#\#CIF_1.1
 
#  CIF produced by WinGX routine CIF_UPDATE
#  Created on 2019-03-18 at 15:44:28
#  Using CIFtbx version 3.0.4  1 Sep 2006
 
#  Dictionary name : cif_core.dic
#  Dictionary vers : 2.4.3
#  Request file    : c:\wingx2014_1\files\acta.reqdat
#  CIF files read  : 149b_01_01_p3m1
 
#------------------ SECTION 1. GLOBAL INFORMATION ---------------------------#
 
data_global
 
#------------------ AUDIT DETAILS -------------------------------------------#
 
_audit_creation_date            2019-03-18
_audit_creation_method          'WinGX routine CIF_UPDATE'
_audit_conform_dict_name        cif_core.dic
_audit_conform_dict_version     2.4.3
_audit_conform_dict_location    ftp://ftp.iucr.org/pub/cif_core.dic
_audit_update_record            ?
 
# PROCESSING SUMMARY (IUCr Office Use Only)
 
_journal_data_validation_number      ?
 
_journal_date_recd_electronic        ?
_journal_date_to_coeditor            ?
_journal_date_from_coeditor          ?
_journal_date_accepted               ?
_journal_date_printers_first         ?
_journal_date_printers_final         ?
_journal_date_proofs_out             ?
_journal_date_proofs_in              ?
_journal_coeditor_name               ?
_journal_coeditor_code               ?
_journal_coeditor_notes
; ?
;
_journal_techeditor_code             ?
_journal_techeditor_notes
; ?
;
_journal_coden_ASTM                  ?
_journal_name_full                   ?
_journal_year                        ?
_journal_volume                      ?
_journal_issue                       ?
_journal_page_first                  ?
_journal_page_last                   ?
_journal_paper_category              ?
_journal_suppl_publ_number           ?
_journal_suppl_publ_pages            ?
 
#==============================================================================
#
# SUBMISSION DETAILS
# Name and address of author for correspondence
 
_publ_contact_author_name       'TAKEDA, Takashi'
_publ_contact_author_address
;
National Institute for Materials Science
Namiki 1-1
Tsukuba-shi
Ibaraki
305-0044 JAPAN
;
_publ_contact_author_email       'TAKEDA.Takashi@nims.go.jp'
_publ_contact_author_fax         ' '
_publ_contact_author_phone       ' '
 
 
_publ_contact_letter
;
 Submission dated :2019-03-18
 
Please consider this CIF submission for publication in Acta Cryst. Section
E.  I certify that all authors have seen and approved of this submission,
that all have made significant scientific contributions to the work reported,
and that all share responsibility and accountability for the results.
 
The CIF has passed the Chester CHECKCIF routines and all possible Alerts
have been responded to.  The CIF also gives a satisfactory PRINTCIF file.
 
When you reply by e-mail with your reference number I will return the
Copyright Transfer Form.
 
The Structure Factor Listing (in CIF format) and any artwork (Schemes,
Figures) as HPGL, PostScript, TIFF or encapsulated PostScript files will be
transferred to Chester by ftp as instructed in Notes for Authors 1.9.
 
<Insert NAME here>
 
;
 
_publ_requested_journal              'Acta Cryst E'
_publ_requested_category             ?   # one of EI/EM/EO
 
#==============================================================================
#
# TITLE AND AUTHOR LIST
 
_publ_section_title
; ?
;
_publ_section_title_footnote
; ?
;
 
# The loop structure below should contain the names and addresses of all
# authors, in the required order of publication. Repeat as necessary.
 
loop_
 _publ_author_name
 _publ_author_footnote
 _publ_author_address
?
?
;?
?
 
#==============================================================================
#
# TEXT
 
_publ_section_synopsis
; ?
;
# A synopsis (< 40 words) in place of the ? character is REQUIRED for
# inorganic structure papers in Acta Cryst C.
#
_publ_section_abstract
; ?
;
# Replace the ? character with a concise structurally-informative abstract
# The abstract should state the formula and systematic compound name if not
# already in the title.  It should also report any crystallographic symmetry
# (not 1) required of the structure by the space group.  Do not give crystal
# data here.
# -----------------------------------------------------------------------------
_publ_section_comment
; ?
;
# A Comment section is optional but recommended for  Acta E submissions.
# -----------------------------------------------------------------------------
_publ_section_acknowledgements
; ?
;
# Replace the ? character with any acknowledgements.
#
_publ_section_related_literature
; ?
;
_publ_section_references
;
Blessing, R. H. (1995) Acta Cryst., A51, 33-38.
 
Blessing, R. H. (1987) Cryst. Rev. 1, 3-58.
 
Blessing, R. H. (1989) J. Appl. Cryst. 22, 396-397.
 
Bruker (2012) APEX2 (Version 2012.10-0), SAINT (version 8.27B), SADABS
(version 2012/1), BrukerAXS Inc, Madison, Wisconsin, USA.
 
JANA2000: Petricek, V. & Dusek, M. (2000). JANA2000. Institute of Physics,
Czech Academy of Sciences, Prague, Czech Republic.
 
PLATON: Spek, A. L. (2009). Acta. Cryst. D65, 148-155.
 
SHELX: Sheldrick, G. M. (2008). Acta Cryst. A64, 112-122.
 
SHELXD: Schneider, T. R. & Sheldrick, G. M. (2002) Acta Cryst. D58, 1772-1779.
;

#  List of references should be in alphabetical sequence with one blank
#  line between each reference.  See Notes for Authors for full
#  specifications as to how references should be presented.
#  Scattering-factor references are not needed here
# -----------------------------------------------------------------------------
_publ_section_figure_captions
; ?

#  Replace the '?" character with e.g.
#  "Fig. 1.  A view of (1).  Displacement ellipsoids are drawn at the 30%
#   probability level."
#  Figures and legends are not required, but are strongly encouraged, for
#  Acta E submissions
#
 
_publ_section_table_legends
; ?
;
#  Replace the '?" character with e.g.
#   "Table 1.  Selected geometric parameters (\%A, \%) for compound (1)."
#
#   "Table 2.  Hydrogen-bond parameters (\%A, \%) for compound (1)."
#
# -----------------------------------------------------------------------------
 
_publ_section_exptl_prep
; ?
;
# Replace the ? character with concise details including reagent quantities
# and reaction conditions of compound preparation. A reference may suffice,
# but do give sufficient brief details if the method is unpublished or
# deviates from a published method. Also give the crystallisation procedure
# and solvent(s).  This is a good place to give any physical details such as
# analytical and supportive spectroscopic data, and melting point if known.
# Long lists of spectroscopic data should not be given here but should be
# placed in the _exptl_special_details section of the CIF.
# ---
_publ_section_exptl_refinement
; ?
;
# Replace the ? character with concise details of any UNUSUAL aspects of the
# data collection and structure analysis.
# If H atoms were not treated as "constrained", details of how they were
# allowed for and range of refined  X-H distances MUST be given here. For
# constrained X-H distances, report the ranges of the various X-H dimensions
# and treatment of U(H).
# Routine statements about data collection and processing, structure
# solution methods or anisotropic refinement should NOT be given here
# (this information is generated automatically from other details in the
# CIF).
# Note that if RESTRAINTS are used in the refinement,  concise details
# of what these were should either be given here or in the
# _refinement_special
#
#------------------  SECTION 2. COMPOUND(S) DETAILS -------------------------#
 
data_149b_01_01_p3m1
 
_audit_creation_date                    2019-03-18T15:44:28-00:00
_audit_creation_method                  'WinGX routine CIF_UPDATE'
 
#==============================================================================
 
# CHEMICAL DATA
 
_chemical_name_systematic
;
 ?
;
_chemical_formula_sum                  
 ' Al4.51 Eu0.41 La3.19 Li N27.28 O2.12 Si15.29 '
_chemical_formula_weight                1479.60
_chemical_absolute_configuration        unk
 
#==============================================================================
 
# CRYSTAL DATA
 
_symmetry_cell_setting                  trigonal
_symmetry_space_group_name_H-M          'P 3 m 1'
_symmetry_space_group_name_Hall         'P 3 -2"'

loop_
 _space_group_symop_operation_xyz
 'x, y, z'
 '-y, x-y, z'
 '-x+y, -x, z'
 '-x+y, y, z'
 'x, x-y, z'
 '-y, -x, z'
 
_cell_measurement_reflns_used           3528
_cell_measurement_theta_min             3.867
_cell_measurement_theta_max             36.291
_cell_length_a                          12.1680(6)
_cell_length_b                          12.1680(6)
_cell_length_c                          4.8290(3)
_cell_angle_alpha                       90
_cell_angle_beta                        90
_cell_angle_gamma                       120
_cell_volume                            619.19(7)
_cell_formula_units_Z                   1
_cell_measurement_temperature           293(2)
_exptl_crystal_description        'columnar'
_exptl_crystal_colour             'clear'
_exptl_crystal_size_max           0.029
_exptl_crystal_size_mid           0.010
_exptl_crystal_size_min           0.008
_exptl_crystal_density_diffrn           3.968
_exptl_crystal_F_000                     691.3 
_exptl_absorpt_coefficient_mu            7.408 
_exptl_absorpt_correction_type    'multi-scan'
_exptl_absorpt_correction_T_min   0.943
_exptl_absorpt_correction_T_max   0.945
_exptl_absorpt_process_details
;
SADABS Sheldrick 2001
;
 
#==============================================================================
 
# EXPERIMENTAL DATA
 
_exptl_special_details
;
 ?
;
_diffrn_ambient_temperature             293(2)
_diffrn_radiation_type                  MoK\a
_diffrn_radiation_wavelength            0.71073
_diffrn_radiation_source          'Bruker TXS fine-focus rotating anode'
_diffrn_radiation_monochromator   'Bruker Helios multilayer confocal mirror'
_diffrn_measurement_device_type   'Bruker APEXII CCD area detector'
_diffrn_measurement_method        'omega scans'
_diffrn_detector_area_resol_mean  8.333
_diffrn_reflns_number                   7432
_diffrn_reflns_av_R_equivalents         0.0272
_diffrn_reflns_theta_min                1.933
_diffrn_reflns_theta_max                35.605
_diffrn_reflns_theta_full               25.242
_diffrn_measured_fraction_theta_max
                                        1
_diffrn_measured_fraction_theta_full
                                        0.998
_diffrn_reflns_Laue_measured_fraction_full
                                        0.998
_diffrn_reflns_Laue_measured_fraction_max
                                        1
_diffrn_reflns_point_group_measured_fraction_full
                                        0.992
_diffrn_reflns_point_group_measured_fraction_max
                                        0.957
_diffrn_reflns_limit_h_min              -13
_diffrn_reflns_limit_h_max              19
_diffrn_reflns_limit_k_min              -19
_diffrn_reflns_limit_k_max              19
_diffrn_reflns_limit_l_min              -7
_diffrn_reflns_limit_l_max              6
 
#==============================================================================
 
# STRUCTURE SOLUTION
 
 
#==============================================================================
 
# REFINEMENT DATA
 
_refine_special_details
;
 Refined as a 2-component twin.
;
_reflns_number_total                    2011
_reflns_number_gt                       1938
_reflns_threshold_expression            'I > 2σ(I)'
_refine_ls_structure_factor_coef        Fsqd
_refine_ls_matrix_type                  full
_refine_ls_R_factor_all                 0.0302
_refine_ls_R_factor_gt                  0.0282
_refine_ls_wR_factor_ref                0.067
_refine_ls_goodness_of_fit_ref          1.044
_refine_ls_restrained_S_all             1.044
_refine_ls_number_reflns                2011
_refine_ls_number_parameters            111
_refine_ls_number_restraints            1
_refine_ls_hydrogen_treatment           undef
_refine_ls_weighting_scheme             calc
_refine_ls_weighting_details
;
 w=1/[σ²(Fo²)+(0.0320P)²+2.8759P]
 where P=(Fo²+2Fc²)/3
;
_refine_ls_shift/su_max                 0.001
_refine_ls_shift/su_mean                0
_refine_diff_density_max                1.31
_refine_diff_density_min                -0.829
_refine_diff_density_rms                0.16
_refine_ls_extinction_method            none
_refine_ls_abs_structure_details
;
 Flack x determined using 882 quotients [(I+)-(I-)]/[(I+)+(I-)]
 (Parsons and Flack (2004), Acta Cryst. A60, s61).
;
_refine_ls_abs_structure_Flack          -0.05(2)
loop_
    _atom_type_symbol
    _atom_type_description
    _atom_type_scat_dispersion_real
    _atom_type_scat_dispersion_imag
    _atom_type_scat_source
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Si Si 0.0817 0.0704 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
La La -0.2871 2.4523 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Li Li -0.0003 0.0001 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.006 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Al Al 0.0645 0.0514 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Eu Eu -0.1578 3.6682 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
 
_computing_data_collection        'APEX2 (Bruker AXS, 2009)'
_computing_cell_refinement        'APEX2 (Bruker AXS, 2009)'
_computing_data_reduction         'SAINT (Bruker AXS, 2009)'
_computing_structure_solution     'SHELXS-97 (Sheldrick, 2008)'
_computing_molecular_graphics     'VESTA (Momma and Izumi, 2011)'
_computing_publication_material   ?
 
#==============================================================================
 
# ATOMIC COORDINATES AND DISPLACEMENT PARAMETERS
 
loop_
    _atom_site_label
    _atom_site_fract_x
    _atom_site_fract_y
    _atom_site_fract_z
    _atom_site_U_iso_or_equiv
    _atom_site_adp_type
    _atom_site_calc_flag
    _atom_site_occupancy
    _atom_site_disorder_assembly
    _atom_site_disorder_group
    _atom_site_type_symbol
La1 0.55166(2) 0.10333(5) 0.3223(2) 0.01180(10) Uani d 0.8852 . . La
Eu1 0.55166(2) 0.10333(5) 0.3223(2) 0.01180(10) Uani d 0.1148 . . Eu
La2 1 0 0.6152(17) 0.0080(10) Uani d 0.136 . . La
Eu2 1 0 0.6152(17) 0.0080(10) Uani d 0.0176 . . Eu
La3 1 0 0.7620(10) 0.0393(11) Uani d 0.3938 . . La
Eu3 1 0 0.7620(10) 0.0393(11) Uani d 0.0511 . . Eu
Li1 0.3333 0.6667 0.876(5) 0.002(5) Uiso d 1 . . Li
Si1 0.59039(15) 0.92235(14) 0.8203(6) 0.0047(2) Uani d 0.7722 . . Si
Al1 0.59039(15) 0.92235(14) 0.8203(6) 0.0047(2) Uani d 0.2278 . . Al
Si2 0.5078(3) 0.75388(13) 0.3263(10) 0.0093(4) Uani d 0.7722 . . Si
Al2 0.5078(3) 0.75388(13) 0.3263(10) 0.0093(4) Uani d 0.2278 . . Al
Si3 0.75925(16) 0.00193(17) 0.3015(6) 0.0052(3) Uani d 0.7722 . . Si
Al3 0.75925(16) 0.00193(17) 0.3015(6) 0.0052(3) Uani d 0.2278 . . Al
Si4 0.81844(12) 0.18156(12) 0.7875(6) 0.0053(5) Uani d 0.7722 . . Si
Al4 0.81844(12) 0.18156(12) 0.7875(6) 0.0053(5) Uani d 0.2278 . . Al
Si5 0.6667 0.3333 0.7874(12) 0.0059(9) Uani d 0.7723 . . Si
Al5 0.6667 0.3333 0.7874(12) 0.0059(9) Uani d 0.2278 . . Al
Si6 1 0 0.116(3) 0.0092(16) Uani d 0.3101 . . Si
Al6 1 0 0.116(3) 0.0092(16) Uani d 0.0914 . . Al
Si7 1 0 0.430(3) 0.0092(16) Uani d 0.3101 . . Si
Al7 1 0 0.430(3) 0.0092(16) Uani d 0.0914 . . Al
N1 0.8634(5) 0.1366(5) 0.489(2) 0.0147(17) Uani d 0.9279 . . N
O1 0.8634(5) 0.1366(5) 0.489(2) 0.0147(17) Uani d 0.0721 . . O
N2 0.6107(6) 0.9245(6) 0.4640(13) 0.0080(9) Uani d 0.9279 . . N
O2 0.6107(6) 0.9245(6) 0.4640(13) 0.0080(9) Uani d 0.0721 . . O
N3 0.8402(8) 0.9201(4) 0.2677(19) 0.0117(18) Uani d 0.9279 . . N
O3 0.8402(8) 0.9201(4) 0.2677(19) 0.0117(18) Uani d 0.0721 . . O
N4 0.3333 0.6667 0.386(6) 0.031(7) Uani d 0.9279 . . N
O4 0.3333 0.6667 0.386(6) 0.031(7) Uani d 0.0721 . . O
N5 0.5521(12) 0.7760(6) 0.956(2) 0.0139(16) Uani d 0.9279 . . N
O5 0.5521(12) 0.7760(6) 0.956(2) 0.0139(16) Uani d 0.0721 . . O
N6 0.4825(5) 0.9650(10) 0.8893(18) 0.0125(17) Uani d 0.9279 . . N
O6 0.4825(5) 0.9650(10) 0.8893(18) 0.0125(17) Uani d 0.0721 . . O
N7 0.7246(6) 0.0474(6) 0.9843(13) 0.0116(11) Uani d 0.9279 . . N
O7 0.7246(6) 0.0474(6) 0.9843(13) 0.0116(11) Uani d 0.0721 . . O
N8 0.6667 0.3333 0.134(3) 0.010(3) Uani d 0.9279 . . N
O8 0.6667 0.3333 0.134(3) 0.010(3) Uani d 0.0721 . . O
N9 0.7422(5) 0.2578(5) 0.663(2) 0.0125(16) Uani d 0.9279 . . N
O9 0.7422(5) 0.2578(5) 0.663(2) 0.0125(16) Uani d 0.0721 . . O
N10 1 0 0.7620(10) 0.0393(11) Uani d 0.3725 . . N
O10 1 0 0.7620(10) 0.0393(11) Uani d 0.029 . . O
 
 
 
#==============================================================================
 
# MOLECULAR GEOMETRY
 
_geom_special_details
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;
loop_
    _geom_bond_atom_site_label_1
    _geom_bond_atom_site_label_2
    _geom_bond_site_symmetry_2
    _geom_bond_distance
    _geom_bond_publ_flag
La1 O6 1_544 2.549(9) ?
La1 N6 1_544 2.549(9) ?
La1 N8 . 2.589(5) ?
La1 N9 . 2.694(6) ?
La1 O9 3_665 2.694(6) ?
La1 N9 3_665 2.694(6) ?
La1 O2 1_545 2.698(6) ?
La1 N2 1_545 2.698(6) ?
La1 O2 4_545 2.698(6) ?
La1 N2 4_545 2.698(6) ?
La2 O3 1_545 2.377(11) ?
La2 N3 1_545 2.377(11) ?
La2 O3 3_665 2.377(11) ?
La2 N3 3_665 2.377(11) ?
La2 O3 2_755 2.377(11) ?
La2 N3 2_755 2.377(11) ?
La3 O3 1_545 2.921(10) ?
La3 N3 1_545 2.921(10) ?
La3 O3 3_665 2.921(10) ?
La3 N3 3_665 2.921(10) ?
La3 O3 2_755 2.921(10) ?
La3 N3 2_755 2.921(10) ?
Li1 O5 2_665 2.337(13) ?
Li1 N5 2_665 2.337(13) ?
Li1 O5 3_565 2.337(13) ?
Li1 N5 3_565 2.337(13) ?
Li1 N5 . 2.337(13) ?
Li1 N4 . 2.37(4) ?
Li1 O4 1_556 2.46(4) ?
Li1 N4 1_556 2.46(4) ?
Si1 N6 . 1.669(4) ?
Si1 N5 . 1.728(5) ?
Si1 N2 . 1.736(7) ?
Si1 O7 1_565 1.768(7) ?
Si1 N7 1_565 1.768(7) ?
Si2 O5 1_554 1.850(11) ?
Si2 N5 1_554 1.850(11) ?
Si2 N4 . 1.860(5) ?
Si2 O2 5_565 1.929(6) ?
Si2 N2 5_565 1.929(6) ?
Si2 N2 . 1.929(6) ?
Si3 O3 1_545 1.723(5) ?
Si3 N3 1_545 1.723(5) ?
Si3 N1 . 1.741(6) ?
Si3 O7 1_554 1.751(7) ?
Si3 N7 1_554 1.751(7) ?
Si3 O2 1_545 1.752(6) ?
Si3 N2 1_545 1.752(6) ?
Si4 N9 . 1.716(10) ?
Si4 N1 . 1.726(11) ?
Si4 N7 . 1.734(7) ?
Si4 O7 6_665 1.734(7) ?
Si4 N7 6_665 1.734(7) ?
Si5 O8 1_556 1.673(16) ?
Si5 N8 1_556 1.673(16) ?
Si5 N9 . 1.701(10) ?
Si5 O9 3_665 1.701(10) ?
Si5 N9 3_665 1.701(10) ?
Si5 O9 2_655 1.701(10) ?
Si5 N9 2_655 1.701(10) ?
Si6 O10 1_554 1.711(16) ?
Si6 N10 1_554 1.711(16) ?
Si6 O3 3_665 1.836(11) ?
Si6 N3 3_665 1.836(11) ?
Si6 O3 1_545 1.836(11) ?
Si6 N3 1_545 1.836(11) ?
Si6 O3 2_755 1.836(11) ?
Si6 N3 2_755 1.836(11) ?
Si7 O3 1_545 1.856(11) ?
Si7 N3 1_545 1.856(11) ?
Si7 O3 3_665 1.856(11) ?
Si7 N3 3_665 1.856(11) ?
N1 Al3 6_665 1.741(6) ?
N1 Si3 6_665 1.741(6) ?
N2 Al3 1_565 1.752(6) ?
N2 Si3 1_565 1.752(6) ?
N2 La1 1_565 2.698(6) ?
N2 Eu1 1_565 2.698(6) ?
N3 Al3 5 1.723(5) ?
N3 Si3 5 1.723(5) ?
N3 Al3 1_565 1.723(5) ?
N3 Si3 1_565 1.723(5) ?
N3 Al6 1_565 1.836(11) ?
N3 Si6 1_565 1.836(11) ?
N3 Al7 1_565 1.856(11) ?
N3 Si7 1_565 1.856(11) ?
N3 Eu2 1_565 2.377(11) ?
N3 La2 1_565 2.377(11) ?
N3 La3 1_565 2.921(10) ?
N3 Eu3 1_565 2.921(10) ?
N4 Al2 2_665 1.861(5) ?
N4 Si2 2_665 1.861(5) ?
N4 Al2 3_565 1.861(5) ?
N4 Si2 3_565 1.861(5) ?
N4 Li1 1_554 2.46(4) ?
N5 Al1 5_565 1.728(5) ?
N5 Si1 5_565 1.728(5) ?
N5 Al2 1_556 1.850(11) ?
N5 Si2 1_556 1.850(11) ?
N6 Al1 4 1.669(4) ?
N6 Si1 4 1.669(4) ?
N6 La1 1_566 2.549(9) ?
N6 Eu1 1_566 2.549(9) ?
N6 Eu1 1_565 3.102(9) ?
N7 Al3 1_556 1.751(7) ?
N7 Si3 1_556 1.751(7) ?
N7 Al1 1_545 1.768(6) ?
N7 Si1 1_545 1.768(6) ?
N7 La1 1_556 2.998(7) ?
N7 Eu1 1_556 2.998(7) ?
N8 Al5 1_554 1.673(16) ?
N8 Si5 1_554 1.673(16) ?
N8 Eu1 2_655 2.589(5) ?
N8 La1 2_655 2.589(5) ?
N8 La1 3_665 2.589(5) ?
N8 Eu1 3_665 2.589(5) ?
N9 Eu1 2_655 2.694(6) ?
N9 La1 2_655 2.694(6) ?
 
loop_
    _geom_angle_atom_site_label_1
    _geom_angle_atom_site_label_2
    _geom_angle_atom_site_label_3
    _geom_angle
    _geom_angle_site_symmetry_1
    _geom_angle_site_symmetry_3
    _geom_angle_publ_flag
O6 La1 N6 0.0(5) 1_544 1_544 ?
O6 La1 N8 104.3(4) 1_544 . ?
N6 La1 N8 104.3(4) 1_544 . ?
O6 La1 N9 147.8(2) 1_544 . ?
N6 La1 N9 147.8(2) 1_544 . ?
N8 La1 N9 69.4(3) . . ?
O6 La1 O9 147.8(2) 1_544 3_665 ?
N6 La1 O9 147.8(2) 1_544 3_665 ?
N8 La1 O9 69.4(3) . 3_665 ?
N9 La1 O9 61.6(4) . 3_665 ?
O6 La1 N9 147.8(2) 1_544 3_665 ?
N6 La1 N9 147.8(2) 1_544 3_665 ?
N8 La1 N9 69.4(3) . 3_665 ?
N9 La1 N9 61.6(4) . 3_665 ?
O9 La1 N9 0.0(5) 3_665 3_665 ?
O6 La1 O2 79.0(2) 1_544 1_545 ?
N6 La1 O2 79.0(2) 1_544 1_545 ?
N8 La1 O2 137.98(13) . 1_545 ?
N9 La1 O2 85.7(2) . 1_545 ?
O9 La1 O2 127.6(2) 3_665 1_545 ?
N9 La1 O2 127.6(2) 3_665 1_545 ?
O6 La1 N2 79.0(2) 1_544 1_545 ?
N6 La1 N2 79.0(2) 1_544 1_545 ?
N8 La1 N2 137.98(13) . 1_545 ?
N9 La1 N2 85.7(2) . 1_545 ?
O9 La1 N2 127.6(2) 3_665 1_545 ?
N9 La1 N2 127.6(2) 3_665 1_545 ?
O2 La1 N2 0.0(3) 1_545 1_545 ?
O6 La1 O2 79.0(2) 1_544 4_545 ?
N6 La1 O2 79.0(2) 1_544 4_545 ?
N8 La1 O2 137.98(13) . 4_545 ?
N9 La1 O2 127.6(2) . 4_545 ?
O9 La1 O2 85.7(2) 3_665 4_545 ?
N9 La1 O2 85.7(2) 3_665 4_545 ?
O2 La1 O2 84.0(3) 1_545 4_545 ?
N2 La1 O2 84.0(3) 1_545 4_545 ?
O6 La1 N2 79.0(2) 1_544 4_545 ?
N6 La1 N2 79.0(2) 1_544 4_545 ?
N8 La1 N2 137.98(13) . 4_545 ?
N9 La1 N2 127.6(2) . 4_545 ?
O9 La1 N2 85.7(2) 3_665 4_545 ?
N9 La1 N2 85.7(2) 3_665 4_545 ?
O2 La1 N2 84.0(3) 1_545 4_545 ?
N2 La1 N2 84.0(3) 1_545 4_545 ?
O2 La1 N2 0.0(5) 4_545 4_545 ?
O3 La2 N3 0.0(4) 1_545 1_545 ?
O3 La2 O3 75.7(4) 1_545 3_665 ?
N3 La2 O3 75.7(4) 1_545 3_665 ?
O3 La2 N3 75.7(4) 1_545 3_665 ?
N3 La2 N3 75.7(4) 1_545 3_665 ?
O3 La2 N3 0.0(5) 3_665 3_665 ?
O3 La2 O3 75.7(4) 1_545 2_755 ?
N3 La2 O3 75.7(4) 1_545 2_755 ?
O3 La2 O3 75.7(4) 3_665 2_755 ?
N3 La2 O3 75.7(4) 3_665 2_755 ?
O3 La2 N3 75.7(4) 1_545 2_755 ?
N3 La2 N3 75.7(4) 1_545 2_755 ?
O3 La2 N3 75.7(4) 3_665 2_755 ?
N3 La2 N3 75.7(4) 3_665 2_755 ?
O3 La2 N3 0.0(4) 2_755 2_755 ?
O3 La3 N3 0.0(3) 1_545 1_545 ?
O3 La3 O3 59.9(3) 1_545 3_665 ?
N3 La3 O3 59.9(3) 1_545 3_665 ?
O3 La3 N3 59.9(3) 1_545 3_665 ?
N3 La3 N3 59.9(3) 1_545 3_665 ?
O3 La3 N3 0.0(4) 3_665 3_665 ?
O3 La3 O3 59.9(3) 1_545 2_755 ?
N3 La3 O3 59.9(3) 1_545 2_755 ?
O3 La3 O3 59.9(3) 3_665 2_755 ?
N3 La3 O3 59.9(3) 3_665 2_755 ?
O3 La3 N3 59.9(3) 1_545 2_755 ?
N3 La3 N3 59.9(3) 1_545 2_755 ?
O3 La3 N3 59.9(3) 3_665 2_755 ?
N3 La3 N3 59.9(3) 3_665 2_755 ?
O3 La3 N3 0.0(3) 2_755 2_755 ?
O5 Li1 N5 0.00(18) 2_665 2_665 ?
O5 Li1 O5 117.3(4) 2_665 3_565 ?
N5 Li1 O5 117.3(4) 2_665 3_565 ?
O5 Li1 N5 117.3(4) 2_665 3_565 ?
N5 Li1 N5 117.3(4) 2_665 3_565 ?
O5 Li1 N5 0.0(3) 3_565 3_565 ?
O5 Li1 N5 117.3(4) 2_665 . ?
N5 Li1 N5 117.3(4) 2_665 . ?
O5 Li1 N5 117.3(4) 3_565 . ?
N5 Li1 N5 117.3(4) 3_565 . ?
O5 Li1 N4 99.5(6) 2_665 . ?
N5 Li1 N4 99.5(6) 2_665 . ?
O5 Li1 N4 99.5(6) 3_565 . ?
N5 Li1 N4 99.5(6) 3_565 . ?
N5 Li1 N4 99.5(6) . . ?
O5 Li1 O4 80.5(6) 2_665 1_556 ?
N5 Li1 O4 80.5(6) 2_665 1_556 ?
O5 Li1 O4 80.5(6) 3_565 1_556 ?
N5 Li1 O4 80.5(6) 3_565 1_556 ?
N5 Li1 O4 80.5(6) . 1_556 ?
N4 Li1 O4 180 . 1_556 ?
O5 Li1 N4 80.5(6) 2_665 1_556 ?
N5 Li1 N4 80.5(6) 2_665 1_556 ?
O5 Li1 N4 80.5(6) 3_565 1_556 ?
N5 Li1 N4 80.5(6) 3_565 1_556 ?
N5 Li1 N4 80.5(6) . 1_556 ?
N4 Li1 N4 180 . 1_556 ?
O4 Li1 N4 0.000(10) 1_556 1_556 ?
O5 Li1 Al2 40.3(4) 2_665 2_666 ?
N5 Li1 Al2 40.3(4) 2_665 2_666 ?
O5 Li1 Al2 101.1(7) 3_565 2_666 ?
N5 Li1 Al2 101.1(7) 3_565 2_666 ?
N5 Li1 Al2 101.1(7) . 2_666 ?
N4 Li1 Al2 139.8(3) . 2_666 ?
O4 Li1 Al2 40.2(3) 1_556 2_666 ?
N4 Li1 Al2 40.2(3) 1_556 2_666 ?
O5 Li1 Si2 40.3(4) 2_665 2_666 ?
N5 Li1 Si2 40.3(4) 2_665 2_666 ?
O5 Li1 Si2 101.1(7) 3_565 2_666 ?
N5 Li1 Si2 101.1(7) 3_565 2_666 ?
N5 Li1 Si2 101.1(7) . 2_666 ?
N4 Li1 Si2 139.8(3) . 2_666 ?
O4 Li1 Si2 40.2(3) 1_556 2_666 ?
N4 Li1 Si2 40.2(3) 1_556 2_666 ?
N6 Si1 N5 113.3(5) . . ?
N6 Si1 N2 108.7(4) . . ?
N5 Si1 N2 110.7(4) . . ?
N6 Si1 O7 100.0(4) . 1_565 ?
N5 Si1 O7 112.0(5) . 1_565 ?
N2 Si1 O7 111.6(3) . 1_565 ?
N6 Si1 N7 100.0(4) . 1_565 ?
N5 Si1 N7 112.0(5) . 1_565 ?
N2 Si1 N7 111.6(3) . 1_565 ?
O7 Si1 N7 0.0(6) 1_565 1_565 ?
O5 Si2 N5 0.0(5) 1_554 1_554 ?
O5 Si2 N4 113.5(9) 1_554 . ?
N5 Si2 N4 113.5(9) 1_554 . ?
O5 Si2 O2 101.0(3) 1_554 5_565 ?
N5 Si2 O2 101.0(3) 1_554 5_565 ?
N4 Si2 O2 120.1(4) . 5_565 ?
O5 Si2 N2 101.0(3) 1_554 5_565 ?
N5 Si2 N2 101.0(3) 1_554 5_565 ?
N4 Si2 N2 120.1(4) . 5_565 ?
O2 Si2 N2 0.0(4) 5_565 5_565 ?
O5 Si2 N2 101.0(3) 1_554 . ?
N5 Si2 N2 101.0(3) 1_554 . ?
N4 Si2 N2 120.1(4) . . ?
O2 Si2 N2 97.5(4) 5_565 . ?
N2 Si2 N2 97.5(4) 5_565 . ?
O3 Si3 N3 0.0(6) 1_545 1_545 ?
O3 Si3 N1 103.6(5) 1_545 . ?
N3 Si3 N1 103.6(5) 1_545 . ?
O3 Si3 O7 113.4(4) 1_545 1_554 ?
N3 Si3 O7 113.4(4) 1_545 1_554 ?
N1 Si3 O7 109.5(4) . 1_554 ?
O3 Si3 N7 113.4(4) 1_545 1_554 ?
N3 Si3 N7 113.4(4) 1_545 1_554 ?
N1 Si3 N7 109.5(4) . 1_554 ?
O7 Si3 N7 0.0(5) 1_554 1_554 ?
O3 Si3 O2 117.8(3) 1_545 1_545 ?
N3 Si3 O2 117.8(3) 1_545 1_545 ?
N1 Si3 O2 110.1(4) . 1_545 ?
O7 Si3 O2 102.4(3) 1_554 1_545 ?
N7 Si3 O2 102.4(3) 1_554 1_545 ?
O3 Si3 N2 117.8(3) 1_545 1_545 ?
N3 Si3 N2 117.8(3) 1_545 1_545 ?
N1 Si3 N2 110.1(4) . 1_545 ?
O7 Si3 N2 102.4(3) 1_554 1_545 ?
N7 Si3 N2 102.4(3) 1_554 1_545 ?
O2 Si3 N2 0.0(7) 1_545 1_545 ?
N9 Si4 N1 102.8(5) . . ?
N9 Si4 N7 114.9(3) . . ?
N1 Si4 N7 108.9(3) . . ?
N9 Si4 O7 114.9(3) . 6_665 ?
N1 Si4 O7 108.9(3) . 6_665 ?
N7 Si4 O7 106.2(5) . 6_665 ?
N9 Si4 N7 114.9(3) . 6_665 ?
N1 Si4 N7 108.9(3) . 6_665 ?
N7 Si4 N7 106.2(5) . 6_665 ?
O7 Si4 N7 0.0(4) 6_665 6_665 ?
O8 Si5 N8 0.000(5) 1_556 1_556 ?
O8 Si5 N9 110.7(4) 1_556 . ?
N8 Si5 N9 110.7(4) 1_556 . ?
O8 Si5 O9 110.7(4) 1_556 3_665 ?
N8 Si5 O9 110.7(4) 1_556 3_665 ?
N9 Si5 O9 108.2(4) . 3_665 ?
O8 Si5 N9 110.7(4) 1_556 3_665 ?
N8 Si5 N9 110.7(4) 1_556 3_665 ?
N9 Si5 N9 108.2(4) . 3_665 ?
O9 Si5 N9 0.0(9) 3_665 3_665 ?
O8 Si5 O9 110.7(4) 1_556 2_655 ?
N8 Si5 O9 110.7(4) 1_556 2_655 ?
N9 Si5 O9 108.2(4) . 2_655 ?
O9 Si5 O9 108.2(4) 3_665 2_655 ?
N9 Si5 O9 108.2(4) 3_665 2_655 ?
O8 Si5 N9 110.7(4) 1_556 2_655 ?
N8 Si5 N9 110.7(4) 1_556 2_655 ?
N9 Si5 N9 108.2(4) . 2_655 ?
O9 Si5 N9 108.2(4) 3_665 2_655 ?
N9 Si5 N9 108.2(4) 3_665 2_655 ?
O9 Si5 N9 0.0(8) 2_655 2_655 ?
Si7 Si6 O10 180 . 1_554 ?
Si7 Si6 N10 180 . 1_554 ?
O10 Si6 N10 0 1_554 1_554 ?
O10 Si6 O3 113.5(5) 1_554 3_665 ?
N10 Si6 O3 113.5(5) 1_554 3_665 ?
O10 Si6 N3 113.5(5) 1_554 3_665 ?
N10 Si6 N3 113.5(5) 1_554 3_665 ?
O3 Si6 N3 0.0(6) 3_665 3_665 ?
O10 Si6 O3 113.5(5) 1_554 1_545 ?
N10 Si6 O3 113.5(5) 1_554 1_545 ?
O3 Si6 O3 105.2(6) 3_665 1_545 ?
N3 Si6 O3 105.2(6) 3_665 1_545 ?
O10 Si6 N3 113.5(5) 1_554 1_545 ?
N10 Si6 N3 113.5(5) 1_554 1_545 ?
O3 Si6 N3 105.2(6) 3_665 1_545 ?
N3 Si6 N3 105.2(6) 3_665 1_545 ?
O3 Si6 N3 0.0(4) 1_545 1_545 ?
O10 Si6 O3 113.5(5) 1_554 2_755 ?
N10 Si6 O3 113.5(5) 1_554 2_755 ?
O3 Si6 O3 105.2(6) 3_665 2_755 ?
N3 Si6 O3 105.2(6) 3_665 2_755 ?
O3 Si6 O3 105.2(6) 1_545 2_755 ?
N3 Si6 O3 105.2(6) 1_545 2_755 ?
O10 Si6 N3 113.5(5) 1_554 2_755 ?
N10 Si6 N3 113.5(5) 1_554 2_755 ?
O3 Si6 N3 105.2(6) 3_665 2_755 ?
N3 Si6 N3 105.2(6) 3_665 2_755 ?
O3 Si6 N3 105.2(6) 1_545 2_755 ?
N3 Si6 N3 105.2(6) 1_545 2_755 ?
O3 Si6 N3 0.0(4) 2_755 2_755 ?
O3 Si7 N3 0.0(4) 1_545 1_545 ?
O3 Si7 O3 103.5(6) 1_545 3_665 ?
N3 Si7 O3 103.5(6) 1_545 3_665 ?
O3 Si7 N3 103.5(6) 1_545 3_665 ?
N3 Si7 N3 103.5(6) 1_545 3_665 ?
O3 Si7 N3 0.0(7) 3_665 3_665 ?
 
 
 
# The following lines are used to test the character set of files sent by
# network email or other means. They are not part of the CIF data set
# abcdefghijklmnopqrstuvwxyzABCDEFGHIJKLMNOPQRSTUVWXYZ0123456789
# !@#$%^&*()_+{}:"~<>?|\-=[];'`,./
 
# END of CIF
