data_mj19312_0m
_audit_creation_date               2019-05-13
_audit_creation_method
;
Olex2 1.2
(compiled 2018.05.29 svn.r3508 for OlexSys, GUI svn.r5506)
;
_shelx_SHELXL_version_number       '2016/6'
_audit_contact_author_address      ?
_audit_contact_author_email        ?
_audit_contact_author_name         ''
_audit_contact_author_phone        ?
_publ_contact_author_id_orcid      ?
_publ_section_references
;
Dolomanov, O.V., Bourhis, L.J., Gildea, R.J, Howard, J.A.K. & Puschmann, H.
 (2009), J. Appl. Cryst. 42, 339-341.

Sheldrick, G.M. (2015). Acta Cryst. A71, 3-8.

Sheldrick, G.M. (2015). Acta Cryst. C71, 3-8.
;
_chemical_name_common              ?
_chemical_name_systematic          ?
_chemical_formula_moiety           'C24 H33 N O3'
_chemical_formula_sum              'C24 H33 N O3'
_chemical_formula_weight           383.51
_chemical_absolute_configuration   rmad
_chemical_melting_point            ?
loop_
  _atom_type_symbol
  _atom_type_description
  _atom_type_scat_dispersion_real
  _atom_type_scat_dispersion_imag
  _atom_type_scat_source
 'C' 'C' 0.0148 0.0070 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
 'H' 'H' 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
 'N' 'N' 0.0253 0.0136 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
 'O' 'O' 0.0412 0.0250 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_shelx_space_group_comment
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
_space_group_crystal_system        'orthorhombic'
_space_group_IT_number             19
_space_group_name_H-M_alt          'P 21 21 21'
_space_group_name_Hall             'P 2ac 2ab'
loop_
  _space_group_symop_operation_xyz
 'x, y, z'
 '-x+1/2, -y, z+1/2'
 '-x, y+1/2, -z+1/2'
 'x+1/2, -y+1/2, -z'

_cell_length_a                     7.33640(10)
_cell_length_b                     11.6884(2)
_cell_length_c                     23.7649(4)
_cell_angle_alpha                  90
_cell_angle_beta                   90
_cell_angle_gamma                  90
_cell_volume                       2037.86(6)
_cell_formula_units_Z              4
_cell_measurement_reflns_used      9900
_cell_measurement_temperature      170(2)
_cell_measurement_theta_max        54.816
_cell_measurement_theta_min        3.667
_shelx_estimated_absorpt_T_max     0.996
_shelx_estimated_absorpt_T_min     0.980
_exptl_absorpt_coefficient_mu      0.412
_exptl_absorpt_correction_T_max    0.7508
_exptl_absorpt_correction_T_min    0.6590
_exptl_absorpt_correction_type     multi-scan
_exptl_absorpt_process_details    
 'SADABS-2016/2 (Bruker,2016/2) was used for absorption correction. wR2(int) was 0.1336 before and 0.0640 after correction. The Ratio of minimum to maximum transmission is 0.8777. The λ/2 correction factor is Not present.'
_exptl_absorpt_special_details     ?
_exptl_crystal_colour              'colourless'
_exptl_crystal_density_diffrn      1.250
_exptl_crystal_density_meas        ?
_exptl_crystal_density_method      ?
_exptl_crystal_description         'block'
_exptl_crystal_F_000               832
_exptl_crystal_size_max            0.05
_exptl_crystal_size_mid            0.02
_exptl_crystal_size_min            0.01
_exptl_transmission_factor_max     ?
_exptl_transmission_factor_min     ?
_diffrn_reflns_av_R_equivalents    0.0523
_diffrn_reflns_av_unetI/netI       0.0398
_diffrn_reflns_Laue_measured_fraction_full  0.999
_diffrn_reflns_Laue_measured_fraction_max  0.997
_diffrn_reflns_limit_h_max         8
_diffrn_reflns_limit_h_min         -8
_diffrn_reflns_limit_k_max         14
_diffrn_reflns_limit_k_min         -14
_diffrn_reflns_limit_l_max         25
_diffrn_reflns_limit_l_min         -28
_diffrn_reflns_number              22458
_diffrn_reflns_point_group_measured_fraction_full  0.999
_diffrn_reflns_point_group_measured_fraction_max  0.997
_diffrn_reflns_theta_full          53.594
_diffrn_reflns_theta_max           54.910
_diffrn_reflns_theta_min           3.236
_diffrn_ambient_temperature        170.04
_diffrn_detector_area_resol_mean   ?
_diffrn_measured_fraction_theta_full  0.999
_diffrn_measured_fraction_theta_max  0.997
_diffrn_measurement_device_type    'Bruker D8 Venture'
_diffrn_measurement_method         'φ and ω scans'
_diffrn_radiation_type             GaK\a
_diffrn_radiation_wavelength       1.34139
_diffrn_source                     ?
_diffrn_standards_number           0
_reflns_Friedel_coverage           0.731
_reflns_Friedel_fraction_full      0.999
_reflns_Friedel_fraction_max       0.997
_reflns_number_gt                  3310
_reflns_number_total               3859
_reflns_special_details
;
 Reflections were merged by SHELXL according to the crystal
 class for the calculation of statistics and refinement.
 
 _reflns_Friedel_fraction is defined as the number of unique
 Friedel pairs measured divided by the number that would be
 possible theoretically, ignoring centric projections and
 systematic absences.
;
_reflns_threshold_expression       'I > 2σ(I)'
_computing_cell_refinement         'SAINT v8.37A (Bruker, 2015)'
_computing_data_collection         ?
_computing_data_reduction          'SAINT v8.37A (Bruker, 2015)'
_computing_molecular_graphics      'Olex2 (Dolomanov et al., 2009)'
_computing_publication_material    'Olex2 (Dolomanov et al., 2009)'
_computing_structure_refinement    'ShelXL (Sheldrick, 2015)'
_computing_structure_solution      'ShelXT (Sheldrick, 2015)'
_refine_diff_density_max           0.195
_refine_diff_density_min           -0.151
_refine_diff_density_rms           0.038
_refine_ls_abs_structure_details
;
 Flack x determined using 1235 quotients [(I+)-(I-)]/[(I+)+(I-)]
 (Parsons, Flack and Wagner, Acta Cryst. B69 (2013) 249-259).
;
_refine_ls_abs_structure_Flack     0.13(14)
_refine_ls_extinction_coef         .
_refine_ls_extinction_method       none
_refine_ls_goodness_of_fit_ref     1.091
_refine_ls_hydrogen_treatment      mixed
_refine_ls_matrix_type             full
_refine_ls_number_parameters       265
_refine_ls_number_reflns           3859
_refine_ls_number_restraints       0
_refine_ls_R_factor_all            0.0509
_refine_ls_R_factor_gt             0.0382
_refine_ls_restrained_S_all        1.091
_refine_ls_shift/su_max            0.000
_refine_ls_shift/su_mean           0.000
_refine_ls_structure_factor_coef   Fsqd
_refine_ls_weighting_details      
 'w=1/[σ²(Fo²)+(0.0337P)²+0.3649P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme        calc
_refine_ls_wR_factor_gt            0.0780
_refine_ls_wR_factor_ref           0.0846
_refine_special_details            ?
_olex2_refinement_description
;
1. Fixed Uiso
 At 1.2 times of:
  All C(H) groups, All C(H,H) groups
 At 1.5 times of:
  All C(H,H,H) groups, All O(H) groups
2.a Ternary CH refined with riding coordinates:
 C2(H2), C4(H4), C6(H6), C8(H8), C22(H22)
2.b Secondary CH2 refined with riding coordinates:
 C3(H3A,H3B), C9(H9A,H9B), C12(H12A,H12B), C13(H13A,H13B), C15(H15A,H15B),
 C16(H16A,H16B), C17(H17A,H17B), C19(H19A,H19B)
2.c Idealised Me refined as rotating group:
 C18(H18A,H18B,H18C), C23(H23A,H23B,H23C), C24(H24A,H24B,H24C)
2.d Idealised tetrahedral OH refined as rotating group:
 O1(H1)
;
_atom_sites_solution_hydrogens     mixed
_atom_sites_solution_primary       dual
_atom_sites_solution_secondary     ?
loop_
  _atom_site_label
  _atom_site_type_symbol
  _atom_site_fract_x
  _atom_site_fract_y
  _atom_site_fract_z
  _atom_site_U_iso_or_equiv
  _atom_site_adp_type
  _atom_site_occupancy
  _atom_site_site_symmetry_order
  _atom_site_calc_flag
  _atom_site_refinement_flags_posn
  _atom_site_refinement_flags_adp
  _atom_site_refinement_flags_occupancy
  _atom_site_disorder_assembly
  _atom_site_disorder_group
 O1 O 0.5081(2) 0.20362(15) 0.40923(7) 0.0268(4) Uani 1 1 d . . . . .
 H1 H 0.404484 0.217121 0.395752 0.040 Uiso 1 1 calc GR . . . .
 O2 O 0.5840(2) 0.59513(14) 0.38743(7) 0.0269(4) Uani 1 1 d . . . . .
 O3 O 0.6846(3) 0.77108(16) 0.40976(10) 0.0449(5) Uani 1 1 d . . . . .
 N1 N 1.1399(2) 0.21868(17) 0.37412(9) 0.0219(5) Uani 1 1 d . . . . .
 C1 C 0.9884(3) 0.2716(2) 0.37048(10) 0.0181(5) Uani 1 1 d . . . . .
 C2 C 0.9602(3) 0.3914(2) 0.34940(10) 0.0216(6) Uani 1 1 d . . . . .
 H2 H 1.066442 0.439810 0.360743 0.026 Uiso 1 1 calc R . . . .
 C3 C 0.9336(4) 0.3996(2) 0.28460(11) 0.0285(6) Uani 1 1 d . . . . .
 H3A H 1.041402 0.436160 0.267194 0.034 Uiso 1 1 calc R . . . .
 H3B H 0.920151 0.321920 0.268474 0.034 Uiso 1 1 calc R . . . .
 C4 C 0.7625(4) 0.4705(2) 0.27215(11) 0.0267(6) Uani 1 1 d . . . . .
 H4 H 0.751673 0.485391 0.230850 0.032 Uiso 1 1 calc R . . . .
 C5 C 0.7752(3) 0.5811(2) 0.30393(11) 0.0250(6) Uani 1 1 d . . . . .
 C6 C 0.7646(3) 0.5618(2) 0.36698(11) 0.0241(6) Uani 1 1 d . . . . .
 H6 H 0.861254 0.607029 0.386609 0.029 Uiso 1 1 calc R . . . .
 C7 C 0.7862(3) 0.4345(2) 0.38012(10) 0.0195(5) Uani 1 1 d . . . . .
 C8 C 0.6242(3) 0.3666(2) 0.35567(10) 0.0204(5) Uani 1 1 d . . . . .
 H8 H 0.513740 0.392798 0.376666 0.024 Uiso 1 1 calc R . . . .
 C9 C 0.5954(4) 0.4036(2) 0.29356(11) 0.0282(6) Uani 1 1 d . . . . .
 H9A H 0.576337 0.335001 0.269824 0.034 Uiso 1 1 calc R . . . .
 H9B H 0.485318 0.452218 0.290739 0.034 Uiso 1 1 calc R . . . .
 C10 C 0.6456(3) 0.2352(2) 0.36904(10) 0.0198(5) Uani 1 1 d . . . . .
 C11 C 0.8290(3) 0.2159(2) 0.39994(10) 0.0174(5) Uani 1 1 d . . . . .
 C12 C 0.8220(3) 0.2833(2) 0.45587(10) 0.0214(5) Uani 1 1 d . . . . .
 H12A H 0.934610 0.269217 0.477734 0.026 Uiso 1 1 calc R . . . .
 H12B H 0.716779 0.257204 0.478601 0.026 Uiso 1 1 calc R . . . .
 C13 C 0.8033(4) 0.4128(2) 0.44306(10) 0.0232(6) Uani 1 1 d . . . . .
 H13A H 0.694290 0.443370 0.462498 0.028 Uiso 1 1 calc R . . . .
 H13B H 0.911463 0.453752 0.457732 0.028 Uiso 1 1 calc R . . . .
 C14 C 0.8983(3) 0.0912(2) 0.40622(10) 0.0204(5) Uani 1 1 d . . . . .
 C15 C 0.8529(4) 0.0190(2) 0.35394(11) 0.0257(6) Uani 1 1 d . . . . .
 H15A H 0.935434 0.041464 0.322907 0.031 Uiso 1 1 calc R . . . .
 H15B H 0.876316 -0.062581 0.362586 0.031 Uiso 1 1 calc R . . . .
 C16 C 0.6569(4) 0.0317(2) 0.33423(12) 0.0290(6) Uani 1 1 d . . . . .
 H16A H 0.572273 0.009005 0.364687 0.035 Uiso 1 1 calc R . . . .
 H16B H 0.634608 -0.018331 0.301343 0.035 Uiso 1 1 calc R . . . .
 C17 C 0.6245(4) 0.1563(2) 0.31818(11) 0.0262(6) Uani 1 1 d . . . . .
 H17A H 0.500146 0.164657 0.302509 0.031 Uiso 1 1 calc R . . . .
 H17B H 0.712606 0.179081 0.288683 0.031 Uiso 1 1 calc R . . . .
 C18 C 0.8346(4) 0.0302(2) 0.45961(11) 0.0281(6) Uani 1 1 d . . . . .
 H18A H 0.872639 0.074190 0.492679 0.042 Uiso 1 1 calc GR . . . .
 H18B H 0.888896 -0.046387 0.461174 0.042 Uiso 1 1 calc GR . . . .
 H18C H 0.701448 0.023523 0.459200 0.042 Uiso 1 1 calc GR . . . .
 C19 C 1.1065(3) 0.1108(2) 0.40535(11) 0.0232(5) Uani 1 1 d . . . . .
 H19A H 1.153953 0.116961 0.444223 0.028 Uiso 1 1 calc R . . . .
 H19B H 1.168338 0.046068 0.386443 0.028 Uiso 1 1 calc R . . . .
 C20 C 0.7957(4) 0.6838(2) 0.28099(14) 0.0331(7) Uani 1 1 d . . . . .
 H20A H 0.811(4) 0.754(3) 0.3056(12) 0.038(8) Uiso 1 1 d . . . . .
 H20B H 0.803(4) 0.693(2) 0.2387(12) 0.033(8) Uiso 1 1 d . . . . .
 C21 C 0.5628(4) 0.7028(2) 0.40628(11) 0.0295(6) Uani 1 1 d . . . . .
 C22 C 0.3652(4) 0.7258(2) 0.42034(13) 0.0379(7) Uani 1 1 d . . . . .
 H22 H 0.313033 0.656447 0.438978 0.045 Uiso 1 1 calc R . . . .
 C23 C 0.2617(5) 0.7472(3) 0.36538(15) 0.0610(10) Uani 1 1 d . . . . .
 H23A H 0.311889 0.814967 0.346653 0.091 Uiso 1 1 calc GR . . . .
 H23B H 0.132422 0.759792 0.373650 0.091 Uiso 1 1 calc GR . . . .
 H23C H 0.274716 0.680604 0.340663 0.091 Uiso 1 1 calc GR . . . .
 C24 C 0.3484(5) 0.8268(3) 0.46042(15) 0.0549(10) Uani 1 1 d . . . . .
 H24A H 0.219418 0.840664 0.468741 0.082 Uiso 1 1 calc GR . . . .
 H24B H 0.401327 0.895007 0.442919 0.082 Uiso 1 1 calc GR . . . .
 H24C H 0.413493 0.809624 0.495427 0.082 Uiso 1 1 calc GR . . . .


_geom_special_details
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;
loop_
  _geom_bond_atom_site_label_1
  _geom_bond_atom_site_label_2
  _geom_bond_distance
  _geom_bond_site_symmetry_2
  _geom_bond_publ_flag
 O1 H1 0.8400 . ?
 O1 C10 1.438(3) . ?
 O2 C6 1.464(3) . ?
 O2 C21 1.344(3) . ?
 O3 C21 1.201(3) . ?
 N1 C1 1.275(3) . ?
 N1 C19 1.484(3) . ?
 C1 C2 1.502(3) . ?
 C1 C11 1.510(3) . ?
 C2 H2 1.0000 . ?
 C2 C3 1.555(4) . ?
 C2 C7 1.555(3) . ?
 C3 H3A 0.9900 . ?
 C3 H3B 0.9900 . ?
 C3 C4 1.533(4) . ?
 C4 H4 1.0000 . ?
 C4 C5 1.500(4) . ?
 C4 C9 1.541(4) . ?
 C5 C6 1.517(4) . ?
 C5 C20 1.327(4) . ?
 C6 H6 1.0000 . ?
 C6 C7 1.529(3) . ?
 C7 C8 1.542(3) . ?
 C7 C13 1.522(3) . ?
 C8 H8 1.0000 . ?
 C8 C9 1.553(3) . ?
 C8 C10 1.576(3) . ?
 C9 H9A 0.9900 . ?
 C9 H9B 0.9900 . ?
 C10 C11 1.550(3) . ?
 C10 C17 1.528(3) . ?
 C11 C12 1.545(3) . ?
 C11 C14 1.551(3) . ?
 C12 H12A 0.9900 . ?
 C12 H12B 0.9900 . ?
 C12 C13 1.551(3) . ?
 C13 H13A 0.9900 . ?
 C13 H13B 0.9900 . ?
 C14 C15 1.539(3) . ?
 C14 C18 1.529(3) . ?
 C14 C19 1.544(3) . ?
 C15 H15A 0.9900 . ?
 C15 H15B 0.9900 . ?
 C15 C16 1.519(4) . ?
 C16 H16A 0.9900 . ?
 C16 H16B 0.9900 . ?
 C16 C17 1.524(4) . ?
 C17 H17A 0.9900 . ?
 C17 H17B 0.9900 . ?
 C18 H18A 0.9800 . ?
 C18 H18B 0.9800 . ?
 C18 H18C 0.9800 . ?
 C19 H19A 0.9900 . ?
 C19 H19B 0.9900 . ?
 C20 H20A 1.02(3) . ?
 C20 H20B 1.01(3) . ?
 C21 C22 1.512(4) . ?
 C22 H22 1.0000 . ?
 C22 C23 1.531(4) . ?
 C22 C24 1.521(4) . ?
 C23 H23A 0.9800 . ?
 C23 H23B 0.9800 . ?
 C23 H23C 0.9800 . ?
 C24 H24A 0.9800 . ?
 C24 H24B 0.9800 . ?
 C24 H24C 0.9800 . ?

loop_
  _geom_angle_atom_site_label_1
  _geom_angle_atom_site_label_2
  _geom_angle_atom_site_label_3
  _geom_angle
  _geom_angle_site_symmetry_1
  _geom_angle_site_symmetry_3
  _geom_angle_publ_flag
 C10 O1 H1 109.5 . . ?
 C21 O2 C6 117.7(2) . . ?
 C1 N1 C19 107.56(19) . . ?
 N1 C1 C2 126.5(2) . . ?
 N1 C1 C11 115.8(2) . . ?
 C2 C1 C11 116.7(2) . . ?
 C1 C2 H2 109.3 . . ?
 C1 C2 C3 113.9(2) . . ?
 C1 C2 C7 104.97(19) . . ?
 C3 C2 H2 109.3 . . ?
 C7 C2 H2 109.3 . . ?
 C7 C2 C3 110.0(2) . . ?
 C2 C3 H3A 109.9 . . ?
 C2 C3 H3B 109.9 . . ?
 H3A C3 H3B 108.3 . . ?
 C4 C3 C2 109.1(2) . . ?
 C4 C3 H3A 109.9 . . ?
 C4 C3 H3B 109.9 . . ?
 C3 C4 H4 110.4 . . ?
 C3 C4 C9 108.2(2) . . ?
 C5 C4 C3 108.6(2) . . ?
 C5 C4 H4 110.4 . . ?
 C5 C4 C9 108.7(2) . . ?
 C9 C4 H4 110.4 . . ?
 C4 C5 C6 111.5(2) . . ?
 C20 C5 C4 125.4(3) . . ?
 C20 C5 C6 123.1(3) . . ?
 O2 C6 C5 109.6(2) . . ?
 O2 C6 H6 110.2 . . ?
 O2 C6 C7 106.55(19) . . ?
 C5 C6 H6 110.2 . . ?
 C5 C6 C7 109.9(2) . . ?
 C7 C6 H6 110.2 . . ?
 C6 C7 C2 107.70(19) . . ?
 C6 C7 C8 110.12(19) . . ?
 C8 C7 C2 106.81(19) . . ?
 C13 C7 C2 109.9(2) . . ?
 C13 C7 C6 111.8(2) . . ?
 C13 C7 C8 110.4(2) . . ?
 C7 C8 H8 106.2 . . ?
 C7 C8 C9 108.7(2) . . ?
 C7 C8 C10 110.40(18) . . ?
 C9 C8 H8 106.2 . . ?
 C9 C8 C10 118.5(2) . . ?
 C10 C8 H8 106.2 . . ?
 C4 C9 C8 110.3(2) . . ?
 C4 C9 H9A 109.6 . . ?
 C4 C9 H9B 109.6 . . ?
 C8 C9 H9A 109.6 . . ?
 C8 C9 H9B 109.6 . . ?
 H9A C9 H9B 108.1 . . ?
 O1 C10 C8 108.34(19) . . ?
 O1 C10 C11 104.89(17) . . ?
 O1 C10 C17 107.41(19) . . ?
 C11 C10 C8 108.89(18) . . ?
 C17 C10 C8 114.7(2) . . ?
 C17 C10 C11 112.03(19) . . ?
 C1 C11 C10 112.95(18) . . ?
 C1 C11 C12 101.86(18) . . ?
 C1 C11 C14 101.29(18) . . ?
 C10 C11 C14 117.83(19) . . ?
 C12 C11 C10 107.71(18) . . ?
 C12 C11 C14 114.01(19) . . ?
 C11 C12 H12A 109.8 . . ?
 C11 C12 H12B 109.8 . . ?
 C11 C12 C13 109.36(19) . . ?
 H12A C12 H12B 108.3 . . ?
 C13 C12 H12A 109.8 . . ?
 C13 C12 H12B 109.8 . . ?
 C7 C13 C12 111.2(2) . . ?
 C7 C13 H13A 109.4 . . ?
 C7 C13 H13B 109.4 . . ?
 C12 C13 H13A 109.4 . . ?
 C12 C13 H13B 109.4 . . ?
 H13A C13 H13B 108.0 . . ?
 C15 C14 C11 111.5(2) . . ?
 C15 C14 C19 106.5(2) . . ?
 C18 C14 C11 114.7(2) . . ?
 C18 C14 C15 110.3(2) . . ?
 C18 C14 C19 112.5(2) . . ?
 C19 C14 C11 100.57(18) . . ?
 C14 C15 H15A 108.9 . . ?
 C14 C15 H15B 108.9 . . ?
 H15A C15 H15B 107.7 . . ?
 C16 C15 C14 113.6(2) . . ?
 C16 C15 H15A 108.9 . . ?
 C16 C15 H15B 108.9 . . ?
 C15 C16 H16A 110.0 . . ?
 C15 C16 H16B 110.0 . . ?
 C15 C16 C17 108.6(2) . . ?
 H16A C16 H16B 108.4 . . ?
 C17 C16 H16A 110.0 . . ?
 C17 C16 H16B 110.0 . . ?
 C10 C17 H17A 109.4 . . ?
 C10 C17 H17B 109.4 . . ?
 C16 C17 C10 111.3(2) . . ?
 C16 C17 H17A 109.4 . . ?
 C16 C17 H17B 109.4 . . ?
 H17A C17 H17B 108.0 . . ?
 C14 C18 H18A 109.5 . . ?
 C14 C18 H18B 109.5 . . ?
 C14 C18 H18C 109.5 . . ?
 H18A C18 H18B 109.5 . . ?
 H18A C18 H18C 109.5 . . ?
 H18B C18 H18C 109.5 . . ?
 N1 C19 C14 107.24(19) . . ?
 N1 C19 H19A 110.3 . . ?
 N1 C19 H19B 110.3 . . ?
 C14 C19 H19A 110.3 . . ?
 C14 C19 H19B 110.3 . . ?
 H19A C19 H19B 108.5 . . ?
 C5 C20 H20A 120.6(16) . . ?
 C5 C20 H20B 120.8(15) . . ?
 H20A C20 H20B 119(2) . . ?
 O2 C21 C22 110.6(2) . . ?
 O3 C21 O2 124.0(2) . . ?
 O3 C21 C22 125.4(2) . . ?
 C21 C22 H22 108.7 . . ?
 C21 C22 C23 108.4(2) . . ?
 C21 C22 C24 110.8(3) . . ?
 C23 C22 H22 108.7 . . ?
 C24 C22 H22 108.7 . . ?
 C24 C22 C23 111.5(3) . . ?
 C22 C23 H23A 109.5 . . ?
 C22 C23 H23B 109.5 . . ?
 C22 C23 H23C 109.5 . . ?
 H23A C23 H23B 109.5 . . ?
 H23A C23 H23C 109.5 . . ?
 H23B C23 H23C 109.5 . . ?
 C22 C24 H24A 109.5 . . ?
 C22 C24 H24B 109.5 . . ?
 C22 C24 H24C 109.5 . . ?
 H24A C24 H24B 109.5 . . ?
 H24A C24 H24C 109.5 . . ?
 H24B C24 H24C 109.5 . . ?

_olex2_submission_special_instructions  'No special instructions were received'
