data_compound6
_audit_creation_date               2019-02-26
_audit_creation_method
;
Olex2 1.2
(compiled 2018.05.29 svn.r3508 for OlexSys, GUI svn.r5506)
;
_shelxl_version_number             2014-3
_audit_contact_author_address      ?
_audit_contact_author_email        ?
_audit_contact_author_name         ''
_audit_contact_author_phone        ?
_publ_contact_author_id_orcid      ?
_publ_section_references
;
Dolomanov, O.V., Bourhis, L.J., Gildea, R.J, Howard, J.A.K. & Puschmann, H.
 (2009), J. Appl. Cryst. 42, 339-341.

Sheldrick, G.M. (2008). Acta Cryst. A64, 112-122.

Sheldrick, G.M. (2015). Acta Cryst. C71, 3-8.
;
_chemical_name_common              ?
_chemical_name_systematic
;
 ?
;
_chemical_formula_moiety           'Bi2 I10, 4(C8 H11 F N)'
_chemical_formula_sum              'C32 H44 Bi2 F4 I10 N4'
_chemical_formula_weight           2247.67
_chemical_absolute_configuration   syn
_chemical_melting_point            ?
loop_
  _atom_type_symbol
  _atom_type_description
  _atom_type_scat_dispersion_real
  _atom_type_scat_dispersion_imag
  _atom_type_scat_source
 'C' 'C' 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
 'H' 'H' 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
 'Bi' 'Bi' -4.1077 10.2566
 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
 'F' 'F' 0.0171 0.0103 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
 'I' 'I' -0.4742 1.8119 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
 'N' 'N' 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_shelx_space_group_comment
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
_space_group_crystal_system        'monoclinic'
_space_group_IT_number             4
_space_group_name_H-M_alt          'P 1 21 1'
_space_group_name_Hall             'P 2yb'
loop_
  _space_group_symop_operation_xyz
 'x, y, z'
 '-x, y+1/2, -z'

_cell_length_a                     12.9207(5)
_cell_length_b                     14.6156(5)
_cell_length_c                     14.2779(5)
_cell_angle_alpha                  90
_cell_angle_beta                   94.3351(14)
_cell_angle_gamma                  90
_cell_volume                       2688.58(17)
_cell_formula_units_Z              2
_cell_measurement_reflns_used      9886
_cell_measurement_temperature      100(2)
_cell_measurement_theta_max        25.28
_cell_measurement_theta_min        2.48
_shelx_estimated_absorpt_T_max     0.417
_shelx_estimated_absorpt_T_min     0.121
_exptl_absorpt_coefficient_mu      12.317
_exptl_absorpt_correction_T_max    0.7452
_exptl_absorpt_correction_T_min    0.5440
_exptl_absorpt_correction_type     multi-scan
_exptl_absorpt_process_details    
 'SADABS-2016/2 (Bruker,2016/2) was used for absorption correction. wR2(int) was 0.1123 before and 0.0675 after correction. The Ratio of minimum to maximum transmission is 0.7300. The λ/2 correction factor is Not present.'
_exptl_crystal_colour              orange
_exptl_crystal_colour_primary      orange
_exptl_crystal_density_diffrn      2.776
_exptl_crystal_density_meas        ?
_exptl_crystal_density_method      ?
_exptl_crystal_description         plank
_exptl_crystal_F_000               1992
_exptl_crystal_size_max            0.296
_exptl_crystal_size_mid            0.187
_exptl_crystal_size_min            0.086
_exptl_special_details
;
 ?
;
_exptl_transmission_factor_max     ?
_exptl_transmission_factor_min     ?
_diffrn_reflns_av_R_equivalents    0.0611
_diffrn_reflns_av_unetI/netI       0.0500
_diffrn_reflns_Laue_measured_fraction_full  0.999
_diffrn_reflns_Laue_measured_fraction_max  0.998
_diffrn_reflns_limit_h_max         15
_diffrn_reflns_limit_h_min         -15
_diffrn_reflns_limit_k_max         17
_diffrn_reflns_limit_k_min         -17
_diffrn_reflns_limit_l_max         17
_diffrn_reflns_limit_l_min         -17
_diffrn_reflns_number              45033
_diffrn_reflns_point_group_measured_fraction_full  0.999
_diffrn_reflns_point_group_measured_fraction_max  0.997
_diffrn_reflns_theta_full          25.242
_diffrn_reflns_theta_max           25.296
_diffrn_reflns_theta_min           2.107
_diffrn_ambient_temperature        100.02
_diffrn_detector_area_resol_mean   10.4167
_diffrn_measured_fraction_theta_full  0.999
_diffrn_measured_fraction_theta_max  0.998
_diffrn_measurement_device_type    'Bruker D8 QUEST area detector'
_diffrn_measurement_method         'ω and φ scans'
_diffrn_radiation_type             MoK\a
_diffrn_radiation_wavelength       0.71073
_diffrn_source                     'microfocus sealed X-ray tube'
_diffrn_standards_number           0
_reflns_Friedel_coverage           0.916
_reflns_Friedel_fraction_full      0.998
_reflns_Friedel_fraction_max       0.996
_reflns_number_gt                  8286
_reflns_number_total               9798
_reflns_special_details
;
 Reflections were merged by SHELXL according to the crystal
 class for the calculation of statistics and refinement.
 
 _reflns_Friedel_fraction is defined as the number of unique
 Friedel pairs measured divided by the number that would be
 possible theoretically, ignoring centric projections and
 systematic absences.
;
_reflns_threshold_expression       'I > 2σ(I)'
_computing_cell_refinement         ?
_computing_data_collection         ?
_computing_data_reduction          ?
_computing_molecular_graphics      'Olex2 (Dolomanov et al., 2009)'
_computing_publication_material    'Olex2 (Dolomanov et al., 2009)'
_computing_structure_refinement    'ShelXL (Sheldrick, 2015)'
_computing_structure_solution      'XS (Sheldrick, 2008)'
_refine_diff_density_max           0.729
_refine_diff_density_min           -0.718
_refine_diff_density_rms           0.163
_refine_ls_abs_structure_details
;
 Flack x determined using 3499 quotients [(I+)-(I-)]/[(I+)+(I-)]
 (Parsons, Flack and Wagner, Acta Cryst. B69 (2013) 249-259).
;
_refine_ls_abs_structure_Flack     0.013(8)
_refine_ls_extinction_coef         .
_refine_ls_extinction_method       none
_refine_ls_goodness_of_fit_ref     0.953
_refine_ls_hydrogen_treatment      constr
_refine_ls_matrix_type             full
_refine_ls_number_parameters       465
_refine_ls_number_reflns           9798
_refine_ls_number_restraints       49
_refine_ls_R_factor_all            0.0396
_refine_ls_R_factor_gt             0.0268
_refine_ls_restrained_S_all        0.953
_refine_ls_shift/su_max            0.001
_refine_ls_shift/su_mean           0.000
_refine_ls_structure_factor_coef   Fsqd
_refine_ls_weighting_details       'w=1/[σ²(Fo²)] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme        calc
_refine_ls_wR_factor_gt            0.0402
_refine_ls_wR_factor_ref           0.0429
_refine_special_details
;
 ?
;
_olex2_refinement_description
;
1. Fixed Uiso
 At 1.2 times of:
  All C(H) groups, All N(H,H,H) groups
 At 1.5 times of:
  All C(H,H,H) groups
2. Uiso/Uaniso restraints and constraints
Uanis(C22) \\sim Ueq, Uanis(C32) \\sim Ueq, Uanis(C8) \\sim Ueq, Uanis(C13)
\\sim Ueq: with sigma of 0.01 and sigma for terminal atoms of 0.02
Uanis(C8) \\sim Ueq: with sigma of 0.001 and sigma for terminal atoms of 0.002
Uanis(N1) \\sim Ueq: with sigma of 0.001 and sigma for terminal atoms of 0.002
Uanis(C16) \\sim Ueq, Uanis(C11) \\sim Ueq: with sigma of 0.01 and sigma for
terminal atoms of 0.02
Uanis(C7) \\sim Ueq: with sigma of 0.01 and sigma for terminal atoms of 0.02
3.a Ternary CH refined with riding coordinates:
 C2(H2), C10(H10), C18(H18), C26(H26)
3.b Aromatic/amide H refined with riding coordinates:
 C23(H23), C21(H21), C7(H7), C5(H5), C20(H20), C4(H4), C8(H8), C28(H28),
 C29(H29), C32(H32), C15(H15), C16(H16), C12(H12), C13(H13), C31(H31), C24(H24)
3.c Fitted hexagon refined as free rotating group:
 C15(C16,C11,C12,C13,C14)
3.d Idealised Me refined as rotating group:
 N3(H3A,H3B,H3C), N1(H1A,H1B,H1C), N2(H2A,H2B,H2C), N4(H4A,H4B,H4C), C17(H17A,
 H17B,H17C), C1(H1D,H1E,H1F), C9(H9A,H9B,H9C), C25(H25A,H25B,H25C)
;
_atom_sites_solution_hydrogens     geom
_atom_sites_solution_primary       direct
_atom_sites_solution_secondary     ?
loop_
  _atom_site_label
  _atom_site_type_symbol
  _atom_site_fract_x
  _atom_site_fract_y
  _atom_site_fract_z
  _atom_site_U_iso_or_equiv
  _atom_site_adp_type
  _atom_site_occupancy
  _atom_site_site_symmetry_order
  _atom_site_calc_flag
  _atom_site_refinement_flags_posn
  _atom_site_refinement_flags_adp
  _atom_site_refinement_flags_occupancy
  _atom_site_disorder_assembly
  _atom_site_disorder_group
 Bi2 Bi 1.39604(5) 0.60904(4) 0.60957(5) 0.01115(17) Uani 1 1 d . . . . .
 Bi1 Bi 1.10974(5) 0.55858(4) 0.39086(5) 0.01111(17) Uani 1 1 d . . . . .
 I1 I 1.18047(9) 0.35863(8) 0.38063(8) 0.0137(3) Uani 1 1 d . . . . .
 I2 I 0.89217(10) 0.49409(9) 0.40039(9) 0.0173(3) Uani 1 1 d . . . . .
 I6 I 1.33988(9) 0.64029(8) 0.38070(9) 0.0136(3) Uani 1 1 d . . . . .
 I5 I 1.16625(10) 0.53168(9) 0.61955(9) 0.0140(3) Uani 1 1 d . . . . .
 I10 I 1.32526(9) 0.80917(8) 0.62828(8) 0.0142(3) Uani 1 1 d . . . . .
 I3 I 1.08234(10) 0.56440(9) 0.18663(9) 0.0208(3) Uani 1 1 d . . . . .
 I9 I 1.41704(10) 0.59710(9) 0.81401(9) 0.0175(3) Uani 1 1 d . . . . .
 I7 I 1.47229(9) 0.41809(8) 0.56483(9) 0.0138(3) Uani 1 1 d . . . . .
 I4 I 1.02574(10) 0.74913(9) 0.42867(9) 0.0163(3) Uani 1 1 d . . . . .
 I8 I 1.61374(9) 0.67204(9) 0.59701(9) 0.0161(3) Uani 1 1 d . . . . .
 F1 F 1.6480(8) 0.6522(8) 0.0113(7) 0.030(3) Uani 1 1 d . . . . .
 F3 F 0.8735(9) 0.4942(8) 0.9815(8) 0.048(4) Uani 1 1 d . . . . .
 N3 N 1.0673(11) 0.7610(11) 0.6920(10) 0.021(4) Uani 1 1 d . . . . .
 H3A H 1.0057 0.7598 0.6567 0.025 Uiso 1 1 calc GR . . . .
 H3B H 1.0972 0.7047 0.6918 0.025 Uiso 1 1 calc GR . . . .
 H3C H 1.1103 0.8027 0.6677 0.025 Uiso 1 1 calc GR . . . .
 N1 N 1.4294(11) 0.4157(11) 0.3073(9) 0.014(3) Uani 1 1 d . U . . .
 H1A H 1.4951 0.3930 0.3142 0.016 Uiso 1 1 calc GR . . . .
 H1B H 1.3863 0.3794 0.3385 0.016 Uiso 1 1 calc GR . . . .
 H1C H 1.4287 0.4734 0.3311 0.016 Uiso 1 1 calc GR . . . .
 N2 N 1.2456(12) 0.8952(12) 0.4011(10) 0.023(4) Uani 1 1 d . . . . .
 H2A H 1.2113 0.8410 0.3930 0.028 Uiso 1 1 calc GR . . . .
 H2B H 1.2259 0.9233 0.4538 0.028 Uiso 1 1 calc GR . . . .
 H2C H 1.3152 0.8847 0.4071 0.028 Uiso 1 1 calc GR . . . .
 N4 N 1.2589(12) 0.2679(12) 0.6085(10) 0.027(4) Uani 1 1 d . . . . .
 H4A H 1.2897 0.2500 0.5562 0.033 Uiso 1 1 calc GR . . . .
 H4B H 1.2516 0.3298 0.6082 0.033 Uiso 1 1 calc GR . . . .
 H4C H 1.1954 0.2411 0.6090 0.033 Uiso 1 1 calc GR . . . .
 C6 C 1.5886(16) 0.5954(14) 0.0591(13) 0.024(5) Uani 1 1 d . . . . .
 F4 F 1.1346(12) 0.3644(8) 1.0095(8) 0.063(4) Uani 1 1 d . . . . .
 F2 F 1.3368(11) 0.7809(9) -0.0100(8) 0.071(5) Uani 1 1 d . . . . .
 C22 C 0.9173(17) 0.5646(14) 0.9334(13) 0.025(5) Uani 1 1 d . U . . .
 C23 C 0.8568(16) 0.6307(12) 0.8989(12) 0.025(5) Uani 1 1 d . . . . .
 H23 H 0.7843 0.6288 0.9061 0.030 Uiso 1 1 calc R . . . .
 C21 C 1.0232(17) 0.5618(13) 0.9242(13) 0.035(6) Uani 1 1 d . . . . .
 H21 H 1.0649 0.5126 0.9489 0.041 Uiso 1 1 calc R . . . .
 C19 C 1.0049(13) 0.7067(11) 0.8412(11) 0.017(4) Uani 1 1 d . . . . .
 C7 C 1.4886(15) 0.6214(13) 0.0720(12) 0.019(4) Uani 1 1 d . U . . .
 H7 H 1.4623 0.6779 0.0476 0.023 Uiso 1 1 calc R . . . .
 C5 C 1.6303(14) 0.5120(12) 0.0946(13) 0.026(5) Uani 1 1 d . . . . .
 H5 H 1.7003 0.4950 0.0875 0.031 Uiso 1 1 calc R . . . .
 C27 C 1.2739(13) 0.2713(11) 0.7792(10) 0.022(4) Uani 1 1 d . . . . .
 C20 C 1.0661(12) 0.6358(10) 0.8763(10) 0.023(4) Uani 1 1 d . . . . .
 H20 H 1.1384 0.6365 0.8683 0.027 Uiso 1 1 calc R . . . .
 C4 C 1.5644(12) 0.4572(12) 0.1396(11) 0.017(4) Uani 1 1 d . . . . .
 H4 H 1.5892 0.3995 0.1623 0.021 Uiso 1 1 calc R . . . .
 C8 C 1.4267(12) 0.5644(9) 0.1208(10) 0.014(3) Uani 1 1 d . U . . .
 H8 H 1.3581 0.5826 0.1316 0.017 Uiso 1 1 calc R . . . .
 C28 C 1.1867(13) 0.2290(11) 0.8082(10) 0.027(4) Uani 1 1 d . . . . .
 H28 H 1.1596 0.1778 0.7734 0.032 Uiso 1 1 calc R . . . .
 C29 C 1.1366(15) 0.2569(13) 0.8851(11) 0.038(5) Uani 1 1 d . . . . .
 H29 H 1.0768 0.2264 0.9045 0.046 Uiso 1 1 calc R . . . .
 C30 C 1.1781(17) 0.3303(13) 0.9308(12) 0.040(5) Uani 1 1 d . . . . .
 C32 C 1.3110(14) 0.3451(12) 0.8316(12) 0.038(5) Uani 1 1 d . U . . .
 H32 H 1.3713 0.3757 0.8139 0.046 Uiso 1 1 calc R . . . .
 C17 C 1.1492(12) 0.8260(12) 0.8402(11) 0.028(4) Uani 1 1 d . . . . .
 H17A H 1.2036 0.7792 0.8416 0.042 Uiso 1 1 calc GR . . . .
 H17B H 1.1371 0.8439 0.9046 0.042 Uiso 1 1 calc GR . . . .
 H17C H 1.1712 0.8796 0.8056 0.042 Uiso 1 1 calc GR . . . .
 C15 C 1.2200(11) 0.7924(7) 0.1096(8) 0.038(6) Uani 1 1 d . . . . .
 H15 H 1.1790 0.7440 0.0823 0.046 Uiso 1 1 calc R . . . .
 C16 C 1.1907(8) 0.8356(9) 0.1902(8) 0.034(5) Uani 1 1 d G U . . .
 H16 H 1.1297 0.8165 0.2180 0.041 Uiso 1 1 calc R . . . .
 C11 C 1.2506(9) 0.9065(8) 0.2302(7) 0.016(4) Uani 1 1 d G U . . .
 C12 C 1.3398(8) 0.9343(8) 0.1894(8) 0.030(5) Uani 1 1 d G . . . .
 H12 H 1.3807 0.9828 0.2167 0.036 Uiso 1 1 calc R . . . .
 C13 C 1.3690(8) 0.8912(9) 0.1088(8) 0.032(5) Uani 1 1 d G U . . .
 H13 H 1.4300 0.9102 0.0810 0.039 Uiso 1 1 calc R . . . .
 C14 C 1.3092(11) 0.8203(9) 0.0689(7) 0.037(6) Uani 1 1 d G . . . .
 C31 C 1.2628(18) 0.3764(12) 0.9098(12) 0.047(6) Uani 1 1 d . . . . .
 H31 H 1.2886 0.4272 0.9459 0.056 Uiso 1 1 calc R . . . .
 C1 C 1.3884(12) 0.3212(11) 0.1660(12) 0.024(4) Uani 1 1 d . . . . .
 H1D H 1.4574 0.2933 0.1754 0.036 Uiso 1 1 calc GR . . . .
 H1E H 1.3662 0.3219 0.0989 0.036 Uiso 1 1 calc GR . . . .
 H1F H 1.3389 0.2855 0.1998 0.036 Uiso 1 1 calc GR . . . .
 C2 C 1.3926(10) 0.4179(8) 0.2031(8) 0.017(3) Uani 1 1 d . . . . .
 H2 H 1.3209 0.4440 0.1967 0.020 Uiso 1 1 calc R . . . .
 C10 C 1.2195(10) 0.9562(9) 0.3165(9) 0.018(3) Uani 1 1 d . . . . .
 H10 H 1.2635 1.0123 0.3244 0.021 Uiso 1 1 calc R . . . .
 C9 C 1.1080(10) 0.9858(10) 0.3145(9) 0.026(3) Uani 1 1 d . . . . .
 H9A H 1.0629 0.9320 0.3075 0.039 Uiso 1 1 calc GR . . . .
 H9B H 1.0925 1.0273 0.2614 0.039 Uiso 1 1 calc GR . . . .
 H9C H 1.0960 1.0174 0.3732 0.039 Uiso 1 1 calc GR . . . .
 C18 C 1.0488(11) 0.7875(9) 0.7916(8) 0.025(3) Uani 1 1 d . . . . .
 H18 H 0.9956 0.8373 0.7888 0.030 Uiso 1 1 calc R . . . .
 C25 C 1.3517(11) 0.1390(10) 0.6895(10) 0.032(4) Uani 1 1 d . . . . .
 H25A H 1.2887 0.1027 0.6952 0.048 Uiso 1 1 calc GR . . . .
 H25B H 1.4035 0.1228 0.7405 0.048 Uiso 1 1 calc GR . . . .
 H25C H 1.3796 0.1262 0.6289 0.048 Uiso 1 1 calc GR . . . .
 C26 C 1.3261(12) 0.2389(10) 0.6956(10) 0.030(4) Uani 1 1 d . . . . .
 H26 H 1.3930 0.2732 0.6948 0.037 Uiso 1 1 calc R . . . .
 C24 C 0.8993(13) 0.7035(13) 0.8518(13) 0.028(5) Uani 1 1 d . . . . .
 H24 H 0.8555 0.7512 0.8269 0.034 Uiso 1 1 calc R . . . .
 C3 C 1.4639(11) 0.4811(10) 0.1539(11) 0.012(3) Uani 1 1 d . . . . .


_geom_special_details
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;
loop_
  _geom_bond_atom_site_label_1
  _geom_bond_atom_site_label_2
  _geom_bond_distance
  _geom_bond_site_symmetry_2
  _geom_bond_publ_flag
 Bi2 I6 3.3250(14) . ?
 Bi2 I5 3.1903(15) . ?
 Bi2 I10 3.0824(14) . ?
 Bi2 I9 2.9163(14) . ?
 Bi2 I7 3.0434(14) . ?
 Bi2 I8 2.9780(15) . ?
 Bi1 I1 3.0688(14) . ?
 Bi1 I2 2.9778(15) . ?
 Bi1 I6 3.2178(15) . ?
 Bi1 I5 3.3149(14) . ?
 Bi1 I3 2.9119(14) . ?
 Bi1 I4 3.0519(14) . ?
 F1 C6 1.35(2) . ?
 F3 C22 1.38(2) . ?
 N3 C18 1.510(18) . ?
 N1 C2 1.527(16) . ?
 N2 C10 1.518(18) . ?
 N4 C26 1.521(19) . ?
 C6 C7 1.37(3) . ?
 C6 C5 1.41(3) . ?
 F4 C30 1.386(19) . ?
 F2 C14 1.336(14) . ?
 C22 C23 1.31(3) . ?
 C22 C21 1.38(3) . ?
 C23 C24 1.39(2) . ?
 C21 C20 1.42(2) . ?
 C19 C20 1.375(19) . ?
 C19 C18 1.51(2) . ?
 C19 C24 1.39(2) . ?
 C7 C8 1.38(2) . ?
 C5 C4 1.37(2) . ?
 C27 C28 1.38(2) . ?
 C27 C32 1.38(2) . ?
 C27 C26 1.49(2) . ?
 C4 C3 1.37(2) . ?
 C8 C3 1.379(18) . ?
 C28 C29 1.38(2) . ?
 C29 C30 1.35(2) . ?
 C30 C31 1.34(2) . ?
 C32 C31 1.40(2) . ?
 C17 C18 1.53(2) . ?
 C15 C16 1.3900 . ?
 C15 C14 1.3900 . ?
 C16 C11 1.3900 . ?
 C11 C12 1.3900 . ?
 C11 C10 1.511(15) . ?
 C12 C13 1.3900 . ?
 C13 C14 1.3900 . ?
 C1 C2 1.510(19) . ?
 C2 C3 1.514(19) . ?
 C10 C9 1.502(18) . ?
 C25 C26 1.50(2) . ?

loop_
  _geom_angle_atom_site_label_1
  _geom_angle_atom_site_label_2
  _geom_angle_atom_site_label_3
  _geom_angle
  _geom_angle_site_symmetry_1
  _geom_angle_site_symmetry_3
  _geom_angle_publ_flag
 I5 Bi2 I6 87.58(4) . . ?
 I10 Bi2 I6 84.87(4) . . ?
 I10 Bi2 I5 92.82(4) . . ?
 I9 Bi2 I6 171.42(4) . . ?
 I9 Bi2 I5 87.17(4) . . ?
 I9 Bi2 I10 88.61(4) . . ?
 I9 Bi2 I7 98.52(4) . . ?
 I9 Bi2 I8 93.55(4) . . ?
 I7 Bi2 I6 88.27(4) . . ?
 I7 Bi2 I5 90.09(4) . . ?
 I7 Bi2 I10 172.43(4) . . ?
 I8 Bi2 I6 92.02(4) . . ?
 I8 Bi2 I5 177.13(4) . . ?
 I8 Bi2 I10 89.98(4) . . ?
 I8 Bi2 I7 87.06(4) . . ?
 I1 Bi1 I6 94.12(4) . . ?
 I1 Bi1 I5 83.67(4) . . ?
 I2 Bi1 I1 89.21(4) . . ?
 I2 Bi1 I6 176.67(4) . . ?
 I2 Bi1 I5 93.20(4) . . ?
 I2 Bi1 I4 86.05(4) . . ?
 I6 Bi1 I5 87.30(4) . . ?
 I3 Bi1 I1 89.67(4) . . ?
 I3 Bi1 I2 90.65(4) . . ?
 I3 Bi1 I6 89.24(4) . . ?
 I3 Bi1 I5 172.26(4) . . ?
 I3 Bi1 I4 97.61(4) . . ?
 I4 Bi1 I1 171.34(4) . . ?
 I4 Bi1 I6 90.66(4) . . ?
 I4 Bi1 I5 89.36(4) . . ?
 Bi1 I6 Bi2 92.20(4) . . ?
 Bi2 I5 Bi1 92.89(4) . . ?
 F1 C6 C7 118.3(18) . . ?
 F1 C6 C5 119.8(18) . . ?
 C7 C6 C5 121.9(18) . . ?
 F3 C22 C21 118.0(19) . . ?
 C23 C22 F3 118.6(19) . . ?
 C23 C22 C21 123.4(19) . . ?
 C22 C23 C24 119.8(19) . . ?
 C22 C21 C20 116.7(18) . . ?
 C20 C19 C18 122.3(15) . . ?
 C20 C19 C24 118.5(16) . . ?
 C24 C19 C18 119.1(14) . . ?
 C6 C7 C8 119.2(18) . . ?
 C4 C5 C6 116.2(17) . . ?
 C28 C27 C32 116.6(14) . . ?
 C28 C27 C26 121.8(14) . . ?
 C32 C27 C26 121.6(15) . . ?
 C19 C20 C21 121.2(17) . . ?
 C5 C4 C3 123.4(16) . . ?
 C3 C8 C7 120.4(16) . . ?
 C27 C28 C29 123.5(14) . . ?
 C30 C29 C28 115.3(16) . . ?
 C29 C30 F4 120.5(18) . . ?
 C31 C30 F4 112.9(18) . . ?
 C31 C30 C29 126.5(16) . . ?
 C27 C32 C31 122.2(16) . . ?
 C16 C15 C14 120.0 . . ?
 C11 C16 C15 120.0 . . ?
 C16 C11 C12 120.0 . . ?
 C16 C11 C10 121.3(9) . . ?
 C12 C11 C10 118.7(9) . . ?
 C13 C12 C11 120.0 . . ?
 C14 C13 C12 120.0 . . ?
 F2 C14 C15 120.6(12) . . ?
 F2 C14 C13 119.3(12) . . ?
 C13 C14 C15 120.0 . . ?
 C30 C31 C32 115.8(16) . . ?
 C1 C2 N1 108.8(11) . . ?
 C1 C2 C3 114.6(11) . . ?
 C3 C2 N1 108.0(11) . . ?
 C11 C10 N2 108.0(11) . . ?
 C9 C10 N2 109.8(11) . . ?
 C9 C10 C11 115.9(11) . . ?
 N3 C18 C17 109.4(12) . . ?
 C19 C18 N3 109.5(12) . . ?
 C19 C18 C17 114.3(12) . . ?
 C27 C26 N4 107.5(13) . . ?
 C27 C26 C25 118.0(13) . . ?
 C25 C26 N4 109.8(13) . . ?
 C19 C24 C23 120.4(17) . . ?
 C4 C3 C8 118.8(15) . . ?
 C4 C3 C2 121.9(14) . . ?
 C8 C3 C2 119.3(13) . . ?

_olex2_submission_special_instructions  'No special instructions were received'
