####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_20038
_database_code_depnum_ccdc_archive 'CCDC 1989799'
loop_
_audit_author_name
_audit_author_address
'Tielyr Creason'
;University of Oklahoma
United States of America
;
_audit_update_record             
;
2020-03-11 deposited with the CCDC.	2020-04-30 downloaded from the CCDC.
;

_audit_creation_method           SHELXL-2018/3
#_shelx_SHELXL_version_number      '2018/3' 
_chemical_name_systematic        ?
_chemical_name_common            ?
_chemical_melting_point          ?
_chemical_formula_moiety         'Cl3 Cu K2'
_chemical_formula_sum            'Cl3 Cu K2'
_chemical_formula_weight         248.09

loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
Cl Cl 0.1484 0.1585 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
K K 0.2009 0.2494 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cu Cu 0.3201 1.2651 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_space_group_crystal_system      orthorhombic
_space_group_IT_number           62
_space_group_name_H-M_alt        'P n m a'
_space_group_name_Hall           '-P 2ac 2n'

_shelx_space_group_comment       
; 
The symmetry employed for this shelxl refinement is uniquely defined 
by the following loop, which should always be used as a source of 
symmetry information in preference to the above space-group names. 
They are only intended as comments. 
;

loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x+1/2, -y, z+1/2'
'-x, y+1/2, -z'
'x+1/2, -y+1/2, -z+1/2'
'-x, -y, -z'
'x-1/2, y, -z-1/2'
'x, -y-1/2, z'
'-x-1/2, y-1/2, z-1/2'

_cell_length_a                   11.9388(5)
_cell_length_b                   4.1112(2)
_cell_length_c                   12.5095(5)
_cell_angle_alpha                90
_cell_angle_beta                 90
_cell_angle_gamma                90
_cell_volume                     614.00(5)
_cell_formula_units_Z            4
_cell_measurement_temperature    100(2)
_cell_measurement_reflns_used    4715
_cell_measurement_theta_min      3.26
_cell_measurement_theta_max      37.74

_exptl_crystal_description       needle
_exptl_crystal_colour            colourless
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    ?
_exptl_crystal_density_diffrn    2.684
_exptl_crystal_F_000             472
_exptl_transmission_factor_min   ?
_exptl_transmission_factor_max   ?
_exptl_crystal_size_max          0.083
_exptl_crystal_size_mid          0.063
_exptl_crystal_size_min          0.058
_exptl_absorpt_coefficient_mu    6.068
_shelx_estimated_absorpt_T_min   0.633
_shelx_estimated_absorpt_T_max   0.720
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_correction_T_min  0.5509
_exptl_absorpt_correction_T_max  0.7474
_exptl_absorpt_process_details   
; 
 SADABS 2016/2: Krause, L., Herbst-Irmer, R., Sheldrick G.M. & Stalke D., 
 J. Appl. Cryst. 48 (2015) 3-10 
;
#_exptl_absorpt_special_details    ? 
_diffrn_ambient_temperature      100(2)
_diffrn_radiation_wavelength     0.71073
_diffrn_radiation_type           MoK\a
_diffrn_source                   'microfocus sealed tube'
_diffrn_measurement_device_type  'Bruker Photon II CMOS'
_diffrn_measurement_method       'ω and φ scans'
_diffrn_detector_area_resol_mean ?
_diffrn_reflns_number            8078
_diffrn_reflns_av_unetI/netI     0.0260
_diffrn_reflns_av_R_equivalents  0.0296
_diffrn_reflns_limit_h_min       -20
_diffrn_reflns_limit_h_max       19
_diffrn_reflns_limit_k_min       -7
_diffrn_reflns_limit_k_max       6
_diffrn_reflns_limit_l_min       -21
_diffrn_reflns_limit_l_max       11
_diffrn_reflns_theta_min         2.358
_diffrn_reflns_theta_max         37.829
_diffrn_reflns_theta_full        25.242
_diffrn_measured_fraction_theta_max 0.987
_diffrn_measured_fraction_theta_full 0.997
_diffrn_reflns_Laue_measured_fraction_max 0.987
_diffrn_reflns_Laue_measured_fraction_full 0.997
_diffrn_reflns_point_group_measured_fraction_max 0.987
_diffrn_reflns_point_group_measured_fraction_full 0.997
_reflns_number_total             1801
_reflns_number_gt                1623
_reflns_threshold_expression     'I > 2σ(I)'
_reflns_Friedel_coverage         0.000
_reflns_Friedel_fraction_max     .
_reflns_Friedel_fraction_full    .

_reflns_special_details          
; 
 Reflections were merged by SHELXL according to the crystal 
 class for the calculation of statistics and refinement. 
  
 _reflns_Friedel_fraction is defined as the number of unique 
 Friedel pairs measured divided by the number that would be 
 possible theoretically, ignoring centric projections and 
 systematic absences. 
;

_computing_data_collection       'APEX3 (Bruker, 2018)'
_computing_cell_refinement       'SAINT (Bruker, 2016)'
_computing_data_reduction        'SAINT (Bruker, 2016)'
_computing_structure_solution    'SHELXT (Sheldrick, 2015a)'
_computing_structure_refinement  'SHELXL-2018/3 (Sheldrick, 2015b)'
_computing_molecular_graphics    'Mercury (CCDC, 2018)'
_computing_publication_material  'SHELXL-2018/3 (Sheldrick, 2015b)'
_refine_special_details          ?
_refine_ls_structure_factor_coef Fsqd
_refine_ls_matrix_type           full
_refine_ls_weighting_scheme      calc
_refine_ls_weighting_details     
'w=1/[σ²(Fo²)+(0.0220P)²+0.3000P] where P=(Fo²+2Fc²)/3'
_atom_sites_solution_primary     dual
_atom_sites_solution_secondary   difmap
_atom_sites_solution_hydrogens   .
_refine_ls_hydrogen_treatment    undef
_refine_ls_extinction_method     'SHELXL-2018/3 (Sheldrick 2018)'
_refine_ls_extinction_coef       0.0036(6)
_refine_ls_extinction_expression Fc^*^=kFc[1+0.001xFc²λ³/sin(2θ)]^-1/4^
_refine_ls_number_reflns         1801
_refine_ls_number_parameters     38
_refine_ls_number_restraints     0
_refine_ls_R_factor_all          0.0264
_refine_ls_R_factor_gt           0.0215
_refine_ls_wR_factor_ref         0.0498
_refine_ls_wR_factor_gt          0.0470
_refine_ls_goodness_of_fit_ref   1.006
_refine_ls_restrained_S_all      1.006
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000

loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Cu1 Cu 0.75408(2) 0.750000 0.69905(2) 0.01139(5) Uani 1 2 d S T P . .
Cl1 Cl 0.63409(3) 0.750000 0.55196(3) 0.00982(7) Uani 1 2 d S T P . .
K1 K 0.82716(3) 0.250000 0.48236(3) 0.01028(6) Uani 1 2 d S T P . .
K2 K 0.48778(3) 0.250000 0.67425(3) 0.01011(6) Uani 1 2 d S T P . .
Cl2 Cl 0.72323(3) 0.250000 0.79223(3) 0.00917(7) Uani 1 2 d S T P . .
Cl3 Cl 0.94091(3) 0.750000 0.64054(3) 0.00989(7) Uani 1 2 d S T P . .


_geom_special_details            
; 
 All esds (except the esd in the dihedral angle between two l.s. planes) 
 are estimated using the full covariance matrix.  The cell esds are taken 
 into account individually in the estimation of esds in distances, angles 
 and torsion angles; correlations between esds in cell parameters are only 
 used when they are defined by crystal symmetry.  An approximate (isotropic) 
 treatment of cell esds is used for estimating esds involving l.s. planes. 
;

loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Cu1 Cl1 2.3319(4) . ?
Cu1 Cl3 2.3475(4) . ?
Cu1 Cl2 2.3916(2) 1_565 ?
Cu1 Cl2 2.3916(2) . ?
Cu1 K1 3.5120(3) . ?
Cu1 K1 3.5121(3) 1_565 ?
Cu1 K1 3.6744(4) 2_665 ?
Cu1 K2 3.7987(4) . ?
Cu1 K2 3.7987(4) 1_565 ?
Cu1 K2 3.8107(3) 6_667 ?
Cu1 K2 3.8107(3) 6_657 ?
Cl1 K2 3.1011(4) . ?
Cl1 K2 3.1011(4) 1_565 ?
Cl1 K2 3.1820(5) 5_666 ?
Cl1 K1 3.2089(4) 1_565 ?
Cl1 K1 3.2089(4) . ?
K1 Cl3 3.1598(4) 1_545 ?
K1 Cl3 3.1599(4) . ?
K1 Cl3 3.1670(5) 5_766 ?
K1 Cl2 3.2007(4) 2_654 ?
K1 Cl2 3.2007(4) 2_664 ?
K1 K1 4.1112(2) 1_545 ?
K1 K1 4.11120(19) 1_565 ?
K2 Cl3 3.1475(4) 6_557 ?
K2 Cl3 3.1475(4) 6_547 ?
K2 Cl2 3.1748(5) . ?
K2 Cl2 3.1862(5) 6_557 ?
K2 K2 4.11120(19) 1_565 ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
Cl1 Cu1 Cl3 109.736(16) . . ?
Cl1 Cu1 Cl2 106.853(11) . 1_565 ?
Cl3 Cu1 Cl2 107.357(11) . 1_565 ?
Cl1 Cu1 Cl2 106.853(11) . . ?
Cl3 Cu1 Cl2 107.357(11) . . ?
Cl2 Cu1 Cl2 118.521(18) 1_565 . ?
Cl1 Cu1 K1 62.847(10) . . ?
Cl3 Cu1 K1 61.529(10) . . ?
Cl2 Cu1 K1 156.563(11) 1_565 . ?
Cl2 Cu1 K1 84.915(10) . . ?
Cl1 Cu1 K1 62.846(10) . 1_565 ?
Cl3 Cu1 K1 61.530(10) . 1_565 ?
Cl2 Cu1 K1 84.915(9) 1_565 1_565 ?
Cl2 Cu1 K1 156.563(11) . 1_565 ?
K1 Cu1 K1 71.648(9) . 1_565 ?
Cl1 Cu1 K1 126.789(13) . 2_665 ?
Cl3 Cu1 K1 123.475(13) . 2_665 ?
Cl2 Cu1 K1 59.287(9) 1_565 2_665 ?
Cl2 Cu1 K1 59.286(9) . 2_665 ?
K1 Cu1 K1 144.098(5) . 2_665 ?
K1 Cu1 K1 144.098(4) 1_565 2_665 ?
Cl1 Cu1 K2 54.646(9) . . ?
Cl3 Cu1 K2 140.333(8) . . ?
Cl2 Cu1 K2 112.086(12) 1_565 . ?
Cl2 Cu1 K2 56.342(10) . . ?
K1 Cu1 K2 80.106(8) . . ?
K1 Cu1 K2 117.491(9) 1_565 . ?
K1 Cu1 K2 81.826(8) 2_665 . ?
Cl1 Cu1 K2 54.647(9) . 1_565 ?
Cl3 Cu1 K2 140.333(8) . 1_565 ?
Cl2 Cu1 K2 56.343(10) 1_565 1_565 ?
Cl2 Cu1 K2 112.084(12) . 1_565 ?
K1 Cu1 K2 117.492(9) . 1_565 ?
K1 Cu1 K2 80.106(7) 1_565 1_565 ?
K1 Cu1 K2 81.826(8) 2_665 1_565 ?
K2 Cu1 K2 65.522(7) . 1_565 ?
Cl1 Cu1 K2 141.074(8) . 6_667 ?
Cl3 Cu1 K2 55.531(9) . 6_667 ?
Cl2 Cu1 K2 56.388(11) 1_565 6_667 ?
Cl2 Cu1 K2 111.945(12) . 6_667 ?
K1 Cu1 K2 117.054(9) . 6_667 ?
K1 Cu1 K2 79.828(8) 1_565 6_667 ?
K1 Cu1 K2 78.002(8) 2_665 6_667 ?
K2 Cu1 K2 159.826(7) . 6_667 ?
K2 Cu1 K2 110.784(4) 1_565 6_667 ?
Cl1 Cu1 K2 141.074(8) . 6_657 ?
Cl3 Cu1 K2 55.531(9) . 6_657 ?
Cl2 Cu1 K2 111.945(12) 1_565 6_657 ?
Cl2 Cu1 K2 56.389(11) . 6_657 ?
K1 Cu1 K2 79.827(7) . 6_657 ?
K1 Cu1 K2 117.055(9) 1_565 6_657 ?
K1 Cu1 K2 78.002(8) 2_665 6_657 ?
K2 Cu1 K2 110.784(4) . 6_657 ?
K2 Cu1 K2 159.825(7) 1_565 6_657 ?
K2 Cu1 K2 65.289(7) 6_667 6_657 ?
Cu1 Cl1 K2 87.524(12) . . ?
Cu1 Cl1 K2 87.524(12) . 1_565 ?
K2 Cl1 K2 83.037(13) . 1_565 ?
Cu1 Cl1 K2 169.304(18) . 5_666 ?
K2 Cl1 K2 100.438(12) . 5_666 ?
K2 Cl1 K2 100.439(12) 1_565 5_666 ?
Cu1 Cl1 K1 76.867(11) . 1_565 ?
K2 Cl1 K1 164.385(16) . 1_565 ?
K2 Cl1 K1 96.537(7) 1_565 1_565 ?
K2 Cl1 K1 94.998(12) 5_666 1_565 ?
Cu1 Cl1 K1 76.866(11) . . ?
K2 Cl1 K1 96.537(7) . . ?
K2 Cl1 K1 164.384(16) 1_565 . ?
K2 Cl1 K1 94.999(12) 5_666 . ?
K1 Cl1 K1 79.672(12) 1_565 . ?
Cl3 K1 Cl3 81.164(13) 1_545 . ?
Cl3 K1 Cl3 85.884(12) 1_545 5_766 ?
Cl3 K1 Cl3 85.885(12) . 5_766 ?
Cl3 K1 Cl2 97.372(8) 1_545 2_654 ?
Cl3 K1 Cl2 164.558(15) . 2_654 ?
Cl3 K1 Cl2 78.674(11) 5_766 2_654 ?
Cl3 K1 Cl2 164.557(15) 1_545 2_664 ?
Cl3 K1 Cl2 97.372(8) . 2_664 ?
Cl3 K1 Cl2 78.674(11) 5_766 2_664 ?
Cl2 K1 Cl2 79.917(12) 2_654 2_664 ?
Cl3 K1 Cl1 73.865(10) 1_545 1_545 ?
Cl3 K1 Cl1 123.748(15) . 1_545 ?
Cl3 K1 Cl1 139.442(7) 5_766 1_545 ?
Cl2 K1 Cl1 69.830(10) 2_654 1_545 ?
Cl2 K1 Cl1 118.555(14) 2_664 1_545 ?
Cl3 K1 Cl1 123.749(15) 1_545 . ?
Cl3 K1 Cl1 73.864(10) . . ?
Cl3 K1 Cl1 139.442(7) 5_766 . ?
Cl2 K1 Cl1 118.555(14) 2_654 . ?
Cl2 K1 Cl1 69.830(10) 2_664 . ?
Cl1 K1 Cl1 79.671(12) 1_545 . ?
Cl3 K1 Cu1 90.242(11) 1_545 . ?
Cl3 K1 Cu1 40.773(8) . . ?
Cl3 K1 Cu1 126.289(10) 5_766 . ?
Cl2 K1 Cu1 154.521(13) 2_654 . ?
Cl2 K1 Cu1 98.682(7) 2_664 . ?
Cl1 K1 Cu1 89.258(11) 1_545 . ?
Cl1 K1 Cu1 40.287(8) . . ?
Cl3 K1 Cu1 40.775(8) 1_545 1_545 ?
Cl3 K1 Cu1 90.242(11) . 1_545 ?
Cl3 K1 Cu1 126.289(10) 5_766 1_545 ?
Cl2 K1 Cu1 98.682(7) 2_654 1_545 ?
Cl2 K1 Cu1 154.521(13) 2_664 1_545 ?
Cl1 K1 Cu1 40.286(8) 1_545 1_545 ?
Cl1 K1 Cu1 89.258(10) . 1_545 ?
Cu1 K1 Cu1 71.648(9) . 1_545 ?
Cl3 K1 Cu1 135.842(8) 1_545 2_664 ?
Cl3 K1 Cu1 135.842(8) . 2_664 ?
Cl3 K1 Cu1 76.266(10) 5_766 2_664 ?
Cl2 K1 Cu1 39.971(6) 2_654 2_664 ?
Cl2 K1 Cu1 39.971(6) 2_664 2_664 ?
Cl1 K1 Cu1 94.133(10) 1_545 2_664 ?
Cl1 K1 Cu1 94.133(10) . 2_664 ?
Cu1 K1 Cu1 132.755(7) . 2_664 ?
Cu1 K1 Cu1 132.754(7) 1_545 2_664 ?
Cl3 K1 K1 49.419(6) 1_545 1_545 ?
Cl3 K1 K1 130.583(6) . 1_545 ?
Cl3 K1 K1 90.0 5_766 1_545 ?
Cl2 K1 K1 50.041(6) 2_654 1_545 ?
Cl2 K1 K1 129.958(6) 2_664 1_545 ?
Cl1 K1 K1 50.164(6) 1_545 1_545 ?
Cl1 K1 K1 129.835(6) . 1_545 ?
Cu1 K1 K1 125.825(4) . 1_545 ?
Cu1 K1 K1 54.176(4) 1_545 1_545 ?
Cu1 K1 K1 90.0 2_664 1_545 ?
Cl3 K1 K1 130.583(6) 1_545 1_565 ?
Cl3 K1 K1 49.419(6) . 1_565 ?
Cl3 K1 K1 90.0 5_766 1_565 ?
Cl2 K1 K1 129.958(6) 2_654 1_565 ?
Cl2 K1 K1 50.041(6) 2_664 1_565 ?
Cl1 K1 K1 129.835(6) 1_545 1_565 ?
Cl1 K1 K1 50.164(6) . 1_565 ?
Cu1 K1 K1 54.176(4) . 1_565 ?
Cu1 K1 K1 125.825(4) 1_545 1_565 ?
Cu1 K1 K1 90.0 2_664 1_565 ?
K1 K1 K1 180.0 1_545 1_565 ?
Cl1 K2 Cl1 83.038(13) . 1_545 ?
Cl1 K2 Cl3 91.740(8) . 6_557 ?
Cl1 K2 Cl3 153.660(15) 1_545 6_557 ?
Cl1 K2 Cl3 153.660(15) . 6_547 ?
Cl1 K2 Cl3 91.740(8) 1_545 6_547 ?
Cl3 K2 Cl3 81.550(13) 6_557 6_547 ?
Cl1 K2 Cl2 74.372(11) . . ?
Cl1 K2 Cl2 74.372(11) 1_545 . ?
Cl3 K2 Cl2 79.351(11) 6_557 . ?
Cl3 K2 Cl2 79.351(11) 6_547 . ?
Cl1 K2 Cl1 79.562(12) . 5_666 ?
Cl1 K2 Cl1 79.562(12) 1_545 5_666 ?
Cl3 K2 Cl1 124.986(11) 6_557 5_666 ?
Cl3 K2 Cl1 124.986(10) 6_547 5_666 ?
Cl2 K2 Cl1 144.910(15) . 5_666 ?
Cl1 K2 Cl2 128.556(10) . 6_557 ?
Cl1 K2 Cl2 128.556(10) 1_545 6_557 ?
Cl3 K2 Cl2 74.151(11) 6_557 6_557 ?
Cl3 K2 Cl2 74.151(11) 6_547 6_557 ?
Cl2 K2 Cl2 144.737(12) . 6_557 ?
Cl1 K2 Cl2 70.353(12) 5_666 6_557 ?
Cl1 K2 Cu1 85.846(10) . 1_545 ?
Cl1 K2 Cu1 37.829(8) 1_545 1_545 ?
Cl3 K2 Cu1 116.237(12) 6_557 1_545 ?
Cl3 K2 Cu1 74.649(8) 6_547 1_545 ?
Cl2 K2 Cu1 38.832(6) . 1_545 ?
Cl1 K2 Cu1 117.086(10) 5_666 1_545 ?
Cl2 K2 Cu1 144.978(6) 6_557 1_545 ?
Cl1 K2 Cu1 37.829(8) . . ?
Cl1 K2 Cu1 85.846(10) 1_545 . ?
Cl3 K2 Cu1 74.649(8) 6_557 . ?
Cl3 K2 Cu1 116.237(12) 6_547 . ?
Cl2 K2 Cu1 38.831(6) . . ?
Cl1 K2 Cu1 117.086(10) 5_666 . ?
Cl2 K2 Cu1 144.978(6) 6_557 . ?
Cu1 K2 Cu1 65.522(7) 1_545 . ?
Cl1 K2 Cu1 167.193(11) . 6_547 ?
Cl1 K2 Cu1 105.070(6) 1_545 6_547 ?
Cl3 K2 Cu1 85.180(10) 6_557 6_547 ?
Cl3 K2 Cu1 37.945(8) 6_547 6_547 ?
Cl2 K2 Cu1 117.059(10) . 6_547 ?
Cl1 K2 Cu1 92.012(10) 5_666 6_547 ?
Cl2 K2 Cu1 38.691(6) 6_557 6_547 ?
Cu1 K2 Cu1 106.674(5) 1_545 6_547 ?
Cu1 K2 Cu1 150.543(10) . 6_547 ?
Cl1 K2 Cu1 105.070(6) . 6_557 ?
Cl1 K2 Cu1 167.193(11) 1_545 6_557 ?
Cl3 K2 Cu1 37.945(8) 6_557 6_557 ?
Cl3 K2 Cu1 85.180(10) 6_547 6_557 ?
Cl2 K2 Cu1 117.059(10) . 6_557 ?
Cl1 K2 Cu1 92.012(10) 5_666 6_557 ?
Cl2 K2 Cu1 38.691(6) 6_557 6_557 ?
Cu1 K2 Cu1 150.543(10) 1_545 6_557 ?
Cu1 K2 Cu1 106.674(5) . 6_557 ?
Cu1 K2 Cu1 65.288(7) 6_547 6_557 ?
Cl1 K2 K2 48.482(6) . 1_565 ?
Cl1 K2 K2 131.519(6) 1_545 1_565 ?
Cl3 K2 K2 49.225(6) 6_557 1_565 ?
Cl3 K2 K2 130.774(6) 6_547 1_565 ?
Cl2 K2 K2 90.0 . 1_565 ?
Cl1 K2 K2 90.000(1) 5_666 1_565 ?
Cl2 K2 K2 90.0 6_557 1_565 ?
Cu1 K2 K2 122.762(3) 1_545 1_565 ?
Cu1 K2 K2 57.239(4) . 1_565 ?
Cu1 K2 K2 122.643(3) 6_547 1_565 ?
Cu1 K2 K2 57.356(3) 6_557 1_565 ?
Cu1 Cl2 Cu1 118.521(18) 1_545 . ?
Cu1 Cl2 K2 84.826(11) 1_545 . ?
Cu1 Cl2 K2 84.826(11) . . ?
Cu1 Cl2 K2 84.920(11) 1_545 6_657 ?
Cu1 Cl2 K2 84.919(11) . 6_657 ?
K2 Cl2 K2 159.861(14) . 6_657 ?
Cu1 Cl2 K1 160.583(14) 1_545 2_665 ?
Cu1 Cl2 K1 80.742(8) . 2_665 ?
K2 Cl2 K1 100.313(12) . 2_665 ?
K2 Cl2 K1 95.079(12) 6_657 2_665 ?
Cu1 Cl2 K1 80.742(8) 1_545 2_655 ?
Cu1 Cl2 K1 160.583(14) . 2_655 ?
K2 Cl2 K1 100.313(12) . 2_655 ?
K2 Cl2 K1 95.079(12) 6_657 2_655 ?
K1 Cl2 K1 79.918(12) 2_665 2_655 ?
Cu1 Cl3 K2 86.525(12) . 6_667 ?
Cu1 Cl3 K2 86.525(12) . 6_657 ?
K2 Cl3 K2 81.551(13) 6_667 6_657 ?
Cu1 Cl3 K1 77.697(11) . . ?
K2 Cl3 K1 164.198(15) 6_667 . ?
K2 Cl3 K1 96.458(7) 6_657 . ?
Cu1 Cl3 K1 77.697(11) . 1_565 ?
K2 Cl3 K1 96.459(7) 6_667 1_565 ?
K2 Cl3 K1 164.198(15) 6_657 1_565 ?
K1 Cl3 K1 81.163(13) . 1_565 ?
Cu1 Cl3 K1 169.129(18) . 5_766 ?
K2 Cl3 K1 101.647(12) 6_667 5_766 ?
K2 Cl3 K1 101.647(12) 6_657 5_766 ?
K1 Cl3 K1 94.116(12) . 5_766 ?
K1 Cl3 K1 94.116(12) 1_565 5_766 ?


_refine_diff_density_max         0.623
_refine_diff_density_min         -0.568
_refine_diff_density_rms         0.136



_exptl_crystal_preparation       Luminescent
