data_tbltbl
_nottingham_internal_coll_name     TBLTBL
_nottingham_internal_coll_number   18186
_nottingham_internal_coll_client   TB/LTB
_nottingham_internal_coll_type     custom
_nottingham_internal_coll_frame_method  '\w scans'
_nottingham_internal_coll_frame_time  7.50
_nottingham_internal_coll_frame_width  1.00
_nottingham_internal_coll_user     pczspa
_nottingham_internal_coll_date     08/05/2019
_nottingham_internal_coll_location  NOTTS
_nottingham_internal_coll_instrument  'SN, XDA 017-09'
_nottingham_internal_NCS_number    ?
_nottingham_internal_process_date  08/05/2019
_nottingham_internal_process_user  pczspa
_nottingham_internal_solution_date  08/05/2019
_nottingham_internal_solution_user  pczspa
_nottingham_internal_refinement_date  19/06/2019
_nottingham_internal_refinement_user  pczspa
_nottingham_internal_self_archive_date  ?
_nottingham_internal_self_validation_date  ?
_nottingham_internal_self_validation_user  ?
_nottingham_internal_validation_date  19/06/2019
_nottingham_internal_validation_user  pczspa
_nottingham_internal_archive_date  ?
_refine_special_details           
 'Hydrogen atoms were observed in the electron density map before being geometrically placed and refined using a riding model.'
_audit_creation_date               2019-06-19
_audit_creation_method
;
Olex2 1.2
(compiled 2018.05.29 svn.r3508 for OlexSys, GUI svn.r5506)
;
_shelx_SHELXL_version_number       '2018/3'
_publ_contact_author_id_orcid      ?
_publ_section_references
;
Dolomanov, O.V., Bourhis, L.J., Gildea, R.J, Howard, J.A.K. & Puschmann, H.
 (2009), J. Appl. Cryst. 42, 339-341.

Sheldrick, G.M. (2015). Acta Cryst. A71, 3-8.

Sheldrick, G.M. (2015). Acta Cryst. C71, 3-8.
;
_chemical_name_common              ?
_chemical_name_systematic          ?
_chemical_formula_moiety           'C24 H35 Au Cl P'
_chemical_formula_sum              'C24 H35 Au Cl P'
_chemical_formula_weight           586.90
_chemical_melting_point            ?
_chemical_oxdiff_formula           'C24 H35 Au Cl P'
_chemical_oxdiff_usercomment      
 'TBLTBL SN-1511 #18186 for TB/LTB fomblin microloop'
loop_
  _atom_type_symbol
  _atom_type_description
  _atom_type_scat_dispersion_real
  _atom_type_scat_dispersion_imag
  _atom_type_scat_source
 'C' 'C' 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
 'H' 'H' 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
 'Au' 'Au' -2.0133 8.8022
 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
 'Cl' 'Cl' 0.1484 0.1585 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
 'P' 'P' 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_shelx_space_group_comment
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
_space_group_crystal_system        'monoclinic'
_space_group_IT_number             14
_space_group_name_H-M_alt          'P 1 21/n 1'
_space_group_name_Hall             '-P 2yn'
loop_
  _space_group_symop_operation_xyz
 'x, y, z'
 '-x+1/2, y+1/2, -z+1/2'
 '-x, -y, -z'
 'x-1/2, -y-1/2, z-1/2'

_cell_length_a                     10.0134(2)
_cell_length_b                     14.7285(3)
_cell_length_c                     15.0955(3)
_cell_angle_alpha                  90
_cell_angle_beta                   92.029(2)
_cell_angle_gamma                  90
_cell_volume                       2224.92(8)
_cell_formula_units_Z              4
_cell_measurement_reflns_used      17253
_cell_measurement_temperature      120(2)
_cell_measurement_theta_max        37.5990
_cell_measurement_theta_min        3.6860
_shelx_estimated_absorpt_T_max     0.564
_shelx_estimated_absorpt_T_min     0.269
_exptl_absorpt_coefficient_mu      6.811
_exptl_absorpt_correction_T_max    0.881
_exptl_absorpt_correction_T_min    0.322
_exptl_absorpt_correction_type     gaussian
_exptl_absorpt_process_details
;
CrysAlisPro 1.171.39.46 (Rigaku Oxford Diffraction, 2018)
Numerical absorption correction based on gaussian integration over
			a multifaceted crystal model
Empirical absorption correction using spherical harmonics,
 implemented in SCALE3 ABSPACK scaling algorithm.
;
_exptl_absorpt_special_details     ?
_exptl_crystal_colour              colourless
_exptl_crystal_colour_primary      colourless
_exptl_crystal_density_diffrn      1.752
_exptl_crystal_density_meas        ?
_exptl_crystal_density_method      ?
_exptl_crystal_description         block
_exptl_crystal_F_000               1160
loop_
  _exptl_crystal_face_index_h
  _exptl_crystal_face_index_k
  _exptl_crystal_face_index_l
  _exptl_crystal_face_perp_dist
 -10 -1 15 0.0476
 10 1 -15 0.0476
 -3 18 -9 0.1197
 5 -18 8 0.1380
 9 -7 15 0.1196
 -4 -19 -7 0.1291
 2 20 7 0.0991
 -13 -1 -6 0.1019
 13 -3 5 0.0939
 4 -19 -4 0.1217
 0 0 21 0.0934
 0 1 -21 0.1049
 7 -12 -14 0.0852
 8 14 -9 0.0824

_exptl_crystal_size_max            0.261
_exptl_crystal_size_mid            0.23
_exptl_crystal_size_min            0.095
loop_
  _exptl_oxdiff_crystal_face_indexfrac_h
  _exptl_oxdiff_crystal_face_indexfrac_k
  _exptl_oxdiff_crystal_face_indexfrac_l
  _exptl_oxdiff_crystal_face_x
  _exptl_oxdiff_crystal_face_y
  _exptl_oxdiff_crystal_face_z
 -10.0020 -1.0091 14.9801 0.1503 0.8636 -0.4434
 10.0020 1.0091 -14.9801 -0.1503 -0.8636 0.4434
 -2.9948 17.9831 -8.9898 -0.0523 -0.6036 -0.7826
 4.9940 -17.9821 7.9923 0.0892 0.4970 0.8780
 8.9857 -6.9981 14.9949 0.7141 0.2893 0.6745
 -3.9907 -18.9747 -7.0055 -0.7924 0.4042 0.4888
 1.9919 19.9731 7.0041 0.7408 -0.3528 -0.6196
 -12.9874 -0.9983 -6.0077 -0.7064 0.3346 -0.5814
 12.9885 -2.9965 5.0070 0.5869 -0.2670 0.7243
 4.0021 -18.9746 -4.0005 -0.3953 0.1922 0.8687
 -0.0126 -0.0115 20.9852 0.7478 0.6429 -0.0046
 0.0125 1.0103 -20.9848 -0.7268 -0.6675 -0.0310
 7.0051 -11.9767 -13.9882 -0.4959 -0.3998 0.7640
 7.9982 13.9901 -8.9815 0.2631 -0.9232 -0.1167

_exptl_transmission_factor_max     ?
_exptl_transmission_factor_min     ?
_diffrn_reflns_av_R_equivalents    0.0414
_diffrn_reflns_av_unetI/netI       0.0390
_diffrn_reflns_Laue_measured_fraction_full  0.996
_diffrn_reflns_Laue_measured_fraction_max  0.960
_diffrn_reflns_limit_h_max         16
_diffrn_reflns_limit_h_min         -17
_diffrn_reflns_limit_k_max         25
_diffrn_reflns_limit_k_min         -24
_diffrn_reflns_limit_l_max         25
_diffrn_reflns_limit_l_min         -25
_diffrn_reflns_number              44846
_diffrn_reflns_point_group_measured_fraction_full  0.996
_diffrn_reflns_point_group_measured_fraction_max  0.960
_diffrn_reflns_theta_full          25.242
_diffrn_reflns_theta_max           37.797
_diffrn_reflns_theta_min           3.034
_diffrn_ambient_environment        N~2~
_diffrn_ambient_temperature        120(2)
_diffrn_crystal_treatment          'flash frozen in gaseous N2'
_diffrn_detector                   'CCD area detector'
_diffrn_detector_area_resol_mean   10.3613
_diffrn_detector_type              'Agilent Diffraction Atlas detector'
_diffrn_measured_fraction_theta_full  0.996
_diffrn_measured_fraction_theta_max  0.960
_diffrn_measurement_details
;
List of Runs (angles in degrees, time in seconds):

  # Type    Start    End  Width  tₑₓₚ   ω     θ     κ     φ   Frames
--------------------------------------------------------------------------
  1  ω   -114.00 -55.00   1.00    7.50    --  -28.72 178.00-150.00   59
  2  ω    -43.00  52.00   1.00    7.50    --   29.65 -38.00-180.00   95
  3  ω      7.00 102.00   1.00    7.50    --   29.65  38.00-180.00   95
  4  ω     -7.00 108.00   1.00    7.50    --   29.65  19.00  30.00  115
  5  ω    -44.00  61.00   1.00    7.50    --   29.65 -77.00-180.00  105
  6  ω    -40.00  -4.00   1.00    7.50    --   29.65 -57.00  30.00   36
;
_diffrn_measurement_device         'κ-geometry diffractometer'
_diffrn_measurement_device_type    'SuperNova, Atlas'
_diffrn_measurement_method         'ω scans'
_diffrn_measurement_specimen_support  'MiTeGen micromount'
_diffrn_orient_matrix_type        
 'CrysAlisPro convention (1999,Acta A55,543-557)'
_diffrn_orient_matrix_UB_11        0.0362776000
_diffrn_orient_matrix_UB_12        0.0209656000
_diffrn_orient_matrix_UB_13        0.0356663000
_diffrn_orient_matrix_UB_21        -0.0380282000
_diffrn_orient_matrix_UB_22        -0.0246016000
_diffrn_orient_matrix_UB_23        0.0306013000
_diffrn_orient_matrix_UB_31        0.0476118000
_diffrn_orient_matrix_UB_32        -0.0356969000
_diffrn_orient_matrix_UB_33        -0.0002116000
_diffrn_radiation_monochromator    mirror
_diffrn_radiation_probe            x-ray
_diffrn_radiation_type             MoK\a
_diffrn_radiation_wavelength       0.71073
_diffrn_source                     'microfocus sealed tube'
_diffrn_source_type                'Agilent Diffraction microfocus tube'
_reflns_Friedel_coverage           0.000
_reflns_Friedel_fraction_full      .
_reflns_Friedel_fraction_max       .
_reflns_number_gt                  9721
_reflns_number_total               11484
_reflns_odcompleteness_completeness  99.88
_reflns_odcompleteness_iscentric   1
_reflns_odcompleteness_theta       36.23
_reflns_special_details
;
 Reflections were merged by SHELXL according to the crystal
 class for the calculation of statistics and refinement.
 
 _reflns_Friedel_fraction is defined as the number of unique
 Friedel pairs measured divided by the number that would be
 possible theoretically, ignoring centric projections and
 systematic absences.
;
_reflns_threshold_expression       'I > 2σ(I)'
_computing_cell_refinement         'CrysAlisPro 1.171.39.46 (Rigaku OD, 2018)'
_computing_data_collection         'CrysAlisPro 1.171.39.46 (Rigaku OD, 2018)'
_computing_data_reduction          'CrysAlisPro 1.171.39.46 (Rigaku OD, 2018)'
_computing_molecular_graphics      'Olex2 (Dolomanov et al., 2009)'
_computing_publication_material    'Olex2 (Dolomanov et al., 2009)'
_computing_structure_refinement    'ShelXL (Sheldrick, 2015)'
_computing_structure_solution      'ShelXT (Sheldrick, 2015)'
_refine_diff_density_max           1.727
_refine_diff_density_min           -1.557
_refine_diff_density_rms           0.151
_refine_ls_extinction_coef         0.00051(6)
_refine_ls_extinction_expression  
 'Fc^*^=kFc[1+0.001xFc²λ³/sin(2θ)]^-1/4^'
_refine_ls_extinction_method       'SHELXL-2018/3 (Sheldrick 2018)'
_refine_ls_goodness_of_fit_ref     1.054
_refine_ls_hydrogen_treatment      constr
_refine_ls_matrix_type             full
_refine_ls_number_parameters       251
_refine_ls_number_reflns           11484
_refine_ls_number_restraints       0
_refine_ls_R_factor_all            0.0355
_refine_ls_R_factor_gt             0.0249
_refine_ls_restrained_S_all        1.054
_refine_ls_shift/su_max            0.003
_refine_ls_shift/su_mean           0.000
_refine_ls_structure_factor_coef   Fsqd
_refine_ls_weighting_details      
 'w=1/[σ²(Fo²)+(0.0162P)²] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme        calc
_refine_ls_wR_factor_gt            0.0467
_refine_ls_wR_factor_ref           0.0506
_olex2_refinement_description
;
1. Fixed Uiso
 At 1.2 times of:
  All C(H) groups, All C(H,H) groups
 At 1.5 times of:
  All C(H,H,H) groups
2.a Secondary CH2 refined with riding coordinates:
 C18(H18A,H18B), C20(H20A,H20B), C24(H24A,H24B), C26(H26A,H26B)
2.b Aromatic/amide H refined with riding coordinates:
 C5(H5), C6(H6), C7(H7), C8(H8), C11(H11), C12(H12), C13(H13), C14(H14),
 C15(H15)
2.c Idealised Me refined as rotating group:
 C17(H17A,H17B,H17C), C19(H19A,H19B,H19C), C21(H21A,H21B,H21C), C23(H23A,H23B,
 H23C), C25(H25A,H25B,H25C), C27(H27A,H27B,H27C)
;
_atom_sites_solution_hydrogens     geom
_atom_sites_solution_primary       dual
_atom_sites_solution_secondary     difmap
loop_
  _atom_site_label
  _atom_site_type_symbol
  _atom_site_fract_x
  _atom_site_fract_y
  _atom_site_fract_z
  _atom_site_U_iso_or_equiv
  _atom_site_adp_type
  _atom_site_occupancy
  _atom_site_site_symmetry_order
  _atom_site_calc_flag
  _atom_site_refinement_flags_posn
  _atom_site_refinement_flags_adp
  _atom_site_refinement_flags_occupancy
  _atom_site_disorder_assembly
  _atom_site_disorder_group
 Au1 Au 0.65195(2) 0.66258(2) 0.07266(2) 0.01201(2) Uani 1 1 d . . . . .
 Cl2 Cl 0.72468(5) 0.59415(3) -0.05443(3) 0.01944(9) Uani 1 1 d . . . . .
 P3 P 0.55941(5) 0.72989(3) 0.18987(3) 0.01075(8) Uani 1 1 d . . . . .
 C4 C 0.67641(17) 0.79468(11) 0.26300(10) 0.0119(3) Uani 1 1 d . . . . .
 C5 C 0.62283(19) 0.85770(11) 0.32196(11) 0.0145(3) Uani 1 1 d . . . . .
 H5 H 0.528856 0.866678 0.321307 0.017 Uiso 1 1 calc R . . . .
 C6 C 0.7036(2) 0.90738(12) 0.38131(11) 0.0170(3) Uani 1 1 d . . . . .
 H6 H 0.664854 0.950801 0.419224 0.020 Uiso 1 1 calc R . . . .
 C7 C 0.8396(2) 0.89340(12) 0.38491(12) 0.0181(4) Uani 1 1 d . . . . .
 H7 H 0.895033 0.926394 0.425878 0.022 Uiso 1 1 calc R . . . .
 C8 C 0.8950(2) 0.83083(12) 0.32829(12) 0.0174(3) Uani 1 1 d . . . . .
 H8 H 0.988810 0.820882 0.331637 0.021 Uiso 1 1 calc R . . . .
 C9 C 0.81614(18) 0.78162(11) 0.26598(11) 0.0129(3) Uani 1 1 d . . . . .
 C10 C 0.89231(17) 0.71887(12) 0.20887(11) 0.0135(3) Uani 1 1 d . . . . .
 C11 C 0.94831(19) 0.63933(13) 0.24486(13) 0.0173(3) Uani 1 1 d . . . . .
 H11 H 0.931830 0.623319 0.304448 0.021 Uiso 1 1 calc R . . . .
 C12 C 1.02725(19) 0.58388(12) 0.19467(13) 0.0190(4) Uani 1 1 d . . . . .
 H12 H 1.064895 0.530307 0.220150 0.023 Uiso 1 1 calc R . . . .
 C13 C 1.0521(2) 0.60577(12) 0.10729(13) 0.0189(3) Uani 1 1 d . . . . .
 H13 H 1.104861 0.566799 0.072616 0.023 Uiso 1 1 calc R . . . .
 C14 C 0.9991(2) 0.68490(13) 0.07121(12) 0.0182(3) Uani 1 1 d . . . . .
 H14 H 1.016150 0.700528 0.011602 0.022 Uiso 1 1 calc R . . . .
 C15 C 0.92108(19) 0.74165(12) 0.12181(12) 0.0163(3) Uani 1 1 d . . . . .
 H15 H 0.886984 0.796522 0.096855 0.020 Uiso 1 1 calc R . . . .
 C16 C 0.42282(18) 0.81101(12) 0.14558(11) 0.0132(3) Uani 1 1 d . . . . .
 C17 C 0.3075(2) 0.82783(13) 0.20842(12) 0.0187(4) Uani 1 1 d . . . . .
 H17A H 0.265897 0.769793 0.223122 0.028 Uiso 1 1 calc GR . . . .
 H17B H 0.240833 0.867521 0.179280 0.028 Uiso 1 1 calc GR . . . .
 H17C H 0.342495 0.856895 0.262843 0.028 Uiso 1 1 calc GR . . . .
 C18 C 0.36330(18) 0.76756(12) 0.05911(11) 0.0152(3) Uani 1 1 d . . . . .
 H18A H 0.437970 0.751316 0.020879 0.018 Uiso 1 1 calc R . . . .
 H18B H 0.317709 0.710463 0.074899 0.018 Uiso 1 1 calc R . . . .
 C19 C 0.2646(2) 0.82627(13) 0.00519(13) 0.0202(4) Uani 1 1 d . . . . .
 H19A H 0.230914 0.792136 -0.046659 0.030 Uiso 1 1 calc GR . . . .
 H19B H 0.309733 0.881392 -0.014398 0.030 Uiso 1 1 calc GR . . . .
 H19C H 0.189761 0.842966 0.042013 0.030 Uiso 1 1 calc GR . . . .
 C20 C 0.48703(19) 0.90381(12) 0.12429(11) 0.0159(3) Uani 1 1 d . . . . .
 H20A H 0.414591 0.946807 0.107245 0.019 Uiso 1 1 calc R . . . .
 H20B H 0.531577 0.927306 0.179219 0.019 Uiso 1 1 calc R . . . .
 C21 C 0.5879(2) 0.90391(13) 0.05180(13) 0.0203(4) Uani 1 1 d . . . . .
 H21A H 0.545007 0.882234 -0.003614 0.030 Uiso 1 1 calc GR . . . .
 H21B H 0.662583 0.863813 0.068723 0.030 Uiso 1 1 calc GR . . . .
 H21C H 0.621220 0.965760 0.043397 0.030 Uiso 1 1 calc GR . . . .
 C22 C 0.49027(18) 0.63892(12) 0.26356(11) 0.0130(3) Uani 1 1 d . . . . .
 C23 C 0.3857(2) 0.58611(12) 0.20758(12) 0.0185(4) Uani 1 1 d . . . . .
 H23A H 0.305825 0.623782 0.197815 0.028 Uiso 1 1 calc GR . . . .
 H23B H 0.361664 0.530449 0.238827 0.028 Uiso 1 1 calc GR . . . .
 H23C H 0.422690 0.570373 0.150344 0.028 Uiso 1 1 calc GR . . . .
 C24 C 0.61166(19) 0.57652(12) 0.28489(12) 0.0170(3) Uani 1 1 d . . . . .
 H24A H 0.643345 0.551300 0.228588 0.020 Uiso 1 1 calc R . . . .
 H24B H 0.684803 0.613992 0.311373 0.020 Uiso 1 1 calc R . . . .
 C25 C 0.5846(2) 0.49765(13) 0.34782(14) 0.0262(4) Uani 1 1 d . . . . .
 H25A H 0.508430 0.462169 0.324384 0.039 Uiso 1 1 calc GR . . . .
 H25B H 0.564145 0.521636 0.406366 0.039 Uiso 1 1 calc GR . . . .
 H25C H 0.663766 0.458670 0.352998 0.039 Uiso 1 1 calc GR . . . .
 C26 C 0.4350(2) 0.67835(13) 0.35046(12) 0.0170(3) Uani 1 1 d . . . . .
 H26A H 0.508437 0.678882 0.396121 0.020 Uiso 1 1 calc R . . . .
 H26B H 0.408566 0.742222 0.339310 0.020 Uiso 1 1 calc R . . . .
 C27 C 0.3163(3) 0.62865(18) 0.38831(15) 0.0339(5) Uani 1 1 d . . . . .
 H27A H 0.239860 0.631972 0.346052 0.051 Uiso 1 1 calc GR . . . .
 H27B H 0.292645 0.657112 0.444311 0.051 Uiso 1 1 calc GR . . . .
 H27C H 0.340013 0.564926 0.398917 0.051 Uiso 1 1 calc GR . . . .


_geom_special_details
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;
loop_
  _geom_bond_atom_site_label_1
  _geom_bond_atom_site_label_2
  _geom_bond_distance
  _geom_bond_site_symmetry_2
  _geom_bond_publ_flag
 Au1 Cl2 2.3079(4) . ?
 Au1 P3 2.2556(4) . ?
 P3 C4 1.8466(16) . ?
 P3 C16 1.9184(17) . ?
 P3 C22 1.8886(18) . ?
 C4 C5 1.405(2) . ?
 C4 C9 1.411(2) . ?
 C5 C6 1.393(2) . ?
 C6 C7 1.377(3) . ?
 C7 C8 1.386(3) . ?
 C8 C9 1.408(2) . ?
 C9 C10 1.492(2) . ?
 C10 C11 1.400(2) . ?
 C10 C15 1.396(2) . ?
 C11 C12 1.381(3) . ?
 C12 C13 1.389(3) . ?
 C13 C14 1.384(3) . ?
 C14 C15 1.391(3) . ?
 C16 C17 1.540(3) . ?
 C16 C18 1.553(2) . ?
 C16 C20 1.549(2) . ?
 C18 C19 1.526(2) . ?
 C20 C21 1.515(3) . ?
 C22 C23 1.534(2) . ?
 C22 C24 1.549(2) . ?
 C22 C26 1.554(3) . ?
 C24 C25 1.531(3) . ?
 C26 C27 1.524(3) . ?

loop_
  _geom_angle_atom_site_label_1
  _geom_angle_atom_site_label_2
  _geom_angle_atom_site_label_3
  _geom_angle
  _geom_angle_site_symmetry_1
  _geom_angle_site_symmetry_3
  _geom_angle_publ_flag
 P3 Au1 Cl2 173.999(16) . . ?
 C4 P3 Au1 115.25(6) . . ?
 C4 P3 C16 108.42(7) . . ?
 C4 P3 C22 104.63(7) . . ?
 C16 P3 Au1 107.94(5) . . ?
 C22 P3 Au1 108.63(6) . . ?
 C22 P3 C16 112.05(8) . . ?
 C5 C4 P3 118.13(13) . . ?
 C5 C4 C9 118.04(15) . . ?
 C9 C4 P3 123.77(13) . . ?
 C6 C5 C4 121.90(17) . . ?
 C7 C6 C5 119.85(17) . . ?
 C6 C7 C8 119.49(16) . . ?
 C7 C8 C9 121.79(18) . . ?
 C4 C9 C10 126.34(14) . . ?
 C8 C9 C4 118.90(16) . . ?
 C8 C9 C10 114.76(16) . . ?
 C11 C10 C9 120.00(16) . . ?
 C15 C10 C9 121.45(15) . . ?
 C15 C10 C11 118.24(17) . . ?
 C12 C11 C10 120.72(17) . . ?
 C11 C12 C13 120.59(17) . . ?
 C14 C13 C12 119.36(18) . . ?
 C13 C14 C15 120.31(17) . . ?
 C14 C15 C10 120.74(17) . . ?
 C17 C16 P3 115.23(12) . . ?
 C17 C16 C18 108.07(15) . . ?
 C17 C16 C20 108.15(15) . . ?
 C18 C16 P3 106.49(11) . . ?
 C20 C16 P3 109.01(12) . . ?
 C20 C16 C18 109.81(14) . . ?
 C19 C18 C16 115.89(14) . . ?
 C21 C20 C16 116.29(15) . . ?
 C23 C22 P3 107.02(11) . . ?
 C23 C22 C24 109.23(14) . . ?
 C23 C22 C26 113.44(15) . . ?
 C24 C22 P3 104.01(12) . . ?
 C24 C22 C26 110.28(14) . . ?
 C26 C22 P3 112.39(12) . . ?
 C25 C24 C22 115.10(17) . . ?
 C27 C26 C22 116.27(16) . . ?

_audit_contact_author_address      ?
_audit_contact_author_email        ?
_audit_contact_author_name         ''
_audit_contact_author_phone        ?
_olex2_exptl_crystal_mounting_method  'in fomblin film on a micromount'
_olex2_submission_special_instructions  'No special instructions were received'
_oxdiff_exptl_absorpt_empirical_details
;
Empirical correction (ABSPACK) includes:
- Absorption correction using spherical harmonics
- Frame scaling
;
_oxdiff_exptl_absorpt_empirical_full_max  1.498
_oxdiff_exptl_absorpt_empirical_full_min  0.806
