
_space_group_name_H-M_alt        'C 1 2/c 1'
_space_group_name_Hall           '-C 2yc'
loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, y, -z+1/2'
'x+1/2, y+1/2, z'
'-x+1/2, y+1/2, -z+1/2'
'-x, -y, -z'
'x, -y, z-1/2'
'-x+1/2, -y+1/2, -z'
'x+1/2, -y+1/2, z-1/2'

_cell_length_a                   24.2640(7)
_cell_length_b                   14.8592(3)
_cell_length_c                   19.8821(6)
_cell_angle_alpha                90
_cell_angle_beta                 127.529(3)
_cell_angle_gamma                90
_cell_volume                     5684.8(3)
_cell_formula_units_Z            8
_cell_measurement_reflns_used    27954
_cell_measurement_temperature    293(2)
_cell_measurement_theta_max      27.8090
_cell_measurement_theta_min      3.6140
_shelx_estimated_absorpt_T_max   0.843
_shelx_estimated_absorpt_T_min   0.735
_exptl_absorpt_coefficient_mu    1.260
_exptl_absorpt_correction_T_max  0.838
_exptl_absorpt_correction_T_min  0.735
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   ?
_exptl_absorpt_special_details   ?
_exptl_crystal_colour            'clear light pink'
_exptl_crystal_colour_lustre     clear
_exptl_crystal_colour_modifier   light
_exptl_crystal_colour_primary    pink
_exptl_crystal_density_diffrn    1.730
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    ?
_exptl_crystal_description       block
_exptl_crystal_F_000             3024
_exptl_crystal_size_max          0.26
_exptl_crystal_size_mid          0.21
_exptl_crystal_size_min          0.14
_exptl_transmission_factor_max   ?
_exptl_transmission_factor_min   ?
_diffrn_reflns_av_R_equivalents  0.0271
_diffrn_reflns_av_unetI/netI     0.0181
_diffrn_reflns_Laue_measured_fraction_full 0.997
_diffrn_reflns_Laue_measured_fraction_max 0.997
_diffrn_reflns_limit_h_max       28
_diffrn_reflns_limit_h_min       -28
_diffrn_reflns_limit_k_max       17
_diffrn_reflns_limit_k_min       -17
_diffrn_reflns_limit_l_max       23
_diffrn_reflns_limit_l_min       -22
_diffrn_reflns_number            29777
_diffrn_reflns_point_group_measured_fraction_full 0.997
_diffrn_reflns_point_group_measured_fraction_max 0.997
_diffrn_reflns_theta_full        25.027
_diffrn_reflns_theta_max         25.027
_diffrn_reflns_theta_min         3.358
_diffrn_ambient_temperature      293(2)
_diffrn_detector_area_resol_mean ?
_diffrn_measured_fraction_theta_full 0.997
_diffrn_measured_fraction_theta_max 0.997
_diffrn_measurement_device_type  'SuperNova, Single source at offset, EosS2'
_diffrn_measurement_method       ?
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_source                   ?
_reflns_Friedel_coverage         0.000
_reflns_Friedel_fraction_full    .
_reflns_Friedel_fraction_max     .
_reflns_number_gt                4744
_reflns_number_total             5011
_reflns_special_details          
;
 Reflections were merged by SHELXL according to the crystal
 class for the calculation of statistics and refinement.
 
 _reflns_Friedel_fraction is defined as the number of unique
 Friedel pairs measured divided by the number that would be
 possible theoretically, ignoring centric projections and
 systematic absences.
;
_reflns_threshold_expression     'I > 2σ(I)'
_computing_cell_refinement       ?
_computing_data_collection       ?
_computing_data_reduction        ?
_computing_molecular_graphics    'Olex2 (Dolomanov et al., 2009)'
_computing_publication_material  'Olex2 (Dolomanov et al., 2009)'
_computing_structure_refinement  'ShelXL (Sheldrick, 2015)'
_computing_structure_solution    'SHELXT 2014/5 (Sheldrick, 2014)'
_refine_diff_density_max         0.930
_refine_diff_density_min         -0.494
_refine_diff_density_rms         0.071
_refine_ls_extinction_coef       .
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.123
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     412
_refine_ls_number_reflns         5011
_refine_ls_number_restraints     12
_refine_ls_R_factor_all          0.0357
_refine_ls_R_factor_gt           0.0335
_refine_ls_restrained_S_all      1.134
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details     
'w=1/[σ²(Fo²)+(0.0383P)²+17.2575P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0883
_refine_ls_wR_factor_ref         0.0895
_refine_special_details          ?
_olex2_refinement_description    
;
1. Fixed Uiso
 At 1.2 times of:
  All C(H) groups
 At 1.5 times of:
  All O(H) groups, All O(H,H) groups
2. Uiso/Uaniso restraints and constraints
Uanis(O18) \\sim Ueq, Uanis(O19) \\sim Ueq: with sigma of 0.01 and sigma for
terminal atoms of 0.02
3. Others
 Fixed Sof: O18(0.5) H18A(0.5) H18B(0.5) H20A(0.5) H20B(0.5)
4.a Riding coordinates:
 O13(H13A,H13B), O14(H14A,H14B), O15(H15A,H15B), O16(H16A,H16B), O17(H17A,
 H17B), O18(H18A,H18B), O19(H19A,H19B), O20(H20A,H20B), O21(H21A,H21B)
4.b Aromatic/amide H refined with riding coordinates:
 C7(H7), C9(H9), C11(H11), C13(H13), C15(H15), C17(H17), C19(H19), C21(H21),
 C23(H23)
4.c Idealised tetrahedral OH refined as rotating group:
 O6(H6)
;
_atom_sites_solution_hydrogens   mixed
_atom_sites_solution_primary     ?
_atom_sites_solution_secondary   ?
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Co1 Co 0.83215(2) 0.73957(2) 0.82047(2) 0.01602(10) Uani 1 1 d . . . . .
Co2 Co 0.34191(2) 0.99365(2) 0.35595(2) 0.01528(10) Uani 1 1 d . . . . .
C1 C 0.70799(13) 0.61496(17) 0.72765(16) 0.0193(5) Uani 1 1 d . . . . .
C2 C 0.48379(13) 0.72451(18) 0.45903(17) 0.0221(6) Uani 1 1 d . . . . .
C3 C 0.25223(15) 0.36917(19) 0.47913(19) 0.0267(6) Uani 1 1 d . . . . .
C4 C 0.34635(14) 0.85601(18) 0.46891(17) 0.0213(6) Uani 1 1 d . . . . .
C5 C 0.35426(15) 0.95574(19) 0.71631(18) 0.0246(6) Uani 1 1 d . . . . .
C6 C 0.63015(13) 0.60902(18) 0.66250(16) 0.0202(5) Uani 1 1 d . . . . .
C7 C 0.59489(13) 0.67191(18) 0.59712(17) 0.0211(6) Uani 1 1 d . . . . .
H7 H 0.618931 0.719250 0.595125 0.025 Uiso 1 1 calc R . . . .
C8 C 0.52355(13) 0.66356(18) 0.53486(17) 0.0205(5) Uani 1 1 d . . . . .
C9 C 0.48712(13) 0.59596(19) 0.54065(18) 0.0248(6) Uani 1 1 d . . . . .
H9 H 0.439329 0.590555 0.499410 0.030 Uiso 1 1 calc R . . . .
C10 C 0.52243(14) 0.53686(18) 0.60813(18) 0.0246(6) Uani 1 1 d . . . . .
C11 C 0.59361(13) 0.54109(18) 0.66787(17) 0.0228(6) Uani 1 1 d . . . . .
H11 H 0.616976 0.498906 0.711365 0.027 Uiso 1 1 calc R . . . .
C12 C 0.42425(14) 0.48490(18) 0.59723(18) 0.0236(6) Uani 1 1 d . . . . .
C13 C 0.41514(15) 0.55839(19) 0.63200(18) 0.0275(6) Uani 1 1 d . . . . .
H13 H 0.450605 0.600098 0.664563 0.033 Uiso 1 1 calc R . . . .
C14 C 0.35159(16) 0.56838(18) 0.61706(18) 0.0256(6) Uani 1 1 d . . . . .
C15 C 0.29930(15) 0.50604(18) 0.57086(18) 0.0249(6) Uani 1 1 d . . . . .
H15 H 0.257815 0.512252 0.563554 0.030 Uiso 1 1 calc R . . . .
C16 C 0.30942(14) 0.43366(18) 0.53529(17) 0.0226(6) Uani 1 1 d . . . . .
C17 C 0.37187(14) 0.42323(18) 0.54788(18) 0.0241(6) Uani 1 1 d . . . . .
H17 H 0.378341 0.375224 0.523339 0.029 Uiso 1 1 calc R . . . .
C18 C 0.34336(16) 0.72627(18) 0.62897(19) 0.0278(6) Uani 1 1 d . . . . .
C19 C 0.34236(16) 0.74602(18) 0.56053(19) 0.0276(6) Uani 1 1 d . . . . .
H19 H 0.338580 0.700154 0.526104 0.033 Uiso 1 1 calc R . . . .
C20 C 0.34706(15) 0.83545(18) 0.54344(18) 0.0250(6) Uani 1 1 d . . . . .
C21 C 0.35238(16) 0.90336(19) 0.59512(18) 0.0276(6) Uani 1 1 d . . . . .
H21 H 0.357061 0.962908 0.584933 0.033 Uiso 1 1 calc R . . . .
C22 C 0.35074(16) 0.88258(18) 0.66180(18) 0.0265(6) Uani 1 1 d . . . . .
C23 C 0.34632(17) 0.79357(19) 0.67909(19) 0.0300(7) Uani 1 1 d . . . . .
H23 H 0.345347 0.779327 0.723909 0.036 Uiso 1 1 calc R . . . .
O1 O 0.73480(9) 0.69003(13) 0.73639(13) 0.0299(5) Uani 1 1 d . . . . .
O2 O 0.73939(9) 0.54410(13) 0.76747(12) 0.0270(4) Uani 1 1 d . . . . .
O3 O 0.50923(10) 0.79972(13) 0.46170(13) 0.0329(5) Uani 1 1 d . . . . .
O4 O 0.42643(9) 0.69595(13) 0.39572(12) 0.0282(5) Uani 1 1 d . . . . .
O5 O 0.25447(12) 0.31480(16) 0.43593(15) 0.0416(6) Uani 1 1 d . . . . .
O6 O 0.19927(11) 0.37811(14) 0.48179(14) 0.0338(5) Uani 1 1 d . . . . .
H6 H 0.167965 0.343728 0.447449 0.051 Uiso 1 1 calc GR . . . .
O7 O 0.33902(13) 0.79127(14) 0.42482(14) 0.0379(5) Uani 1 1 d . . . . .
O8 O 0.35294(10) 0.93723(12) 0.45697(12) 0.0251(4) Uani 1 1 d . . . . .
O9 O 0.37667(14) 1.03161(14) 0.71602(15) 0.0416(6) Uani 1 1 d . . . . .
O10 O 0.33426(10) 0.93606(13) 0.75973(12) 0.0245(4) Uani 1 1 d . . . . .
O11 O 0.48821(10) 0.46684(14) 0.61507(15) 0.0344(5) Uani 1 1 d . . . . .
O12 O 0.33918(13) 0.63937(13) 0.65097(14) 0.0364(5) Uani 1 1 d . . . . .
O13 O 0.79359(11) 0.86658(13) 0.81947(14) 0.0340(5) Uani 1 1 d . . . . .
H13A H 0.748990 0.864797 0.787687 0.051 Uiso 1 1 d R . . . .
H13B H 0.802430 0.907077 0.796417 0.051 Uiso 1 1 d R . . . .
O14 O 0.82301(12) 0.77981(15) 0.71203(13) 0.0360(5) Uani 1 1 d . . . . .
H14A H 0.804453 0.737033 0.673448 0.054 Uiso 1 1 d R . . . .
H14B H 0.864193 0.787023 0.724258 0.054 Uiso 1 1 d R . . . .
O15 O 0.38661(9) 0.88201(11) 0.33529(11) 0.0194(4) Uani 1 1 d . . . . .
H15A H 0.428558 0.867669 0.374268 0.029 Uiso 1 1 d R . . . .
H15B H 0.382688 0.903599 0.292508 0.029 Uiso 1 1 d R . . . .
O16 O 0.44250(10) 1.05029(14) 0.43662(13) 0.0337(5) Uani 1 1 d . . . . .
H16A H 0.425054 1.031155 0.459953 0.051 Uiso 1 1 d R . . . .
H16B H 0.451544 1.105795 0.442953 0.051 Uiso 1 1 d R . . . .
O17 O 0.30890(11) 1.11312(13) 0.38071(13) 0.0309(5) Uani 1 1 d . . . . .
H17A H 0.301000 1.119259 0.416839 0.046 Uiso 1 1 d R . . . .
H17B H 0.278190 1.145999 0.338969 0.046 Uiso 1 1 d R . . . .
O18 O 0.5131(4) 1.0449(8) 0.3786(5) 0.127(4) Uani 0.5 1 d . U . . .
H18A H 0.469043 1.048130 0.343983 0.190 Uiso 0.5 1 d R . . . .
H18B H 0.528323 1.018850 0.354823 0.190 Uiso 0.5 1 d R . . . .
O19 O 0.9430(2) 0.8338(3) 0.7518(3) 0.1264(18) Uani 1 1 d . U . . .
H19A H 0.971453 0.866152 0.795048 0.190 Uiso 1 1 d R . . . .
H19B H 0.941523 0.851852 0.710228 0.190 Uiso 1 1 d R . . . .
O20 O 0.500000 0.0873(4) 0.750000 0.0848(15) Uani 1 2 d S T P . .
H20A H 0.465350 0.055253 0.735560 0.127 Uiso 0.5 1 d R . . . .
H20B H 0.534600 0.051943 0.778600 0.127 Uiso 0.5 1 d R . . . .
O21 O 0.08030(14) 0.2956(2) 0.3862(2) 0.0667(8) Uani 1 1 d . . . . .
H21A H 0.074042 0.268637 0.418805 0.100 Uiso 1 1 d R . . . .
H21B H 0.043802 0.324687 0.348735 0.100 Uiso 1 1 d R . . . .


_geom_special_details            
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Co1 O1 2.0260(19) . ?
Co1 O4 2.0542(19) 8_566 ?
Co1 O7 2.030(2) 8_566 ?
Co1 O13 2.101(2) . ?
Co1 O14 2.115(2) . ?
Co1 O15 2.1500(17) 8_566 ?
Co2 O2 2.0655(18) 8_465 ?
Co2 O8 2.0381(18) . ?
Co2 O10 2.0862(18) 6_575 ?
Co2 O15 2.1540(18) . ?
Co2 O16 2.1140(19) . ?
Co2 H16A 1.8905 . ?
Co2 O17 2.125(2) . ?
C1 C6 1.507(3) . ?
C1 O1 1.249(3) . ?
C1 O2 1.257(3) . ?
C2 C8 1.501(4) . ?
C2 O3 1.262(3) . ?
C2 O4 1.252(3) . ?
C3 C16 1.484(4) . ?
C3 O5 1.204(4) . ?
C3 O6 1.325(3) . ?
C4 C20 1.503(4) . ?
C4 O7 1.239(3) . ?
C4 O8 1.259(3) . ?
C5 C22 1.500(4) . ?
C5 O9 1.253(4) . ?
C5 O10 1.256(3) . ?
C6 C7 1.393(4) . ?
C6 C11 1.390(4) . ?
C7 H7 0.9300 . ?
C7 C8 1.390(4) . ?
C8 C9 1.388(4) . ?
C9 H9 0.9300 . ?
C9 C10 1.380(4) . ?
C10 C11 1.378(4) . ?
C10 O11 1.389(3) . ?
C11 H11 0.9300 . ?
C12 C13 1.380(4) . ?
C12 C17 1.378(4) . ?
C12 O11 1.391(3) . ?
C13 H13 0.9300 . ?
C13 C14 1.389(4) . ?
C14 C15 1.375(4) . ?
C14 O12 1.380(3) . ?
C15 H15 0.9300 . ?
C15 C16 1.389(4) . ?
C16 C17 1.386(4) . ?
C17 H17 0.9300 . ?
C18 C19 1.378(4) . ?
C18 C23 1.383(4) . ?
C18 O12 1.387(3) . ?
C19 H19 0.9300 . ?
C19 C20 1.393(4) . ?
C20 C21 1.389(4) . ?
C21 H21 0.9300 . ?
C21 C22 1.385(4) . ?
C22 C23 1.387(4) . ?
C23 H23 0.9300 . ?
O6 H6 0.8200 . ?
O13 H13A 0.8591 . ?
O13 H13B 0.8590 . ?
O14 H14A 0.8800 . ?
O14 H14B 0.8792 . ?
O15 H15A 0.8491 . ?
O15 H15B 0.8584 . ?
O16 H16A 0.8453 . ?
O16 H16B 0.8429 . ?
O17 H17A 0.8537 . ?
O17 H17B 0.8540 . ?
O18 H18A 0.8500 . ?
O18 H18B 0.8500 . ?
O19 H19A 0.8501 . ?
O19 H19B 0.8493 . ?
O20 H20A 0.8497 2_656 ?
O20 H20A 0.8496 . ?
O20 H20B 0.8500 . ?
O20 H20B 0.8500 2_656 ?
O21 H21A 0.8500 . ?
O21 H21B 0.8500 . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
O1 Co1 O4 172.62(8) . 8_566 ?
O1 Co1 O7 95.16(10) . 8_566 ?
O1 Co1 O13 91.72(8) . . ?
O1 Co1 O14 85.18(9) . . ?
O1 Co1 O15 96.78(8) . 8_566 ?
O4 Co1 O13 83.10(8) 8_566 . ?
O4 Co1 O14 89.39(8) 8_566 . ?
O4 Co1 O15 88.47(7) 8_566 8_566 ?
O7 Co1 O4 89.95(9) 8_566 8_566 ?
O7 Co1 O13 88.36(9) 8_566 . ?
O7 Co1 O14 176.45(9) 8_566 . ?
O7 Co1 O15 90.54(8) 8_566 8_566 ?
O13 Co1 O14 88.10(9) . . ?
O13 Co1 O15 171.49(8) . 8_566 ?
O14 Co1 O15 92.93(8) . 8_566 ?
O2 Co2 O10 88.09(8) 8_465 6_575 ?
O2 Co2 O15 96.52(7) 8_465 . ?
O2 Co2 O16 171.59(8) 8_465 . ?
O2 Co2 H16A 160.2 8_465 . ?
O2 Co2 O17 89.76(8) 8_465 . ?
O8 Co2 O2 95.43(8) . 8_465 ?
O8 Co2 O10 174.00(8) . 6_575 ?
O8 Co2 O15 95.28(7) . . ?
O8 Co2 O16 91.04(8) . . ?
O8 Co2 H16A 68.4 . . ?
O8 Co2 O17 87.54(8) . . ?
O10 Co2 O15 89.12(7) 6_575 . ?
O10 Co2 O16 85.01(8) 6_575 . ?
O10 Co2 H16A 107.2 6_575 . ?
O10 Co2 O17 87.63(8) 6_575 . ?
O15 Co2 H16A 96.3 . . ?
O16 Co2 O15 88.20(8) . . ?
O16 Co2 H16A 23.5 . . ?
O16 Co2 O17 85.15(8) . . ?
O17 Co2 O15 172.83(8) . . ?
O17 Co2 H16A 78.6 . . ?
O1 C1 C6 116.5(2) . . ?
O1 C1 O2 126.6(2) . . ?
O2 C1 C6 117.0(2) . . ?
O3 C2 C8 119.6(2) . . ?
O4 C2 C8 116.5(2) . . ?
O4 C2 O3 123.9(2) . . ?
O5 C3 C16 122.8(3) . . ?
O5 C3 O6 124.2(3) . . ?
O6 C3 C16 113.0(2) . . ?
O7 C4 C20 116.8(2) . . ?
O7 C4 O8 126.2(3) . . ?
O8 C4 C20 117.0(2) . . ?
O9 C5 C22 118.8(2) . . ?
O9 C5 O10 124.3(3) . . ?
O10 C5 C22 116.9(2) . . ?
C7 C6 C1 119.9(2) . . ?
C11 C6 C1 120.0(2) . . ?
C11 C6 C7 120.1(2) . . ?
C6 C7 H7 120.2 . . ?
C8 C7 C6 119.7(2) . . ?
C8 C7 H7 120.2 . . ?
C7 C8 C2 122.0(2) . . ?
C9 C8 C2 117.9(2) . . ?
C9 C8 C7 120.1(2) . . ?
C8 C9 H9 120.3 . . ?
C10 C9 C8 119.4(2) . . ?
C10 C9 H9 120.3 . . ?
C9 C10 O11 121.2(2) . . ?
C11 C10 C9 121.3(3) . . ?
C11 C10 O11 117.4(2) . . ?
C6 C11 H11 120.3 . . ?
C10 C11 C6 119.4(2) . . ?
C10 C11 H11 120.3 . . ?
C13 C12 O11 121.3(3) . . ?
C17 C12 C13 121.5(3) . . ?
C17 C12 O11 117.1(3) . . ?
C12 C13 H13 120.9 . . ?
C12 C13 C14 118.2(3) . . ?
C14 C13 H13 120.9 . . ?
C15 C14 C13 121.5(3) . . ?
C15 C14 O12 117.0(3) . . ?
O12 C14 C13 121.4(3) . . ?
C14 C15 H15 120.5 . . ?
C14 C15 C16 119.0(3) . . ?
C16 C15 H15 120.5 . . ?
C15 C16 C3 120.6(2) . . ?
C17 C16 C3 118.8(2) . . ?
C17 C16 C15 120.5(3) . . ?
C12 C17 C16 119.1(3) . . ?
C12 C17 H17 120.4 . . ?
C16 C17 H17 120.4 . . ?
C19 C18 C23 121.3(3) . . ?
C19 C18 O12 123.3(3) . . ?
C23 C18 O12 115.3(2) . . ?
C18 C19 H19 120.4 . . ?
C18 C19 C20 119.3(3) . . ?
C20 C19 H19 120.4 . . ?
C19 C20 C4 118.7(2) . . ?
C21 C20 C4 121.5(2) . . ?
C21 C20 C19 119.8(3) . . ?
C20 C21 H21 119.9 . . ?
C22 C21 C20 120.1(3) . . ?
C22 C21 H21 119.9 . . ?
C21 C22 C5 120.5(2) . . ?
C21 C22 C23 120.1(3) . . ?
C23 C22 C5 119.4(2) . . ?
C18 C23 C22 119.3(3) . . ?
C18 C23 H23 120.4 . . ?
C22 C23 H23 120.4 . . ?
C1 O1 Co1 133.31(17) . . ?
C1 O2 Co2 135.82(17) . 8_566 ?
C2 O4 Co1 129.56(18) . 8_465 ?
C3 O6 H6 109.5 . . ?
C4 O7 Co1 141.74(19) . 8_465 ?
C4 O8 Co2 128.66(17) . . ?
C5 O10 Co2 131.15(18) . 6_576 ?
C10 O11 C12 118.1(2) . . ?
C14 O12 C18 118.5(2) . . ?
Co1 O13 H13A 109.5 . . ?
Co1 O13 H13B 112.3 . . ?
H13A O13 H13B 104.0 . . ?
Co1 O14 H14A 111.4 . . ?
Co1 O14 H14B 110.9 . . ?
H14A O14 H14B 102.8 . . ?
Co1 O15 Co2 109.54(8) 8_465 . ?
Co1 O15 H15A 102.1 8_465 . ?
Co1 O15 H15B 119.4 8_465 . ?
Co2 O15 H15A 118.8 . . ?
Co2 O15 H15B 97.8 . . ?
H15A O15 H15B 110.2 . . ?
Co2 O16 H16A 63.2 . . ?
Co2 O16 H16B 125.3 . . ?
H16A O16 H16B 114.8 . . ?
Co2 O17 H17A 126.4 . . ?
Co2 O17 H17B 118.8 . . ?
H17A O17 H17B 104.3 . . ?
H18A O18 H18B 109.5 . . ?
H19A O19 H19B 109.4 . . ?
H20A O20 H20A 111.8 . 2_656 ?
H20A O20 H20B 19.4 . 2_656 ?
H20A O20 H20B 104.5 2_656 2_656 ?
H20A O20 H20B 104.5 . . ?
H20B O20 H20A 19.4 . 2_656 ?
H20B O20 H20B 103.7 . 2_656 ?
H21A O21 H21B 109.5 . . ?

_olex2_submission_special_instructions 'No special instructions were received'

# start Validation Reply Form
_vrf_PLAT910_Co-HL               
;
PROBLEM: Missing # of FCF Reflection(s) Below Theta(Min).         12 Note  
RESPONSE:The missing FCF reflections below theta(min) 
were caused by the high beamstop theta(min) limit set.
;
# end Validation Reply Form
