data_publication_text
_publ_requested_journal          'Journal of the American Chemical Society'
_publ_contact_author_name        'Wenyuan Wang'
_publ_contact_author_address     
;College of Chemistry and Materials
Science, Northwest University, Xi'An 710127, People's Republic of China
;
_publ_contact_author_email       wangwy@nwu.edu.cn

_publ_contact_author_phone       0086-29-81535037
_publ_contact_author_fax         0086-29-81535037
_publ_section_title              
;
Syntheses and structures of a boron monohydride and an anionic oxoborane supported by a beta-diketiminate ligand
;
loop_
_publ_author_name
_publ_author_address
'Yan Guo'
;College of Chemistry and Materials
Science, Northwest University, Xi'An 710127, People's Republic of China
;
'Sanping Chen'
;College of Chemistry and Materials
Science, Northwest University, Xi'An 710127, People's Republic of China
'Jiaxiu Yu'
;College of Chemistry and Materials
Science, Northwest University, Xi'An 710127, People's Republic of China
;
'Jingjing Liu'
;College of Chemistry and Materials
Science, Northwest University, Xi'An 710127, People's Republic of China
;
'Shenglai Yao'
;Technische Universitaet Berlin,
Institute of Chemistry
Strasse des 17. Juni 136, D-10623 Berlin, Germany
;
'Yaoyu Wang'
;College of Chemistry and Materials
Science, Northwest University, Xi'An 710127, People's Republic of China
;
;
'Weiqun Shi'
;Laboratory of Nuclear Energy Chemistry
Institute of High Energy Physics, Chinese Academy of Sciences, Beijing 100049, China
;
'Kongqiu Hu'
;Laboratory of Nuclear Energy Chemistry
Institute of High Energy Physics, Chinese Academy of Sciences, Beijing 100049, China
;
'Anyang Li'
;College of Chemistry and Materials
Science, Northwest University, Xi'An 710127, People's Republic of China
;
'Driess, Matthias'
;Technische Universitaeat Berlin,
Institute of Chemistry
Strasse des 17. Juni 136, D-10623 Berlin, Germany
;
'Wenyuan Wang'
;College of Chemistry and Materials
Science, Northwest University, Xi'An 710127, People's Republic of China
;

data_3
_audit_creation_date               2018-12-08
_audit_creation_method
;
Olex2 1.2
(compiled 2018.05.29 svn.r3508 for OlexSys, GUI svn.r5506)
;
_shelx_SHELXL_version_number       '2018/3'
_chemical_name_common              ?
_chemical_name_systematic          ?
_chemical_formula_moiety           'C18 H42 Cl Ge N Si2'
_chemical_formula_sum              'C18 H42 Cl Ge N Si2'
_chemical_formula_weight           436.74
_chemical_melting_point            ?
loop_
  _atom_type_symbol
  _atom_type_description
  _atom_type_scat_dispersion_real
  _atom_type_scat_dispersion_imag
  _atom_type_scat_source
 'C' 'C' 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
 'H' 'H' 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
 'Cl' 'Cl' 0.1484 0.1585 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
 'Ge' 'Ge' 0.1547 1.8001 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
 'N' 'N' 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
 'Si' 'Si' 0.0817 0.0704 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_shelx_space_group_comment
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
_space_group_crystal_system        'triclinic'
_space_group_IT_number             2
_space_group_name_H-M_alt          'P -1'
_space_group_name_Hall             '-P 1'
loop_
  _space_group_symop_operation_xyz
 'x, y, z'
 '-x, -y, -z'

_cell_length_a                     8.8067(15)
_cell_length_b                     11.4818(19)
_cell_length_c                     11.740(2)
_cell_angle_alpha                  78.044(5)
_cell_angle_beta                   88.887(5)
_cell_angle_gamma                  89.957(5)
_cell_volume                       1161.2(3)
_cell_formula_units_Z              2
_cell_measurement_reflns_used      9964
_cell_measurement_temperature      153(2)
_cell_measurement_theta_max        26.458
_cell_measurement_theta_min        3.254
_shelx_estimated_absorpt_T_max     0.837
_shelx_estimated_absorpt_T_min     0.748
_exptl_absorpt_coefficient_mu      1.538
_exptl_absorpt_correction_T_max    0.7454
_exptl_absorpt_correction_T_min    0.4894
_exptl_absorpt_correction_type     multi-scan
_exptl_absorpt_process_details    
 'SADABS-2014/5 (Bruker,2014/5) was used for absorption correction. wR2(int) was 0.1209 before and 0.0378 after correction. The Ratio of minimum to maximum transmission is 0.6566. The λ/2 correction factor is Not present.'
_exptl_absorpt_special_details     ?
_exptl_crystal_colour              yellow
_exptl_crystal_colour_primary      yellow
_exptl_crystal_density_diffrn      1.249
_exptl_crystal_density_meas        ?
_exptl_crystal_density_method      ?
_exptl_crystal_description         block
_exptl_crystal_F_000               468
_exptl_crystal_size_max            0.2
_exptl_crystal_size_mid            0.14
_exptl_crystal_size_min            0.12
_exptl_transmission_factor_max     ?
_exptl_transmission_factor_min     ?
_diffrn_reflns_av_R_equivalents    0.0238
_diffrn_reflns_av_unetI/netI       0.0264
_diffrn_reflns_Laue_measured_fraction_full  0.982
_diffrn_reflns_Laue_measured_fraction_max  0.980
_diffrn_reflns_limit_h_max         10
_diffrn_reflns_limit_h_min         -10
_diffrn_reflns_limit_k_max         14
_diffrn_reflns_limit_k_min         -14
_diffrn_reflns_limit_l_max         14
_diffrn_reflns_limit_l_min         -14
_diffrn_reflns_number              13987
_diffrn_reflns_point_group_measured_fraction_full  0.982
_diffrn_reflns_point_group_measured_fraction_max  0.980
_diffrn_reflns_theta_full          25.242
_diffrn_reflns_theta_max           26.458
_diffrn_reflns_theta_min           2.313
_diffrn_ambient_temperature        153.01
_diffrn_detector_area_resol_mean   ?
_diffrn_measured_fraction_theta_full  0.982
_diffrn_measured_fraction_theta_max  0.980
_diffrn_measurement_device_type    'CCD area detector'
_diffrn_measurement_method         'phi and omega scans'
_diffrn_radiation_monochromator    'graphite'
_diffrn_radiation_type             MoK\a
_diffrn_radiation_wavelength       0.71073
_diffrn_source                     ?
_reflns_Friedel_coverage           0.000
_reflns_Friedel_fraction_full      .
_reflns_Friedel_fraction_max       .
_reflns_number_gt                  4480
_reflns_number_total               4694
_reflns_special_details
;
 Reflections were merged by SHELXL according to the crystal
 class for the calculation of statistics and refinement.
 
 _reflns_Friedel_fraction is defined as the number of unique
 Friedel pairs measured divided by the number that would be
 possible theoretically, ignoring centric projections and
 systematic absences.
;
_reflns_threshold_expression       'I > 2σ(I)'
_computing_cell_refinement         'SAINT v8.37A (Bruker, 2015)'
_computing_data_collection         ?
_computing_data_reduction          'SAINT v8.37A (Bruker, 2015)'
_computing_molecular_graphics      'Olex2 (Dolomanov et al., 2009)'
_computing_publication_material    'Olex2 (Dolomanov et al., 2009)'
_computing_structure_refinement    'ShelXL (Sheldrick, 2015)'
_computing_structure_solution      'ShelXT (Sheldrick, 2015)'
_refine_diff_density_max           0.345
_refine_diff_density_min           -0.360
_refine_diff_density_rms           0.052
_refine_ls_extinction_coef         .
_refine_ls_extinction_method       none
_refine_ls_goodness_of_fit_ref     1.076
_refine_ls_hydrogen_treatment      constr
_refine_ls_matrix_type             full
_refine_ls_number_parameters       220
_refine_ls_number_reflns           4694
_refine_ls_number_restraints       0
_refine_ls_R_factor_all            0.0244
_refine_ls_R_factor_gt             0.0231
_refine_ls_restrained_S_all        1.076
_refine_ls_shift/su_max            0.002
_refine_ls_shift/su_mean           0.000
_refine_ls_structure_factor_coef   Fsqd
_refine_ls_weighting_details      
 'w=1/[σ²(Fo²)+(0.0319P)²+0.3691P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme        calc
_refine_ls_wR_factor_gt            0.0623
_refine_ls_wR_factor_ref           0.0631
_refine_special_details            ?
_olex2_refinement_description
;
1. Fixed Uiso
 At 1.2 times of:
  All C(H) groups
 At 1.5 times of:
  All C(H,H,H) groups
2.a Ternary CH refined with riding coordinates:
 C1(H1), C10(H10), C13(H13), C16(H16), C7(H7), C4(H4)
2.b Idealised Me refined as rotating group:
 C11(H11A,H11B,H11C), C2(H2A,H2B,H2C), C3(H3A,H3B,H3C), C5(H5A,H5B,H5C),
 C15(H15A,H15B,H15C), C14(H14A,H14B,H14C), C12(H12A,H12B,H12C), C8(H8A,H8B,H8C),
  C17(H17A,H17B,H17C), C6(H6A,H6B,H6C), C18(H18A,H18B,H18C), C9(H9A,H9B,H9C)
;
_atom_sites_solution_hydrogens     geom
_atom_sites_solution_primary       dual
_atom_sites_solution_secondary     ?
loop_
  _atom_site_label
  _atom_site_type_symbol
  _atom_site_fract_x
  _atom_site_fract_y
  _atom_site_fract_z
  _atom_site_U_iso_or_equiv
  _atom_site_adp_type
  _atom_site_occupancy
  _atom_site_site_symmetry_order
  _atom_site_calc_flag
  _atom_site_refinement_flags_posn
  _atom_site_refinement_flags_adp
  _atom_site_refinement_flags_occupancy
  _atom_site_disorder_assembly
  _atom_site_disorder_group
 Ge1 Ge 0.20231(2) 0.93596(2) 0.61443(2) 0.02289(6) Uani 1 1 d . . . . .
 Si2 Si 0.29178(4) 0.68178(3) 0.63976(3) 0.01291(8) Uani 1 1 d . . . . .
 Si1 Si 0.27178(4) 0.80158(3) 0.86622(3) 0.01432(8) Uani 1 1 d . . . . .
 Cl1 Cl -0.03622(5) 0.97784(4) 0.67019(4) 0.04073(11) Uani 1 1 d . . . . .
 N1 N 0.24641(12) 0.79266(9) 0.71914(9) 0.0147(2) Uani 1 1 d . . . . .
 C1 C 0.36976(15) 0.66380(12) 0.95339(11) 0.0187(3) Uani 1 1 d . . . . .
 H1 H 0.433305 0.630067 0.896592 0.022 Uiso 1 1 calc R . . . .
 C10 C 0.49913(15) 0.67937(13) 0.59274(12) 0.0200(3) Uani 1 1 d . . . . .
 H10 H 0.505228 0.620334 0.541040 0.024 Uiso 1 1 calc R . . . .
 C13 C 0.24216(15) 0.52720(11) 0.72399(11) 0.0175(3) Uani 1 1 d . . . . .
 H13 H 0.296357 0.517477 0.799423 0.021 Uiso 1 1 calc R . . . .
 C16 C 0.18210(16) 0.72576(13) 0.49818(12) 0.0214(3) Uani 1 1 d . . . . .
 H16 H 0.203394 0.812426 0.468784 0.026 Uiso 1 1 calc R . . . .
 C11 C 0.61198(16) 0.63565(15) 0.69055(13) 0.0272(3) Uani 1 1 d . . . . .
 H11A H 0.615704 0.692800 0.741939 0.041 Uiso 1 1 calc GR . . . .
 H11B H 0.713175 0.628435 0.656532 0.041 Uiso 1 1 calc GR . . . .
 H11C H 0.579003 0.557843 0.735548 0.041 Uiso 1 1 calc GR . . . .
 C2 C 0.26153(17) 0.56382(13) 1.01395(12) 0.0243(3) Uani 1 1 d . . . . .
 H2A H 0.209360 0.588185 1.079680 0.036 Uiso 1 1 calc GR . . . .
 H2B H 0.319892 0.491270 1.042393 0.036 Uiso 1 1 calc GR . . . .
 H2C H 0.186430 0.548353 0.958327 0.036 Uiso 1 1 calc GR . . . .
 C7 C 0.39829(17) 0.93539(13) 0.86960(13) 0.0245(3) Uani 1 1 d . . . . .
 H7 H 0.423914 0.930054 0.953125 0.029 Uiso 1 1 calc R . . . .
 C4 C 0.08550(16) 0.83238(13) 0.93886(12) 0.0215(3) Uani 1 1 d . . . . .
 H4 H 0.053972 0.913710 0.897778 0.026 Uiso 1 1 calc R . . . .
 C3 C 0.47863(18) 0.69170(15) 1.04580(13) 0.0299(3) Uani 1 1 d . . . . .
 H3A H 0.558818 0.745845 1.007423 0.045 Uiso 1 1 calc GR . . . .
 H3B H 0.524325 0.617630 1.087608 0.045 Uiso 1 1 calc GR . . . .
 H3C H 0.421851 0.729348 1.101024 0.045 Uiso 1 1 calc GR . . . .
 C5 C -0.04818(17) 0.75049(15) 0.92904(14) 0.0285(3) Uani 1 1 d . . . . .
 H5A H -0.065871 0.751048 0.846774 0.043 Uiso 1 1 calc GR . . . .
 H5B H -0.139384 0.778640 0.964050 0.043 Uiso 1 1 calc GR . . . .
 H5C H -0.025020 0.669258 0.969997 0.043 Uiso 1 1 calc GR . . . .
 C15 C 0.07287(17) 0.50595(14) 0.75655(14) 0.0284(3) Uani 1 1 d . . . . .
 H15A H 0.032612 0.573716 0.786298 0.043 Uiso 1 1 calc GR . . . .
 H15B H 0.061368 0.433136 0.816672 0.043 Uiso 1 1 calc GR . . . .
 H15C H 0.016822 0.497480 0.687406 0.043 Uiso 1 1 calc GR . . . .
 C14 C 0.3016(2) 0.42773(13) 0.66571(14) 0.0304(3) Uani 1 1 d . . . . .
 H14A H 0.252002 0.432988 0.590799 0.046 Uiso 1 1 calc GR . . . .
 H14B H 0.278988 0.350207 0.716205 0.046 Uiso 1 1 calc GR . . . .
 H14C H 0.411618 0.436484 0.652894 0.046 Uiso 1 1 calc GR . . . .
 C12 C 0.55391(18) 0.79774(15) 0.51733(14) 0.0319(3) Uani 1 1 d . . . . .
 H12A H 0.485580 0.821720 0.451768 0.048 Uiso 1 1 calc GR . . . .
 H12B H 0.656972 0.788171 0.487691 0.048 Uiso 1 1 calc GR . . . .
 H12C H 0.554204 0.859024 0.564330 0.048 Uiso 1 1 calc GR . . . .
 C8 C 0.3212(2) 1.05637(15) 0.82955(18) 0.0398(4) Uani 1 1 d . . . . .
 H8A H 0.290023 1.064897 0.748570 0.060 Uiso 1 1 calc GR . . . .
 H8B H 0.392619 1.120209 0.835302 0.060 Uiso 1 1 calc GR . . . .
 H8C H 0.231656 1.061308 0.879196 0.060 Uiso 1 1 calc GR . . . .
 C17 C 0.00860(18) 0.71500(16) 0.51223(15) 0.0325(4) Uani 1 1 d . . . . .
 H17A H -0.020905 0.630870 0.526317 0.049 Uiso 1 1 calc GR . . . .
 H17B H -0.038928 0.758087 0.441040 0.049 Uiso 1 1 calc GR . . . .
 H17C H -0.025076 0.749171 0.578288 0.049 Uiso 1 1 calc GR . . . .
 C6 C 0.10866(19) 0.84107(17) 1.06651(14) 0.0341(4) Uani 1 1 d . . . . .
 H6A H 0.143207 0.764108 1.110955 0.051 Uiso 1 1 calc GR . . . .
 H6B H 0.012419 0.862416 1.100067 0.051 Uiso 1 1 calc GR . . . .
 H6C H 0.185107 0.902223 1.069749 0.051 Uiso 1 1 calc GR . . . .
 C18 C 0.2355(2) 0.66399(19) 0.40024(14) 0.0413(4) Uani 1 1 d . . . . .
 H18A H 0.343726 0.680417 0.383425 0.062 Uiso 1 1 calc GR . . . .
 H18B H 0.177260 0.694266 0.330061 0.062 Uiso 1 1 calc GR . . . .
 H18C H 0.219591 0.577899 0.424807 0.062 Uiso 1 1 calc GR . . . .
 C9 C 0.55053(19) 0.93611(16) 0.80339(17) 0.0363(4) Uani 1 1 d . . . . .
 H9A H 0.602368 0.860097 0.830209 0.054 Uiso 1 1 calc GR . . . .
 H9B H 0.614202 1.001245 0.817955 0.054 Uiso 1 1 calc GR . . . .
 H9C H 0.532148 0.947439 0.719759 0.054 Uiso 1 1 calc GR . . . .


_geom_special_details
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;
loop_
  _geom_bond_atom_site_label_1
  _geom_bond_atom_site_label_2
  _geom_bond_distance
  _geom_bond_site_symmetry_2
  _geom_bond_publ_flag
 Ge1 Cl1 2.2689(6) . ?
 Ge1 N1 1.8838(11) . ?
 Si2 N1 1.7678(11) . ?
 Si2 C10 1.8993(14) . ?
 Si2 C13 1.8910(14) . ?
 Si2 C16 1.9144(14) . ?
 Si1 N1 1.7693(11) . ?
 Si1 C1 1.9121(14) . ?
 Si1 C7 1.9060(15) . ?
 Si1 C4 1.9009(14) . ?
 C1 C2 1.539(2) . ?
 C1 C3 1.5440(19) . ?
 C10 C11 1.537(2) . ?
 C10 C12 1.533(2) . ?
 C13 C15 1.5389(19) . ?
 C13 C14 1.5347(19) . ?
 C16 C17 1.536(2) . ?
 C16 C18 1.537(2) . ?
 C7 C8 1.534(2) . ?
 C7 C9 1.536(2) . ?
 C4 C5 1.528(2) . ?
 C4 C6 1.540(2) . ?

loop_
  _geom_angle_atom_site_label_1
  _geom_angle_atom_site_label_2
  _geom_angle_atom_site_label_3
  _geom_angle
  _geom_angle_site_symmetry_1
  _geom_angle_site_symmetry_3
  _geom_angle_publ_flag
 N1 Ge1 Cl1 102.78(4) . . ?
 N1 Si2 C10 114.48(6) . . ?
 N1 Si2 C13 112.16(6) . . ?
 N1 Si2 C16 104.84(6) . . ?
 C10 Si2 C16 105.25(6) . . ?
 C13 Si2 C10 107.17(6) . . ?
 C13 Si2 C16 112.86(6) . . ?
 N1 Si1 C1 112.36(6) . . ?
 N1 Si1 C7 108.38(6) . . ?
 N1 Si1 C4 111.55(6) . . ?
 C7 Si1 C1 107.46(7) . . ?
 C4 Si1 C1 111.34(6) . . ?
 C4 Si1 C7 105.38(7) . . ?
 Si2 N1 Ge1 109.28(6) . . ?
 Si2 N1 Si1 132.58(6) . . ?
 Si1 N1 Ge1 116.68(6) . . ?
 C2 C1 Si1 114.88(9) . . ?
 C2 C1 C3 107.86(12) . . ?
 C3 C1 Si1 113.55(10) . . ?
 C11 C10 Si2 115.89(9) . . ?
 C12 C10 Si2 113.20(10) . . ?
 C12 C10 C11 110.10(12) . . ?
 C15 C13 Si2 115.27(10) . . ?
 C14 C13 Si2 113.45(10) . . ?
 C14 C13 C15 109.64(12) . . ?
 C17 C16 Si2 115.05(10) . . ?
 C17 C16 C18 109.27(13) . . ?
 C18 C16 Si2 114.70(11) . . ?
 C8 C7 Si1 114.46(11) . . ?
 C8 C7 C9 108.79(14) . . ?
 C9 C7 Si1 114.50(10) . . ?
 C5 C4 Si1 116.83(10) . . ?
 C5 C4 C6 110.81(13) . . ?
 C6 C4 Si1 111.27(10) . . ?

_olex2_submission_special_instructions  'No special instructions were received'


data_1
_audit_creation_date               2018-04-05
_audit_creation_method
;
Olex2 1.2-alpha
(compiled 2018.04.03 svn.r3497 for OlexSys, GUI svn.r5484)
;
_shelx_SHELXL_version_number       '2014/7'
_chemical_name_common              ?
_chemical_name_systematic          ?
_chemical_formula_moiety           'C72 H168 Ge5 N4 Si8, 0.5(C6 H14)'
_chemical_formula_sum              'C75 H175 Ge5 N4 Si8'
_chemical_formula_weight           1720.85
_chemical_melting_point            ?
loop_
  _atom_type_symbol
  _atom_type_description
  _atom_type_scat_dispersion_real
  _atom_type_scat_dispersion_imag
  _atom_type_scat_source
 'C' 'C' 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
 'H' 'H' 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
 'Ge' 'Ge' 0.1547 1.8001 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
 'N' 'N' 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
 'Si' 'Si' 0.0817 0.0704 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_shelx_space_group_comment
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
_space_group_crystal_system        'triclinic'
_space_group_IT_number             2
_space_group_name_H-M_alt          'P -1'
_space_group_name_Hall             '-P 1'
loop_
  _space_group_symop_operation_xyz
 'x, y, z'
 '-x, -y, -z'

_cell_length_a                     14.1368(10)
_cell_length_b                     17.2672(14)
_cell_length_c                     22.5417(17)
_cell_angle_alpha                  74.282(2)
_cell_angle_beta                   81.579(2)
_cell_angle_gamma                  89.928(3)
_cell_volume                       5235.4(7)
_cell_formula_units_Z              2
_cell_measurement_reflns_used      9684
_cell_measurement_temperature      170
_cell_measurement_theta_max        27.523
_cell_measurement_theta_min        2.904
_shelx_estimated_absorpt_T_max     ?
_shelx_estimated_absorpt_T_min     ?
_exptl_absorpt_coefficient_mu      1.544
_exptl_absorpt_correction_T_max    0.7456
_exptl_absorpt_correction_T_min    0.6554
_exptl_absorpt_correction_type     multi-scan
_exptl_absorpt_process_details    
 'SADABS-2016/2 (Bruker,2016/2) was used for absorption correction. wR2(int) was 0.0828 before and 0.0563 after correction. The Ratio of minimum to maximum transmission is 0.8790. The λ/2 correction factor is Not present.'
_exptl_absorpt_special_details     ?
_exptl_crystal_colour              red
_exptl_crystal_density_diffrn      1.092
_exptl_crystal_density_meas        ?
_exptl_crystal_density_method      ?
_exptl_crystal_description         block
_exptl_crystal_F_000               1850
_exptl_crystal_size_max            0.30
_exptl_crystal_size_mid            0.15
_exptl_crystal_size_min            0.10
_exptl_transmission_factor_max     0.7456
_exptl_transmission_factor_min     0.6554
_diffrn_reflns_av_R_equivalents    0.0576
_diffrn_reflns_av_unetI/netI       0.0507
_diffrn_reflns_Laue_measured_fraction_full  0.996
_diffrn_reflns_Laue_measured_fraction_max  0.987
_diffrn_reflns_limit_h_max         18
_diffrn_reflns_limit_h_min         -18
_diffrn_reflns_limit_k_max         22
_diffrn_reflns_limit_k_min         -22
_diffrn_reflns_limit_l_max         29
_diffrn_reflns_limit_l_min         -29
_diffrn_reflns_number              128745
_diffrn_reflns_point_group_measured_fraction_full  0.996
_diffrn_reflns_point_group_measured_fraction_max  0.987
_diffrn_reflns_theta_full          25.242
_diffrn_reflns_theta_max           27.735
_diffrn_reflns_theta_min           2.916
_diffrn_ambient_temperature        170.0
_diffrn_detector_area_resol_mean   ?
_diffrn_measured_fraction_theta_full  0.996
_diffrn_measured_fraction_theta_max  0.987
_diffrn_measurement_device_type    'Bruker D8 VENTURE'
_diffrn_measurement_method         'φ and ω scans'
_diffrn_radiation_type             MoK\a
_diffrn_radiation_wavelength       0.71073
_diffrn_source                     'fine-focus sealed tube'
_diffrn_special_details            ?
_diffrn_standards_number           0
_reflns_Friedel_coverage           0.000
_reflns_Friedel_fraction_full      .
_reflns_Friedel_fraction_max       .
_reflns_number_gt                  18358
_reflns_number_total               24308
_reflns_special_details
;
 Reflections were merged by SHELXL according to the crystal
 class for the calculation of statistics and refinement.
 
 Structure factors included contributions from the .fab file.
 
 _reflns_Friedel_fraction is defined as the number of unique
 Friedel pairs measured divided by the number that would be
 possible theoretically, ignoring centric projections and
 systematic absences.
;
_reflns_threshold_expression       'I > 2σ(I)'
_computing_cell_refinement         'SAINT V8.38A (?, 2016)'
_computing_data_collection         ?
_computing_data_reduction          'SAINT V8.38A (?, 2016)'
_computing_molecular_graphics      'Olex2 (Dolomanov et al., 2009)'
_computing_publication_material    'Olex2 (Dolomanov et al., 2009)'
_computing_structure_refinement    'ShelXL (Sheldrick, 2015)'
_computing_structure_solution      ?
_refine_diff_density_max           1.789
_refine_diff_density_min           -1.321
_refine_diff_density_rms           0.122
_refine_ls_extinction_coef         .
_refine_ls_extinction_method       none
_refine_ls_goodness_of_fit_ref     1.093
_refine_ls_hydrogen_treatment      constr
_refine_ls_matrix_type             full
_refine_ls_number_parameters       952
_refine_ls_number_reflns           24308
_refine_ls_number_restraints       29
_refine_ls_R_factor_all            0.0951
_refine_ls_R_factor_gt             0.0690
_refine_ls_restrained_S_all        1.093
_refine_ls_shift/su_max            0.007
_refine_ls_shift/su_mean           0.000
_refine_ls_structure_factor_coef   Fsqd
_refine_ls_weighting_details      
 'w=1/[σ²(Fo²)+(0.0252P)²+40.7258P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme        calc
_refine_ls_wR_factor_gt            0.1580
_refine_ls_wR_factor_ref           0.1695
_refine_special_details            ?
_olex2_refinement_description
;
1. Fixed Uiso
 At 1.2 times of:
  All C(H) groups, All C(H,H) groups
 At 1.5 times of:
  All C(H,H,H) groups
2. Restrained distances
 C74-C75 = C76-C77
 1.5 with sigma of 0.02
3. Rigid body (RIGU) restrains
 C73, C74, C75, C76, C77, C78
 with sigma for 1-2 distances of 0.004 and sigma for 1-3 distances of 0.004
4. Others
 Sof(Ge1)=Sof(Ge2)=Sof(Ge3)=Sof(Ge4)=Sof(Ge5)=1-FVAR(1)
 Sof(Ge6)=Sof(Ge7)=Sof(Ge8)=Sof(Ge9)=Sof(Ge10)=FVAR(1)
 Fixed Sof: C73(0.5) H73A(0.5) H73B(0.5) H73C(0.5) C74(0.5) H74A(0.5)
 H74B(0.5) C75(0.5) H75A(0.5) H75B(0.5) C76(0.5) H76A(0.5) H76B(0.5) C77(0.5)
 H77A(0.5) H77B(0.5) C78(0.5) H78A(0.5) H78B(0.5) H78C(0.5)
5.a Ternary CH refined with riding coordinates:
 C2(H2), C5(H5), C8(H8), C11(H11), C14(H14), C17(H17), C20(H20), C23(H23),
 C26(H26), C29(H29), C32(H32), C35(H35), C38(H38), C41(H41), C44(H44), C47(H47),
  C50(H50), C53(H53), C56(H56), C59(H59), C62(H62), C65(H65), C68(H68), C71(H71)
5.b Secondary CH2 refined with riding coordinates:
 C74(H74A,H74B), C75(H75A,H75B), C76(H76A,H76B), C77(H77A,H77B)
5.c Idealised Me refined as rotating group:
 C1(H1A,H1B,H1C), C3(H3A,H3B,H3C), C4(H4A,H4B,H4C), C6(H6A,H6B,H6C), C7(H7A,
 H7B,H7C), C9(H9A,H9B,H9C), C10(H10A,H10B,H10C), C12(H12A,H12B,H12C), C13(H13A,
 H13B,H13C), C15(H15A,H15B,H15C), C16(H16A,H16B,H16C), C18(H18A,H18B,H18C),
 C19(H19A,H19B,H19C), C21(H21A,H21B,H21C), C22(H22A,H22B,H22C), C24(H24A,H24B,
 H24C), C25(H25A,H25B,H25C), C27(H27A,H27B,H27C), C28(H28A,H28B,H28C), C30(H30A,
 H30B,H30C), C31(H31A,H31B,H31C), C33(H33A,H33B,H33C), C34(H34A,H34B,H34C),
 C36(H36A,H36B,H36C), C37(H37A,H37B,H37C), C39(H39A,H39B,H39C), C40(H40A,H40B,
 H40C), C42(H42A,H42B,H42C), C43(H43A,H43B,H43C), C45(H45A,H45B,H45C), C46(H46A,
 H46B,H46C), C48(H48A,H48B,H48C), C49(H49A,H49B,H49C), C51(H51A,H51B,H51C),
 C52(H52A,H52B,H52C), C54(H54A,H54B,H54C), C55(H55A,H55B,H55C), C57(H57A,H57B,
 H57C), C58(H58A,H58B,H58C), C60(H60A,H60B,H60C), C61(H61A,H61B,H61C), C63(H63A,
 H63B,H63C), C64(H64A,H64B,H64C), C66(H66A,H66B,H66C), C67(H67A,H67B,H67C),
 C69(H69A,H69B,H69C), C70(H70A,H70B,H70C), C72(H72A,H72B,H72C), C73(H73A,H73B,
 H73C), C78(H78A,H78B,H78C)
;
_atom_sites_solution_hydrogens     geom
_atom_sites_solution_primary       ?
_atom_sites_solution_secondary     ?
loop_
  _atom_site_label
  _atom_site_type_symbol
  _atom_site_fract_x
  _atom_site_fract_y
  _atom_site_fract_z
  _atom_site_U_iso_or_equiv
  _atom_site_adp_type
  _atom_site_occupancy
  _atom_site_site_symmetry_order
  _atom_site_calc_flag
  _atom_site_refinement_flags_posn
  _atom_site_refinement_flags_adp
  _atom_site_refinement_flags_occupancy
  _atom_site_disorder_assembly
  _atom_site_disorder_group
 Ge1 Ge 0.35322(17) 0.56120(16) 0.77280(13) 0.0167(4) Uani 0.812(18) 1 d . . P A
 2
 Ge2 Ge 0.49615(18) 0.6204(2) 0.71210(16) 0.0179(4) Uani 0.812(18) 1 d . . P A 2
 Ge3 Ge 0.3747(2) 0.7102(2) 0.74873(19) 0.0170(4) Uani 0.812(18) 1 d . . P A 2
 Ge4 Ge 0.2682(2) 0.82557(18) 0.72263(17) 0.0168(4) Uani 0.812(18) 1 d . . P A 2
 Ge5 Ge 0.3825(2) 0.83175(14) 0.78721(15) 0.0184(4) Uani 0.812(18) 1 d . . P A 2
 Ge6 Ge 0.361(2) 0.8226(13) 0.7944(10) 0.049(4) Uani 0.188(18) 1 d . . P A 1
 Ge7 Ge 0.2483(18) 0.8166(13) 0.7297(10) 0.039(4) Uani 0.188(18) 1 d . . P A 1
 Ge8 Ge 0.3567(19) 0.6967(14) 0.7544(10) 0.039(3) Uani 0.188(18) 1 d . . P A 1
 Ge9 Ge 0.330(2) 0.5462(13) 0.7788(7) 0.040(3) Uani 0.188(18) 1 d . . P A 1
 Ge10 Ge 0.4780(19) 0.6067(14) 0.7189(9) 0.045(3) Uani 0.188(18) 1 d . . P A 1
 Si1 Si 0.24473(11) 0.41688(9) 0.75937(7) 0.0257(3) Uani 1 1 d . . . . .
 Si2 Si 0.23871(13) 0.45621(9) 0.89492(7) 0.0321(4) Uani 1 1 d . . . . .
 Si3 Si 0.68902(11) 0.54691(10) 0.71258(8) 0.0286(3) Uani 1 1 d . . . . .
 Si4 Si 0.62053(11) 0.66199(10) 0.58511(7) 0.0278(3) Uani 1 1 d . . . . .
 Si5 Si 0.06828(11) 0.89124(9) 0.72873(7) 0.0254(3) Uani 1 1 d . . . . .
 Si6 Si 0.19982(11) 0.88941(9) 0.59622(7) 0.0251(3) Uani 1 1 d . . . . .
 Si7 Si 0.43549(12) 0.82681(9) 0.91503(7) 0.0299(3) Uani 1 1 d . . . . .
 Si8 Si 0.48699(11) 0.98040(9) 0.79047(7) 0.0247(3) Uani 1 1 d . . . . .
 N1 N 0.2688(3) 0.4685(3) 0.8141(2) 0.0250(9) Uani 1 1 d . . . . .
 N2 N 0.6141(3) 0.6084(3) 0.6647(2) 0.0248(9) Uani 1 1 d . . . . .
 N3 N 0.4392(3) 0.8844(3) 0.8371(2) 0.0258(9) Uani 1 1 d . . . . .
 N4 N 0.1679(3) 0.8736(3) 0.67760(19) 0.0222(9) Uani 1 1 d . . . . .
 C1 C 0.4413(6) 0.4415(5) 0.9071(4) 0.055(2) Uani 1 1 d . . . . .
 H1A H 0.4523 0.4464 0.8623 0.083 Uiso 1 1 calc GR . . . .
 H1B H 0.4336 0.3844 0.9303 0.083 Uiso 1 1 calc GR . . . .
 H1C H 0.4960 0.4660 0.9185 0.083 Uiso 1 1 calc GR . . . .
 C2 C 0.3500(5) 0.4849(4) 0.9232(3) 0.0391(14) Uani 1 1 d . . . . .
 H2 H 0.3644 0.5428 0.9001 0.047 Uiso 1 1 calc R . . . .
 C3 C 0.3349(7) 0.4832(5) 0.9932(3) 0.065(2) Uani 1 1 d . . . . .
 H3A H 0.3941 0.5018 1.0037 0.098 Uiso 1 1 calc GR . . . .
 H3B H 0.3178 0.4281 1.0189 0.098 Uiso 1 1 calc GR . . . .
 H3C H 0.2832 0.5186 1.0012 0.098 Uiso 1 1 calc GR . . . .
 C4 C 0.1726(5) 0.6159(4) 0.8875(3) 0.0460(17) Uani 1 1 d . . . . .
 H4A H 0.1791 0.6300 0.8419 0.069 Uiso 1 1 calc GR . . . .
 H4B H 0.2340 0.6263 0.8998 0.069 Uiso 1 1 calc GR . . . .
 H4C H 0.1237 0.6485 0.9035 0.069 Uiso 1 1 calc GR . . . .
 C5 C 0.1433(5) 0.5274(4) 0.9143(3) 0.0407(15) Uani 1 1 d . . . . .
 H5 H 0.1347 0.5173 0.9606 0.049 Uiso 1 1 calc R . . . .
 C6 C 0.0445(5) 0.5119(4) 0.8987(3) 0.0526(19) Uani 1 1 d . . . . .
 H6A H 0.0488 0.5203 0.8536 0.079 Uiso 1 1 calc GR . . . .
 H6B H -0.0006 0.5491 0.9121 0.079 Uiso 1 1 calc GR . . . .
 H6C H 0.0222 0.4563 0.9204 0.079 Uiso 1 1 calc GR . . . .
 C7 C 0.1362(8) 0.3453(5) 1.0047(3) 0.074(3) Uani 1 1 d . . . . .
 H7A H 0.0864 0.3851 1.0021 0.112 Uiso 1 1 calc GR . . . .
 H7B H 0.1819 0.3561 1.0305 0.112 Uiso 1 1 calc GR . . . .
 H7C H 0.1068 0.2912 1.0233 0.112 Uiso 1 1 calc GR . . . .
 C8 C 0.1892(6) 0.3510(4) 0.9384(3) 0.0504(19) Uani 1 1 d . . . . .
 H8 H 0.1411 0.3367 0.9143 0.061 Uiso 1 1 calc R . . . .
 C9 C 0.2654(7) 0.2860(4) 0.9431(4) 0.069(3) Uani 1 1 d . . . . .
 H9A H 0.2984 0.2882 0.9013 0.103 Uiso 1 1 calc GR . . . .
 H9B H 0.2341 0.2327 0.9624 0.103 Uiso 1 1 calc GR . . . .
 H9C H 0.3119 0.2961 0.9687 0.103 Uiso 1 1 calc GR . . . .
 C10 C 0.0535(5) 0.3529(4) 0.8095(4) 0.0501(18) Uani 1 1 d . . . . .
 H10A H 0.0299 0.3793 0.7705 0.075 Uiso 1 1 calc GR . . . .
 H10B H 0.0514 0.3901 0.8357 0.075 Uiso 1 1 calc GR . . . .
 H10C H 0.0133 0.3047 0.8317 0.075 Uiso 1 1 calc GR . . . .
 C11 C 0.1562(4) 0.3291(3) 0.7950(3) 0.0343(13) Uani 1 1 d . . . . .
 H11 H 0.1759 0.2995 0.8357 0.041 Uiso 1 1 calc R . . . .
 C12 C 0.1568(6) 0.2674(4) 0.7557(4) 0.0525(19) Uani 1 1 d . . . . .
 H12A H 0.1321 0.2923 0.7168 0.079 Uiso 1 1 calc GR . . . .
 H12B H 0.1162 0.2200 0.7795 0.079 Uiso 1 1 calc GR . . . .
 H12C H 0.2224 0.2510 0.7461 0.079 Uiso 1 1 calc GR . . . .
 C13 C 0.4000(5) 0.3122(4) 0.7794(3) 0.0435(16) Uani 1 1 d . . . . .
 H13A H 0.4608 0.2940 0.7620 0.065 Uiso 1 1 calc GR . . . .
 H13B H 0.3526 0.2671 0.7932 0.065 Uiso 1 1 calc GR . . . .
 H13C H 0.4093 0.3320 0.8150 0.065 Uiso 1 1 calc GR . . . .
 C14 C 0.3642(4) 0.3803(3) 0.7293(3) 0.0308(12) Uani 1 1 d . . . . .
 H14 H 0.4111 0.4266 0.7212 0.037 Uiso 1 1 calc R . . . .
 C15 C 0.3716(5) 0.3572(4) 0.6673(3) 0.0412(15) Uani 1 1 d . . . . .
 H15A H 0.3590 0.4042 0.6341 0.062 Uiso 1 1 calc GR . . . .
 H15B H 0.3244 0.3137 0.6717 0.062 Uiso 1 1 calc GR . . . .
 H15C H 0.4360 0.3391 0.6568 0.062 Uiso 1 1 calc GR . . . .
 C16 C 0.1576(6) 0.4590(5) 0.6459(3) 0.0518(19) Uani 1 1 d . . . . .
 H16A H 0.1462 0.5032 0.6102 0.078 Uiso 1 1 calc GR . . . .
 H16B H 0.0972 0.4290 0.6656 0.078 Uiso 1 1 calc GR . . . .
 H16C H 0.2034 0.4228 0.6316 0.078 Uiso 1 1 calc GR . . . .
 C17 C 0.1985(4) 0.4934(4) 0.6934(3) 0.0310(12) Uani 1 1 d . . . . .
 H17 H 0.2552 0.5288 0.6696 0.037 Uiso 1 1 calc R . . . .
 C18 C 0.1260(5) 0.5490(4) 0.7155(3) 0.0380(14) Uani 1 1 d . . . . .
 H18A H 0.1158 0.5939 0.6800 0.057 Uiso 1 1 calc GR . . . .
 H18B H 0.1504 0.5699 0.7469 0.057 Uiso 1 1 calc GR . . . .
 H18C H 0.0653 0.5188 0.7338 0.057 Uiso 1 1 calc GR . . . .
 C19 C 0.6510(6) 0.3849(4) 0.8012(4) 0.055(2) Uani 1 1 d . . . . .
 H19A H 0.6077 0.3372 0.8133 0.083 Uiso 1 1 calc GR . . . .
 H19B H 0.6442 0.4115 0.8348 0.083 Uiso 1 1 calc GR . . . .
 H19C H 0.7172 0.3688 0.7935 0.083 Uiso 1 1 calc GR . . . .
 C20 C 0.6260(4) 0.4432(4) 0.7418(3) 0.0382(14) Uani 1 1 d . . . . .
 H20 H 0.5567 0.4537 0.7519 0.046 Uiso 1 1 calc R . . . .
 C21 C 0.6314(5) 0.4013(4) 0.6887(4) 0.0518(18) Uani 1 1 d . . . . .
 H21A H 0.6056 0.4364 0.6532 0.078 Uiso 1 1 calc GR . . . .
 H21B H 0.5937 0.3503 0.7038 0.078 Uiso 1 1 calc GR . . . .
 H21C H 0.6982 0.3908 0.6755 0.078 Uiso 1 1 calc GR . . . .
 C22 C 0.7732(5) 0.5520(5) 0.8226(3) 0.0515(18) Uani 1 1 d . . . . .
 H22A H 0.8370 0.5696 0.7992 0.077 Uiso 1 1 calc GR . . . .
 H22B H 0.7667 0.4931 0.8339 0.077 Uiso 1 1 calc GR . . . .
 H22C H 0.7644 0.5701 0.8606 0.077 Uiso 1 1 calc GR . . . .
 C23 C 0.6964(5) 0.5884(4) 0.7819(3) 0.0350(13) Uani 1 1 d . . . . .
 H23 H 0.6331 0.5750 0.8095 0.042 Uiso 1 1 calc R . . . .
 C24 C 0.7103(5) 0.6804(4) 0.7639(3) 0.0436(16) Uani 1 1 d . . . . .
 H24A H 0.7714 0.6966 0.7363 0.065 Uiso 1 1 calc GR . . . .
 H24B H 0.7106 0.6982 0.8017 0.065 Uiso 1 1 calc GR . . . .
 H24C H 0.6579 0.7052 0.7423 0.065 Uiso 1 1 calc GR . . . .
 C25 C 0.8658(5) 0.4658(4) 0.7012(4) 0.0495(18) Uani 1 1 d . . . . .
 H25A H 0.9260 0.4625 0.6745 0.074 Uiso 1 1 calc GR . . . .
 H25B H 0.8266 0.4163 0.7090 0.074 Uiso 1 1 calc GR . . . .
 H25C H 0.8795 0.4725 0.7410 0.074 Uiso 1 1 calc GR . . . .
 C26 C 0.8114(4) 0.5380(4) 0.6690(3) 0.0380(14) Uani 1 1 d . . . . .
 H26 H 0.8006 0.5288 0.6285 0.046 Uiso 1 1 calc R . . . .
 C27 C 0.8773(5) 0.6138(4) 0.6522(3) 0.0421(15) Uani 1 1 d . . . . .
 H27A H 0.9335 0.6079 0.6229 0.063 Uiso 1 1 calc GR . . . .
 H27B H 0.8978 0.6209 0.6901 0.063 Uiso 1 1 calc GR . . . .
 H27C H 0.8426 0.6608 0.6329 0.063 Uiso 1 1 calc GR . . . .
 C28 C 0.7064(5) 0.5485(5) 0.5213(3) 0.0532(19) Uani 1 1 d . . . . .
 H28A H 0.6614 0.5529 0.4915 0.080 Uiso 1 1 calc GR . . . .
 H28B H 0.6802 0.5097 0.5609 0.080 Uiso 1 1 calc GR . . . .
 H28C H 0.7676 0.5300 0.5046 0.080 Uiso 1 1 calc GR . . . .
 C29 C 0.7223(4) 0.6311(4) 0.5324(3) 0.0392(15) Uani 1 1 d . . . . .
 H29 H 0.7799 0.6273 0.5539 0.047 Uiso 1 1 calc R . . . .
 C30 C 0.7484(6) 0.6948(5) 0.4687(3) 0.056(2) Uani 1 1 d . . . . .
 H30A H 0.8017 0.6763 0.4437 0.085 Uiso 1 1 calc GR . . . .
 H30B H 0.7673 0.7460 0.4755 0.085 Uiso 1 1 calc GR . . . .
 H30C H 0.6928 0.7024 0.4467 0.085 Uiso 1 1 calc GR . . . .
 C31 C 0.4902(5) 0.6947(6) 0.4942(3) 0.058(2) Uani 1 1 d . . . . .
 H31A H 0.5295 0.6709 0.4646 0.087 Uiso 1 1 calc GR . . . .
 H31B H 0.5116 0.7509 0.4869 0.087 Uiso 1 1 calc GR . . . .
 H31C H 0.4230 0.6925 0.4883 0.087 Uiso 1 1 calc GR . . . .
 C32 C 0.5004(4) 0.6471(4) 0.5614(3) 0.0343(13) Uani 1 1 d . . . . .
 H32 H 0.4536 0.6709 0.5887 0.041 Uiso 1 1 calc R . . . .
 C33 C 0.4639(5) 0.5603(4) 0.5741(3) 0.0457(16) Uani 1 1 d . . . . .
 H33A H 0.3959 0.5595 0.5697 0.069 Uiso 1 1 calc GR . . . .
 H33B H 0.4718 0.5302 0.6165 0.069 Uiso 1 1 calc GR . . . .
 H33C H 0.5003 0.5355 0.5442 0.069 Uiso 1 1 calc GR . . . .
 C34 C 0.7329(5) 0.7986(4) 0.5893(3) 0.0375(14) Uani 1 1 d . . . . .
 H34A H 0.7863 0.7792 0.5650 0.056 Uiso 1 1 calc GR . . . .
 H34B H 0.7343 0.7749 0.6339 0.056 Uiso 1 1 calc GR . . . .
 H34C H 0.7386 0.8574 0.5797 0.056 Uiso 1 1 calc GR . . . .
 C35 C 0.6381(4) 0.7740(4) 0.5727(3) 0.0315(12) Uani 1 1 d . . . . .
 H35 H 0.6405 0.7993 0.5270 0.038 Uiso 1 1 calc R . . . .
 C36 C 0.5563(5) 0.8127(4) 0.6055(3) 0.0389(14) Uani 1 1 d . . . . .
 H36A H 0.5691 0.8710 0.5947 0.058 Uiso 1 1 calc GR . . . .
 H36B H 0.5513 0.7902 0.6507 0.058 Uiso 1 1 calc GR . . . .
 H36C H 0.4960 0.8018 0.5920 0.058 Uiso 1 1 calc GR . . . .
 C37 C 0.6279(4) 0.8931(4) 0.7308(3) 0.0377(14) Uani 1 1 d . . . . .
 H37A H 0.6589 0.8848 0.6912 0.057 Uiso 1 1 calc GR . . . .
 H37B H 0.5892 0.8447 0.7549 0.057 Uiso 1 1 calc GR . . . .
 H37C H 0.6768 0.9036 0.7545 0.057 Uiso 1 1 calc GR . . . .
 C38 C 0.5631(4) 0.9653(4) 0.7175(3) 0.0323(13) Uani 1 1 d . . . . .
 H38 H 0.5173 0.9533 0.6910 0.039 Uiso 1 1 calc R . . . .
 C39 C 0.6248(5) 1.0398(4) 0.6772(3) 0.0421(15) Uani 1 1 d . . . . .
 H39A H 0.6600 1.0272 0.6403 0.063 Uiso 1 1 calc GR . . . .
 H39B H 0.6702 1.0546 0.7015 0.063 Uiso 1 1 calc GR . . . .
 H39C H 0.5834 1.0848 0.6640 0.063 Uiso 1 1 calc GR . . . .
 C40 C 0.6563(4) 0.9998(4) 0.8451(3) 0.0383(14) Uani 1 1 d . . . . .
 H40A H 0.6994 1.0112 0.8053 0.057 Uiso 1 1 calc GR . . . .
 H40B H 0.6487 0.9414 0.8635 0.057 Uiso 1 1 calc GR . . . .
 H40C H 0.6833 1.0246 0.8735 0.057 Uiso 1 1 calc GR . . . .
 C41 C 0.5575(4) 1.0347(3) 0.8339(3) 0.0313(12) Uani 1 1 d . . . . .
 H41 H 0.5190 1.0271 0.8761 0.038 Uiso 1 1 calc R . . . .
 C42 C 0.5695(5) 1.1261(4) 0.8042(3) 0.0408(15) Uani 1 1 d . . . . .
 H42A H 0.6039 1.1368 0.7616 0.061 Uiso 1 1 calc GR . . . .
 H42B H 0.6059 1.1504 0.8288 0.061 Uiso 1 1 calc GR . . . .
 H42C H 0.5063 1.1494 0.8032 0.061 Uiso 1 1 calc GR . . . .
 C43 C 0.6288(5) 0.7734(4) 0.9058(3) 0.0426(16) Uani 1 1 d . . . . .
 H43A H 0.6706 0.7275 0.9130 0.064 Uiso 1 1 calc GR . . . .
 H43B H 0.6419 0.8085 0.9316 0.064 Uiso 1 1 calc GR . . . .
 H43C H 0.6409 0.8038 0.8617 0.064 Uiso 1 1 calc GR . . . .
 C44 C 0.5248(5) 0.7430(4) 0.9232(3) 0.0359(14) Uani 1 1 d . . . . .
 H44 H 0.5161 0.7135 0.9685 0.043 Uiso 1 1 calc R . . . .
 C45 C 0.5069(6) 0.6804(4) 0.8889(3) 0.0454(17) Uani 1 1 d . . . . .
 H45A H 0.5200 0.7053 0.8438 0.068 Uiso 1 1 calc GR . . . .
 H45B H 0.4400 0.6605 0.9007 0.068 Uiso 1 1 calc GR . . . .
 H45C H 0.5491 0.6355 0.9002 0.068 Uiso 1 1 calc GR . . . .
 C46 C 0.2958(7) 0.7178(5) 1.0061(4) 0.063(2) Uani 1 1 d . . . . .
 H46A H 0.2346 0.6878 1.0126 0.095 Uiso 1 1 calc GR . . . .
 H46B H 0.2941 0.7490 1.0366 0.095 Uiso 1 1 calc GR . . . .
 H46C H 0.3476 0.6799 1.0112 0.095 Uiso 1 1 calc GR . . . .
 C47 C 0.3130(5) 0.7751(4) 0.9398(3) 0.0380(14) Uani 1 1 d . . . . .
 H47 H 0.3101 0.7396 0.9116 0.046 Uiso 1 1 calc R . . . .
 C48 C 0.2264(5) 0.8300(5) 0.9299(4) 0.0519(18) Uani 1 1 d . . . . .
 H48A H 0.2380 0.8676 0.8880 0.078 Uiso 1 1 calc GR . . . .
 H48B H 0.2182 0.8604 0.9611 0.078 Uiso 1 1 calc GR . . . .
 H48C H 0.1684 0.7967 0.9342 0.078 Uiso 1 1 calc GR . . . .
 C49 C 0.4900(6) 0.8348(5) 1.0318(3) 0.056(2) Uani 1 1 d . . . . .
 H49A H 0.5408 0.7990 1.0231 0.084 Uiso 1 1 calc GR . . . .
 H49B H 0.4336 0.8025 1.0566 0.084 Uiso 1 1 calc GR . . . .
 H49C H 0.5125 0.8696 1.0552 0.084 Uiso 1 1 calc GR . . . .
 C50 C 0.4631(5) 0.8873(4) 0.9697(3) 0.0366(14) Uani 1 1 d . . . . .
 H50 H 0.5210 0.9224 0.9479 0.044 Uiso 1 1 calc R . . . .
 C51 C 0.3848(5) 0.9440(4) 0.9841(3) 0.0460(17) Uani 1 1 d . . . . .
 H51A H 0.3681 0.9782 0.9450 0.069 Uiso 1 1 calc GR . . . .
 H51B H 0.4083 0.9779 1.0078 0.069 Uiso 1 1 calc GR . . . .
 H51C H 0.3280 0.9122 1.0087 0.069 Uiso 1 1 calc GR . . . .
 C52 C 0.3199(5) 1.0614(4) 0.8235(3) 0.0427(16) Uani 1 1 d . . . . .
 H52A H 0.2644 1.0918 0.8104 0.064 Uiso 1 1 calc GR . . . .
 H52B H 0.3598 1.0940 0.8405 0.064 Uiso 1 1 calc GR . . . .
 H52C H 0.2980 1.0115 0.8556 0.064 Uiso 1 1 calc GR . . . .
 C53 C 0.3791(4) 1.0410(3) 0.7668(3) 0.0333(13) Uani 1 1 d . . . . .
 H53 H 0.3368 1.0033 0.7547 0.040 Uiso 1 1 calc R . . . .
 C54 C 0.3971(5) 1.1147(4) 0.7101(3) 0.0397(15) Uani 1 1 d . . . . .
 H54A H 0.4275 1.0982 0.6737 0.060 Uiso 1 1 calc GR . . . .
 H54B H 0.4393 1.1541 0.7186 0.060 Uiso 1 1 calc GR . . . .
 H54C H 0.3361 1.1390 0.7016 0.060 Uiso 1 1 calc GR . . . .
 C55 C 0.1321(5) 1.0502(4) 0.5503(4) 0.055(2) Uani 1 1 d . . . . .
 H55A H 0.1978 1.0705 0.5329 0.083 Uiso 1 1 calc GR . . . .
 H55B H 0.1180 1.0528 0.5936 0.083 Uiso 1 1 calc GR . . . .
 H55C H 0.0875 1.0831 0.5257 0.083 Uiso 1 1 calc GR . . . .
 C56 C 0.1212(4) 0.9628(4) 0.5483(3) 0.0388(15) Uani 1 1 d . . . . .
 H56 H 0.0535 0.9448 0.5668 0.047 Uiso 1 1 calc R . . . .
 C57 C 0.1332(5) 0.9590(5) 0.4803(3) 0.056(2) Uani 1 1 d . . . . .
 H57A H 0.0923 0.9982 0.4572 0.085 Uiso 1 1 calc GR . . . .
 H57B H 0.1147 0.9047 0.4792 0.085 Uiso 1 1 calc GR . . . .
 H57C H 0.2002 0.9716 0.4611 0.085 Uiso 1 1 calc GR . . . .
 C58 C 0.3566(5) 0.9982(4) 0.5954(3) 0.0422(15) Uani 1 1 d . . . . .
 H58A H 0.4263 1.0039 0.5922 0.063 Uiso 1 1 calc GR . . . .
 H58B H 0.3270 0.9928 0.6385 0.063 Uiso 1 1 calc GR . . . .
 H58C H 0.3330 1.0460 0.5678 0.063 Uiso 1 1 calc GR . . . .
 C59 C 0.3308(4) 0.9234(4) 0.5763(2) 0.0290(12) Uani 1 1 d . . . . .
 H59 H 0.3651 0.8788 0.6019 0.035 Uiso 1 1 calc R . . . .
 C60 C 0.3753(5) 0.9314(5) 0.5083(3) 0.0466(17) Uani 1 1 d . . . . .
 H60A H 0.3516 0.9794 0.4809 0.070 Uiso 1 1 calc GR . . . .
 H60B H 0.3574 0.8836 0.4964 0.070 Uiso 1 1 calc GR . . . .
 H60C H 0.4451 0.9365 0.5043 0.070 Uiso 1 1 calc GR . . . .
 C61 C 0.0887(4) 0.7570(4) 0.5811(3) 0.0398(14) Uani 1 1 d . . . . .
 H61A H 0.0477 0.7974 0.5593 0.060 Uiso 1 1 calc GR . . . .
 H61B H 0.0636 0.7403 0.6257 0.060 Uiso 1 1 calc GR . . . .
 H61C H 0.0896 0.7101 0.5644 0.060 Uiso 1 1 calc GR . . . .
 C62 C 0.1905(4) 0.7930(4) 0.5714(3) 0.0320(12) Uani 1 1 d . . . . .
 H62 H 0.2135 0.8076 0.5255 0.038 Uiso 1 1 calc R . . . .
 C63 C 0.2561(5) 0.7274(4) 0.6017(3) 0.0398(15) Uani 1 1 d . . . . .
 H63A H 0.2539 0.6819 0.5836 0.060 Uiso 1 1 calc GR . . . .
 H63B H 0.2341 0.7088 0.6467 0.060 Uiso 1 1 calc GR . . . .
 H63C H 0.3219 0.7495 0.5941 0.060 Uiso 1 1 calc GR . . . .
 C64 C -0.1078(5) 0.9765(5) 0.7247(4) 0.0536(19) Uani 1 1 d . . . . .
 H64A H -0.0733 1.0177 0.7367 0.080 Uiso 1 1 calc GR . . . .
 H64B H -0.1395 0.9370 0.7622 0.080 Uiso 1 1 calc GR . . . .
 H64C H -0.1559 1.0020 0.6993 0.080 Uiso 1 1 calc GR . . . .
 C65 C -0.0365(4) 0.9338(3) 0.6866(3) 0.0326(13) Uani 1 1 d . . . . .
 H65 H -0.0084 0.9759 0.6480 0.039 Uiso 1 1 calc R . . . .
 C66 C -0.0910(4) 0.8728(4) 0.6652(3) 0.0385(14) Uani 1 1 d . . . . .
 H66A H -0.1335 0.9011 0.6365 0.058 Uiso 1 1 calc GR . . . .
 H66B H -0.1291 0.8355 0.7015 0.058 Uiso 1 1 calc GR . . . .
 H66C H -0.0455 0.8426 0.6440 0.058 Uiso 1 1 calc GR . . . .
 C67 C 0.1323(5) 1.0508(4) 0.7220(4) 0.055(2) Uani 1 1 d . . . . .
 H67A H 0.1822 1.0495 0.6872 0.082 Uiso 1 1 calc GR . . . .
 H67B H 0.1529 1.0880 0.7440 0.082 Uiso 1 1 calc GR . . . .
 H67C H 0.0730 1.0691 0.7058 0.082 Uiso 1 1 calc GR . . . .
 C68 C 0.1146(4) 0.9660(4) 0.7671(3) 0.0375(14) Uani 1 1 d . . . . .
 H68 H 0.1794 0.9476 0.7763 0.045 Uiso 1 1 calc R . . . .
 C69 C 0.0585(5) 0.9689(5) 0.8298(4) 0.059(2) Uani 1 1 d . . . . .
 H69A H -0.0063 0.9864 0.8241 0.088 Uiso 1 1 calc GR . . . .
 H69B H 0.0909 1.0070 0.8462 0.088 Uiso 1 1 calc GR . . . .
 H69C H 0.0550 0.9153 0.8593 0.088 Uiso 1 1 calc GR . . . .
 C70 C -0.0659(6) 0.7925(5) 0.8313(3) 0.057(2) Uani 1 1 d . . . . .
 H70A H -0.1177 0.7948 0.8064 0.086 Uiso 1 1 calc GR . . . .
 H70B H -0.0676 0.8394 0.8479 0.086 Uiso 1 1 calc GR . . . .
 H70C H -0.0742 0.7431 0.8658 0.086 Uiso 1 1 calc GR . . . .
 C71 C 0.0307(5) 0.7927(4) 0.7900(3) 0.0356(13) Uani 1 1 d . . . . .
 H71 H 0.0800 0.7833 0.8185 0.043 Uiso 1 1 calc R . . . .
 C72 C 0.0320(5) 0.7202(4) 0.7629(3) 0.0418(15) Uani 1 1 d . . . . .
 H72A H -0.0188 0.7244 0.7371 0.063 Uiso 1 1 calc GR . . . .
 H72B H 0.0216 0.6705 0.7971 0.063 Uiso 1 1 calc GR . . . .
 H72C H 0.0942 0.7194 0.7374 0.063 Uiso 1 1 calc GR . . . .
 C73 C 0.1733(14) 0.0706(10) 1.0299(9) 0.076(4) Uani 0.5 1 d . U P . .
 H73A H 0.1548 0.1159 1.0469 0.114 Uiso 0.5 1 calc GR . P . .
 H73B H 0.2432 0.0702 1.0209 0.114 Uiso 0.5 1 calc GR . P . .
 H73C H 0.1488 0.0200 1.0603 0.114 Uiso 0.5 1 calc GR . P . .
 C74 C 0.1346(13) 0.0787(12) 0.9745(10) 0.084(5) Uani 0.5 1 d D U P . .
 H74A H 0.1275 0.0249 0.9675 0.101 Uiso 0.5 1 calc R . P . .
 H74B H 0.1792 0.1123 0.9389 0.101 Uiso 0.5 1 calc R . P . .
 C75 C 0.0425(15) 0.1150(15) 0.9771(12) 0.107(7) Uani 0.5 1 d D U P . .
 H75A H -0.0019 0.0814 1.0129 0.129 Uiso 0.5 1 calc R . P . .
 H75B H 0.0498 0.1688 0.9841 0.129 Uiso 0.5 1 calc R . P . .
 C76 C 0.0020(16) 0.1236(14) 0.9214(11) 0.101(6) Uani 0.5 1 d D U P . .
 H76A H 0.0001 0.0687 0.9159 0.121 Uiso 0.5 1 calc R . P . .
 H76B H 0.0512 0.1548 0.8875 0.121 Uiso 0.5 1 calc R . P . .
 C77 C -0.0912(16) 0.1580(15) 0.9050(13) 0.123(7) Uani 0.5 1 d D U P . .
 H77A H -0.0897 0.2088 0.9173 0.148 Uiso 0.5 1 calc R . P . .
 H77B H -0.1375 0.1220 0.9381 0.148 Uiso 0.5 1 calc R . P . .
 C78 C -0.1592(16) 0.1848(12) 0.8433(12) 0.107(7) Uani 0.5 1 d . U P . .
 H78A H -0.1219 0.1769 0.8054 0.161 Uiso 0.5 1 calc GR . P . .
 H78B H -0.1754 0.2415 0.8362 0.161 Uiso 0.5 1 calc GR . P . .
 H78C H -0.2182 0.1510 0.8542 0.161 Uiso 0.5 1 calc GR . P . .


_geom_special_details
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;
loop_
  _geom_bond_atom_site_label_1
  _geom_bond_atom_site_label_2
  _geom_bond_distance
  _geom_bond_site_symmetry_2
  _geom_bond_publ_flag
 Ge1 Ge2 2.332(3) . ?
 Ge1 Ge3 2.491(4) . ?
 Ge1 N1 1.930(5) . ?
 Ge2 Ge3 2.511(5) . ?
 Ge2 N2 1.887(5) . ?
 Ge3 Ge4 2.490(6) . ?
 Ge3 Ge5 2.487(5) . ?
 Ge4 Ge5 2.349(5) . ?
 Ge4 N4 1.921(5) . ?
 Ge5 N3 1.885(5) . ?
 Ge6 Ge7 2.33(2) . ?
 Ge6 Ge8 2.57(2) . ?
 Ge6 N3 2.04(2) . ?
 Ge7 Ge8 2.56(3) . ?
 Ge7 Si5 2.85(2) . ?
 Ge7 N4 1.84(2) . ?
 Ge8 Ge9 2.522(19) . ?
 Ge8 Ge10 2.50(3) . ?
 Ge9 Ge10 2.385(14) . ?
 Ge9 Si1 2.71(3) . ?
 Ge9 Si2 2.78(2) . ?
 Ge9 N1 1.55(3) . ?
 Ge10 N2 2.12(3) . ?
 Si1 N1 1.776(4) . ?
 Si1 C11 1.887(6) . ?
 Si1 C14 1.899(6) . ?
 Si1 C17 1.898(6) . ?
 Si2 N1 1.763(4) . ?
 Si2 C2 1.895(7) . ?
 Si2 C5 1.906(7) . ?
 Si2 C8 1.895(7) . ?
 Si3 N2 1.769(4) . ?
 Si3 C20 1.904(7) . ?
 Si3 C23 1.903(6) . ?
 Si3 C26 1.889(6) . ?
 Si4 N2 1.770(5) . ?
 Si4 C29 1.899(6) . ?
 Si4 C32 1.891(6) . ?
 Si4 C35 1.889(6) . ?
 Si5 N4 1.766(4) . ?
 Si5 C65 1.916(6) . ?
 Si5 C68 1.903(6) . ?
 Si5 C71 1.896(6) . ?
 Si6 N4 1.769(4) . ?
 Si6 C56 1.901(6) . ?
 Si6 C59 1.895(6) . ?
 Si6 C62 1.905(6) . ?
 Si7 N3 1.762(5) . ?
 Si7 C44 1.909(6) . ?
 Si7 C47 1.886(7) . ?
 Si7 C50 1.897(6) . ?
 Si8 N3 1.777(5) . ?
 Si8 C38 1.908(6) . ?
 Si8 C41 1.902(6) . ?
 Si8 C53 1.907(6) . ?
 C1 H1A 0.9800 . ?
 C1 H1B 0.9800 . ?
 C1 H1C 0.9800 . ?
 C1 C2 1.539(10) . ?
 C2 H2 1.0000 . ?
 C2 C3 1.554(9) . ?
 C3 H3A 0.9800 . ?
 C3 H3B 0.9800 . ?
 C3 H3C 0.9800 . ?
 C4 H4A 0.9800 . ?
 C4 H4B 0.9800 . ?
 C4 H4C 0.9800 . ?
 C4 C5 1.517(9) . ?
 C5 H5 1.0000 . ?
 C5 C6 1.530(10) . ?
 C6 H6A 0.9800 . ?
 C6 H6B 0.9800 . ?
 C6 H6C 0.9800 . ?
 C7 H7A 0.9800 . ?
 C7 H7B 0.9800 . ?
 C7 H7C 0.9800 . ?
 C7 C8 1.547(10) . ?
 C8 H8 1.0000 . ?
 C8 C9 1.548(11) . ?
 C9 H9A 0.9800 . ?
 C9 H9B 0.9800 . ?
 C9 H9C 0.9800 . ?
 C10 H10A 0.9800 . ?
 C10 H10B 0.9800 . ?
 C10 H10C 0.9800 . ?
 C10 C11 1.522(9) . ?
 C11 H11 1.0000 . ?
 C11 C12 1.558(8) . ?
 C12 H12A 0.9800 . ?
 C12 H12B 0.9800 . ?
 C12 H12C 0.9800 . ?
 C13 H13A 0.9800 . ?
 C13 H13B 0.9800 . ?
 C13 H13C 0.9800 . ?
 C13 C14 1.536(8) . ?
 C14 H14 1.0000 . ?
 C14 C15 1.543(8) . ?
 C15 H15A 0.9800 . ?
 C15 H15B 0.9800 . ?
 C15 H15C 0.9800 . ?
 C16 H16A 0.9800 . ?
 C16 H16B 0.9800 . ?
 C16 H16C 0.9800 . ?
 C16 C17 1.536(8) . ?
 C17 H17 1.0000 . ?
 C17 C18 1.525(8) . ?
 C18 H18A 0.9800 . ?
 C18 H18B 0.9800 . ?
 C18 H18C 0.9800 . ?
 C19 H19A 0.9800 . ?
 C19 H19B 0.9800 . ?
 C19 H19C 0.9800 . ?
 C19 C20 1.529(9) . ?
 C20 H20 1.0000 . ?
 C20 C21 1.552(9) . ?
 C21 H21A 0.9800 . ?
 C21 H21B 0.9800 . ?
 C21 H21C 0.9800 . ?
 C22 H22A 0.9800 . ?
 C22 H22B 0.9800 . ?
 C22 H22C 0.9800 . ?
 C22 C23 1.548(9) . ?
 C23 H23 1.0000 . ?
 C23 C24 1.534(9) . ?
 C24 H24A 0.9800 . ?
 C24 H24B 0.9800 . ?
 C24 H24C 0.9800 . ?
 C25 H25A 0.9800 . ?
 C25 H25B 0.9800 . ?
 C25 H25C 0.9800 . ?
 C25 C26 1.530(9) . ?
 C26 H26 1.0000 . ?
 C26 C27 1.535(9) . ?
 C27 H27A 0.9800 . ?
 C27 H27B 0.9800 . ?
 C27 H27C 0.9800 . ?
 C28 H28A 0.9800 . ?
 C28 H28B 0.9800 . ?
 C28 H28C 0.9800 . ?
 C28 C29 1.536(9) . ?
 C29 H29 1.0000 . ?
 C29 C30 1.548(10) . ?
 C30 H30A 0.9800 . ?
 C30 H30B 0.9800 . ?
 C30 H30C 0.9800 . ?
 C31 H31A 0.9800 . ?
 C31 H31B 0.9800 . ?
 C31 H31C 0.9800 . ?
 C31 C32 1.544(9) . ?
 C32 H32 1.0000 . ?
 C32 C33 1.523(9) . ?
 C33 H33A 0.9800 . ?
 C33 H33B 0.9800 . ?
 C33 H33C 0.9800 . ?
 C34 H34A 0.9800 . ?
 C34 H34B 0.9800 . ?
 C34 H34C 0.9800 . ?
 C34 C35 1.533(8) . ?
 C35 H35 1.0000 . ?
 C35 C36 1.533(8) . ?
 C36 H36A 0.9800 . ?
 C36 H36B 0.9800 . ?
 C36 H36C 0.9800 . ?
 C37 H37A 0.9800 . ?
 C37 H37B 0.9800 . ?
 C37 H37C 0.9800 . ?
 C37 C38 1.537(8) . ?
 C38 H38 1.0000 . ?
 C38 C39 1.543(9) . ?
 C39 H39A 0.9800 . ?
 C39 H39B 0.9800 . ?
 C39 H39C 0.9800 . ?
 C40 H40A 0.9800 . ?
 C40 H40B 0.9800 . ?
 C40 H40C 0.9800 . ?
 C40 C41 1.547(8) . ?
 C41 H41 1.0000 . ?
 C41 C42 1.538(8) . ?
 C42 H42A 0.9800 . ?
 C42 H42B 0.9800 . ?
 C42 H42C 0.9800 . ?
 C43 H43A 0.9800 . ?
 C43 H43B 0.9800 . ?
 C43 H43C 0.9800 . ?
 C43 C44 1.521(10) . ?
 C44 H44 1.0000 . ?
 C44 C45 1.529(8) . ?
 C45 H45A 0.9800 . ?
 C45 H45B 0.9800 . ?
 C45 H45C 0.9800 . ?
 C46 H46A 0.9800 . ?
 C46 H46B 0.9800 . ?
 C46 H46C 0.9800 . ?
 C46 C47 1.538(9) . ?
 C47 H47 1.0000 . ?
 C47 C48 1.552(10) . ?
 C48 H48A 0.9800 . ?
 C48 H48B 0.9800 . ?
 C48 H48C 0.9800 . ?
 C49 H49A 0.9800 . ?
 C49 H49B 0.9800 . ?
 C49 H49C 0.9800 . ?
 C49 C50 1.549(9) . ?
 C50 H50 1.0000 . ?
 C50 C51 1.534(9) . ?
 C51 H51A 0.9800 . ?
 C51 H51B 0.9800 . ?
 C51 H51C 0.9800 . ?
 C52 H52A 0.9800 . ?
 C52 H52B 0.9800 . ?
 C52 H52C 0.9800 . ?
 C52 C53 1.546(8) . ?
 C53 H53 1.0000 . ?
 C53 C54 1.531(9) . ?
 C54 H54A 0.9800 . ?
 C54 H54B 0.9800 . ?
 C54 H54C 0.9800 . ?
 C55 H55A 0.9800 . ?
 C55 H55B 0.9800 . ?
 C55 H55C 0.9800 . ?
 C55 C56 1.529(10) . ?
 C56 H56 1.0000 . ?
 C56 C57 1.538(9) . ?
 C57 H57A 0.9800 . ?
 C57 H57B 0.9800 . ?
 C57 H57C 0.9800 . ?
 C58 H58A 0.9800 . ?
 C58 H58B 0.9800 . ?
 C58 H58C 0.9800 . ?
 C58 C59 1.529(9) . ?
 C59 H59 1.0000 . ?
 C59 C60 1.538(8) . ?
 C60 H60A 0.9800 . ?
 C60 H60B 0.9800 . ?
 C60 H60C 0.9800 . ?
 C61 H61A 0.9800 . ?
 C61 H61B 0.9800 . ?
 C61 H61C 0.9800 . ?
 C61 C62 1.531(8) . ?
 C62 H62 1.0000 . ?
 C62 C63 1.541(8) . ?
 C63 H63A 0.9800 . ?
 C63 H63B 0.9800 . ?
 C63 H63C 0.9800 . ?
 C64 H64A 0.9800 . ?
 C64 H64B 0.9800 . ?
 C64 H64C 0.9800 . ?
 C64 C65 1.545(8) . ?
 C65 H65 1.0000 . ?
 C65 C66 1.522(9) . ?
 C66 H66A 0.9800 . ?
 C66 H66B 0.9800 . ?
 C66 H66C 0.9800 . ?
 C67 H67A 0.9800 . ?
 C67 H67B 0.9800 . ?
 C67 H67C 0.9800 . ?
 C67 C68 1.537(10) . ?
 C68 H68 1.0000 . ?
 C68 C69 1.529(9) . ?
 C69 H69A 0.9800 . ?
 C69 H69B 0.9800 . ?
 C69 H69C 0.9800 . ?
 C70 H70A 0.9800 . ?
 C70 H70B 0.9800 . ?
 C70 H70C 0.9800 . ?
 C70 C71 1.536(9) . ?
 C71 H71 1.0000 . ?
 C71 C72 1.533(9) . ?
 C72 H72A 0.9800 . ?
 C72 H72B 0.9800 . ?
 C72 H72C 0.9800 . ?
 C73 H73A 0.9800 . ?
 C73 H73B 0.9800 . ?
 C73 H73C 0.9800 . ?
 C73 C74 1.41(3) . ?
 C74 H74A 0.9900 . ?
 C74 H74B 0.9900 . ?
 C74 C75 1.445(17) . ?
 C75 H75A 0.9900 . ?
 C75 H75B 0.9900 . ?
 C75 C76 1.43(3) . ?
 C76 H76A 0.9900 . ?
 C76 H76B 0.9900 . ?
 C76 C77 1.500(18) . ?
 C77 H77A 0.9900 . ?
 C77 H77B 0.9900 . ?
 C77 C78 1.76(3) . ?
 C78 H78A 0.9800 . ?
 C78 H78B 0.9800 . ?
 C78 H78C 0.9800 . ?

loop_
  _geom_angle_atom_site_label_1
  _geom_angle_atom_site_label_2
  _geom_angle_atom_site_label_3
  _geom_angle
  _geom_angle_site_symmetry_1
  _geom_angle_site_symmetry_3
  _geom_angle_publ_flag
 Ge2 Ge1 Ge3 62.65(13) . . ?
 N1 Ge1 Ge2 151.7(2) . . ?
 N1 Ge1 Ge3 145.7(2) . . ?
 Ge1 Ge2 Ge3 61.76(11) . . ?
 N2 Ge2 Ge1 148.5(2) . . ?
 N2 Ge2 Ge3 149.6(2) . . ?
 Ge1 Ge3 Ge2 55.58(12) . . ?
 Ge4 Ge3 Ge1 134.86(15) . . ?
 Ge4 Ge3 Ge2 148.8(2) . . ?
 Ge5 Ge3 Ge1 148.7(2) . . ?
 Ge5 Ge3 Ge2 134.86(15) . . ?
 Ge5 Ge3 Ge4 56.32(14) . . ?
 Ge5 Ge4 Ge3 61.78(14) . . ?
 N4 Ge4 Ge3 147.8(2) . . ?
 N4 Ge4 Ge5 150.4(2) . . ?
 Ge4 Ge5 Ge3 61.90(14) . . ?
 N3 Ge5 Ge3 147.4(2) . . ?
 N3 Ge5 Ge4 150.7(2) . . ?
 Ge7 Ge6 Ge8 62.8(7) . . ?
 N3 Ge6 Ge7 151.7(9) . . ?
 N3 Ge6 Ge8 143.8(9) . . ?
 Ge6 Ge7 Ge8 63.2(7) . . ?
 Ge6 Ge7 Si5 126.9(9) . . ?
 Ge8 Ge7 Si5 154.2(7) . . ?
 N4 Ge7 Ge6 146.3(11) . . ?
 N4 Ge7 Ge8 147.4(11) . . ?
 N4 Ge7 Si5 36.9(4) . . ?
 Ge7 Ge8 Ge6 54.0(7) . . ?
 Ge9 Ge8 Ge6 148.5(9) . . ?
 Ge9 Ge8 Ge7 134.2(7) . . ?
 Ge10 Ge8 Ge6 135.9(7) . . ?
 Ge10 Ge8 Ge7 150.3(10) . . ?
 Ge10 Ge8 Ge9 56.7(5) . . ?
 Ge8 Ge9 Si1 150.1(7) . . ?
 Ge8 Ge9 Si2 121.3(7) . . ?
 Ge10 Ge9 Ge8 61.2(6) . . ?
 Ge10 Ge9 Si1 122.6(7) . . ?
 Ge10 Ge9 Si2 146.0(9) . . ?
 Si1 Ge9 Si2 73.7(8) . . ?
 N1 Ge9 Ge8 149.6(9) . . ?
 N1 Ge9 Ge10 148.7(9) . . ?
 N1 Ge9 Si1 38.4(6) . . ?
 N1 Ge9 Si2 35.3(4) . . ?
 Ge9 Ge10 Ge8 62.1(5) . . ?
 N2 Ge10 Ge8 142.5(9) . . ?
 N2 Ge10 Ge9 155.3(10) . . ?
 N1 Si1 Ge9 32.9(4) . . ?
 N1 Si1 C11 112.6(2) . . ?
 N1 Si1 C14 106.0(2) . . ?
 N1 Si1 C17 107.1(2) . . ?
 C11 Si1 Ge9 145.0(5) . . ?
 C11 Si1 C14 110.2(3) . . ?
 C11 Si1 C17 111.1(3) . . ?
 C14 Si1 Ge9 91.8(5) . . ?
 C17 Si1 Ge9 84.8(3) . . ?
 C17 Si1 C14 109.7(3) . . ?
 N1 Si2 Ge9 30.6(5) . . ?
 N1 Si2 C2 106.9(3) . . ?
 N1 Si2 C5 112.8(2) . . ?
 N1 Si2 C8 112.4(3) . . ?
 C2 Si2 Ge9 83.7(6) . . ?
 C2 Si2 C5 105.9(3) . . ?
 C5 Si2 Ge9 101.6(3) . . ?
 C8 Si2 Ge9 141.8(5) . . ?
 C8 Si2 C2 113.0(3) . . ?
 C8 Si2 C5 105.8(3) . . ?
 N2 Si3 C20 105.8(2) . . ?
 N2 Si3 C23 108.3(2) . . ?
 N2 Si3 C26 112.7(3) . . ?
 C23 Si3 C20 108.8(3) . . ?
 C26 Si3 C20 109.0(3) . . ?
 C26 Si3 C23 111.9(3) . . ?
 N2 Si4 C29 113.5(3) . . ?
 N2 Si4 C32 107.2(3) . . ?
 N2 Si4 C35 111.7(2) . . ?
 C32 Si4 C29 111.7(3) . . ?
 C35 Si4 C29 106.5(3) . . ?
 C35 Si4 C32 106.0(3) . . ?
 N4 Si5 Ge7 38.8(5) . . ?
 N4 Si5 C65 112.8(2) . . ?
 N4 Si5 C68 105.0(2) . . ?
 N4 Si5 C71 108.0(2) . . ?
 C65 Si5 Ge7 150.5(4) . . ?
 C68 Si5 Ge7 89.4(5) . . ?
 C68 Si5 C65 110.7(3) . . ?
 C71 Si5 Ge7 80.5(6) . . ?
 C71 Si5 C65 110.7(3) . . ?
 C71 Si5 C68 109.4(3) . . ?
 N4 Si6 C56 113.5(2) . . ?
 N4 Si6 C59 106.8(2) . . ?
 N4 Si6 C62 112.6(2) . . ?
 C56 Si6 C62 105.2(3) . . ?
 C59 Si6 C56 112.4(3) . . ?
 C59 Si6 C62 106.1(3) . . ?
 N3 Si7 C44 112.4(2) . . ?
 N3 Si7 C47 106.4(3) . . ?
 N3 Si7 C50 114.0(3) . . ?
 C47 Si7 C44 106.1(3) . . ?
 C47 Si7 C50 112.1(3) . . ?
 C50 Si7 C44 105.8(3) . . ?
 N3 Si8 C38 107.7(2) . . ?
 N3 Si8 C41 112.9(2) . . ?
 N3 Si8 C53 105.5(3) . . ?
 C41 Si8 C38 111.9(3) . . ?
 C41 Si8 C53 109.6(3) . . ?
 C53 Si8 C38 108.9(3) . . ?
 Ge9 N1 Si1 108.7(6) . . ?
 Ge9 N1 Si2 114.1(6) . . ?
 Si1 N1 Ge1 109.9(2) . . ?
 Si2 N1 Ge1 112.9(2) . . ?
 Si2 N1 Si1 137.2(3) . . ?
 Si3 N2 Ge2 110.6(3) . . ?
 Si3 N2 Ge10 108.0(5) . . ?
 Si3 N2 Si4 137.2(3) . . ?
 Si4 N2 Ge2 112.2(3) . . ?
 Si4 N2 Ge10 114.5(5) . . ?
 Si7 N3 Ge5 114.1(3) . . ?
 Si7 N3 Ge6 107.7(7) . . ?
 Si7 N3 Si8 136.7(3) . . ?
 Si8 N3 Ge5 109.2(2) . . ?
 Si8 N3 Ge6 115.5(7) . . ?
 Si5 N4 Ge4 111.1(2) . . ?
 Si5 N4 Ge7 104.3(7) . . ?
 Si5 N4 Si6 136.8(2) . . ?
 Si6 N4 Ge4 112.1(2) . . ?
 Si6 N4 Ge7 118.6(7) . . ?
 H1A C1 H1B 109.5 . . ?
 H1A C1 H1C 109.5 . . ?
 H1B C1 H1C 109.5 . . ?
 C2 C1 H1A 109.5 . . ?
 C2 C1 H1B 109.5 . . ?
 C2 C1 H1C 109.5 . . ?
 Si2 C2 H2 105.0 . . ?
 C1 C2 Si2 116.1(5) . . ?
 C1 C2 H2 105.0 . . ?
 C1 C2 C3 110.4(6) . . ?
 C3 C2 Si2 114.2(5) . . ?
 C3 C2 H2 105.0 . . ?
 C2 C3 H3A 109.5 . . ?
 C2 C3 H3B 109.5 . . ?
 C2 C3 H3C 109.5 . . ?
 H3A C3 H3B 109.5 . . ?
 H3A C3 H3C 109.5 . . ?
 H3B C3 H3C 109.5 . . ?
 H4A C4 H4B 109.5 . . ?
 H4A C4 H4C 109.5 . . ?
 H4B C4 H4C 109.5 . . ?
 C5 C4 H4A 109.5 . . ?
 C5 C4 H4B 109.5 . . ?
 C5 C4 H4C 109.5 . . ?
 Si2 C5 H5 105.8 . . ?
 C4 C5 Si2 114.1(5) . . ?
 C4 C5 H5 105.8 . . ?
 C4 C5 C6 109.6(6) . . ?
 C6 C5 Si2 115.0(4) . . ?
 C6 C5 H5 105.8 . . ?
 C5 C6 H6A 109.5 . . ?
 C5 C6 H6B 109.5 . . ?
 C5 C6 H6C 109.5 . . ?
 H6A C6 H6B 109.5 . . ?
 H6A C6 H6C 109.5 . . ?
 H6B C6 H6C 109.5 . . ?
 H7A C7 H7B 109.5 . . ?
 H7A C7 H7C 109.5 . . ?
 H7B C7 H7C 109.5 . . ?
 C8 C7 H7A 109.5 . . ?
 C8 C7 H7B 109.5 . . ?
 C8 C7 H7C 109.5 . . ?
 Si2 C8 H8 107.0 . . ?
 C7 C8 Si2 113.0(5) . . ?
 C7 C8 H8 107.0 . . ?
 C7 C8 C9 108.8(6) . . ?
 C9 C8 Si2 113.7(6) . . ?
 C9 C8 H8 107.0 . . ?
 C8 C9 H9A 109.5 . . ?
 C8 C9 H9B 109.5 . . ?
 C8 C9 H9C 109.5 . . ?
 H9A C9 H9B 109.5 . . ?
 H9A C9 H9C 109.5 . . ?
 H9B C9 H9C 109.5 . . ?
 H10A C10 H10B 109.5 . . ?
 H10A C10 H10C 109.5 . . ?
 H10B C10 H10C 109.5 . . ?
 C11 C10 H10A 109.5 . . ?
 C11 C10 H10B 109.5 . . ?
 C11 C10 H10C 109.5 . . ?
 Si1 C11 H11 106.6 . . ?
 C10 C11 Si1 114.3(4) . . ?
 C10 C11 H11 106.6 . . ?
 C10 C11 C12 108.3(5) . . ?
 C12 C11 Si1 113.9(5) . . ?
 C12 C11 H11 106.6 . . ?
 C11 C12 H12A 109.5 . . ?
 C11 C12 H12B 109.5 . . ?
 C11 C12 H12C 109.5 . . ?
 H12A C12 H12B 109.5 . . ?
 H12A C12 H12C 109.5 . . ?
 H12B C12 H12C 109.5 . . ?
 H13A C13 H13B 109.5 . . ?
 H13A C13 H13C 109.5 . . ?
 H13B C13 H13C 109.5 . . ?
 C14 C13 H13A 109.5 . . ?
 C14 C13 H13B 109.5 . . ?
 C14 C13 H13C 109.5 . . ?
 Si1 C14 H14 105.6 . . ?
 C13 C14 Si1 111.7(4) . . ?
 C13 C14 H14 105.6 . . ?
 C13 C14 C15 110.3(5) . . ?
 C15 C14 Si1 117.0(4) . . ?
 C15 C14 H14 105.6 . . ?
 C14 C15 H15A 109.5 . . ?
 C14 C15 H15B 109.5 . . ?
 C14 C15 H15C 109.5 . . ?
 H15A C15 H15B 109.5 . . ?
 H15A C15 H15C 109.5 . . ?
 H15B C15 H15C 109.5 . . ?
 H16A C16 H16B 109.5 . . ?
 H16A C16 H16C 109.5 . . ?
 H16B C16 H16C 109.5 . . ?
 C17 C16 H16A 109.5 . . ?
 C17 C16 H16B 109.5 . . ?
 C17 C16 H16C 109.5 . . ?
 Si1 C17 H17 106.0 . . ?
 C16 C17 Si1 115.8(4) . . ?
 C16 C17 H17 106.0 . . ?
 C18 C17 Si1 113.6(4) . . ?
 C18 C17 C16 108.7(5) . . ?
 C18 C17 H17 106.0 . . ?
 C17 C18 H18A 109.5 . . ?
 C17 C18 H18B 109.5 . . ?
 C17 C18 H18C 109.5 . . ?
 H18A C18 H18B 109.5 . . ?
 H18A C18 H18C 109.5 . . ?
 H18B C18 H18C 109.5 . . ?
 H19A C19 H19B 109.5 . . ?
 H19A C19 H19C 109.5 . . ?
 H19B C19 H19C 109.5 . . ?
 C20 C19 H19A 109.5 . . ?
 C20 C19 H19B 109.5 . . ?
 C20 C19 H19C 109.5 . . ?
 Si3 C20 H20 105.2 . . ?
 C19 C20 Si3 118.7(5) . . ?
 C19 C20 H20 105.2 . . ?
 C19 C20 C21 110.5(6) . . ?
 C21 C20 Si3 110.9(5) . . ?
 C21 C20 H20 105.2 . . ?
 C20 C21 H21A 109.5 . . ?
 C20 C21 H21B 109.5 . . ?
 C20 C21 H21C 109.5 . . ?
 H21A C21 H21B 109.5 . . ?
 H21A C21 H21C 109.5 . . ?
 H21B C21 H21C 109.5 . . ?
 H22A C22 H22B 109.5 . . ?
 H22A C22 H22C 109.5 . . ?
 H22B C22 H22C 109.5 . . ?
 C23 C22 H22A 109.5 . . ?
 C23 C22 H22B 109.5 . . ?
 C23 C22 H22C 109.5 . . ?
 Si3 C23 H23 106.5 . . ?
 C22 C23 Si3 115.5(4) . . ?
 C22 C23 H23 106.5 . . ?
 C24 C23 Si3 113.4(4) . . ?
 C24 C23 C22 107.9(5) . . ?
 C24 C23 H23 106.5 . . ?
 C23 C24 H24A 109.5 . . ?
 C23 C24 H24B 109.5 . . ?
 C23 C24 H24C 109.5 . . ?
 H24A C24 H24B 109.5 . . ?
 H24A C24 H24C 109.5 . . ?
 H24B C24 H24C 109.5 . . ?
 H25A C25 H25B 109.5 . . ?
 H25A C25 H25C 109.5 . . ?
 H25B C25 H25C 109.5 . . ?
 C26 C25 H25A 109.5 . . ?
 C26 C25 H25B 109.5 . . ?
 C26 C25 H25C 109.5 . . ?
 Si3 C26 H26 106.2 . . ?
 C25 C26 Si3 114.1(5) . . ?
 C25 C26 H26 106.2 . . ?
 C25 C26 C27 108.5(5) . . ?
 C27 C26 Si3 114.9(4) . . ?
 C27 C26 H26 106.2 . . ?
 C26 C27 H27A 109.5 . . ?
 C26 C27 H27B 109.5 . . ?
 C26 C27 H27C 109.5 . . ?
 H27A C27 H27B 109.5 . . ?
 H27A C27 H27C 109.5 . . ?
 H27B C27 H27C 109.5 . . ?
 H28A C28 H28B 109.5 . . ?
 H28A C28 H28C 109.5 . . ?
 H28B C28 H28C 109.5 . . ?
 C29 C28 H28A 109.5 . . ?
 C29 C28 H28B 109.5 . . ?
 C29 C28 H28C 109.5 . . ?
 Si4 C29 H29 106.6 . . ?
 C28 C29 Si4 114.6(5) . . ?
 C28 C29 H29 106.6 . . ?
 C28 C29 C30 109.2(5) . . ?
 C30 C29 Si4 112.8(5) . . ?
 C30 C29 H29 106.6 . . ?
 C29 C30 H30A 109.5 . . ?
 C29 C30 H30B 109.5 . . ?
 C29 C30 H30C 109.5 . . ?
 H30A C30 H30B 109.5 . . ?
 H30A C30 H30C 109.5 . . ?
 H30B C30 H30C 109.5 . . ?
 H31A C31 H31B 109.5 . . ?
 H31A C31 H31C 109.5 . . ?
 H31B C31 H31C 109.5 . . ?
 C32 C31 H31A 109.5 . . ?
 C32 C31 H31B 109.5 . . ?
 C32 C31 H31C 109.5 . . ?
 Si4 C32 H32 104.9 . . ?
 C31 C32 Si4 114.6(5) . . ?
 C31 C32 H32 104.9 . . ?
 C33 C32 Si4 116.4(4) . . ?
 C33 C32 C31 110.0(5) . . ?
 C33 C32 H32 104.9 . . ?
 C32 C33 H33A 109.5 . . ?
 C32 C33 H33B 109.5 . . ?
 C32 C33 H33C 109.5 . . ?
 H33A C33 H33B 109.5 . . ?
 H33A C33 H33C 109.5 . . ?
 H33B C33 H33C 109.5 . . ?
 H34A C34 H34B 109.5 . . ?
 H34A C34 H34C 109.5 . . ?
 H34B C34 H34C 109.5 . . ?
 C35 C34 H34A 109.5 . . ?
 C35 C34 H34B 109.5 . . ?
 C35 C34 H34C 109.5 . . ?
 Si4 C35 H35 106.3 . . ?
 C34 C35 Si4 114.0(4) . . ?
 C34 C35 H35 106.3 . . ?
 C36 C35 Si4 114.6(4) . . ?
 C36 C35 C34 108.7(5) . . ?
 C36 C35 H35 106.3 . . ?
 C35 C36 H36A 109.5 . . ?
 C35 C36 H36B 109.5 . . ?
 C35 C36 H36C 109.5 . . ?
 H36A C36 H36B 109.5 . . ?
 H36A C36 H36C 109.5 . . ?
 H36B C36 H36C 109.5 . . ?
 H37A C37 H37B 109.5 . . ?
 H37A C37 H37C 109.5 . . ?
 H37B C37 H37C 109.5 . . ?
 C38 C37 H37A 109.5 . . ?
 C38 C37 H37B 109.5 . . ?
 C38 C37 H37C 109.5 . . ?
 Si8 C38 H38 106.4 . . ?
 C37 C38 Si8 113.7(4) . . ?
 C37 C38 H38 106.4 . . ?
 C37 C38 C39 108.4(5) . . ?
 C39 C38 Si8 114.9(4) . . ?
 C39 C38 H38 106.4 . . ?
 C38 C39 H39A 109.5 . . ?
 C38 C39 H39B 109.5 . . ?
 C38 C39 H39C 109.5 . . ?
 H39A C39 H39B 109.5 . . ?
 H39A C39 H39C 109.5 . . ?
 H39B C39 H39C 109.5 . . ?
 H40A C40 H40B 109.5 . . ?
 H40A C40 H40C 109.5 . . ?
 H40B C40 H40C 109.5 . . ?
 C41 C40 H40A 109.5 . . ?
 C41 C40 H40B 109.5 . . ?
 C41 C40 H40C 109.5 . . ?
 Si8 C41 H41 106.2 . . ?
 C40 C41 Si8 114.4(4) . . ?
 C40 C41 H41 106.2 . . ?
 C42 C41 Si8 113.5(4) . . ?
 C42 C41 C40 109.5(5) . . ?
 C42 C41 H41 106.2 . . ?
 C41 C42 H42A 109.5 . . ?
 C41 C42 H42B 109.5 . . ?
 C41 C42 H42C 109.5 . . ?
 H42A C42 H42B 109.5 . . ?
 H42A C42 H42C 109.5 . . ?
 H42B C42 H42C 109.5 . . ?
 H43A C43 H43B 109.5 . . ?
 H43A C43 H43C 109.5 . . ?
 H43B C43 H43C 109.5 . . ?
 C44 C43 H43A 109.5 . . ?
 C44 C43 H43B 109.5 . . ?
 C44 C43 H43C 109.5 . . ?
 Si7 C44 H44 106.1 . . ?
 C43 C44 Si7 113.7(4) . . ?
 C43 C44 H44 106.1 . . ?
 C43 C44 C45 109.8(5) . . ?
 C45 C44 Si7 114.2(4) . . ?
 C45 C44 H44 106.1 . . ?
 C44 C45 H45A 109.5 . . ?
 C44 C45 H45B 109.5 . . ?
 C44 C45 H45C 109.5 . . ?
 H45A C45 H45B 109.5 . . ?
 H45A C45 H45C 109.5 . . ?
 H45B C45 H45C 109.5 . . ?
 H46A C46 H46B 109.5 . . ?
 H46A C46 H46C 109.5 . . ?
 H46B C46 H46C 109.5 . . ?
 C47 C46 H46A 109.5 . . ?
 C47 C46 H46B 109.5 . . ?
 C47 C46 H46C 109.5 . . ?
 Si7 C47 H47 104.9 . . ?
 C46 C47 Si7 115.1(5) . . ?
 C46 C47 H47 104.9 . . ?
 C46 C47 C48 109.3(6) . . ?
 C48 C47 Si7 116.4(5) . . ?
 C48 C47 H47 104.9 . . ?
 C47 C48 H48A 109.5 . . ?
 C47 C48 H48B 109.5 . . ?
 C47 C48 H48C 109.5 . . ?
 H48A C48 H48B 109.5 . . ?
 H48A C48 H48C 109.5 . . ?
 H48B C48 H48C 109.5 . . ?
 H49A C49 H49B 109.5 . . ?
 H49A C49 H49C 109.5 . . ?
 H49B C49 H49C 109.5 . . ?
 C50 C49 H49A 109.5 . . ?
 C50 C49 H49B 109.5 . . ?
 C50 C49 H49C 109.5 . . ?
 Si7 C50 H50 106.3 . . ?
 C49 C50 Si7 113.4(4) . . ?
 C49 C50 H50 106.3 . . ?
 C51 C50 Si7 115.0(4) . . ?
 C51 C50 C49 108.8(5) . . ?
 C51 C50 H50 106.3 . . ?
 C50 C51 H51A 109.5 . . ?
 C50 C51 H51B 109.5 . . ?
 C50 C51 H51C 109.5 . . ?
 H51A C51 H51B 109.5 . . ?
 H51A C51 H51C 109.5 . . ?
 H51B C51 H51C 109.5 . . ?
 H52A C52 H52B 109.5 . . ?
 H52A C52 H52C 109.5 . . ?
 H52B C52 H52C 109.5 . . ?
 C53 C52 H52A 109.5 . . ?
 C53 C52 H52B 109.5 . . ?
 C53 C52 H52C 109.5 . . ?
 Si8 C53 H53 105.2 . . ?
 C52 C53 Si8 110.9(4) . . ?
 C52 C53 H53 105.2 . . ?
 C54 C53 Si8 117.4(4) . . ?
 C54 C53 C52 111.7(5) . . ?
 C54 C53 H53 105.2 . . ?
 C53 C54 H54A 109.5 . . ?
 C53 C54 H54B 109.5 . . ?
 C53 C54 H54C 109.5 . . ?
 H54A C54 H54B 109.5 . . ?
 H54A C54 H54C 109.5 . . ?
 H54B C54 H54C 109.5 . . ?
 H55A C55 H55B 109.5 . . ?
 H55A C55 H55C 109.5 . . ?
 H55B C55 H55C 109.5 . . ?
 C56 C55 H55A 109.5 . . ?
 C56 C55 H55B 109.5 . . ?
 C56 C55 H55C 109.5 . . ?
 Si6 C56 H56 106.4 . . ?
 C55 C56 Si6 115.1(5) . . ?
 C55 C56 H56 106.4 . . ?
 C55 C56 C57 110.0(6) . . ?
 C57 C56 Si6 112.1(5) . . ?
 C57 C56 H56 106.4 . . ?
 C56 C57 H57A 109.5 . . ?
 C56 C57 H57B 109.5 . . ?
 C56 C57 H57C 109.5 . . ?
 H57A C57 H57B 109.5 . . ?
 H57A C57 H57C 109.5 . . ?
 H57B C57 H57C 109.5 . . ?
 H58A C58 H58B 109.5 . . ?
 H58A C58 H58C 109.5 . . ?
 H58B C58 H58C 109.5 . . ?
 C59 C58 H58A 109.5 . . ?
 C59 C58 H58B 109.5 . . ?
 C59 C58 H58C 109.5 . . ?
 Si6 C59 H59 105.1 . . ?
 C58 C59 Si6 115.5(4) . . ?
 C58 C59 H59 105.1 . . ?
 C58 C59 C60 110.2(5) . . ?
 C60 C59 Si6 114.7(4) . . ?
 C60 C59 H59 105.1 . . ?
 C59 C60 H60A 109.5 . . ?
 C59 C60 H60B 109.5 . . ?
 C59 C60 H60C 109.5 . . ?
 H60A C60 H60B 109.5 . . ?
 H60A C60 H60C 109.5 . . ?
 H60B C60 H60C 109.5 . . ?
 H61A C61 H61B 109.5 . . ?
 H61A C61 H61C 109.5 . . ?
 H61B C61 H61C 109.5 . . ?
 C62 C61 H61A 109.5 . . ?
 C62 C61 H61B 109.5 . . ?
 C62 C61 H61C 109.5 . . ?
 Si6 C62 H62 106.4 . . ?
 C61 C62 Si6 114.6(4) . . ?
 C61 C62 H62 106.4 . . ?
 C61 C62 C63 109.2(5) . . ?
 C63 C62 Si6 113.2(4) . . ?
 C63 C62 H62 106.4 . . ?
 C62 C63 H63A 109.5 . . ?
 C62 C63 H63B 109.5 . . ?
 C62 C63 H63C 109.5 . . ?
 H63A C63 H63B 109.5 . . ?
 H63A C63 H63C 109.5 . . ?
 H63B C63 H63C 109.5 . . ?
 H64A C64 H64B 109.5 . . ?
 H64A C64 H64C 109.5 . . ?
 H64B C64 H64C 109.5 . . ?
 C65 C64 H64A 109.5 . . ?
 C65 C64 H64B 109.5 . . ?
 C65 C64 H64C 109.5 . . ?
 Si5 C65 H65 106.5 . . ?
 C64 C65 Si5 112.9(5) . . ?
 C64 C65 H65 106.5 . . ?
 C66 C65 Si5 114.6(4) . . ?
 C66 C65 C64 109.4(5) . . ?
 C66 C65 H65 106.5 . . ?
 C65 C66 H66A 109.5 . . ?
 C65 C66 H66B 109.5 . . ?
 C65 C66 H66C 109.5 . . ?
 H66A C66 H66B 109.5 . . ?
 H66A C66 H66C 109.5 . . ?
 H66B C66 H66C 109.5 . . ?
 H67A C67 H67B 109.5 . . ?
 H67A C67 H67C 109.5 . . ?
 H67B C67 H67C 109.5 . . ?
 C68 C67 H67A 109.5 . . ?
 C68 C67 H67B 109.5 . . ?
 C68 C67 H67C 109.5 . . ?
 Si5 C68 H68 105.3 . . ?
 C67 C68 Si5 112.0(5) . . ?
 C67 C68 H68 105.3 . . ?
 C69 C68 Si5 116.7(5) . . ?
 C69 C68 C67 111.1(6) . . ?
 C69 C68 H68 105.3 . . ?
 C68 C69 H69A 109.5 . . ?
 C68 C69 H69B 109.5 . . ?
 C68 C69 H69C 109.5 . . ?
 H69A C69 H69B 109.5 . . ?
 H69A C69 H69C 109.5 . . ?
 H69B C69 H69C 109.5 . . ?
 H70A C70 H70B 109.5 . . ?
 H70A C70 H70C 109.5 . . ?
 H70B C70 H70C 109.5 . . ?
 C71 C70 H70A 109.5 . . ?
 C71 C70 H70B 109.5 . . ?
 C71 C70 H70C 109.5 . . ?
 Si5 C71 H71 106.2 . . ?
 C70 C71 Si5 115.2(5) . . ?
 C70 C71 H71 106.2 . . ?
 C72 C71 Si5 113.1(4) . . ?
 C72 C71 C70 109.2(6) . . ?
 C72 C71 H71 106.2 . . ?
 C71 C72 H72A 109.5 . . ?
 C71 C72 H72B 109.5 . . ?
 C71 C72 H72C 109.5 . . ?
 H72A C72 H72B 109.5 . . ?
 H72A C72 H72C 109.5 . . ?
 H72B C72 H72C 109.5 . . ?
 H73A C73 H73B 109.5 . . ?
 H73A C73 H73C 109.5 . . ?
 H73B C73 H73C 109.5 . . ?
 C74 C73 H73A 109.5 . . ?
 C74 C73 H73B 109.5 . . ?
 C74 C73 H73C 109.5 . . ?
 C73 C74 H74A 109.3 . . ?
 C73 C74 H74B 109.3 . . ?
 C73 C74 C75 111.7(18) . . ?
 H74A C74 H74B 107.9 . . ?
 C75 C74 H74A 109.3 . . ?
 C75 C74 H74B 109.3 . . ?
 C74 C75 H75A 109.1 . . ?
 C74 C75 H75B 109.1 . . ?
 H75A C75 H75B 107.8 . . ?
 C76 C75 C74 112(2) . . ?
 C76 C75 H75A 109.1 . . ?
 C76 C75 H75B 109.1 . . ?
 C75 C76 H76A 104.9 . . ?
 C75 C76 H76B 104.9 . . ?
 C75 C76 C77 130(2) . . ?
 H76A C76 H76B 105.8 . . ?
 C77 C76 H76A 104.9 . . ?
 C77 C76 H76B 104.9 . . ?
 C76 C77 H77A 101.3 . . ?
 C76 C77 H77B 101.3 . . ?
 C76 C77 C78 143(2) . . ?
 H77A C77 H77B 104.5 . . ?
 C78 C77 H77A 101.3 . . ?
 C78 C77 H77B 101.3 . . ?
 C77 C78 H78A 109.5 . . ?
 C77 C78 H78B 109.5 . . ?
 C77 C78 H78C 109.5 . . ?
 H78A C78 H78B 109.5 . . ?
 H78A C78 H78C 109.5 . . ?
 H78B C78 H78C 109.5 . . ?

loop_
  _geom_torsion_atom_site_label_1
  _geom_torsion_atom_site_label_2
  _geom_torsion_atom_site_label_3
  _geom_torsion_atom_site_label_4
  _geom_torsion
  _geom_torsion_site_symmetry_1
  _geom_torsion_site_symmetry_2
  _geom_torsion_site_symmetry_3
  _geom_torsion_site_symmetry_4
  _geom_torsion_publ_flag
 Ge1 Ge2 N2 Si3 -64.8(5) . . . . ?
 Ge1 Ge2 N2 Si4 115.8(4) . . . . ?
 Ge3 Ge2 N2 Si3 123.2(4) . . . . ?
 Ge3 Ge2 N2 Si4 -56.3(5) . . . . ?
 Ge3 Ge5 N3 Si7 -53.4(5) . . . . ?
 Ge3 Ge5 N3 Si8 124.6(3) . . . . ?
 Ge4 Ge5 N3 Si7 121.1(4) . . . . ?
 Ge4 Ge5 N3 Si8 -60.9(5) . . . . ?
 Ge6 Ge7 N4 Si5 -78.6(18) . . . . ?
 Ge6 Ge7 N4 Si6 106.2(16) . . . . ?
 Ge7 Si5 N4 Si6 173.9(10) . . . . ?
 Ge7 Si5 C71 C70 163.1(7) . . . . ?
 Ge7 Si5 C71 C72 -70.3(6) . . . . ?
 Ge8 Ge7 N4 Si5 134.5(15) . . . . ?
 Ge8 Ge7 N4 Si6 -41(2) . . . . ?
 Ge8 Ge9 N1 Si1 127.3(17) . . . . ?
 Ge8 Ge9 N1 Si2 -51(2) . . . . ?
 Ge9 Si1 N1 Si2 177.5(9) . . . . ?
 Ge9 Si1 C11 C10 65.2(9) . . . . ?
 Ge9 Si1 C11 C12 -169.6(7) . . . . ?
 Ge9 Si1 C14 C13 100.4(5) . . . . ?
 Ge9 Si1 C14 C15 -131.2(6) . . . . ?
 Ge9 Si1 C17 C16 165.1(7) . . . . ?
 Ge9 Si1 C17 C18 -68.1(6) . . . . ?
 Ge9 Si2 N1 Si1 -177.5(9) . . . . ?
 Ge9 Si2 C2 C1 -73.8(6) . . . . ?
 Ge9 Si2 C2 C3 155.9(6) . . . . ?
 Ge9 Si2 C8 C7 -174.4(9) . . . . ?
 Ge9 Si2 C8 C9 60.9(10) . . . . ?
 Ge10 Ge9 N1 Si1 -65.9(19) . . . . ?
 Ge10 Ge9 N1 Si2 115.9(17) . . . . ?
 Si1 Ge9 N1 Si2 -178.2(7) . . . . ?
 Si2 Ge9 N1 Si1 178.2(7) . . . . ?
 Si5 Ge7 N4 Si6 -175.2(8) . . . . ?
 N1 Si1 C11 C10 72.7(5) . . . . ?
 N1 Si1 C11 C12 -162.1(5) . . . . ?
 N1 Si1 C14 C13 70.2(5) . . . . ?
 N1 Si1 C14 C15 -161.3(4) . . . . ?
 N1 Si1 C17 C16 -170.4(5) . . . . ?
 N1 Si1 C17 C18 -43.6(5) . . . . ?
 N1 Si2 C2 C1 -53.6(5) . . . . ?
 N1 Si2 C2 C3 176.1(5) . . . . ?
 N1 Si2 C8 C7 -163.6(6) . . . . ?
 N1 Si2 C8 C9 71.7(6) . . . . ?
 N2 Si3 C26 C25 -161.0(4) . . . . ?
 N2 Si3 C26 C27 72.8(5) . . . . ?
 N2 Si4 C29 C28 73.2(5) . . . . ?
 N2 Si4 C29 C30 -161.1(5) . . . . ?
 N2 Si4 C32 C31 175.9(5) . . . . ?
 N2 Si4 C32 C33 -53.9(5) . . . . ?
 N2 Si4 C35 C34 63.7(5) . . . . ?
 N2 Si4 C35 C36 -62.5(5) . . . . ?
 N3 Si7 C47 C46 177.1(5) . . . . ?
 N3 Si7 C47 C48 -53.0(5) . . . . ?
 N3 Si7 C50 C49 -162.4(5) . . . . ?
 N3 Si7 C50 C51 71.4(6) . . . . ?
 N4 Si5 C71 C70 -169.1(5) . . . . ?
 N4 Si5 C71 C72 -42.5(5) . . . . ?
 N4 Si6 C59 C58 -56.6(5) . . . . ?
 N4 Si6 C59 C60 173.6(4) . . . . ?
 C2 Si2 N1 Ge1 -37.9(3) . . . . ?
 C2 Si2 N1 Ge9 -42.3(8) . . . . ?
 C2 Si2 N1 Si1 140.2(4) . . . . ?
 C2 Si2 C8 C7 75.3(7) . . . . ?
 C2 Si2 C8 C9 -49.4(6) . . . . ?
 C5 Si2 N1 Ge1 78.1(3) . . . . ?
 C5 Si2 N1 Ge9 73.6(8) . . . . ?
 C5 Si2 N1 Si1 -103.8(4) . . . . ?
 C5 Si2 C2 C1 -174.1(5) . . . . ?
 C5 Si2 C2 C3 55.6(5) . . . . ?
 C5 Si2 C8 C7 -40.1(7) . . . . ?
 C5 Si2 C8 C9 -164.7(5) . . . . ?
 C8 Si2 N1 Ge1 -162.4(3) . . . . ?
 C8 Si2 N1 Ge9 -166.8(8) . . . . ?
 C8 Si2 N1 Si1 15.7(5) . . . . ?
 C8 Si2 C2 C1 70.5(6) . . . . ?
 C8 Si2 C2 C3 -59.7(6) . . . . ?
 C11 Si1 N1 Ge1 -176.3(3) . . . . ?
 C11 Si1 N1 Ge9 -172.0(7) . . . . ?
 C11 Si1 N1 Si2 5.5(5) . . . . ?
 C11 Si1 C14 C13 -51.9(5) . . . . ?
 C11 Si1 C14 C15 76.6(5) . . . . ?
 C11 Si1 C17 C16 -47.0(6) . . . . ?
 C11 Si1 C17 C18 79.8(5) . . . . ?
 C14 Si1 N1 Ge1 63.2(3) . . . . ?
 C14 Si1 N1 Ge9 67.5(7) . . . . ?
 C14 Si1 N1 Si2 -115.0(4) . . . . ?
 C14 Si1 C11 C10 -169.2(5) . . . . ?
 C14 Si1 C11 C12 -44.0(6) . . . . ?
 C14 Si1 C17 C16 75.1(5) . . . . ?
 C14 Si1 C17 C18 -158.1(4) . . . . ?
 C17 Si1 N1 Ge1 -53.9(3) . . . . ?
 C17 Si1 N1 Ge9 -49.6(8) . . . . ?
 C17 Si1 N1 Si2 127.9(4) . . . . ?
 C17 Si1 C11 C10 -47.3(5) . . . . ?
 C17 Si1 C11 C12 77.9(5) . . . . ?
 C17 Si1 C14 C13 -174.5(4) . . . . ?
 C17 Si1 C14 C15 -46.0(5) . . . . ?
 C20 Si3 N2 Ge2 64.7(3) . . . . ?
 C20 Si3 N2 Ge10 57.7(7) . . . . ?
 C20 Si3 N2 Si4 -116.1(4) . . . . ?
 C20 Si3 C26 C25 -43.8(6) . . . . ?
 C20 Si3 C26 C27 -170.0(5) . . . . ?
 C23 Si3 N2 Ge2 -51.9(3) . . . . ?
 C23 Si3 N2 Ge10 -58.9(8) . . . . ?
 C23 Si3 N2 Si4 127.3(4) . . . . ?
 C23 Si3 C26 C25 76.7(5) . . . . ?
 C23 Si3 C26 C27 -49.6(6) . . . . ?
 C26 Si3 N2 Ge2 -176.3(3) . . . . ?
 C26 Si3 N2 Ge10 176.8(7) . . . . ?
 C26 Si3 N2 Si4 3.0(5) . . . . ?
 C29 Si4 N2 Ge2 -165.3(3) . . . . ?
 C29 Si4 N2 Ge10 -158.0(8) . . . . ?
 C29 Si4 N2 Si3 15.5(5) . . . . ?
 C29 Si4 C32 C31 -59.2(6) . . . . ?
 C29 Si4 C32 C33 71.1(5) . . . . ?
 C29 Si4 C35 C34 -60.7(5) . . . . ?
 C29 Si4 C35 C36 173.1(4) . . . . ?
 C32 Si4 N2 Ge2 -41.4(3) . . . . ?
 C32 Si4 N2 Ge10 -34.1(8) . . . . ?
 C32 Si4 N2 Si3 139.4(4) . . . . ?
 C32 Si4 C29 C28 -48.2(6) . . . . ?
 C32 Si4 C29 C30 77.5(5) . . . . ?
 C32 Si4 C35 C34 -179.9(4) . . . . ?
 C32 Si4 C35 C36 53.9(5) . . . . ?
 C35 Si4 N2 Ge2 74.3(3) . . . . ?
 C35 Si4 N2 Ge10 81.6(8) . . . . ?
 C35 Si4 N2 Si3 -104.9(4) . . . . ?
 C35 Si4 C29 C28 -163.6(5) . . . . ?
 C35 Si4 C29 C30 -37.8(5) . . . . ?
 C35 Si4 C32 C31 56.5(5) . . . . ?
 C35 Si4 C32 C33 -173.3(4) . . . . ?
 C38 Si8 N3 Ge5 -49.9(3) . . . . ?
 C38 Si8 N3 Ge6 -56.7(7) . . . . ?
 C38 Si8 N3 Si7 127.4(4) . . . . ?
 C41 Si8 N3 Ge5 -174.0(3) . . . . ?
 C41 Si8 N3 Ge6 179.2(7) . . . . ?
 C41 Si8 N3 Si7 3.3(5) . . . . ?
 C44 Si7 N3 Ge5 74.3(3) . . . . ?
 C44 Si7 N3 Ge6 81.0(7) . . . . ?
 C44 Si7 N3 Si8 -102.9(4) . . . . ?
 C44 Si7 C47 C46 57.3(6) . . . . ?
 C44 Si7 C47 C48 -172.8(5) . . . . ?
 C44 Si7 C50 C49 -38.5(6) . . . . ?
 C44 Si7 C50 C51 -164.7(5) . . . . ?
 C47 Si7 N3 Ge5 -41.3(3) . . . . ?
 C47 Si7 N3 Ge6 -34.7(7) . . . . ?
 C47 Si7 N3 Si8 141.4(4) . . . . ?
 C47 Si7 C50 C49 76.7(6) . . . . ?
 C47 Si7 C50 C51 -49.5(6) . . . . ?
 C50 Si7 N3 Ge5 -165.4(3) . . . . ?
 C50 Si7 N3 Ge6 -158.7(7) . . . . ?
 C50 Si7 N3 Si8 17.4(5) . . . . ?
 C50 Si7 C47 C46 -57.7(6) . . . . ?
 C50 Si7 C47 C48 72.2(5) . . . . ?
 C53 Si8 N3 Ge5 66.3(3) . . . . ?
 C53 Si8 N3 Ge6 59.5(7) . . . . ?
 C53 Si8 N3 Si7 -116.4(4) . . . . ?
 C56 Si6 N4 Ge4 -163.2(3) . . . . ?
 C56 Si6 N4 Ge7 -170.7(9) . . . . ?
 C56 Si6 N4 Si5 16.1(5) . . . . ?
 C56 Si6 C59 C58 68.6(5) . . . . ?
 C56 Si6 C59 C60 -61.3(5) . . . . ?
 C59 Si6 N4 Ge4 -38.7(3) . . . . ?
 C59 Si6 N4 Ge7 -46.3(9) . . . . ?
 C59 Si6 N4 Si5 140.5(4) . . . . ?
 C62 Si6 N4 Ge4 77.4(3) . . . . ?
 C62 Si6 N4 Ge7 69.8(9) . . . . ?
 C62 Si6 N4 Si5 -103.4(4) . . . . ?
 C62 Si6 C59 C58 -176.9(4) . . . . ?
 C62 Si6 C59 C60 53.3(5) . . . . ?
 C65 Si5 N4 Ge4 -176.8(3) . . . . ?
 C65 Si5 N4 Ge7 -169.9(8) . . . . ?
 C65 Si5 N4 Si6 3.9(5) . . . . ?
 C65 Si5 C71 C70 -45.2(6) . . . . ?
 C65 Si5 C71 C72 81.5(5) . . . . ?
 C68 Si5 N4 Ge4 62.6(3) . . . . ?
 C68 Si5 N4 Ge7 69.4(8) . . . . ?
 C68 Si5 N4 Si6 -116.7(4) . . . . ?
 C68 Si5 C71 C70 77.1(6) . . . . ?
 C68 Si5 C71 C72 -156.3(5) . . . . ?
 C71 Si5 N4 Ge4 -54.1(3) . . . . ?
 C71 Si5 N4 Ge7 -47.3(8) . . . . ?
 C71 Si5 N4 Si6 126.6(4) . . . . ?
 C73 C74 C75 C76 -179.9(19) . . . . ?
 C74 C75 C76 C77 -180(2) . . . . ?
 C75 C76 C77 C78 174(2) . . . . ?

loop_
  _platon_missing_refln_index_h
  _platon_missing_refln_index_k
  _platon_missing_refln_index_l
  _platon_missing_refln_theta
 1 0 0 1.457
 -1 1 0 1.866
 0 1 0 1.226
 1 1 0 1.942
 -1 2 0 2.802
 0 2 0 2.453
 1 2 0 2.904
 0 -2 1 2.863
 -1 -1 1 2.394
 0 -1 1 1.744
 1 -1 1 2.145
 -1 0 1 1.856
 0 0 1 0.949
 1 0 1 1.614
 -1 1 1 2.042
 0 1 1 1.329
 1 1 1 1.902
 -1 2 1 2.811
 0 2 1 2.375
 1 2 1 2.763
 1 8 1 9.787
 0 -1 2 2.527
 1 -1 2 2.744
 -1 0 2 2.564
 0 0 2 1.899
 1 0 2 2.212
 -1 1 2 2.580
 0 1 2 1.958
 1 1 2 2.294
 0 2 2 2.660
 1 4 2 4.947
 3 5 2 7.339
 2 6 2 7.679
 4 6 2 9.213
 -1 -6 3 8.863
 0 0 3 2.849
 0 1 3 2.777
 0 7 3 8.298
 4 7 3 10.120
 -5 -3 4 10.013
 -3 0 5 6.941
 -3 1 6 7.529
 4 6 6 9.583

_platon_squeeze_details
;
TITL mo_2018040P -1_1_0m_a  R = 0.08
CELL   14.1368   17.2672   22.5417     74.28     81.58     89.93
SPGR P-1
# Solvent Accessible Volume =       573
# Electrons Found in S.A.V. =       114
# Note: Atoms in Void as Cxxx and Qxxx all others
C101 1.000 0.500 0.500 !       2.63 eA-3
Q102 0.817 0.580 0.092 !       2.12 eA-3
Q103 0.810 0.613 0.227 !       2.01 eA-3
C104 0.080 0.685 0.426 !       1.80 eA-3
C105 0.171 0.783 0.300 !       1.72 eA-3
C106 0.114 0.735 0.409 !       1.69 eA-3
C107 0.152 0.762 0.364 !       1.62 eA-3
C108 0.146 0.800 0.324 !       1.58 eA-3
Q109 0.352 0.483 0.281 !       1.57 eA-3
C110 0.065 0.648 0.423 !       1.56 eA-3
C111 0.068 0.770 0.355 !       1.55 eA-3
C112 0.250 0.739 0.403 !       1.51 eA-3
C113 0.193 0.747 0.404 !       1.49 eA-3
C114 0.063 0.595 0.465 !       1.47 eA-3
C115 0.111 0.813 0.365 !       1.45 eA-3
C116 0.099 0.782 0.327 !       1.44 eA-3
C117 0.105 0.798 0.298 !       1.37 eA-3
C118 0.082 0.767 0.389 !       1.34 eA-3
Q119 0.612 0.200 0.073 !       1.32 eA-3
C120 0.042 0.734 0.420 !       1.23 eA-3
Q121 0.099 0.783 0.268 !       1.22 eA-3
C122 0.076 0.825 0.334 !       1.21 eA-3
C123 0.014 0.626 0.456 !       1.14 eA-3
Q124 0.142 0.825 0.221 !       1.11 eA-3
Q125 0.098 0.846 0.143 !       1.11 eA-3
Q126 1.001 0.979 0.005 !       1.08 eA-3
C127 0.058 0.719 0.461 !       1.08 eA-3
Q128 0.177 0.879 0.241 !       1.08 eA-3
C129 0.020 0.673 0.421 !       1.04 eA-3
Q130 0.784 0.564 0.179 !       1.03 eA-3
C131 0.064 0.718 0.374 !       1.02 eA-3
Q132 0.551 0.061 0.193 !       0.99 eA-3
Q133 0.228 0.767 0.268 !       0.97 eA-3
Q134 0.134 0.453 0.257 !       0.97 eA-3
C135 0.139 0.659 0.425 !       0.94 eA-3
C136 0.023 0.782 0.328 !       0.93 eA-3
Q137 0.141 0.405 0.124 !       0.90 eA-3
C138 0.028 0.825 0.304 !       0.89 eA-3
Q139 0.185 0.825 0.140 !       0.89 eA-3
Q140 0.217 0.123 0.282 !       0.88 eA-3
Q141 0.982 0.145 0.257 !       0.88 eA-3
C142 0.999 0.630 0.407 !       0.85 eA-3
Q143 0.162 0.782 0.166 !       0.85 eA-3
C144 0.166 0.689 0.424 !       0.85 eA-3
C145 0.077 0.690 0.354 !       0.84 eA-3
Q146 0.158 0.721 0.261 !       0.84 eA-3
Q147 0.424 0.374 0.404 !       0.82 eA-3
C148 0.156 0.639 0.471 !       0.80 eA-3
Q149 0.179 0.999 0.282 !       0.80 eA-3
Q150 0.662 0.129 0.268 !       0.80 eA-3
Q151 0.688 0.639 0.257 !       0.79 eA-3
Q152 0.178 0.184 0.169 !       0.79 eA-3
Q153 0.151 0.596 0.244 !       0.79 eA-3
C154 0.989 0.779 0.374 !       0.78 eA-3
Q155 0.610 0.142 0.151 !       0.77 eA-3
Q156 0.593 0.438 0.212 !       0.77 eA-3
Q157 0.127 0.188 0.491 !       0.77 eA-3
Q158 0.622 0.533 0.295 !       0.76 eA-3
Q159 0.707 0.329 0.216 !       0.76 eA-3
Q160 0.325 0.782 0.265 !       0.76 eA-3
Q161 0.947 0.205 0.289 !       0.76 eA-3
C162 0.114 0.859 0.381 !       0.76 eA-3
Q163 0.994 0.795 0.280 !       0.76 eA-3
Q164 0.549 0.347 0.098 !       0.75 eA-3
Q165 0.097 0.139 0.203 !       0.75 eA-3
Q166 0.671 0.169 0.272 !       0.75 eA-3
Q167 0.375 0.190 0.279 !       0.75 eA-3
Q168 0.976 0.343 0.268 !       0.75 eA-3
C169 0.232 0.827 0.308 !       0.75 eA-3
Q170 0.296 0.186 0.242 !       0.75 eA-3
Q171 0.019 0.655 0.335 !       0.74 eA-3
Q172 0.201 0.877 0.277 !       0.74 eA-3
Q173 0.498 0.326 0.304 !       0.73 eA-3
Q174 0.061 0.096 0.320 !       0.73 eA-3
Q175 0.477 0.091 0.272 !       0.73 eA-3
Q176 0.074 0.159 0.399 !       0.73 eA-3
Q177 0.843 0.141 0.392 !       0.72 eA-3
C178 0.117 0.840 0.297 !       0.72 eA-3
Q179 1.003 0.905 0.392 !       0.72 eA-3
Q180 0.238 0.673 0.385 !       0.72 eA-3
Q181 0.660 0.577 0.257 !       0.71 eA-3
Q182 0.261 0.921 0.220 !       0.71 eA-3
Q183 0.149 0.562 0.471 !       0.70 eA-3
Q184 0.575 0.296 0.230 !       0.70 eA-3
Q185 0.108 0.856 0.178 !       0.70 eA-3
Q186 0.952 0.064 0.254 !       0.70 eA-3
Q187 0.042 0.889 0.187 !       0.70 eA-3
Q188 0.922 0.654 0.287 !       0.70 eA-3
Q189 0.217 0.049 0.151 !       0.70 eA-3
Q190 0.155 0.780 0.207 !       0.69 eA-3
Q191 0.594 0.503 0.230 !       0.69 eA-3
Q192 0.896 0.721 0.464 !       0.69 eA-3
Q193 0.899 0.871 0.374 !       0.69 eA-3
Q194 0.191 0.295 0.220 !       0.68 eA-3
Q195 0.711 0.108 0.336 !       0.68 eA-3
Q196 0.503 0.624 0.147 !       0.68 eA-3
C197 1.007 0.766 0.451 !       0.68 eA-3
Q198 0.074 0.857 0.219 !       0.68 eA-3
Q199 0.991 0.249 0.175 !       0.68 eA-3
;
loop_
  _platon_squeeze_void_nr
  _platon_squeeze_void_average_x
  _platon_squeeze_void_average_y
  _platon_squeeze_void_average_z
  _platon_squeeze_void_volume
  _platon_squeeze_void_count_electrons
  _platon_squeeze_void_content
 1 0.000 0.500 0.500 510 113 ' '
 2 0.060 0.686 0.017 13 1 ' '
 3 0.139 0.602 0.105 19 0 ' '
 4 0.863 0.396 0.896 20 0 ' '
 5 0.941 0.312 -0.014 12 0 ' '

_platon_squeeze_void_probe_radius  1.20

_olex2_submission_special_instructions  'No special instructions were received'

data_4
_audit_creation_date               2018-07-19
_audit_creation_method
;
Olex2 1.2
(compiled 2018.05.29 svn.r3508 for OlexSys, GUI svn.r5506)
;
_shelx_SHELXL_version_number       '2014/7'
_chemical_name_common              ?
_chemical_name_systematic          ?
_chemical_formula_moiety           'C23 H47 Cl Ge N2 Si2'
_chemical_formula_sum              'C23 H47 Cl Ge N2 Si2'
_chemical_formula_weight           515.84
_chemical_melting_point            ?
loop_
  _atom_type_symbol
  _atom_type_description
  _atom_type_scat_dispersion_real
  _atom_type_scat_dispersion_imag
  _atom_type_scat_source
 'C' 'C' 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
 'H' 'H' 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
 'Cl' 'Cl' 0.1484 0.1585 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
 'Ge' 'Ge' 0.1547 1.8001 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
 'N' 'N' 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
 'Si' 'Si' 0.0817 0.0704 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_shelx_space_group_comment
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
_space_group_crystal_system        'triclinic'
_space_group_IT_number             2
_space_group_name_H-M_alt          'P -1'
_space_group_name_Hall             '-P 1'
loop_
  _space_group_symop_operation_xyz
 'x, y, z'
 '-x, -y, -z'

_cell_length_a                     8.5254(5)
_cell_length_b                     10.1936(5)
_cell_length_c                     15.8413(8)
_cell_angle_alpha                  95.2350(10)
_cell_angle_beta                   92.008(2)
_cell_angle_gamma                  94.0570(10)
_cell_volume                       1366.31(13)
_cell_formula_units_Z              2
_cell_measurement_reflns_used      8240
_cell_measurement_temperature      150(2)
_cell_measurement_theta_max        27.57
_cell_measurement_theta_min        2.40
_shelx_estimated_absorpt_T_max     ?
_shelx_estimated_absorpt_T_min     ?
_exptl_absorpt_coefficient_mu      1.319
_exptl_absorpt_correction_T_max    0.7456
_exptl_absorpt_correction_T_min    0.4682
_exptl_absorpt_correction_type     multi-scan
_exptl_absorpt_process_details    
 'SADABS-2014/5 (Bruker,2014/5) was used for absorption correction. wR2(int) was 0.1552 before and 0.0541 after correction. The Ratio of minimum to maximum transmission is 0.6280. The λ/2 correction factor is 0.00150.'
_exptl_absorpt_special_details     ?
_exptl_crystal_colour              yellow
_exptl_crystal_colour_primary      yellow
_exptl_crystal_density_diffrn      1.254
_exptl_crystal_density_meas        ?
_exptl_crystal_density_method      ?
_exptl_crystal_description         rodlike
_exptl_crystal_F_000               552
_exptl_crystal_size_max            0.8
_exptl_crystal_size_mid            0.15
_exptl_crystal_size_min            0.13
_exptl_transmission_factor_max     ?
_exptl_transmission_factor_min     ?
_diffrn_reflns_av_R_equivalents    0.0379
_diffrn_reflns_av_unetI/netI       0.0546
_diffrn_reflns_Laue_measured_fraction_full  0.992
_diffrn_reflns_Laue_measured_fraction_max  0.991
_diffrn_reflns_limit_h_max         11
_diffrn_reflns_limit_h_min         -9
_diffrn_reflns_limit_k_max         13
_diffrn_reflns_limit_k_min         -12
_diffrn_reflns_limit_l_max         20
_diffrn_reflns_limit_l_min         -20
_diffrn_reflns_number              12282
_diffrn_reflns_point_group_measured_fraction_full  0.992
_diffrn_reflns_point_group_measured_fraction_max  0.991
_diffrn_reflns_theta_full          25.242
_diffrn_reflns_theta_max           27.573
_diffrn_reflns_theta_min           2.012
_diffrn_ambient_temperature        150
_diffrn_detector_area_resol_mean   ?
_diffrn_measured_fraction_theta_full  0.992
_diffrn_measured_fraction_theta_max  0.991
_diffrn_measurement_device_type    'Bruker D8 CMOS'
_diffrn_measurement_method         'φ and ω scans'
_diffrn_radiation_type             MoK\a
_diffrn_radiation_wavelength       0.71073
_diffrn_source                     ?
_diffrn_standards_number           0
_reflns_Friedel_coverage           0.000
_reflns_Friedel_fraction_full      .
_reflns_Friedel_fraction_max       .
_reflns_number_gt                  5597
_reflns_number_total               6260
_reflns_special_details
;
 Reflections were merged by SHELXL according to the crystal
 class for the calculation of statistics and refinement.
 
 _reflns_Friedel_fraction is defined as the number of unique
 Friedel pairs measured divided by the number that would be
 possible theoretically, ignoring centric projections and
 systematic absences.
;
_reflns_threshold_expression       'I > 2σ(I)'
_computing_cell_refinement         'SAINT v8.34A (Bruker, 2013)'
_computing_data_collection         ?
_computing_data_reduction          'SAINT v8.34A (Bruker, 2013)'
_computing_molecular_graphics      'Olex2 (Dolomanov et al., 2009)'
_computing_publication_material    'Olex2 (Dolomanov et al., 2009)'
_computing_structure_refinement    'ShelXL (Sheldrick, 2015)'
_computing_structure_solution      'SIR2004 (Burla et al.,  2007)'
_refine_diff_density_max           0.775
_refine_diff_density_min           -0.708
_refine_diff_density_rms           0.075
_refine_ls_extinction_coef         .
_refine_ls_extinction_method       none
_refine_ls_goodness_of_fit_ref     1.038
_refine_ls_hydrogen_treatment      constr
_refine_ls_matrix_type             full
_refine_ls_number_parameters       274
_refine_ls_number_reflns           6260
_refine_ls_number_restraints       0
_refine_ls_R_factor_all            0.0390
_refine_ls_R_factor_gt             0.0335
_refine_ls_restrained_S_all        1.038
_refine_ls_shift/su_max            0.001
_refine_ls_shift/su_mean           0.000
_refine_ls_structure_factor_coef   Fsqd
_refine_ls_weighting_details      
 'w=1/[σ²(Fo²)+(0.0355P)²+0.5274P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme        calc
_refine_ls_wR_factor_gt            0.0852
_refine_ls_wR_factor_ref           0.0883
_refine_special_details            ?
_olex2_refinement_description
;
1. Fixed Uiso
 At 1.2 times of:
  All C(H) groups
 At 1.5 times of:
  All C(H,H,H) groups
2.a Ternary CH refined with riding coordinates:
 C2(H2), C5(H5), C8(H8), C11(H11), C14(H14), C17(H17)
2.b Aromatic/amide H refined with riding coordinates:
 C19(H19), C20(H20), C21(H21), C22(H22), C23(H23)
2.c Idealised Me refined as rotating group:
 C1(H1A,H1B,H1C), C3(H3A,H3B,H3C), C4(H4A,H4B,H4C), C6(H6A,H6B,H6C), C7(H7A,
 H7B,H7C), C9(H9A,H9B,H9C), C10(H10A,H10B,H10C), C12(H12A,H12B,H12C), C13(H13A,
 H13B,H13C), C15(H15A,H15B,H15C), C16(H16A,H16B,H16C), C18(H18A,H18B,H18C)
;
_atom_sites_solution_hydrogens     geom
_atom_sites_solution_primary       direct
_atom_sites_solution_secondary     ?
loop_
  _atom_site_label
  _atom_site_type_symbol
  _atom_site_fract_x
  _atom_site_fract_y
  _atom_site_fract_z
  _atom_site_U_iso_or_equiv
  _atom_site_adp_type
  _atom_site_occupancy
  _atom_site_site_symmetry_order
  _atom_site_calc_flag
  _atom_site_refinement_flags_posn
  _atom_site_refinement_flags_adp
  _atom_site_refinement_flags_occupancy
  _atom_site_disorder_assembly
  _atom_site_disorder_group
 C1 C 0.6387(2) 0.1927(2) 0.75245(14) 0.0234(4) Uani 1 1 d . . . . .
 H1A H 0.7054 0.2224 0.8032 0.035 Uiso 1 1 calc GR . . . .
 H1B H 0.5987 0.2694 0.7281 0.035 Uiso 1 1 calc GR . . . .
 H1C H 0.7007 0.1446 0.7106 0.035 Uiso 1 1 calc GR . . . .
 C2 C 0.5003(2) 0.10153(17) 0.77649(12) 0.0170(4) Uani 1 1 d . . . . .
 H2 H 0.4564 0.0564 0.7211 0.020 Uiso 1 1 calc R . . . .
 C3 C 0.5625(3) -0.01047(19) 0.82432(13) 0.0245(4) Uani 1 1 d . . . . .
 H3A H 0.6459 -0.0509 0.7924 0.037 Uiso 1 1 calc GR . . . .
 H3B H 0.4763 -0.0774 0.8304 0.037 Uiso 1 1 calc GR . . . .
 H3C H 0.6048 0.0257 0.8806 0.037 Uiso 1 1 calc GR . . . .
 C4 C 0.2391(3) 0.0103(2) 0.95007(13) 0.0271(5) Uani 1 1 d . . . . .
 H4A H 0.2056 0.0746 0.9944 0.041 Uiso 1 1 calc GR . . . .
 H4B H 0.3537 0.0069 0.9548 0.041 Uiso 1 1 calc GR . . . .
 H4C H 0.1883 -0.0772 0.9569 0.041 Uiso 1 1 calc GR . . . .
 C5 C 0.1913(2) 0.05228(19) 0.86150(12) 0.0194(4) Uani 1 1 d . . . . .
 H5 H 0.2040 -0.0270 0.8209 0.023 Uiso 1 1 calc R . . . .
 C6 C 0.0145(3) 0.0706(2) 0.85843(15) 0.0301(5) Uani 1 1 d . . . . .
 H6A H -0.0436 -0.0114 0.8707 0.045 Uiso 1 1 calc GR . . . .
 H6B H -0.0181 0.0928 0.8018 0.045 Uiso 1 1 calc GR . . . .
 H6C H -0.0080 0.1423 0.9008 0.045 Uiso 1 1 calc GR . . . .
 C7 C 0.5525(3) 0.2827(2) 0.96319(14) 0.0319(5) Uani 1 1 d . . . . .
 H7A H 0.5837 0.3536 1.0079 0.048 Uiso 1 1 calc GR . . . .
 H7B H 0.6359 0.2758 0.9224 0.048 Uiso 1 1 calc GR . . . .
 H7C H 0.5354 0.1989 0.9884 0.048 Uiso 1 1 calc GR . . . .
 C8 C 0.3990(2) 0.31418(19) 0.91733(12) 0.0209(4) Uani 1 1 d . . . . .
 H8 H 0.4229 0.3999 0.8927 0.025 Uiso 1 1 calc R . . . .
 C9 C 0.2774(3) 0.3412(2) 0.98547(13) 0.0282(5) Uani 1 1 d . . . . .
 H9A H 0.2806 0.2746 1.0262 0.042 Uiso 1 1 calc GR . . . .
 H9B H 0.1719 0.3371 0.9583 0.042 Uiso 1 1 calc GR . . . .
 H9C H 0.3025 0.4292 1.0152 0.042 Uiso 1 1 calc GR . . . .
 C10 C -0.0202(3) 0.4545(2) 0.85883(14) 0.0302(5) Uani 1 1 d . . . . .
 H10A H -0.0349 0.4831 0.9186 0.045 Uiso 1 1 calc GR . . . .
 H10B H -0.0160 0.3583 0.8517 0.045 Uiso 1 1 calc GR . . . .
 H10C H -0.1082 0.4799 0.8240 0.045 Uiso 1 1 calc GR . . . .
 C11 C 0.1347(3) 0.52077(19) 0.83088(13) 0.0226(4) Uani 1 1 d . . . . .
 H11 H 0.2141 0.5140 0.8780 0.027 Uiso 1 1 calc R . . . .
 C12 C 0.1177(3) 0.6698(2) 0.82717(16) 0.0394(6) Uani 1 1 d . . . . .
 H12A H 0.0381 0.6825 0.7831 0.059 Uiso 1 1 calc GR . . . .
 H12B H 0.2189 0.7132 0.8138 0.059 Uiso 1 1 calc GR . . . .
 H12C H 0.0854 0.7083 0.8822 0.059 Uiso 1 1 calc GR . . . .
 C13 C -0.0952(2) 0.4334(2) 0.64934(14) 0.0262(4) Uani 1 1 d . . . . .
 H13A H -0.1302 0.5090 0.6846 0.039 Uiso 1 1 calc GR . . . .
 H13B H -0.1144 0.3529 0.6780 0.039 Uiso 1 1 calc GR . . . .
 H13C H -0.1536 0.4237 0.5945 0.039 Uiso 1 1 calc GR . . . .
 C14 C 0.0816(2) 0.45623(17) 0.63514(12) 0.0177(4) Uani 1 1 d . . . . .
 H14 H 0.1071 0.3877 0.5894 0.021 Uiso 1 1 calc R . . . .
 C15 C 0.1079(3) 0.59104(19) 0.59884(14) 0.0266(5) Uani 1 1 d . . . . .
 H15A H 0.0323 0.5956 0.5513 0.040 Uiso 1 1 calc GR . . . .
 H15B H 0.2152 0.6012 0.5789 0.040 Uiso 1 1 calc GR . . . .
 H15C H 0.0928 0.6620 0.6432 0.040 Uiso 1 1 calc GR . . . .
 C16 C 0.5316(3) 0.5701(2) 0.78219(14) 0.0276(5) Uani 1 1 d . . . . .
 H16A H 0.5775 0.4888 0.7958 0.041 Uiso 1 1 calc GR . . . .
 H16B H 0.4831 0.6102 0.8325 0.041 Uiso 1 1 calc GR . . . .
 H16C H 0.6144 0.6322 0.7644 0.041 Uiso 1 1 calc GR . . . .
 C17 C 0.4062(2) 0.53785(18) 0.71002(13) 0.0208(4) Uani 1 1 d . . . . .
 H17 H 0.3698 0.6258 0.6984 0.025 Uiso 1 1 calc R . . . .
 C18 C 0.4833(3) 0.4891(2) 0.62838(14) 0.0255(4) Uani 1 1 d . . . . .
 H18A H 0.5577 0.5590 0.6118 0.038 Uiso 1 1 calc GR . . . .
 H18B H 0.4021 0.4663 0.5831 0.038 Uiso 1 1 calc GR . . . .
 H18C H 0.5396 0.4109 0.6380 0.038 Uiso 1 1 calc GR . . . .
 C19 C 0.4138(2) 0.17130(19) 0.54938(13) 0.0224(4) Uani 1 1 d . . . . .
 H19 H 0.4676 0.1762 0.6032 0.027 Uiso 1 1 calc R . . . .
 C20 C 0.5001(3) 0.1656(2) 0.47740(14) 0.0272(5) Uani 1 1 d . . . . .
 H20 H 0.6117 0.1667 0.4816 0.033 Uiso 1 1 calc R . . . .
 C21 C 0.4218(3) 0.1580(2) 0.39874(14) 0.0295(5) Uani 1 1 d . . . . .
 H21 H 0.4786 0.1547 0.3481 0.035 Uiso 1 1 calc R . . . .
 C22 C 0.2589(3) 0.1555(2) 0.39541(13) 0.0313(5) Uani 1 1 d . . . . .
 H22 H 0.2021 0.1495 0.3424 0.038 Uiso 1 1 calc R . . . .
 C23 C 0.1806(3) 0.1618(2) 0.47005(13) 0.0251(4) Uani 1 1 d . . . . .
 H23 H 0.0689 0.1600 0.4675 0.030 Uiso 1 1 calc R . . . .
 Cl1 Cl 0.17840(6) -0.05621(4) 0.65450(3) 0.02151(11) Uani 1 1 d . . . . .
 Ge1 Ge 0.10533(2) 0.16040(2) 0.65420(2) 0.01569(7) Uani 1 1 d . . . . .
 N1 N 0.23723(18) 0.26551(14) 0.74046(9) 0.0138(3) Uani 1 1 d . . . . .
 N2 N 0.2563(2) 0.17021(15) 0.54595(10) 0.0190(3) Uani 1 1 d . . . . .
 Si1 Si 0.32831(6) 0.18873(5) 0.82402(3) 0.01441(11) Uani 1 1 d . . . . .
 Si2 Si 0.21802(6) 0.43624(5) 0.73185(3) 0.01477(11) Uani 1 1 d . . . . .


_geom_special_details
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;
loop_
  _geom_bond_atom_site_label_1
  _geom_bond_atom_site_label_2
  _geom_bond_distance
  _geom_bond_site_symmetry_2
  _geom_bond_publ_flag
 C1 H1A 0.9800 . ?
 C1 H1B 0.9800 . ?
 C1 H1C 0.9800 . ?
 C1 C2 1.531(3) . ?
 C2 H2 1.0000 . ?
 C2 C3 1.541(2) . ?
 C2 Si1 1.910(2) . ?
 C3 H3A 0.9800 . ?
 C3 H3B 0.9800 . ?
 C3 H3C 0.9800 . ?
 C4 H4A 0.9800 . ?
 C4 H4B 0.9800 . ?
 C4 H4C 0.9800 . ?
 C4 C5 1.553(3) . ?
 C5 H5 1.0000 . ?
 C5 C6 1.532(3) . ?
 C5 Si1 1.903(2) . ?
 C6 H6A 0.9800 . ?
 C6 H6B 0.9800 . ?
 C6 H6C 0.9800 . ?
 C7 H7A 0.9800 . ?
 C7 H7B 0.9800 . ?
 C7 H7C 0.9800 . ?
 C7 C8 1.542(3) . ?
 C8 H8 1.0000 . ?
 C8 C9 1.543(3) . ?
 C8 Si1 1.9149(19) . ?
 C9 H9A 0.9800 . ?
 C9 H9B 0.9800 . ?
 C9 H9C 0.9800 . ?
 C10 H10A 0.9800 . ?
 C10 H10B 0.9800 . ?
 C10 H10C 0.9800 . ?
 C10 C11 1.538(3) . ?
 C11 H11 1.0000 . ?
 C11 C12 1.542(3) . ?
 C11 Si2 1.904(2) . ?
 C12 H12A 0.9800 . ?
 C12 H12B 0.9800 . ?
 C12 H12C 0.9800 . ?
 C13 H13A 0.9800 . ?
 C13 H13B 0.9800 . ?
 C13 H13C 0.9800 . ?
 C13 C14 1.536(3) . ?
 C14 H14 1.0000 . ?
 C14 C15 1.542(3) . ?
 C14 Si2 1.9254(18) . ?
 C15 H15A 0.9800 . ?
 C15 H15B 0.9800 . ?
 C15 H15C 0.9800 . ?
 C16 H16A 0.9800 . ?
 C16 H16B 0.9800 . ?
 C16 H16C 0.9800 . ?
 C16 C17 1.535(3) . ?
 C17 H17 1.0000 . ?
 C17 C18 1.530(3) . ?
 C17 Si2 1.906(2) . ?
 C18 H18A 0.9800 . ?
 C18 H18B 0.9800 . ?
 C18 H18C 0.9800 . ?
 C19 H19 0.9500 . ?
 C19 C20 1.378(3) . ?
 C19 N2 1.341(3) . ?
 C20 H20 0.9500 . ?
 C20 C21 1.386(3) . ?
 C21 H21 0.9500 . ?
 C21 C22 1.386(3) . ?
 C22 H22 0.9500 . ?
 C22 C23 1.377(3) . ?
 C23 H23 0.9500 . ?
 C23 N2 1.337(2) . ?
 Cl1 Ge1 2.3366(5) . ?
 Ge1 N1 1.9324(14) . ?
 Ge1 N2 2.1849(18) . ?
 N1 Si1 1.7806(15) . ?
 N1 Si2 1.7766(15) . ?

loop_
  _geom_angle_atom_site_label_1
  _geom_angle_atom_site_label_2
  _geom_angle_atom_site_label_3
  _geom_angle
  _geom_angle_site_symmetry_1
  _geom_angle_site_symmetry_3
  _geom_angle_publ_flag
 H1A C1 H1B 109.5 . . ?
 H1A C1 H1C 109.5 . . ?
 H1B C1 H1C 109.5 . . ?
 C2 C1 H1A 109.5 . . ?
 C2 C1 H1B 109.5 . . ?
 C2 C1 H1C 109.5 . . ?
 C1 C2 H2 104.5 . . ?
 C1 C2 C3 109.61(16) . . ?
 C1 C2 Si1 115.38(13) . . ?
 C3 C2 H2 104.5 . . ?
 C3 C2 Si1 116.91(14) . . ?
 Si1 C2 H2 104.5 . . ?
 C2 C3 H3A 109.5 . . ?
 C2 C3 H3B 109.5 . . ?
 C2 C3 H3C 109.5 . . ?
 H3A C3 H3B 109.5 . . ?
 H3A C3 H3C 109.5 . . ?
 H3B C3 H3C 109.5 . . ?
 H4A C4 H4B 109.5 . . ?
 H4A C4 H4C 109.5 . . ?
 H4B C4 H4C 109.5 . . ?
 C5 C4 H4A 109.5 . . ?
 C5 C4 H4B 109.5 . . ?
 C5 C4 H4C 109.5 . . ?
 C4 C5 H5 105.0 . . ?
 C4 C5 Si1 114.11(14) . . ?
 C6 C5 C4 108.76(17) . . ?
 C6 C5 H5 105.0 . . ?
 C6 C5 Si1 117.63(13) . . ?
 Si1 C5 H5 105.0 . . ?
 C5 C6 H6A 109.5 . . ?
 C5 C6 H6B 109.5 . . ?
 C5 C6 H6C 109.5 . . ?
 H6A C6 H6B 109.5 . . ?
 H6A C6 H6C 109.5 . . ?
 H6B C6 H6C 109.5 . . ?
 H7A C7 H7B 109.5 . . ?
 H7A C7 H7C 109.5 . . ?
 H7B C7 H7C 109.5 . . ?
 C8 C7 H7A 109.5 . . ?
 C8 C7 H7B 109.5 . . ?
 C8 C7 H7C 109.5 . . ?
 C7 C8 H8 106.2 . . ?
 C7 C8 C9 107.60(17) . . ?
 C7 C8 Si1 114.47(13) . . ?
 C9 C8 H8 106.2 . . ?
 C9 C8 Si1 115.54(14) . . ?
 Si1 C8 H8 106.2 . . ?
 C8 C9 H9A 109.5 . . ?
 C8 C9 H9B 109.5 . . ?
 C8 C9 H9C 109.5 . . ?
 H9A C9 H9B 109.5 . . ?
 H9A C9 H9C 109.5 . . ?
 H9B C9 H9C 109.5 . . ?
 H10A C10 H10B 109.5 . . ?
 H10A C10 H10C 109.5 . . ?
 H10B C10 H10C 109.5 . . ?
 C11 C10 H10A 109.5 . . ?
 C11 C10 H10B 109.5 . . ?
 C11 C10 H10C 109.5 . . ?
 C10 C11 H11 105.8 . . ?
 C10 C11 C12 109.49(19) . . ?
 C10 C11 Si2 115.10(14) . . ?
 C12 C11 H11 105.8 . . ?
 C12 C11 Si2 114.08(16) . . ?
 Si2 C11 H11 105.8 . . ?
 C11 C12 H12A 109.5 . . ?
 C11 C12 H12B 109.5 . . ?
 C11 C12 H12C 109.5 . . ?
 H12A C12 H12B 109.5 . . ?
 H12A C12 H12C 109.5 . . ?
 H12B C12 H12C 109.5 . . ?
 H13A C13 H13B 109.5 . . ?
 H13A C13 H13C 109.5 . . ?
 H13B C13 H13C 109.5 . . ?
 C14 C13 H13A 109.5 . . ?
 C14 C13 H13B 109.5 . . ?
 C14 C13 H13C 109.5 . . ?
 C13 C14 H14 106.6 . . ?
 C13 C14 C15 107.42(16) . . ?
 C13 C14 Si2 115.11(14) . . ?
 C15 C14 H14 106.6 . . ?
 C15 C14 Si2 113.86(13) . . ?
 Si2 C14 H14 106.6 . . ?
 C14 C15 H15A 109.5 . . ?
 C14 C15 H15B 109.5 . . ?
 C14 C15 H15C 109.5 . . ?
 H15A C15 H15B 109.5 . . ?
 H15A C15 H15C 109.5 . . ?
 H15B C15 H15C 109.5 . . ?
 H16A C16 H16B 109.5 . . ?
 H16A C16 H16C 109.5 . . ?
 H16B C16 H16C 109.5 . . ?
 C17 C16 H16A 109.5 . . ?
 C17 C16 H16B 109.5 . . ?
 C17 C16 H16C 109.5 . . ?
 C16 C17 H17 104.2 . . ?
 C16 C17 Si2 118.51(15) . . ?
 C18 C17 C16 110.01(18) . . ?
 C18 C17 H17 104.2 . . ?
 C18 C17 Si2 113.93(13) . . ?
 Si2 C17 H17 104.2 . . ?
 C17 C18 H18A 109.5 . . ?
 C17 C18 H18B 109.5 . . ?
 C17 C18 H18C 109.5 . . ?
 H18A C18 H18B 109.5 . . ?
 H18A C18 H18C 109.5 . . ?
 H18B C18 H18C 109.5 . . ?
 C20 C19 H19 118.9 . . ?
 N2 C19 H19 118.9 . . ?
 N2 C19 C20 122.20(19) . . ?
 C19 C20 H20 120.5 . . ?
 C19 C20 C21 119.0(2) . . ?
 C21 C20 H20 120.5 . . ?
 C20 C21 H21 120.7 . . ?
 C22 C21 C20 118.7(2) . . ?
 C22 C21 H21 120.7 . . ?
 C21 C22 H22 120.5 . . ?
 C23 C22 C21 119.1(2) . . ?
 C23 C22 H22 120.5 . . ?
 C22 C23 H23 118.9 . . ?
 N2 C23 C22 122.2(2) . . ?
 N2 C23 H23 118.9 . . ?
 N1 Ge1 Cl1 106.54(4) . . ?
 N1 Ge1 N2 100.00(6) . . ?
 N2 Ge1 Cl1 84.82(4) . . ?
 Si1 N1 Ge1 120.10(8) . . ?
 Si2 N1 Ge1 110.06(7) . . ?
 Si2 N1 Si1 128.82(8) . . ?
 C19 N2 Ge1 125.57(13) . . ?
 C23 N2 C19 118.82(19) . . ?
 C23 N2 Ge1 115.28(15) . . ?
 C2 Si1 C8 111.05(9) . . ?
 C5 Si1 C2 105.34(9) . . ?
 C5 Si1 C8 110.46(9) . . ?
 N1 Si1 C2 106.64(8) . . ?
 N1 Si1 C5 111.24(8) . . ?
 N1 Si1 C8 111.86(8) . . ?
 C11 Si2 C14 109.16(9) . . ?
 C11 Si2 C17 106.85(9) . . ?
 C17 Si2 C14 103.23(9) . . ?
 N1 Si2 C11 111.99(8) . . ?
 N1 Si2 C14 109.31(7) . . ?
 N1 Si2 C17 115.82(8) . . ?

loop_
  _geom_torsion_atom_site_label_1
  _geom_torsion_atom_site_label_2
  _geom_torsion_atom_site_label_3
  _geom_torsion_atom_site_label_4
  _geom_torsion
  _geom_torsion_site_symmetry_1
  _geom_torsion_site_symmetry_2
  _geom_torsion_site_symmetry_3
  _geom_torsion_site_symmetry_4
  _geom_torsion_publ_flag
 C19 C20 C21 C22 -0.5(3) . . . . ?
 C20 C19 N2 C23 0.8(3) . . . . ?
 C20 C19 N2 Ge1 173.98(14) . . . . ?
 C20 C21 C22 C23 0.6(3) . . . . ?
 C21 C22 C23 N2 0.0(3) . . . . ?
 C22 C23 N2 C19 -0.7(3) . . . . ?
 C22 C23 N2 Ge1 -174.57(16) . . . . ?
 Ge1 N1 Si1 C2 75.63(11) . . . . ?
 Ge1 N1 Si1 C5 -38.72(12) . . . . ?
 Ge1 N1 Si1 C8 -162.78(10) . . . . ?
 Ge1 N1 Si2 C11 117.75(9) . . . . ?
 Ge1 N1 Si2 C14 -3.35(11) . . . . ?
 Ge1 N1 Si2 C17 -119.38(9) . . . . ?
 N2 C19 C20 C21 -0.2(3) . . . . ?
 Si1 N1 Si2 C11 -50.50(14) . . . . ?
 Si1 N1 Si2 C14 -171.60(12) . . . . ?
 Si1 N1 Si2 C17 72.37(14) . . . . ?
 Si2 N1 Si1 C2 -117.14(12) . . . . ?
 Si2 N1 Si1 C5 128.51(12) . . . . ?
 Si2 N1 Si1 C8 4.45(16) . . . . ?

_olex2_submission_special_instructions  'No special instructions were received'
