 
data_norh 
 
_audit_creation_method            SHELXL-97 
_chemical_name_systematic 
; 
 ? 
; 
_chemical_name_common             4 
_chemical_melting_point           ? 
_chemical_formula_moiety          'C25 H36 N O Rh' 
_chemical_formula_sum 
 'C25 H36 N O Rh' 
_chemical_formula_weight          469.46 
 
loop_ 
 _atom_type_symbol 
 _atom_type_description 
 _atom_type_scat_dispersion_real 
 _atom_type_scat_dispersion_imag 
 _atom_type_scat_source 
 'C'  'C'   0.0033   0.0016 
 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' 
 'H'  'H'   0.0000   0.0000 
 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' 
 'N'  'N'   0.0061   0.0033 
 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' 
 'O'  'O'   0.0106   0.0060 
 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' 
 'Rh'  'Rh'  -1.1178   0.9187 
 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' 
 
_symmetry_cell_setting                 triclinic
_symmetry_space_group_name_H-M        'P -1'
_symmetry_space_group_name_Hall       '	-P 1'
_symmetry_Int_Tables_number            2
 
loop_ 
 _symmetry_equiv_pos_as_xyz 
 'x, y, z' 
 '-x, -y, -z' 
 
_cell_length_a                    8.8811(2) 
_cell_length_b                    8.8115(2) 
_cell_length_c                    15.1061(3) 
_cell_angle_alpha                 90.6294(9) 
_cell_angle_beta                  101.8877(10) 
_cell_angle_gamma                 107.159(2) 
_cell_volume                      1102.04(4) 
_cell_formula_units_Z             2 
_cell_measurement_temperature     103(2) 
_cell_measurement_reflns_used     ? 
_cell_measurement_theta_min       2.43 
_cell_measurement_theta_max       25.5 
 
_exptl_crystal_description        prism 
_exptl_crystal_colour             yellow 
_exptl_crystal_size_max           0.30 
_exptl_crystal_size_mid           0.20 
_exptl_crystal_size_min           0.10 
_exptl_crystal_density_meas       ? 
_exptl_crystal_density_diffrn     1.415 
_exptl_crystal_density_method     'not measured' 
_exptl_crystal_F_000              492 
_exptl_absorpt_coefficient_mu     0.790 
_exptl_absorpt_correction_type    multi-scan  
_exptl_absorpt_correction_T_min   0.7975 
_exptl_absorpt_correction_T_max   0.9252 
_exptl_absorpt_process_details    
'Jacobson, R. (1998) Private communication' 
 
_exptl_special_details 
; 
 ? 
; 
 
_diffrn_ambient_temperature       103(2) 
_diffrn_radiation_wavelength      0.71069 
_diffrn_radiation_type            MoK\a 
_diffrn_radiation_source          'fine-focus sealed tube' 
_diffrn_radiation_monochromator   graphite 
_diffrn_measurement_device_type   'Rigaku Mercury'   
_diffrn_measurement_method        ω 
_diffrn_detector_area_resol_mean  7.31  
_diffrn_reflns_number             9717 
_diffrn_reflns_av_R_equivalents   0.0308 
_diffrn_reflns_av_sigmaI/netI     0.0320 
_diffrn_reflns_limit_h_min        -10 
_diffrn_reflns_limit_h_max        10 
_diffrn_reflns_limit_k_min        -10 
_diffrn_reflns_limit_k_max        10 
_diffrn_reflns_limit_l_min        -16 
_diffrn_reflns_limit_l_max        18 
_diffrn_reflns_theta_min          2.43 
_diffrn_reflns_theta_max          25.50 
_reflns_number_total              4057 
_reflns_number_gt                 3858 
_reflns_threshold_expression      >2sigma(I) 
 
_computing_data_collection        'CrystalClear'  
_computing_cell_refinement        'HKL2000' 
_computing_data_reduction         'HKL2000' 
_computing_structure_solution     'SHELXS-97 (Sheldrick, 1990)' 
_computing_structure_refinement   'SHELXL-97 (Sheldrick, 1997)' 
_computing_molecular_graphics     ? 
_computing_publication_material   ? 
 
_refine_special_details 
; 
 Refinement of F² against ALL reflections.  The weighted R-factor wR and 
 goodness of fit S are based on F², conventional R-factors R are based 
 on F, with F set to zero for negative F². The threshold expression of 
 F² > 2sigma(F²) is used only for calculating R-factors(gt) etc. and is 
 not relevant to the choice of reflections for refinement.  R-factors based 
 on F² are statistically about twice as large as those based on F, and R- 
 factors based on ALL data will be even larger. 
; 
 
_refine_ls_structure_factor_coef  Fsqd  
_refine_ls_matrix_type            full 
_refine_ls_weighting_scheme       calc  
_refine_ls_weighting_details 
 'calc w=1/[σ²(Fo²)+(0.0233P)²+0.7391P] where P=(Fo²+2Fc²)/3' 
_atom_sites_solution_primary      direct 
_atom_sites_solution_secondary    difmap 
_atom_sites_solution_hydrogens    geom 
_refine_ls_hydrogen_treatment     constr
_refine_ls_extinction_method      none 
_refine_ls_extinction_coef        ? 
_refine_ls_number_reflns          4057 
_refine_ls_number_parameters      259 
_refine_ls_number_restraints      0 
_refine_ls_R_factor_all           0.0252 
_refine_ls_R_factor_gt            0.0237 
_refine_ls_wR_factor_ref          0.0607 
_refine_ls_wR_factor_gt           0.0600 
_refine_ls_goodness_of_fit_ref    1.167 
_refine_ls_restrained_S_all       1.167 
_refine_ls_shift/su_max           0.001 
_refine_ls_shift/su_mean          0.000 
 
loop_ 
 _atom_site_label 
 _atom_site_type_symbol 
 _atom_site_fract_x 
 _atom_site_fract_y 
 _atom_site_fract_z 
 _atom_site_U_iso_or_equiv 
 _atom_site_adp_type 
 _atom_site_occupancy 
 _atom_site_symmetry_multiplicity 
 _atom_site_calc_flag 
 _atom_site_refinement_flags 
 _atom_site_disorder_assembly 
 _atom_site_disorder_group 
Rh1 Rh 0.168895(17) 0.236906(17) 0.309223(10) 0.01213(7) Uani 1 1 d . . . 
N1 N 0.2445(2) 0.3646(2) 0.20162(12) 0.0141(3) Uani 1 1 d . . . 
C1 C 0.1626(2) 0.3355(2) 0.11620(14) 0.0164(4) Uani 1 1 d . . . 
C2 C 0.0201(3) 0.2064(3) 0.08462(15) 0.0185(4) Uani 1 1 d . . . 
H1 H -0.0246 0.1968 0.0213 0.022 Uiso 1 1 calc R . . 
C3 C -0.0613(2) 0.0936(2) 0.13404(14) 0.0167(4) Uani 1 1 d . . . 
O1 O -0.02446(17) 0.08689(17) 0.22071(10) 0.0168(3) Uani 1 1 d . . . 
C4 C 0.2157(3) 0.4443(3) 0.04396(15) 0.0218(5) Uani 1 1 d . . . 
H2 H 0.1598 0.5256 0.0382 0.033 Uiso 1 1 calc R . . 
H3 H 0.1889 0.3816 -0.0142 0.033 Uiso 1 1 calc R . . 
H4 H 0.3326 0.4961 0.0612 0.033 Uiso 1 1 calc R . . 
C5 C -0.2090(3) -0.0371(3) 0.08552(15) 0.0227(5) Uani 1 1 d . . . 
H5 H -0.1944 -0.1410 0.0992 0.034 Uiso 1 1 calc R . . 
H6 H -0.2245 -0.0273 0.0199 0.034 Uiso 1 1 calc R . . 
H7 H -0.3041 -0.0279 0.1059 0.034 Uiso 1 1 calc R . . 
C6 C 0.3194(2) 0.4097(2) 0.41638(14) 0.0162(4) Uani 1 1 d . . . 
H8 H 0.3661 0.5173 0.3954 0.019 Uiso 1 1 calc R . . 
C7 C 0.2427(3) 0.4133(3) 0.49717(15) 0.0192(4) Uani 1 1 d . . . 
H9 H 0.2530 0.5250 0.5149 0.023 Uiso 1 1 calc R . . 
H10 H 0.3015 0.3711 0.5491 0.023 Uiso 1 1 calc R . . 
C8 C 0.0631(3) 0.3146(3) 0.47631(15) 0.0199(4) Uani 1 1 d . . . 
H11 H 0.0334 0.2741 0.5332 0.024 Uiso 1 1 calc R . . 
H12 H -0.0031 0.3845 0.4533 0.024 Uiso 1 1 calc R . . 
C9 C 0.0247(2) 0.1757(2) 0.40725(14) 0.0162(4) Uani 1 1 d . . . 
H13 H -0.0933 0.1284 0.3803 0.019 Uiso 1 1 calc R . . 
C10 C 0.1129(2) 0.0677(2) 0.40832(14) 0.0167(4) Uani 1 1 d . . . 
H14 H 0.0463 -0.0417 0.3815 0.020 Uiso 1 1 calc R . . 
C11 C 0.2576(3) 0.0706(3) 0.48302(15) 0.0185(4) Uani 1 1 d . . . 
H15 H 0.2576 -0.0399 0.4942 0.022 Uiso 1 1 calc R . . 
H16 H 0.2496 0.1218 0.5398 0.022 Uiso 1 1 calc R . . 
C12 C 0.4164(2) 0.1628(3) 0.45655(15) 0.0190(4) Uani 1 1 d . . . 
H17 H 0.5009 0.2053 0.5123 0.023 Uiso 1 1 calc R . . 
H18 H 0.4522 0.0888 0.4221 0.023 Uiso 1 1 calc R . . 
C13 C 0.3977(2) 0.2990(2) 0.39960(14) 0.0156(4) Uani 1 1 d . . . 
H19 H 0.4896 0.3438 0.3693 0.019 Uiso 1 1 calc R . . 
C14 C 0.3888(2) 0.4995(2) 0.22157(13) 0.0143(4) Uani 1 1 d . . . 
C15 C 0.5392(2) 0.4729(2) 0.22611(14) 0.0161(4) Uani 1 1 d . . . 
C16 C 0.6783(3) 0.6038(3) 0.24924(15) 0.0207(5) Uani 1 1 d . . . 
H20 H 0.7807 0.5887 0.2517 0.025 Uiso 1 1 calc R . . 
C17 C 0.6707(3) 0.7547(3) 0.26861(15) 0.0231(5) Uani 1 1 d . . . 
H21 H 0.7669 0.8416 0.2859 0.028 Uiso 1 1 calc R . . 
C18 C 0.5216(3) 0.7783(3) 0.26269(15) 0.0219(5) Uani 1 1 d . . . 
H22 H 0.5169 0.8823 0.2759 0.026 Uiso 1 1 calc R . . 
C19 C 0.3777(3) 0.6528(2) 0.23778(14) 0.0177(4) Uani 1 1 d . . . 
C20 C 0.5501(3) 0.3083(3) 0.20314(15) 0.0190(4) Uani 1 1 d . . . 
H23 H 0.4501 0.2278 0.2132 0.023 Uiso 1 1 calc R . . 
C21 C 0.2160(3) 0.6857(3) 0.22556(16) 0.0238(5) Uani 1 1 d . . . 
H24 H 0.1322 0.5923 0.1886 0.029 Uiso 1 1 calc R . . 
C22 C 0.6958(3) 0.2722(3) 0.26282(16) 0.0260(5) Uani 1 1 d . . . 
H25 H 0.6906 0.1617 0.2489 0.039 Uiso 1 1 calc R . . 
H26 H 0.6941 0.2879 0.3269 0.039 Uiso 1 1 calc R . . 
H27 H 0.7958 0.3442 0.2507 0.039 Uiso 1 1 calc R . . 
C23 C 0.5559(3) 0.2860(3) 0.10322(17) 0.0327(6) Uani 1 1 d . . . 
H28 H 0.6545 0.3615 0.0918 0.049 Uiso 1 1 calc R . . 
H29 H 0.4613 0.3052 0.0645 0.049 Uiso 1 1 calc R . . 
H30 H 0.5557 0.1769 0.0895 0.049 Uiso 1 1 calc R . . 
C24 C 0.1664(3) 0.7027(3) 0.31488(18) 0.0342(6) Uani 1 1 d . . . 
H31 H 0.1489 0.6012 0.3432 0.051 Uiso 1 1 calc R . . 
H32 H 0.0664 0.7321 0.3034 0.051 Uiso 1 1 calc R . . 
H33 H 0.2521 0.7857 0.3555 0.051 Uiso 1 1 calc R . . 
C25 C 0.2146(4) 0.8336(3) 0.1728(2) 0.0408(7) Uani 1 1 d . . . 
H34 H 0.2829 0.9296 0.2111 0.061 Uiso 1 1 calc R . . 
H35 H 0.1038 0.8389 0.1554 0.061 Uiso 1 1 calc R . . 
H36 H 0.2563 0.8267 0.1181 0.061 Uiso 1 1 calc R . . 
 
 
_geom_special_details 
; 
 All esds (except the esd in the dihedral angle between two l.s. planes) 
 are estimated using the full covariance matrix.  The cell esds are taken 
 into account individually in the estimation of esds in distances, angles 
 and torsion angles; correlations between esds in cell parameters are only 
 used when they are defined by crystal symmetry.  An approximate (isotropic) 
 treatment of cell esds is used for estimating esds involving l.s. planes. 
; 
 
loop_ 
 _geom_bond_atom_site_label_1 
 _geom_bond_atom_site_label_2 
 _geom_bond_distance 
 _geom_bond_site_symmetry_2 
 _geom_bond_publ_flag 
Rh1 O1 2.0396(14) . ? 
Rh1 N1 2.0985(17) . ? 
Rh1 C13 2.1157(19) . ? 
Rh1 C9 2.125(2) . ? 
Rh1 C6 2.140(2) . ? 
Rh1 C10 2.152(2) . ? 
N1 C1 1.325(3) . ? 
N1 C14 1.442(2) . ? 
C1 C2 1.419(3) . ? 
C1 C4 1.517(3) . ? 
C2 C3 1.372(3) . ? 
C2 H1 0.9500 . ? 
C3 O1 1.289(3) . ? 
C3 C5 1.510(3) . ? 
C4 H2 0.9800 . ? 
C4 H3 0.9800 . ? 
C4 H4 0.9800 . ? 
C5 H5 0.9800 . ? 
C5 H6 0.9800 . ? 
C5 H7 0.9800 . ? 
C6 C13 1.402(3) . ? 
C6 C7 1.520(3) . ? 
C6 H8 1.0000 . ? 
C7 C8 1.539(3) . ? 
C7 H9 0.9900 . ? 
C7 H10 0.9900 . ? 
C8 C9 1.511(3) . ? 
C8 H11 0.9900 . ? 
C8 H12 0.9900 . ? 
C9 C10 1.398(3) . ? 
C9 H13 1.0000 . ? 
C10 C11 1.519(3) . ? 
C10 H14 1.0000 . ? 
C11 C12 1.540(3) . ? 
C11 H15 0.9900 . ? 
C11 H16 0.9900 . ? 
C12 C13 1.513(3) . ? 
C12 H17 0.9900 . ? 
C12 H18 0.9900 . ? 
C13 H19 1.0000 . ? 
C14 C19 1.405(3) . ? 
C14 C15 1.411(3) . ? 
C15 C16 1.397(3) . ? 
C15 C20 1.523(3) . ? 
C16 C17 1.383(3) . ? 
C16 H20 0.9500 . ? 
C17 C18 1.385(3) . ? 
C17 H21 0.9500 . ? 
C18 C19 1.399(3) . ? 
C18 H22 0.9500 . ? 
C19 C21 1.523(3) . ? 
C20 C23 1.533(3) . ? 
C20 C22 1.535(3) . ? 
C20 H23 1.0000 . ? 
C21 C24 1.522(4) . ? 
C21 C25 1.537(3) . ? 
C21 H24 1.0000 . ? 
C22 H25 0.9800 . ? 
C22 H26 0.9800 . ? 
C22 H27 0.9800 . ? 
C23 H28 0.9800 . ? 
C23 H29 0.9800 . ? 
C23 H30 0.9800 . ? 
C24 H31 0.9800 . ? 
C24 H32 0.9800 . ? 
C24 H33 0.9800 . ? 
C25 H34 0.9800 . ? 
C25 H35 0.9800 . ? 
C25 H36 0.9800 . ? 
 
loop_ 
 _geom_angle_atom_site_label_1 
 _geom_angle_atom_site_label_2 
 _geom_angle_atom_site_label_3 
 _geom_angle 
 _geom_angle_site_symmetry_1 
 _geom_angle_site_symmetry_3 
 _geom_angle_publ_flag 
O1 Rh1 N1 90.43(6) . . ? 
O1 Rh1 C13 154.59(7) . . ? 
N1 Rh1 C13 96.95(7) . . ? 
O1 Rh1 C9 85.45(7) . . ? 
N1 Rh1 C9 153.89(8) . . ? 
C13 Rh1 C9 97.75(8) . . ? 
O1 Rh1 C6 163.91(7) . . ? 
N1 Rh1 C6 96.84(7) . . ? 
C13 Rh1 C6 38.46(8) . . ? 
C9 Rh1 C6 81.71(8) . . ? 
O1 Rh1 C10 86.52(7) . . ? 
N1 Rh1 C10 167.21(7) . . ? 
C13 Rh1 C10 80.92(8) . . ? 
C9 Rh1 C10 38.17(8) . . ? 
C6 Rh1 C10 89.32(8) . . ? 
C1 N1 C14 117.09(17) . . ? 
C1 N1 Rh1 124.10(14) . . ? 
C14 N1 Rh1 118.67(13) . . ? 
N1 C1 C2 124.41(19) . . ? 
N1 C1 C4 120.93(18) . . ? 
C2 C1 C4 114.64(18) . . ? 
C3 C2 C1 128.2(2) . . ? 
C3 C2 H1 115.9 . . ? 
C1 C2 H1 115.9 . . ? 
O1 C3 C2 126.13(19) . . ? 
O1 C3 C5 114.69(18) . . ? 
C2 C3 C5 119.18(19) . . ? 
C3 O1 Rh1 126.53(13) . . ? 
C1 C4 H2 109.5 . . ? 
C1 C4 H3 109.5 . . ? 
H2 C4 H3 109.5 . . ? 
C1 C4 H4 109.5 . . ? 
H2 C4 H4 109.5 . . ? 
H3 C4 H4 109.5 . . ? 
C3 C5 H5 109.5 . . ? 
C3 C5 H6 109.5 . . ? 
H5 C5 H6 109.5 . . ? 
C3 C5 H7 109.5 . . ? 
H5 C5 H7 109.5 . . ? 
H6 C5 H7 109.5 . . ? 
C13 C6 C7 124.74(19) . . ? 
C13 C6 Rh1 69.84(11) . . ? 
C7 C6 Rh1 113.12(13) . . ? 
C13 C6 H8 113.8 . . ? 
C7 C6 H8 113.8 . . ? 
Rh1 C6 H8 113.8 . . ? 
C6 C7 C8 112.19(17) . . ? 
C6 C7 H9 109.2 . . ? 
C8 C7 H9 109.2 . . ? 
C6 C7 H10 109.2 . . ? 
C8 C7 H10 109.2 . . ? 
H9 C7 H10 107.9 . . ? 
C9 C8 C7 112.65(18) . . ? 
C9 C8 H11 109.1 . . ? 
C7 C8 H11 109.1 . . ? 
C9 C8 H12 109.1 . . ? 
C7 C8 H12 109.1 . . ? 
H11 C8 H12 107.8 . . ? 
C10 C9 C8 125.51(19) . . ? 
C10 C9 Rh1 71.96(12) . . ? 
C8 C9 Rh1 110.45(13) . . ? 
C10 C9 H13 113.8 . . ? 
C8 C9 H13 113.8 . . ? 
Rh1 C9 H13 113.8 . . ? 
C9 C10 C11 123.76(19) . . ? 
C9 C10 Rh1 69.88(11) . . ? 
C11 C10 Rh1 113.78(13) . . ? 
C9 C10 H14 113.9 . . ? 
C11 C10 H14 113.9 . . ? 
Rh1 C10 H14 113.9 . . ? 
C10 C11 C12 110.81(17) . . ? 
C10 C11 H15 109.5 . . ? 
C12 C11 H15 109.5 . . ? 
C10 C11 H16 109.5 . . ? 
C12 C11 H16 109.5 . . ? 
H15 C11 H16 108.1 . . ? 
C13 C12 C11 112.05(17) . . ? 
C13 C12 H17 109.2 . . ? 
C11 C12 H17 109.2 . . ? 
C13 C12 H18 109.2 . . ? 
C11 C12 H18 109.2 . . ? 
H17 C12 H18 107.9 . . ? 
C6 C13 C12 126.20(19) . . ? 
C6 C13 Rh1 71.70(11) . . ? 
C12 C13 Rh1 111.13(13) . . ? 
C6 C13 H19 113.4 . . ? 
C12 C13 H19 113.4 . . ? 
Rh1 C13 H19 113.4 . . ? 
C19 C14 C15 121.53(18) . . ? 
C19 C14 N1 119.91(18) . . ? 
C15 C14 N1 118.55(18) . . ? 
C16 C15 C14 117.87(19) . . ? 
C16 C15 C20 120.74(19) . . ? 
C14 C15 C20 121.35(18) . . ? 
C17 C16 C15 121.6(2) . . ? 
C17 C16 H20 119.2 . . ? 
C15 C16 H20 119.2 . . ? 
C16 C17 C18 119.5(2) . . ? 
C16 C17 H21 120.2 . . ? 
C18 C17 H21 120.2 . . ? 
C17 C18 C19 121.6(2) . . ? 
C17 C18 H22 119.2 . . ? 
C19 C18 H22 119.2 . . ? 
C18 C19 C14 117.8(2) . . ? 
C18 C19 C21 119.96(19) . . ? 
C14 C19 C21 122.18(18) . . ? 
C15 C20 C23 111.36(18) . . ? 
C15 C20 C22 113.26(18) . . ? 
C23 C20 C22 108.88(19) . . ? 
C15 C20 H23 107.7 . . ? 
C23 C20 H23 107.7 . . ? 
C22 C20 H23 107.7 . . ? 
C24 C21 C19 113.01(19) . . ? 
C24 C21 C25 109.8(2) . . ? 
C19 C21 C25 111.7(2) . . ? 
C24 C21 H24 107.4 . . ? 
C19 C21 H24 107.4 . . ? 
C25 C21 H24 107.4 . . ? 
C20 C22 H25 109.5 . . ? 
C20 C22 H26 109.5 . . ? 
H25 C22 H26 109.5 . . ? 
C20 C22 H27 109.5 . . ? 
H25 C22 H27 109.5 . . ? 
H26 C22 H27 109.5 . . ? 
C20 C23 H28 109.5 . . ? 
C20 C23 H29 109.5 . . ? 
H28 C23 H29 109.5 . . ? 
C20 C23 H30 109.5 . . ? 
H28 C23 H30 109.5 . . ? 
H29 C23 H30 109.5 . . ? 
C21 C24 H31 109.5 . . ? 
C21 C24 H32 109.5 . . ? 
H31 C24 H32 109.5 . . ? 
C21 C24 H33 109.5 . . ? 
H31 C24 H33 109.5 . . ? 
H32 C24 H33 109.5 . . ? 
C21 C25 H34 109.5 . . ? 
C21 C25 H35 109.5 . . ? 
H34 C25 H35 109.5 . . ? 
C21 C25 H36 109.5 . . ? 
H34 C25 H36 109.5 . . ? 
H35 C25 H36 109.5 . . ? 
 
loop_ 
 _geom_torsion_atom_site_label_1 
 _geom_torsion_atom_site_label_2 
 _geom_torsion_atom_site_label_3 
 _geom_torsion_atom_site_label_4 
 _geom_torsion 
 _geom_torsion_site_symmetry_1 
 _geom_torsion_site_symmetry_2 
 _geom_torsion_site_symmetry_3 
 _geom_torsion_site_symmetry_4 
 _geom_torsion_publ_flag 
O1 Rh1 N1 C1 4.15(17) . . . . ? 
C13 Rh1 N1 C1 159.78(17) . . . . ? 
C9 Rh1 N1 C1 -76.4(2) . . . . ? 
C6 Rh1 N1 C1 -161.47(17) . . . . ? 
C10 Rh1 N1 C1 80.2(4) . . . . ? 
O1 Rh1 N1 C14 179.81(15) . . . . ? 
C13 Rh1 N1 C14 -24.56(15) . . . . ? 
C9 Rh1 N1 C14 99.3(2) . . . . ? 
C6 Rh1 N1 C14 14.19(16) . . . . ? 
C10 Rh1 N1 C14 -104.1(3) . . . . ? 
C14 N1 C1 C2 178.82(19) . . . . ? 
Rh1 N1 C1 C2 -5.5(3) . . . . ? 
C14 N1 C1 C4 -2.5(3) . . . . ? 
Rh1 N1 C1 C4 173.22(15) . . . . ? 
N1 C1 C2 C3 2.3(4) . . . . ? 
C4 C1 C2 C3 -176.5(2) . . . . ? 
C1 C2 C3 O1 2.0(4) . . . . ? 
C1 C2 C3 C5 -178.2(2) . . . . ? 
C2 C3 O1 Rh1 -2.1(3) . . . . ? 
C5 C3 O1 Rh1 178.10(13) . . . . ? 
N1 Rh1 O1 C3 -0.57(17) . . . . ? 
C13 Rh1 O1 C3 -107.9(2) . . . . ? 
C9 Rh1 O1 C3 153.62(17) . . . . ? 
C6 Rh1 O1 C3 116.6(3) . . . . ? 
C10 Rh1 O1 C3 -168.13(17) . . . . ? 
O1 Rh1 C6 C13 151.1(2) . . . . ? 
N1 Rh1 C6 C13 -92.57(12) . . . . ? 
C9 Rh1 C6 C13 113.73(13) . . . . ? 
C10 Rh1 C6 C13 76.18(13) . . . . ? 
O1 Rh1 C6 C7 30.9(3) . . . . ? 
N1 Rh1 C6 C7 147.21(15) . . . . ? 
C13 Rh1 C6 C7 -120.2(2) . . . . ? 
C9 Rh1 C6 C7 -6.49(15) . . . . ? 
C10 Rh1 C6 C7 -44.03(15) . . . . ? 
C13 C6 C7 C8 -91.4(2) . . . . ? 
Rh1 C6 C7 C8 -10.6(2) . . . . ? 
C6 C7 C8 C9 29.9(3) . . . . ? 
C7 C8 C9 C10 47.0(3) . . . . ? 
C7 C8 C9 Rh1 -34.9(2) . . . . ? 
O1 Rh1 C9 C10 90.16(12) . . . . ? 
N1 Rh1 C9 C10 171.81(14) . . . . ? 
C13 Rh1 C9 C10 -64.48(13) . . . . ? 
C6 Rh1 C9 C10 -99.56(13) . . . . ? 
O1 Rh1 C9 C8 -147.80(15) . . . . ? 
N1 Rh1 C9 C8 -66.2(2) . . . . ? 
C13 Rh1 C9 C8 57.56(16) . . . . ? 
C6 Rh1 C9 C8 22.48(15) . . . . ? 
C10 Rh1 C9 C8 122.0(2) . . . . ? 
C8 C9 C10 C11 3.1(3) . . . . ? 
Rh1 C9 C10 C11 105.77(19) . . . . ? 
C8 C9 C10 Rh1 -102.6(2) . . . . ? 
O1 Rh1 C10 C9 -87.06(12) . . . . ? 
N1 Rh1 C10 C9 -163.5(3) . . . . ? 
C13 Rh1 C10 C9 115.10(13) . . . . ? 
C6 Rh1 C10 C9 77.39(13) . . . . ? 
O1 Rh1 C10 C11 153.91(16) . . . . ? 
N1 Rh1 C10 C11 77.4(4) . . . . ? 
C13 Rh1 C10 C11 -3.93(15) . . . . ? 
C9 Rh1 C10 C11 -119.0(2) . . . . ? 
C6 Rh1 C10 C11 -41.64(16) . . . . ? 
C9 C10 C11 C12 -95.6(2) . . . . ? 
Rh1 C10 C11 C12 -14.7(2) . . . . ? 
C10 C11 C12 C13 33.5(3) . . . . ? 
C7 C6 C13 C12 1.5(3) . . . . ? 
Rh1 C6 C13 C12 -103.20(19) . . . . ? 
C7 C6 C13 Rh1 104.74(19) . . . . ? 
C11 C12 C13 C6 45.3(3) . . . . ? 
C11 C12 C13 Rh1 -37.0(2) . . . . ? 
O1 Rh1 C13 C6 -161.81(14) . . . . ? 
N1 Rh1 C13 C6 92.26(12) . . . . ? 
C9 Rh1 C13 C6 -66.10(13) . . . . ? 
C10 Rh1 C13 C6 -100.48(13) . . . . ? 
O1 Rh1 C13 C12 -39.2(3) . . . . ? 
N1 Rh1 C13 C12 -145.11(15) . . . . ? 
C9 Rh1 C13 C12 56.53(16) . . . . ? 
C6 Rh1 C13 C12 122.6(2) . . . . ? 
C10 Rh1 C13 C12 22.15(15) . . . . ? 
C1 N1 C14 C19 84.2(2) . . . . ? 
Rh1 N1 C14 C19 -91.75(19) . . . . ? 
C1 N1 C14 C15 -97.1(2) . . . . ? 
Rh1 N1 C14 C15 87.0(2) . . . . ? 
C19 C14 C15 C16 1.3(3) . . . . ? 
N1 C14 C15 C16 -177.37(18) . . . . ? 
C19 C14 C15 C20 -176.41(19) . . . . ? 
N1 C14 C15 C20 4.9(3) . . . . ? 
C14 C15 C16 C17 1.0(3) . . . . ? 
C20 C15 C16 C17 178.8(2) . . . . ? 
C15 C16 C17 C18 -1.8(3) . . . . ? 
C16 C17 C18 C19 0.2(3) . . . . ? 
C17 C18 C19 C14 2.0(3) . . . . ? 
C17 C18 C19 C21 -175.7(2) . . . . ? 
C15 C14 C19 C18 -2.8(3) . . . . ? 
N1 C14 C19 C18 175.89(18) . . . . ? 
C15 C14 C19 C21 174.84(19) . . . . ? 
N1 C14 C19 C21 -6.5(3) . . . . ? 
C16 C15 C20 C23 -84.5(2) . . . . ? 
C14 C15 C20 C23 93.1(2) . . . . ? 
C16 C15 C20 C22 38.6(3) . . . . ? 
C14 C15 C20 C22 -143.8(2) . . . . ? 
C18 C19 C21 C24 -80.7(3) . . . . ? 
C14 C19 C21 C24 101.8(2) . . . . ? 
C18 C19 C21 C25 43.7(3) . . . . ? 
C14 C19 C21 C25 -133.8(2) . . . . ? 
 
_diffrn_measured_fraction_theta_max    0.988 
_diffrn_reflns_theta_full              25.50 
_diffrn_measured_fraction_theta_full   0.988 
_refine_diff_density_max    0.379 
_refine_diff_density_min   -0.653 
_refine_diff_density_rms    0.109 
