 
data_anlea-t7-red 
 
_audit_creation_method            SHELXL-97 
_chemical_name_systematic 
; 
 ? 
; 
_chemical_name_common             ? 
_chemical_melting_point           ? 
_chemical_formula_moiety          
'C120 H104 Au10 N8 P8 S4, 2(F6 P), C2 H3 N, O' 
_chemical_formula_sum 
 'C122 H107 Au10 F12 N9 O P10 S4' 
_chemical_formula_weight          4350.77 
 
loop_ 
 _atom_type_symbol 
 _atom_type_description 
 _atom_type_scat_dispersion_real 
 _atom_type_scat_dispersion_imag 
 _atom_type_scat_source 
 'C'  'C'   0.0033   0.0016 
 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' 
 'H'  'H'   0.0000   0.0000 
 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' 
 'N'  'N'   0.0061   0.0033 
 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' 
 'P'  'P'   0.1023   0.0942 
 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' 
 'S'  'S'   0.1246   0.1234 
 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' 
 'F'  'F'   0.0171   0.0103 
 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' 
 'O'  'O'   0.0106   0.0060 
 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' 
 'Au'  'Au'  -2.0133   8.8022 
 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' 
 
_symmetry_cell_setting            'monoclinic' 
_symmetry_space_group_name_H-M    'P 21/n'
_symmetry_space_group_name_Hall   '-P 2yn' 
 
loop_ 
 _symmetry_equiv_pos_as_xyz 
 'x, y, z' 
 '-x+1/2, y+1/2, -z+1/2' 
 '-x, -y, -z' 
 'x-1/2, -y-1/2, z-1/2' 
 
_cell_length_a                    24.844(5) 
_cell_length_b                    19.736(4) 
_cell_length_c                    29.107(6) 
_cell_angle_alpha                 90.00 
_cell_angle_beta                  109.15(3) 
_cell_angle_gamma                 90.00 
_cell_volume                      13482(5) 
_cell_formula_units_Z             4 
_cell_measurement_temperature     194(2) 
_cell_measurement_reflns_used     269093 
_cell_measurement_theta_min       0.41 
_cell_measurement_theta_max       29.48 
 
_exptl_crystal_description        'prism' 
_exptl_crystal_colour             'yellow' 
_exptl_crystal_size_max           ? 
_exptl_crystal_size_mid           ? 
_exptl_crystal_size_min           ? 
_exptl_crystal_density_meas       ? 
_exptl_crystal_density_diffrn     2.144 
_exptl_crystal_density_method     'not measured' 
_exptl_crystal_F_000              8088 
_exptl_absorpt_coefficient_mu     11.082 
_exptl_absorpt_correction_type    ? 
_exptl_absorpt_correction_T_min   ? 
_exptl_absorpt_correction_T_max   ? 
_exptl_absorpt_process_details    ? 
 
_exptl_special_details 
; 
 ? 
; 
 
_diffrn_ambient_temperature       194(2) 
_diffrn_radiation_wavelength      0.71990 
_diffrn_radiation_type            'synchrotron'
_diffrn_radiation_source          ? 
_diffrn_radiation_monochromator   ? 
_diffrn_measurement_device_type   'mar CCD' 
_diffrn_measurement_method        ? 
_diffrn_detector_area_resol_mean  ? 
_diffrn_standards_number          ? 
_diffrn_standards_interval_count  ? 
_diffrn_standards_interval_time   ? 
_diffrn_standards_decay_%         ? 
_diffrn_reflns_number             47152 
_diffrn_reflns_av_R_equivalents   0.0296 
_diffrn_reflns_av_sigmaI/netI     0.0326 
_diffrn_reflns_limit_h_min        -30 
_diffrn_reflns_limit_h_max        29 
_diffrn_reflns_limit_k_min        -24 
_diffrn_reflns_limit_k_max        0 
_diffrn_reflns_limit_l_min        -35 
_diffrn_reflns_limit_l_max        35 
_diffrn_reflns_theta_min          1.83 
_diffrn_reflns_theta_max          26.00 
_reflns_number_total              24957 
_reflns_number_gt                 23043 
_reflns_threshold_expression      >2sigma(I) 
 
_computing_data_collection        ? 
_computing_cell_refinement        ? 
_computing_data_reduction         ? 
_computing_structure_solution     'SHELXS-97 (Sheldrick, 1990)' 
_computing_structure_refinement   'SHELXL-97 (Sheldrick, 1997)' 
_computing_molecular_graphics     ? 
_computing_publication_material   ? 
 
_refine_special_details 
; 
 Refinement of F² against ALL reflections.  The weighted R-factor wR and 
 goodness of fit S are based on F², conventional R-factors R are based 
 on F, with F set to zero for negative F². The threshold expression of 
 F² > 2sigma(F²) is used only for calculating R-factors(gt) etc. and is 
 not relevant to the choice of reflections for refinement.  R-factors based 
 on F² are statistically about twice as large as those based on F, and R- 
 factors based on ALL data will be even larger. 
; 
 
_refine_ls_structure_factor_coef  Fsqd  
_refine_ls_matrix_type            full 
_refine_ls_weighting_scheme       calc  
_refine_ls_weighting_details 
 'calc w=1/[σ²(Fo²)+(0.0457P)²+52.1373P] where P=(Fo²+2Fc²)/3' 
_atom_sites_solution_primary      direct 
_atom_sites_solution_secondary    difmap 
_atom_sites_solution_hydrogens    geom 
_refine_ls_hydrogen_treatment     mixed 
_refine_ls_extinction_method      none 
_refine_ls_extinction_coef        ? 
_refine_ls_number_reflns          24957 
_refine_ls_number_parameters      1617 
_refine_ls_number_restraints      0 
_refine_ls_R_factor_all           0.0323 
_refine_ls_R_factor_gt            0.0297 
_refine_ls_wR_factor_ref          0.0819 
_refine_ls_wR_factor_gt           0.0803 
_refine_ls_goodness_of_fit_ref    1.032 
_refine_ls_restrained_S_all       1.032 
_refine_ls_shift/su_max           0.000 
_refine_ls_shift/su_mean          0.000 
 
loop_ 
 _atom_site_label 
 _atom_site_type_symbol 
 _atom_site_fract_x 
 _atom_site_fract_y 
 _atom_site_fract_z 
 _atom_site_U_iso_or_equiv 
 _atom_site_adp_type 
 _atom_site_occupancy 
 _atom_site_symmetry_multiplicity 
 _atom_site_calc_flag 
 _atom_site_refinement_flags 
 _atom_site_disorder_assembly 
 _atom_site_disorder_group 
Au1 Au 0.340025(9) -0.046340(10) 0.891492(7) 0.02636(5) Uani 1 1 d . . . 
Au2 Au 0.290828(10) 0.087300(11) 0.834695(7) 0.02830(5) Uani 1 1 d . . . 
Au3 Au 0.229331(10) 0.143365(11) 0.908687(8) 0.02945(5) Uani 1 1 d . . . 
Au4 Au 0.144943(10) 0.129920(10) 0.965336(8) 0.02785(5) Uani 1 1 d . . . 
Au5 Au 0.067203(9) 0.035200(10) 0.886917(7) 0.02540(5) Uani 1 1 d . . . 
Au6 Au 0.075097(10) -0.106395(11) 0.835525(7) 0.02896(5) Uani 1 1 d . . . 
Au7 Au 0.187746(10) -0.155071(11) 0.918461(8) 0.02972(5) Uani 1 1 d . . . 
Au8 Au 0.316102(9) -0.134643(10) 0.970874(8) 0.02646(5) Uani 1 1 d . . . 
Au9 Au 0.226365(9) -0.002653(10) 0.949018(7) 0.02311(5) Uani 1 1 d . . . 
Au10 Au 0.184099(10) -0.009351(11) 0.837940(7) 0.02786(5) Uani 1 1 d . . . 
C1 C -0.0264(3) -0.0801(3) 0.8888(2) 0.0296(12) Uani 1 1 d . . . 
C2 C -0.0034(3) 0.1146(3) 0.7787(2) 0.0330(13) Uani 1 1 d . . . 
C3 C 0.2793(3) 0.1804(3) 1.0346(2) 0.0362(13) Uani 1 1 d . . . 
C4 C 0.4412(3) -0.1203(3) 0.8544(2) 0.0349(13) Uani 1 1 d . . . 
C5 C 0.3307(3) -0.1253(4) 0.7825(2) 0.0431(16) Uani 1 1 d . . . 
C6 C 0.4347(3) 0.0737(3) 0.8932(2) 0.0339(13) Uani 1 1 d . . . 
C7 C 0.0173(3) -0.1051(3) 0.9289(2) 0.0336(13) Uani 1 1 d . . . 
H7 H 0.0504 -0.1242 0.9245 0.040 Uiso 1 1 calc R . . 
C8 C 0.2397(3) -0.1796(3) 1.0449(2) 0.0308(12) Uani 1 1 d . . . 
C9 C 0.4208(3) 0.1039(3) 0.9312(2) 0.0401(14) Uani 1 1 d . . . 
H9 H 0.3838 0.1221 0.9255 0.048 Uiso 1 1 calc R . . 
C10 C -0.0744(3) -0.0521(3) 0.8959(2) 0.0367(14) Uani 1 1 d . . . 
H10 H -0.1048 -0.0354 0.8691 0.044 Uiso 1 1 calc R . . 
C11 C 0.0942(3) 0.2812(3) 0.9164(2) 0.0386(14) Uani 1 1 d . . . 
C12 C 0.0126(3) -0.1021(3) 0.9754(2) 0.0358(13) Uani 1 1 d . . . 
H12 H 0.0421 -0.1201 1.0024 0.043 Uiso 1 1 calc R . . 
C13 C 0.3237(3) 0.2588(3) 0.9712(3) 0.0423(15) Uani 1 1 d . . . 
C14 C 0.0482(3) 0.1085(4) 0.7695(2) 0.0409(15) Uani 1 1 d . . . 
H14 H 0.0762 0.0769 0.7872 0.049 Uiso 1 1 calc R . . 
C15 C -0.0673(3) -0.1544(4) 0.8009(2) 0.0464(18) Uani 1 1 d . . . 
C16 C 0.1466(3) -0.2649(3) 0.9928(3) 0.0395(15) Uani 1 1 d . . . 
C17 C 0.3767(3) -0.2751(3) 1.0335(3) 0.0433(16) Uani 1 1 d . . . 
C18 C -0.0654(3) 0.1038(3) 0.8446(2) 0.0364(14) Uani 1 1 d . . . 
C19 C -0.0775(3) -0.0489(3) 0.9424(2) 0.0402(15) Uani 1 1 d . . . 
H19 H -0.1102 -0.0293 0.9471 0.048 Uiso 1 1 calc R . . 
C20 C -0.0355(4) -0.0227(4) 0.7138(3) 0.058(2) Uani 1 1 d . . . 
C21 C 0.3523(3) -0.1746(4) 0.7591(2) 0.0445(16) Uani 1 1 d . . . 
H21 H 0.3921 -0.1827 0.7690 0.053 Uiso 1 1 calc R . . 
C22 C 0.2258(4) -0.1121(3) 1.0499(3) 0.0472(18) Uani 1 1 d . . . 
H22 H 0.1986 -0.0897 1.0235 0.057 Uiso 1 1 calc R . . 
C23 C -0.0466(3) 0.1551(4) 0.7493(2) 0.0437(16) Uani 1 1 d . . . 
H23 H -0.0831 0.1555 0.7533 0.052 Uiso 1 1 calc R . . 
C24 C 0.4900(3) 0.0467(3) 0.9029(3) 0.0434(16) Uani 1 1 d . . . 
H24 H 0.5003 0.0262 0.8774 0.052 Uiso 1 1 calc R . . 
C25 C 0.3623(3) 0.2884(3) 1.0126(3) 0.0464(16) Uani 1 1 d . . . 
H25 H 0.3560 0.2853 1.0430 0.056 Uiso 1 1 calc R . . 
C26 C 0.2427(3) -0.3536(3) 0.9760(3) 0.0423(16) Uani 1 1 d . . . 
H26A H 0.2335 -0.3698 1.0048 0.051 Uiso 1 1 calc R . . 
H26B H 0.2770 -0.3783 0.9753 0.051 Uiso 1 1 calc R . . 
C27 C -0.0752(3) -0.0168(4) 0.7450(2) 0.0504(19) Uani 1 1 d . . . 
H27A H -0.0982 0.0249 0.7354 0.061 Uiso 1 1 calc R . . 
H27B H -0.1019 -0.0557 0.7373 0.061 Uiso 1 1 calc R . . 
C28 C 0.3338(4) -0.2895(4) 0.9299(3) 0.059(2) Uani 1 1 d . . . 
C29 C 0.1299(3) 0.2770(3) 1.0227(2) 0.0434(15) Uani 1 1 d . . . 
C30 C -0.0344(3) -0.0731(3) 0.9821(2) 0.0382(14) Uani 1 1 d . . . 
H30 H -0.0373 -0.0699 1.0138 0.046 Uiso 1 1 calc R . . 
C31 C 0.5289(3) 0.0501(4) 0.9491(3) 0.0504(19) Uani 1 1 d . . . 
H31 H 0.5659 0.0315 0.9552 0.060 Uiso 1 1 calc R . . 
C32 C 0.4038(4) 0.1410(4) 0.8020(3) 0.0501(19) Uani 1 1 d . . . 
C33 C 0.2152(3) 0.3429(3) 0.9518(3) 0.0523(19) Uani 1 1 d . . . 
H33A H 0.1767 0.3631 0.9389 0.063 Uiso 1 1 calc R . . 
H33B H 0.2296 0.3370 0.9241 0.063 Uiso 1 1 calc R . . 
C34 C 0.5153(3) 0.0801(4) 0.9868(3) 0.053(2) Uani 1 1 d . . . 
H34 H 0.5425 0.0821 1.0185 0.064 Uiso 1 1 calc R . . 
C35 C 0.3058(3) 0.1172(3) 1.0441(3) 0.0479(18) Uani 1 1 d . . . 
H35 H 0.3134 0.0932 1.0186 0.057 Uiso 1 1 calc R . . 
C36 C 0.4612(3) 0.1073(4) 0.9775(3) 0.0482(17) Uani 1 1 d . . . 
H36 H 0.4517 0.1286 1.0031 0.058 Uiso 1 1 calc R . . 
C37 C -0.0457(3) 0.1527(4) 0.8808(3) 0.0466(16) Uani 1 1 d . . . 
H37 H -0.0060 0.1608 0.8951 0.056 Uiso 1 1 calc R . . 
C38 C 0.4445(3) -0.1712(4) 0.8889(2) 0.0434(16) Uani 1 1 d . . . 
H38 H 0.4125 -0.1810 0.8988 0.052 Uiso 1 1 calc R . . 
C39 C 0.2545(4) 0.3934(4) 0.9881(4) 0.066(3) Uani 1 1 d . . . 
C40 C -0.0359(3) 0.1952(4) 0.7137(2) 0.0467(17) Uani 1 1 d . . . 
H40 H -0.0645 0.2251 0.6945 0.056 Uiso 1 1 calc R . . 
C41 C 0.4887(3) -0.1081(4) 0.8399(3) 0.0518(18) Uani 1 1 d . . . 
H41 H 0.4870 -0.0740 0.8164 0.062 Uiso 1 1 calc R . . 
C42 C 0.0963(3) 0.2607(4) 0.8717(3) 0.0512(18) Uani 1 1 d . . . 
H42 H 0.1243 0.2286 0.8703 0.061 Uiso 1 1 calc R . . 
C43 C 0.0578(3) 0.1494(5) 0.7343(3) 0.055(2) Uani 1 1 d . . . 
H43 H 0.0938 0.1481 0.7295 0.066 Uiso 1 1 calc R . . 
C44 C 0.1918(4) -0.3725(4) 0.9290(4) 0.068(3) Uani 1 1 d . . . 
C45 C -0.1236(3) 0.0930(4) 0.8241(3) 0.0482(17) Uani 1 1 d . . . 
H45 H -0.1374 0.0598 0.7993 0.058 Uiso 1 1 calc R . . 
C46 C 0.1160(3) 0.2328(4) 1.0536(3) 0.0488(17) Uani 1 1 d . . . 
H46 H 0.1134 0.1857 1.0463 0.059 Uiso 1 1 calc R . . 
C47 C 0.4098(4) 0.3224(4) 1.0095(3) 0.0543(19) Uani 1 1 d . . . 
H47 H 0.4351 0.3445 1.0372 0.065 Uiso 1 1 calc R . . 
C48 C 0.0159(3) 0.1917(4) 0.7062(2) 0.0528(19) Uani 1 1 d . . . 
H48 H 0.0227 0.2186 0.6816 0.063 Uiso 1 1 calc R . . 
C49 C 0.1506(4) -0.3043(4) 1.0330(3) 0.0495(17) Uani 1 1 d . . . 
H49 H 0.1856 -0.3077 1.0591 0.059 Uiso 1 1 calc R . . 
C50 C 0.3740(3) -0.3295(4) 1.0631(3) 0.0522(18) Uani 1 1 d . . . 
H50 H 0.3402 -0.3558 1.0558 0.063 Uiso 1 1 calc R . . 
C51 C 0.2787(3) -0.2127(5) 1.0844(2) 0.0506(18) Uani 1 1 d . . . 
H51 H 0.2878 -0.2589 1.0817 0.061 Uiso 1 1 calc R . . 
C52 C 0.4198(4) 0.3239(4) 0.9660(4) 0.062(2) Uani 1 1 d . . . 
H52 H 0.4526 0.3467 0.9639 0.074 Uiso 1 1 calc R . . 
C53 C 0.3156(4) -0.2120(5) 0.7214(3) 0.061(2) Uani 1 1 d . . . 
H53 H 0.3303 -0.2461 0.7059 0.073 Uiso 1 1 calc R . . 
C54 C 0.3344(4) 0.2612(4) 0.9280(3) 0.061(2) Uani 1 1 d . . . 
H54 H 0.3085 0.2411 0.8997 0.073 Uiso 1 1 calc R . . 
C55 C 0.4948(4) -0.2069(5) 0.9083(3) 0.062(2) Uani 1 1 d . . . 
H55 H 0.4974 -0.2410 0.9319 0.075 Uiso 1 1 calc R . . 
C56 C 0.0972(3) -0.2657(4) 0.9522(3) 0.058(2) Uani 1 1 d . . . 
H56 H 0.0963 -0.2427 0.9233 0.070 Uiso 1 1 calc R . . 
C57 C 0.1018(4) -0.3392(4) 1.0345(4) 0.063(2) Uani 1 1 d . . . 
H57 H 0.1034 -0.3650 1.0624 0.076 Uiso 1 1 calc R . . 
C58 C 0.5378(3) -0.1451(4) 0.8592(3) 0.060(2) Uani 1 1 d . . . 
H58 H 0.5695 -0.1369 0.8487 0.072 Uiso 1 1 calc R . . 
C59 C 0.4384(5) 0.2555(5) 0.7624(4) 0.082(3) Uani 1 1 d . . . 
H59 H 0.4502 0.2954 0.7502 0.098 Uiso 1 1 calc R . . 
C60 C 0.2725(3) -0.1114(6) 0.7666(3) 0.069(3) Uani 1 1 d . . . 
H60 H 0.2577 -0.0771 0.7820 0.082 Uiso 1 1 calc R . . 
C61 C 0.3949(5) -0.0015(5) 0.7574(3) 0.074(3) Uani 1 1 d . . . 
H61A H 0.4216 0.0344 0.7548 0.089 Uiso 1 1 calc R . . 
H61B H 0.4113 -0.0455 0.7521 0.089 Uiso 1 1 calc R . . 
C62 C 0.0585(3) 0.2858(5) 0.8288(3) 0.057(2) Uani 1 1 d . . . 
H62 H 0.0610 0.2712 0.7984 0.069 Uiso 1 1 calc R . . 
C63 C -0.1250(4) -0.1486(5) 0.7899(3) 0.060(2) Uani 1 1 d . . . 
H63 H -0.1406 -0.1064 0.7950 0.072 Uiso 1 1 calc R . . 
C64 C 0.1097(4) 0.3224(4) 1.1063(3) 0.061(2) Uani 1 1 d . . . 
H64 H 0.1042 0.3380 1.1353 0.074 Uiso 1 1 calc R . . 
C65 C -0.1417(4) 0.1787(5) 0.8752(3) 0.066(2) Uani 1 1 d . . . 
H65 H -0.1677 0.2047 0.8855 0.079 Uiso 1 1 calc R . . 
C66 C 0.5413(4) -0.1937(5) 0.8937(3) 0.066(3) Uani 1 1 d . . . 
H66 H 0.5758 -0.2183 0.9075 0.079 Uiso 1 1 calc R . . 
C67 C 0.3646(4) 0.1894(5) 0.7780(3) 0.070(3) Uani 1 1 d . . . 
H67 H 0.3258 0.1839 0.7755 0.084 Uiso 1 1 calc R . . 
C68 C -0.0443(5) -0.2192(5) 0.7970(4) 0.072(3) Uani 1 1 d . . . 
H68 H -0.0042 -0.2244 0.8059 0.086 Uiso 1 1 calc R . . 
C69 C 0.4605(4) 0.1498(5) 0.8049(4) 0.069(3) Uani 1 1 d . . . 
H69 H 0.4880 0.1166 0.8207 0.083 Uiso 1 1 calc R . . 
C70 C 0.0516(4) -0.3365(4) 0.9956(4) 0.071(3) Uani 1 1 d . . . 
H70 H 0.0188 -0.3594 0.9975 0.085 Uiso 1 1 calc R . . 
C71 C 0.3057(5) -0.2634(5) 0.8830(3) 0.082(3) Uani 1 1 d . . . 
H71 H 0.2789 -0.2275 0.8785 0.098 Uiso 1 1 calc R . . 
C72 C -0.0848(4) 0.1894(5) 0.8956(3) 0.059(2) Uani 1 1 d . . . 
H72 H -0.0716 0.2226 0.9204 0.071 Uiso 1 1 calc R . . 
C73 C 0.1055(4) 0.2550(4) 1.0955(3) 0.0558(19) Uani 1 1 d . . . 
H73 H 0.0955 0.2236 1.1161 0.067 Uiso 1 1 calc R . . 
C74 C 0.2509(5) -0.0780(4) 1.0923(3) 0.070(3) Uani 1 1 d . . . 
H74 H 0.2407 -0.0322 1.0954 0.084 Uiso 1 1 calc R . . 
C75 C -0.1618(4) 0.1305(5) 0.8396(3) 0.060(2) Uani 1 1 d . . . 
H75 H -0.2016 0.1228 0.8257 0.072 Uiso 1 1 calc R . . 
C76 C 0.3039(3) -0.1783(6) 1.1272(3) 0.071(3) Uani 1 1 d . . . 
H76 H 0.3298 -0.2012 1.1541 0.085 Uiso 1 1 calc R . . 
C77 C 0.4266(3) -0.2376(4) 1.0452(4) 0.066(2) Uani 1 1 d . . . 
H77 H 0.4287 -0.1999 1.0255 0.079 Uiso 1 1 calc R . . 
C78 C 0.4773(5) 0.2073(5) 0.7847(4) 0.078(3) Uani 1 1 d . . . 
H78 H 0.5159 0.2126 0.7866 0.094 Uiso 1 1 calc R . . 
C79 C 0.2634(4) 0.3926(5) 1.0350(4) 0.073(3) Uani 1 1 d . . . 
H79 H 0.2439 0.3622 1.0494 0.087 Uiso 1 1 calc R . . 
C80 C 0.3214(4) 0.0889(4) 1.0904(4) 0.073(3) Uani 1 1 d . . . 
H80 H 0.3410 0.0468 1.0967 0.088 Uiso 1 1 calc R . . 
C81 C 0.0489(4) -0.3007(5) 0.9541(5) 0.077(3) Uani 1 1 d . . . 
H81 H 0.0146 -0.2998 0.9271 0.093 Uiso 1 1 calc R . . 
C82 C 0.0474(5) -0.0552(5) 0.7061(3) 0.077(3) Uani 1 1 d . . . 
H82 H 0.0819 -0.0802 0.7182 0.093 Uiso 1 1 calc R . . 
C83 C -0.0500(4) 0.0158(4) 0.6699(3) 0.061(2) Uani 1 1 d . . . 
H83 H -0.0838 0.0423 0.6594 0.074 Uiso 1 1 calc R . . 
C84 C -0.0135(5) 0.0130(5) 0.6434(3) 0.074(3) Uani 1 1 d . . . 
H84 H -0.0225 0.0355 0.6130 0.089 Uiso 1 1 calc R . . 
C85 C 0.3281(4) 0.4726(4) 0.9968(5) 0.086(4) Uani 1 1 d . . . 
H85 H 0.3509 0.5001 0.9836 0.103 Uiso 1 1 calc R . . 
C86 C 0.3838(4) 0.2934(5) 0.9256(4) 0.070(3) Uani 1 1 d . . . 
H86 H 0.3920 0.2940 0.8959 0.084 Uiso 1 1 calc R . . 
C87 C -0.1382(6) -0.2640(7) 0.7650(4) 0.105(5) Uani 1 1 d . . . 
H87 H -0.1627 -0.3002 0.7497 0.126 Uiso 1 1 calc R . . 
C88 C 0.1337(6) 0.3457(4) 1.0342(4) 0.089(4) Uani 1 1 d . . . 
H88 H 0.1442 0.3773 1.0140 0.107 Uiso 1 1 calc R . . 
C89 C 0.1221(6) 0.3681(5) 1.0753(4) 0.098(4) Uani 1 1 d . . . 
H89 H 0.1228 0.4152 1.0821 0.118 Uiso 1 1 calc R . . 
C90 C 0.3435(4) 0.0077(5) 0.7200(3) 0.111(5) Uani 1 1 d G . . 
C91 C 0.3308(5) -0.0205(5) 0.6739(3) 0.150(8) Uani 1 1 d G . . 
H91 H 0.3590 -0.0454 0.6656 0.180 Uiso 1 1 calc R . . 
C92 C 0.2768(5) -0.0123(6) 0.6400(3) 0.164(8) Uani 1 1 d G . . 
H92 H 0.2681 -0.0315 0.6085 0.197 Uiso 1 1 calc R . . 
C93 C 0.2355(4) 0.0242(6) 0.6521(3) 0.159(8) Uani 1 1 d G . . 
H93 H 0.1986 0.0298 0.6289 0.191 Uiso 1 1 calc R . . 
C94 C 0.2482(4) 0.0524(7) 0.6982(4) 0.160(8) Uani 1 1 d G . . 
H94 H 0.2200 0.0773 0.7065 0.192 Uiso 1 1 calc R . . 
C95 C 0.3808(5) 0.2460(6) 0.7575(4) 0.094(4) Uani 1 1 d . . . 
H95 H 0.3530 0.2781 0.7402 0.112 Uiso 1 1 calc R . . 
C96 C 0.4209(4) -0.3453(5) 1.1035(4) 0.070(3) Uani 1 1 d . . . 
H96 H 0.4189 -0.3816 1.1243 0.084 Uiso 1 1 calc R . . 
C97 C 0.0357(6) -0.0226(5) 0.6617(3) 0.079(3) Uani 1 1 d . . . 
H97 H 0.0619 -0.0250 0.6442 0.095 Uiso 1 1 calc R . . 
C98 C -0.1618(4) -0.2034(6) 0.7711(3) 0.073(3) Uani 1 1 d . . . 
H98 H -0.2019 -0.1985 0.7629 0.088 Uiso 1 1 calc R . . 
C99 C 0.0176(4) 0.3314(5) 0.8300(3) 0.073(3) Uani 1 1 d . . . 
H99 H -0.0077 0.3498 0.8007 0.087 Uiso 1 1 calc R . . 
C100 C 0.3748(5) -0.3411(4) 0.9372(5) 0.084(4) Uani 1 1 d . . . 
H100 H 0.3930 -0.3578 0.9691 0.101 Uiso 1 1 calc R . . 
C101 C 0.2585(4) -0.1999(7) 0.7066(3) 0.092(4) Uani 1 1 d . . . 
H101 H 0.2335 -0.2266 0.6814 0.110 Uiso 1 1 calc R . . 
C102 C -0.0790(6) -0.2744(5) 0.7806(4) 0.096(4) Uani 1 1 d . . . 
H102 H -0.0634 -0.3182 0.7797 0.115 Uiso 1 1 calc R . . 
C103 C 0.2916(4) -0.1104(6) 1.1313(3) 0.080(3) Uani 1 1 d . . . 
H103 H 0.3107 -0.0861 1.1603 0.096 Uiso 1 1 calc R . . 
C104 C 0.3342(5) 0.4778(5) 1.0448(5) 0.087(4) Uani 1 1 d . . . 
H104 H 0.3606 0.5091 1.0649 0.104 Uiso 1 1 calc R . . 
C105 C 0.4698(4) -0.3083(5) 1.1131(4) 0.083(3) Uani 1 1 d . . . 
H105 H 0.5022 -0.3204 1.1399 0.100 Uiso 1 1 calc R . . 
C106 C 0.2689(4) 0.2134(6) 1.0725(3) 0.076(3) Uani 1 1 d . . . 
H106 H 0.2518 0.2570 1.0669 0.091 Uiso 1 1 calc R . . 
C107 C 0.2363(4) -0.1481(7) 0.7283(4) 0.095(4) Uani 1 1 d . . . 
H107 H 0.1967 -0.1383 0.7167 0.114 Uiso 1 1 calc R . . 
C108 C 0.1765(5) -0.3374(6) 0.8881(4) 0.083(3) Uani 1 1 d . . . 
H108 H 0.1997 -0.3009 0.8844 0.099 Uiso 1 1 calc R . . 
C109 C 0.3081(4) 0.1227(7) 1.1277(4) 0.090(4) Uani 1 1 d . . . 
H109 H 0.3168 0.1025 1.1589 0.108 Uiso 1 1 calc R . . 
C110 C 0.3035(6) 0.4394(6) 1.0630(5) 0.107(5) Uani 1 1 d . . . 
H110 H 0.3084 0.4433 1.0966 0.128 Uiso 1 1 calc R . . 
C111 C 0.3178(7) -0.2911(7) 0.8434(5) 0.109(5) Uani 1 1 d . . . 
H111 H 0.2984 -0.2768 0.8110 0.131 Uiso 1 1 calc R . . 
C112 C 0.0512(5) 0.3251(7) 0.9173(4) 0.099(4) Uani 1 1 d . . . 
H112 H 0.0474 0.3380 0.9475 0.119 Uiso 1 1 calc R . . 
C113 C 0.4730(4) -0.2540(5) 1.0847(5) 0.095(4) Uani 1 1 d . . . 
H113 H 0.5071 -0.2281 1.0922 0.114 Uiso 1 1 calc R . . 
C114 C 0.1098(6) -0.4373(8) 0.9044(6) 0.121(5) Uani 1 1 d . . . 
H114 H 0.0873 -0.4744 0.9081 0.146 Uiso 1 1 calc R . . 
C115 C 0.3607(7) -0.3417(9) 0.8540(7) 0.120(6) Uani 1 1 d . . . 
H115 H 0.3705 -0.3590 0.8273 0.144 Uiso 1 1 calc R . . 
C116 C 0.0138(6) 0.3503(8) 0.8744(4) 0.119(6) Uani 1 1 d . . . 
H116 H -0.0150 0.3811 0.8755 0.142 Uiso 1 1 calc R . . 
C117 C 0.2827(5) 0.1848(8) 1.1188(4) 0.105(5) Uani 1 1 d . . . 
H117 H 0.2745 0.2086 1.1441 0.126 Uiso 1 1 calc R . . 
C118 C 0.3892(7) -0.3680(7) 0.8987(7) 0.115(6) Uani 1 1 d . . . 
H118 H 0.4171 -0.4025 0.9032 0.138 Uiso 1 1 calc R . . 
C119 C 0.1277(6) -0.3533(9) 0.8510(5) 0.121(5) Uani 1 1 d . . . 
H119 H 0.1182 -0.3311 0.8204 0.145 Uiso 1 1 calc R . . 
C120 C 0.0941(7) -0.4007(11) 0.8593(6) 0.145(7) Uani 1 1 d . . . 
H120 H 0.0589 -0.4107 0.8348 0.174 Uiso 1 1 calc R . . 
O1 O 0.8503(4) 0.4972(4) 0.9832(5) 0.085(5) Uani 0.630(14) 1 d P A 1 
O2 O -0.0248(8) 0.5222(10) 0.0236(9) 0.090(8) Uani 0.370(14) 1 d P A 2 
F1 F 0.434(2) 0.9308(15) 0.280(2) 0.31(3) Uani 0.504(19) 1 d P B 1 
F2 F 0.3644(8) 0.9959(17) 0.2275(9) 0.152(15) Uani 0.504(19) 1 d P B 1 
F3 F 0.4343(7) 1.0722(7) 0.2354(4) 0.085(5) Uani 0.504(19) 1 d P B 1 
F4 F 0.4936(7) 0.9982(14) 0.2735(11) 0.177(14) Uani 0.504(19) 1 d P B 1 
F5 F 0.4328(6) 0.9829(6) 0.1949(4) 0.183(5) Uani 1 1 d . B . 
F6 F 0.4230(6) 1.0200(9) 0.2960(4) 0.230(8) Uani 1 1 d . B . 
F7 F 0.7346(5) 0.4044(5) 0.9046(3) 0.071(3) Uani 0.50 1 d P . . 
F8 F 0.7631(8) 0.3468(7) 0.8553(4) 0.117(5) Uani 0.50 1 d P . . 
F9 F 0.7281(6) 0.4240(6) 0.7957(4) 0.086(4) Uani 0.50 1 d P . . 
F10 F 0.6958(8) 0.4764(11) 0.8473(5) 0.167(10) Uani 0.50 1 d P . . 
F11 F 0.7885(6) 0.4593(10) 0.8715(5) 0.144(8) Uani 0.50 1 d P . . 
F12 F 0.6786(7) 0.3734(9) 0.8371(5) 0.114(5) Uani 0.50 1 d P . . 
F13 F 0.4837(4) 0.4449(3) 0.0327(3) 0.130(3) Uani 1 1 d . . . 
F14 F 0.5594(4) 0.5177(3) 0.0445(3) 0.118(3) Uani 1 1 d . . . 
F15 F 0.5335(4) 0.4434(4) -0.0193(3) 0.135(3) Uani 1 1 d . . . 
N1 N 0.3926(2) -0.0009(3) 0.8074(2) 0.0396(13) Uani 1 1 d . . . 
N2 N 0.3022(5) 0.0442(5) 0.7322(3) 0.107(4) Uani 1 1 d G . . 
N3 N 0.2100(2) 0.2750(2) 0.97189(19) 0.0363(12) Uani 1 1 d . . . 
N4 N 0.2891(4) 0.4278(4) 0.9667(3) 0.083(3) Uani 1 1 d . . . 
N5 N -0.0458(2) -0.0151(3) 0.79872(17) 0.0334(11) Uani 1 1 d . . . 
N6 N 0.0128(4) -0.0535(3) 0.7328(2) 0.0613(19) Uani 1 1 d . . . 
N7 N 0.2566(2) -0.2805(2) 0.98248(19) 0.0342(11) Uani 1 1 d . . . 
N8 N 0.1567(4) -0.4189(4) 0.9416(4) 0.086(3) Uani 1 1 d . . . 
P1 P 0.37571(7) -0.07318(8) 0.83152(5) 0.0317(3) Uani 1 1 d . . . 
P2 P 0.38090(7) 0.07346(8) 0.83339(6) 0.0333(3) Uani 1 1 d . . . 
P3 P 0.26078(7) 0.21385(7) 0.97380(6) 0.0319(3) Uani 1 1 d . . . 
P4 P 0.14522(7) 0.24455(8) 0.97022(6) 0.0347(3) Uani 1 1 d . . . 
P5 P -0.01361(6) 0.05838(8) 0.82482(5) 0.0281(3) Uani 1 1 d . . . 
P6 P -0.01708(7) -0.08816(8) 0.82956(5) 0.0299(3) Uani 1 1 d . . . 
P7 P 0.20785(7) -0.21989(7) 0.98654(6) 0.0296(3) Uani 1 1 d . . . 
P8 P 0.31932(7) -0.24892(7) 0.98014(6) 0.0336(3) Uani 1 1 d . . . 
P9 P 0.42937(12) 0.99461(15) 0.24885(12) 0.0796(8) Uani 1 1 d . . . 
P10 P 0.5000 0.5000 0.0000 0.109(2) Uani 1 2 d S . . 
P11 P 0.7319(2) 0.4155(3) 0.85199(16) 0.0630(12) Uani 0.50 1 d P . . 
S1 S 0.32285(6) -0.01815(6) 0.96296(5) 0.0239(3) Uani 1 1 d . . . 
S2 S 0.19623(6) 0.10513(7) 0.82837(5) 0.0293(3) Uani 1 1 d . . . 
S3 S 0.13883(6) 0.01257(6) 0.95986(5) 0.0240(3) Uani 1 1 d . . . 
S4 S 0.16831(7) -0.12459(7) 0.83724(5) 0.0313(3) Uani 1 1 d . . . 
F1' F 0.3904(11) 0.9310(11) 0.2416(8) 0.152(11) Uani 0.496(19) 1 d P B 2 
F2' F 0.3734(17) 1.0251(18) 0.2196(14) 0.25(2) Uani 0.496(19) 1 d P B 2 
F3' F 0.4834(16) 1.0375(16) 0.2621(16) 0.23(2) Uani 0.496(19) 1 d P B 2 
F4' F 0.4668(13) 0.9324(9) 0.2491(11) 0.176(13) Uani 0.496(19) 1 d P B 2 
C121 C 0.6553(16) 0.844(2) 0.6910(18) 0.23(3) Uani 0.515(11) 1 d P C 1 
H12A H 0.6869 0.8762 0.7034 0.352 Uiso 0.515(11) 1 calc PR C 1 
H12B H 0.6192 0.8691 0.6801 0.352 Uiso 0.515(11) 1 calc PR C 1 
H12C H 0.6600 0.8189 0.6636 0.352 Uiso 0.515(11) 1 calc PR C 1 
C122 C 0.6550(11) 0.7975(14) 0.7293(10) 0.085(7) Uani 0.515(11) 1 d P C 1 
N9 N 0.6760(10) 0.7549(13) 0.7561(9) 0.104(7) Uani 0.515(11) 1 d P C 1 
C123 C 0.7825(9) 0.5726(11) 0.7886(9) 0.080(6) Uani 0.485(11) 1 d P C 2 
H12D H 0.7609 0.5337 0.7710 0.120 Uiso 0.485(11) 1 calc PR C 2 
H12E H 0.8065 0.5581 0.8211 0.120 Uiso 0.485(11) 1 calc PR C 2 
H12F H 0.8065 0.5908 0.7708 0.120 Uiso 0.485(11) 1 calc PR C 2 
C124 C 0.7435(13) 0.6242(15) 0.7931(10) 0.096(8) Uani 0.485(11) 1 d P C 2 
N10 N 0.7130(12) 0.665(3) 0.7939(13) 0.25(3) Uani 0.485(11) 1 d P C 2 
 
 
_geom_special_details 
; 
 All esds (except the esd in the dihedral angle between two l.s. planes) 
 are estimated using the full covariance matrix.  The cell esds are taken 
 into account individually in the estimation of esds in distances, angles 
 and torsion angles; correlations between esds in cell parameters are only 
 used when they are defined by crystal symmetry.  An approximate (isotropic) 
 treatment of cell esds is used for estimating esds involving l.s. planes. 
; 
 
loop_ 
 _geom_bond_atom_site_label_1 
 _geom_bond_atom_site_label_2 
 _geom_bond_distance 
 _geom_bond_site_symmetry_2 
 _geom_bond_publ_flag 
Au1 P1 2.2648(15) . ? 
Au1 S1 2.3241(13) . ? 
Au1 Au8 3.1033(6) . ? 
Au1 Au2 3.1397(6) . ? 
Au2 P2 2.2671(16) . ? 
Au2 S2 2.3232(16) . ? 
Au2 Au3 3.2181(7) . ? 
Au2 Au10 3.2928(6) . ? 
Au3 P3 2.2730(16) . ? 
Au3 S2 2.3343(15) . ? 
Au3 Au4 3.0746(8) . ? 
Au3 Au9 3.1217(6) . ? 
Au4 P4 2.2667(16) . ? 
Au4 S3 2.3230(14) . ? 
Au4 Au5 3.0890(9) . ? 
Au5 P5 2.2639(17) . ? 
Au5 S3 2.3227(16) . ? 
Au5 Au6 3.2059(6) . ? 
Au6 P6 2.2678(17) . ? 
Au6 S4 2.3277(16) . ? 
Au6 Au7 3.1859(12) . ? 
Au6 Au10 3.2988(6) . ? 
Au7 P7 2.2722(15) . ? 
Au7 S4 2.3313(15) . ? 
Au7 Au8 3.0768(10) . ? 
Au7 Au9 3.1938(6) . ? 
Au8 P8 2.2697(15) . ? 
Au8 S1 2.3223(14) . ? 
Au8 Au9 3.3511(6) . ? 
Au9 S1 2.3165(15) . ? 
Au9 S3 2.3173(14) . ? 
Au9 Au10 3.0571(9) . ? 
Au10 S4 2.3070(15) . ? 
Au10 S2 2.3084(15) . ? 
C1 C10 1.389(9) . ? 
C1 C7 1.397(9) . ? 
C1 P6 1.821(6) . ? 
C2 C23 1.386(9) . ? 
C2 C14 1.397(9) . ? 
C2 P5 1.823(6) . ? 
C3 C106 1.375(11) . ? 
C3 C35 1.395(9) . ? 
C3 P3 1.802(7) . ? 
C4 C41 1.398(10) . ? 
C4 C38 1.404(9) . ? 
C4 P1 1.801(6) . ? 
C5 C21 1.390(9) . ? 
C5 C60 1.393(11) . ? 
C5 P1 1.817(7) . ? 
C6 C9 1.395(9) . ? 
C6 C24 1.413(9) . ? 
C6 P2 1.814(7) . ? 
C7 C12 1.397(8) . ? 
C7 H7 0.9500 . ? 
C8 C22 1.396(9) . ? 
C8 C51 1.398(9) . ? 
C8 P7 1.807(6) . ? 
C9 C36 1.394(10) . ? 
C9 H9 0.9500 . ? 
C10 C19 1.380(9) . ? 
C10 H10 0.9500 . ? 
C11 C42 1.380(10) . ? 
C11 C112 1.382(11) . ? 
C11 P4 1.811(7) . ? 
C12 C30 1.372(9) . ? 
C12 H12 0.9500 . ? 
C13 C54 1.368(10) . ? 
C13 C25 1.400(10) . ? 
C13 P3 1.819(7) . ? 
C14 C43 1.386(9) . ? 
C14 H14 0.9500 . ? 
C15 C63 1.367(12) . ? 
C15 C68 1.419(12) . ? 
C15 P6 1.811(7) . ? 
C16 C49 1.381(10) . ? 
C16 C56 1.397(11) . ? 
C16 P7 1.823(6) . ? 
C17 C77 1.387(10) . ? 
C17 C50 1.394(10) . ? 
C17 P8 1.805(8) . ? 
C18 C45 1.388(10) . ? 
C18 C37 1.392(10) . ? 
C18 P5 1.812(6) . ? 
C19 C30 1.378(10) . ? 
C19 H19 0.9500 . ? 
C20 N6 1.295(12) . ? 
C20 C83 1.429(10) . ? 
C20 C27 1.551(11) . ? 
C21 C53 1.387(10) . ? 
C21 H21 0.9500 . ? 
C22 C74 1.363(11) . ? 
C22 H22 0.9500 . ? 
C23 C40 1.399(9) . ? 
C23 H23 0.9500 . ? 
C24 C31 1.378(11) . ? 
C24 H24 0.9500 . ? 
C25 C47 1.386(11) . ? 
C25 H25 0.9500 . ? 
C26 N7 1.482(7) . ? 
C26 C44 1.575(12) . ? 
C26 H26A 0.9900 . ? 
C26 H26B 0.9900 . ? 
C27 N5 1.493(8) . ? 
C27 H27A 0.9900 . ? 
C27 H27B 0.9900 . ? 
C28 C100 1.405(13) . ? 
C28 C71 1.410(15) . ? 
C28 P8 1.806(7) . ? 
C29 C46 1.377(10) . ? 
C29 C88 1.393(10) . ? 
C29 P4 1.808(7) . ? 
C30 H30 0.9500 . ? 
C31 C34 1.382(12) . ? 
C31 H31 0.9500 . ? 
C32 C67 1.379(11) . ? 
C32 C69 1.394(12) . ? 
C32 P2 1.810(7) . ? 
C33 N3 1.485(8) . ? 
C33 C39 1.544(11) . ? 
C33 H33A 0.9900 . ? 
C33 H33B 0.9900 . ? 
C34 C36 1.388(11) . ? 
C34 H34 0.9500 . ? 
C35 C80 1.392(11) . ? 
C35 H35 0.9500 . ? 
C36 H36 0.9500 . ? 
C37 C72 1.390(10) . ? 
C37 H37 0.9500 . ? 
C38 C55 1.385(10) . ? 
C38 H38 0.9500 . ? 
C39 C79 1.310(14) . ? 
C39 N4 1.394(13) . ? 
C40 C48 1.374(11) . ? 
C40 H40 0.9500 . ? 
C41 C58 1.375(11) . ? 
C41 H41 0.9500 . ? 
C42 C62 1.385(10) . ? 
C42 H42 0.9500 . ? 
C43 C48 1.377(11) . ? 
C43 H43 0.9500 . ? 
C44 C108 1.320(15) . ? 
C44 N8 1.393(12) . ? 
C45 C75 1.390(11) . ? 
C45 H45 0.9500 . ? 
C46 C73 1.397(10) . ? 
C46 H46 0.9500 . ? 
C47 C52 1.367(12) . ? 
C47 H47 0.9500 . ? 
C48 H48 0.9500 . ? 
C49 C57 1.407(11) . ? 
C49 H49 0.9500 . ? 
C50 C96 1.391(12) . ? 
C50 H50 0.9500 . ? 
C51 C76 1.373(12) . ? 
C51 H51 0.9500 . ? 
C52 C86 1.362(13) . ? 
C52 H52 0.9500 . ? 
C53 C101 1.360(12) . ? 
C53 H53 0.9500 . ? 
C54 C86 1.405(11) . ? 
C54 H54 0.9500 . ? 
C55 C66 1.380(13) . ? 
C55 H55 0.9500 . ? 
C56 C81 1.400(11) . ? 
C56 H56 0.9500 . ? 
C57 C70 1.382(14) . ? 
C57 H57 0.9500 . ? 
C58 C66 1.369(13) . ? 
C58 H58 0.9500 . ? 
C59 C78 1.358(14) . ? 
C59 C95 1.405(15) . ? 
C59 H59 0.9500 . ? 
C60 C107 1.384(12) . ? 
C60 H60 0.9500 . ? 
C61 C90 1.392(13) . ? 
C61 N1 1.475(9) . ? 
C61 H61A 0.9900 . ? 
C61 H61B 0.9900 . ? 
C62 C99 1.367(12) . ? 
C62 H62 0.9500 . ? 
C63 C98 1.406(11) . ? 
C63 H63 0.9500 . ? 
C64 C73 1.364(11) . ? 
C64 C89 1.379(13) . ? 
C64 H64 0.9500 . ? 
C65 C72 1.357(13) . ? 
C65 C75 1.373(13) . ? 
C65 H65 0.9500 . ? 
C66 H66 0.9500 . ? 
C67 C95 1.386(12) . ? 
C67 H67 0.9500 . ? 
C68 C102 1.375(12) . ? 
C68 H68 0.9500 . ? 
C69 C78 1.404(11) . ? 
C69 H69 0.9500 . ? 
C70 C81 1.383(15) . ? 
C70 H70 0.9500 . ? 
C71 C111 1.396(13) . ? 
C71 H71 0.9500 . ? 
C72 H72 0.9500 . ? 
C73 H73 0.9500 . ? 
C74 C103 1.404(15) . ? 
C74 H74 0.9500 . ? 
C75 H75 0.9500 . ? 
C76 C103 1.388(16) . ? 
C76 H76 0.9500 . ? 
C77 C113 1.374(13) . ? 
C77 H77 0.9500 . ? 
C78 H78 0.9500 . ? 
C79 C110 1.405(14) . ? 
C79 H79 0.9500 . ? 
C80 C109 1.404(16) . ? 
C80 H80 0.9500 . ? 
C81 H81 0.9500 . ? 
C82 N6 1.337(11) . ? 
C82 C97 1.387(12) . ? 
C82 H82 0.9500 . ? 
C83 C84 1.369(13) . ? 
C83 H83 0.9500 . ? 
C84 C97 1.359(15) . ? 
C84 H84 0.9500 . ? 
C85 C104 1.358(17) . ? 
C85 N4 1.391(12) . ? 
C85 H85 0.9500 . ? 
C86 H86 0.9500 . ? 
C87 C98 1.369(17) . ? 
C87 C102 1.405(19) . ? 
C87 H87 0.9500 . ? 
C88 C89 1.391(12) . ? 
C88 H88 0.9500 . ? 
C89 H89 0.9500 . ? 
C90 C91 1.3900 . ? 
C90 N2 1.390(12) . ? 
C91 C92 1.3900 . ? 
C91 H91 0.9500 . ? 
C92 C93 1.3900 . ? 
C92 H92 0.9500 . ? 
C93 C94 1.3900 . ? 
C93 H93 0.9500 . ? 
C94 N2 1.390(13) . ? 
C94 H94 0.9500 . ? 
C95 H95 0.9500 . ? 
C96 C105 1.366(13) . ? 
C96 H96 0.9500 . ? 
C97 H97 0.9500 . ? 
C98 H98 0.9500 . ? 
C99 C116 1.377(15) . ? 
C99 H99 0.9500 . ? 
C100 C118 1.390(15) . ? 
C100 H100 0.9500 . ? 
C101 C107 1.407(14) . ? 
C101 H101 0.9500 . ? 
C102 H102 0.9500 . ? 
C103 H103 0.9500 . ? 
C104 C110 1.304(19) . ? 
C104 H104 0.9500 . ? 
C105 C113 1.372(14) . ? 
C105 H105 0.9500 . ? 
C106 C117 1.396(13) . ? 
C106 H106 0.9500 . ? 
C107 H107 0.9500 . ? 
C108 C119 1.369(16) . ? 
C108 H108 0.9500 . ? 
C109 C117 1.364(18) . ? 
C109 H109 0.9500 . ? 
C110 H110 0.9500 . ? 
C111 C115 1.42(2) . ? 
C111 H111 0.9500 . ? 
C112 C116 1.382(14) . ? 
C112 H112 0.9500 . ? 
C113 H113 0.9500 . ? 
C114 N8 1.354(15) . ? 
C114 C120 1.44(2) . ? 
C114 H114 0.9500 . ? 
C115 C118 1.36(2) . ? 
C115 H115 0.9500 . ? 
C116 H116 0.9500 . ? 
C117 H117 0.9500 . ? 
C118 H118 0.9500 . ? 
C119 C120 1.33(2) . ? 
C119 H119 0.9500 . ? 
C120 H120 0.9500 . ? 
F1 P9 1.53(3) . ? 
F2 P9 1.529(19) . ? 
F3 P9 1.594(14) . ? 
F4 P9 1.522(17) . ? 
F5 P9 1.618(10) . ? 
F6 P9 1.518(10) . ? 
F7 P11 1.528(9) . ? 
F8 P11 1.550(15) . ? 
F9 P11 1.618(10) . ? 
F10 P11 1.479(16) . ? 
F11 P11 1.588(14) . ? 
F12 P11 1.501(15) . ? 
F13 P10 1.583(6) . ? 
F14 P10 1.649(9) . ? 
F15 P10 1.601(6) . ? 
N1 P1 1.703(6) . ? 
N1 P2 1.719(6) . ? 
N3 P4 1.703(6) . ? 
N3 P3 1.733(5) . ? 
N5 P5 1.709(5) . ? 
N5 P6 1.724(5) . ? 
N7 P8 1.700(5) . ? 
N7 P7 1.733(5) . ? 
P9 F2' 1.50(3) . ? 
P9 F3' 1.53(2) . ? 
P9 F4' 1.538(17) . ? 
P9 F1' 1.556(17) . ? 
P10 F13 1.583(6) 3_665 ? 
P10 F15 1.601(6) 3_665 ? 
P10 F14 1.649(9) 3_665 ? 
C121 C122 1.45(6) . ? 
C121 H12A 0.9800 . ? 
C121 H12B 0.9800 . ? 
C121 H12C 0.9800 . ? 
C122 N9 1.15(3) . ? 
C123 C124 1.44(4) . ? 
C123 H12D 0.9800 . ? 
C123 H12E 0.9800 . ? 
C123 H12F 0.9800 . ? 
C124 N10 1.11(5) . ? 
 
loop_ 
 _geom_angle_atom_site_label_1 
 _geom_angle_atom_site_label_2 
 _geom_angle_atom_site_label_3 
 _geom_angle 
 _geom_angle_site_symmetry_1 
 _geom_angle_site_symmetry_3 
 _geom_angle_publ_flag 
P1 Au1 S1 168.27(6) . . ? 
P1 Au1 Au8 131.42(4) . . ? 
S1 Au1 Au8 48.07(3) . . ? 
P1 Au1 Au2 88.50(4) . . ? 
S1 Au1 Au2 96.67(4) . . ? 
Au8 Au1 Au2 136.656(13) . . ? 
P2 Au2 S2 174.50(5) . . ? 
P2 Au2 Au1 72.04(4) . . ? 
S2 Au2 Au1 112.20(4) . . ? 
P2 Au2 Au3 137.78(5) . . ? 
S2 Au2 Au3 46.44(4) . . ? 
Au1 Au2 Au3 97.166(14) . . ? 
P2 Au2 Au10 137.67(4) . . ? 
S2 Au2 Au10 44.51(4) . . ? 
Au1 Au2 Au10 71.11(2) . . ? 
Au3 Au2 Au10 67.443(18) . . ? 
P3 Au3 S2 160.85(5) . . ? 
P3 Au3 Au4 73.38(4) . . ? 
S2 Au3 Au4 115.53(4) . . ? 
P3 Au3 Au9 107.19(4) . . ? 
S2 Au3 Au9 91.96(4) . . ? 
Au4 Au3 Au9 67.311(9) . . ? 
P3 Au3 Au2 131.28(4) . . ? 
S2 Au3 Au2 46.15(4) . . ? 
Au4 Au3 Au2 152.404(12) . . ? 
Au9 Au3 Au2 90.528(13) . . ? 
P4 Au4 S3 176.52(6) . . ? 
P4 Au4 Au3 87.65(4) . . ? 
S3 Au4 Au3 95.17(3) . . ? 
P4 Au4 Au5 129.69(5) . . ? 
S3 Au4 Au5 48.32(3) . . ? 
Au3 Au4 Au5 91.547(16) . . ? 
P5 Au5 S3 168.93(5) . . ? 
P5 Au5 Au4 130.04(4) . . ? 
S3 Au5 Au4 48.33(4) . . ? 
P5 Au5 Au6 88.72(4) . . ? 
S3 Au5 Au6 96.50(3) . . ? 
Au4 Au5 Au6 138.865(12) . . ? 
P6 Au6 S4 177.00(5) . . ? 
P6 Au6 Au7 136.04(4) . . ? 
S4 Au6 Au7 46.91(4) . . ? 
P6 Au6 Au5 71.49(4) . . ? 
S4 Au6 Au5 109.71(4) . . ? 
Au7 Au6 Au5 94.721(17) . . ? 
P6 Au6 Au10 135.30(4) . . ? 
S4 Au6 Au10 44.37(4) . . ? 
Au7 Au6 Au10 69.390(19) . . ? 
Au5 Au6 Au10 70.088(17) . . ? 
P7 Au7 S4 160.52(5) . . ? 
P7 Au7 Au8 75.28(5) . . ? 
S4 Au7 Au8 107.77(5) . . ? 
P7 Au7 Au6 135.86(4) . . ? 
S4 Au7 Au6 46.81(4) . . ? 
Au8 Au7 Au6 147.789(16) . . ? 
P7 Au7 Au9 109.11(4) . . ? 
S4 Au7 Au9 89.01(4) . . ? 
Au8 Au7 Au9 64.578(9) . . ? 
Au6 Au7 Au9 92.061(17) . . ? 
P8 Au8 S1 174.11(5) . . ? 
P8 Au8 Au7 85.36(4) . . ? 
S1 Au8 Au7 100.22(3) . . ? 
P8 Au8 Au1 129.69(4) . . ? 
S1 Au8 Au1 48.12(3) . . ? 
Au7 Au8 Au1 97.18(2) . . ? 
P8 Au8 Au9 142.21(4) . . ? 
S1 Au8 Au9 43.68(3) . . ? 
Au7 Au8 Au9 59.403(14) . . ? 
Au1 Au8 Au9 72.550(18) . . ? 
S1 Au9 S3 163.08(5) . . ? 
S1 Au9 Au10 98.99(4) . . ? 
S3 Au9 Au10 97.91(4) . . ? 
S1 Au9 Au3 92.12(3) . . ? 
S3 Au9 Au3 94.04(3) . . ? 
Au10 Au9 Au3 71.609(10) . . ? 
S1 Au9 Au7 97.10(3) . . ? 
S3 Au9 Au7 87.16(3) . . ? 
Au10 Au9 Au7 72.373(11) . . ? 
Au3 Au9 Au7 143.780(15) . . ? 
S1 Au9 Au8 43.81(3) . . ? 
S3 Au9 Au8 132.11(3) . . ? 
Au10 Au9 Au8 98.25(2) . . ? 
Au3 Au9 Au8 133.842(14) . . ? 
Au7 Au9 Au8 56.019(18) . . ? 
S4 Au10 S2 172.97(5) . . ? 
S4 Au10 Au9 92.89(4) . . ? 
S2 Au10 Au9 94.14(4) . . ? 
S4 Au10 Au2 135.00(4) . . ? 
S2 Au10 Au2 44.87(4) . . ? 
Au9 Au10 Au2 90.28(3) . . ? 
S4 Au10 Au6 44.88(4) . . ? 
S2 Au10 Au6 134.79(4) . . ? 
Au9 Au10 Au6 92.43(3) . . ? 
Au2 Au10 Au6 177.293(9) . . ? 
C10 C1 C7 119.1(5) . . ? 
C10 C1 P6 123.9(5) . . ? 
C7 C1 P6 117.0(4) . . ? 
C23 C2 C14 120.4(6) . . ? 
C23 C2 P5 122.5(5) . . ? 
C14 C2 P5 116.5(5) . . ? 
C106 C3 C35 117.8(7) . . ? 
C106 C3 P3 124.0(6) . . ? 
C35 C3 P3 118.2(5) . . ? 
C41 C4 C38 118.9(6) . . ? 
C41 C4 P1 123.3(5) . . ? 
C38 C4 P1 117.8(5) . . ? 
C21 C5 C60 120.0(7) . . ? 
C21 C5 P1 122.9(5) . . ? 
C60 C5 P1 117.0(5) . . ? 
C9 C6 C24 118.8(6) . . ? 
C9 C6 P2 117.8(5) . . ? 
C24 C6 P2 123.4(5) . . ? 
C12 C7 C1 120.3(6) . . ? 
C12 C7 H7 119.9 . . ? 
C1 C7 H7 119.9 . . ? 
C22 C8 C51 119.3(6) . . ? 
C22 C8 P7 118.1(5) . . ? 
C51 C8 P7 122.7(5) . . ? 
C36 C9 C6 120.0(7) . . ? 
C36 C9 H9 120.0 . . ? 
C6 C9 H9 120.0 . . ? 
C19 C10 C1 119.4(6) . . ? 
C19 C10 H10 120.3 . . ? 
C1 C10 H10 120.3 . . ? 
C42 C11 C112 118.1(7) . . ? 
C42 C11 P4 117.8(5) . . ? 
C112 C11 P4 124.0(6) . . ? 
C30 C12 C7 120.1(6) . . ? 
C30 C12 H12 119.9 . . ? 
C7 C12 H12 119.9 . . ? 
C54 C13 C25 119.4(7) . . ? 
C54 C13 P3 119.0(6) . . ? 
C25 C13 P3 121.6(5) . . ? 
C43 C14 C2 118.8(6) . . ? 
C43 C14 H14 120.6 . . ? 
C2 C14 H14 120.6 . . ? 
C63 C15 C68 118.4(7) . . ? 
C63 C15 P6 124.0(6) . . ? 
C68 C15 P6 116.9(6) . . ? 
C49 C16 C56 120.7(7) . . ? 
C49 C16 P7 121.9(6) . . ? 
C56 C16 P7 116.8(5) . . ? 
C77 C17 C50 118.7(7) . . ? 
C77 C17 P8 116.6(6) . . ? 
C50 C17 P8 124.7(6) . . ? 
C45 C18 C37 119.5(6) . . ? 
C45 C18 P5 122.4(5) . . ? 
C37 C18 P5 118.2(5) . . ? 
C30 C19 C10 121.9(6) . . ? 
C30 C19 H19 119.0 . . ? 
C10 C19 H19 119.0 . . ? 
N6 C20 C83 124.0(8) . . ? 
N6 C20 C27 117.6(6) . . ? 
C83 C20 C27 117.5(9) . . ? 
C53 C21 C5 120.0(7) . . ? 
C53 C21 H21 120.0 . . ? 
C5 C21 H21 120.0 . . ? 
C74 C22 C8 120.7(8) . . ? 
C74 C22 H22 119.7 . . ? 
C8 C22 H22 119.7 . . ? 
C2 C23 C40 119.1(6) . . ? 
C2 C23 H23 120.5 . . ? 
C40 C23 H23 120.5 . . ? 
C31 C24 C6 120.0(7) . . ? 
C31 C24 H24 120.0 . . ? 
C6 C24 H24 120.0 . . ? 
C47 C25 C13 120.2(7) . . ? 
C47 C25 H25 119.9 . . ? 
C13 C25 H25 119.9 . . ? 
N7 C26 C44 115.4(6) . . ? 
N7 C26 H26A 108.4 . . ? 
C44 C26 H26A 108.4 . . ? 
N7 C26 H26B 108.4 . . ? 
C44 C26 H26B 108.4 . . ? 
H26A C26 H26B 107.5 . . ? 
N5 C27 C20 115.3(6) . . ? 
N5 C27 H27A 108.4 . . ? 
C20 C27 H27A 108.4 . . ? 
N5 C27 H27B 108.4 . . ? 
C20 C27 H27B 108.4 . . ? 
H27A C27 H27B 107.5 . . ? 
C100 C28 C71 121.1(8) . . ? 
C100 C28 P8 121.7(8) . . ? 
C71 C28 P8 116.9(7) . . ? 
C46 C29 C88 118.1(7) . . ? 
C46 C29 P4 119.7(5) . . ? 
C88 C29 P4 122.1(6) . . ? 
C12 C30 C19 119.2(6) . . ? 
C12 C30 H30 120.4 . . ? 
C19 C30 H30 120.4 . . ? 
C24 C31 C34 121.3(7) . . ? 
C24 C31 H31 119.4 . . ? 
C34 C31 H31 119.4 . . ? 
C67 C32 C69 118.4(7) . . ? 
C67 C32 P2 118.6(6) . . ? 
C69 C32 P2 122.7(6) . . ? 
N3 C33 C39 115.5(6) . . ? 
N3 C33 H33A 108.4 . . ? 
C39 C33 H33A 108.4 . . ? 
N3 C33 H33B 108.4 . . ? 
C39 C33 H33B 108.4 . . ? 
H33A C33 H33B 107.5 . . ? 
C31 C34 C36 119.0(7) . . ? 
C31 C34 H34 120.5 . . ? 
C36 C34 H34 120.5 . . ? 
C80 C35 C3 120.9(8) . . ? 
C80 C35 H35 119.6 . . ? 
C3 C35 H35 119.6 . . ? 
C34 C36 C9 120.9(7) . . ? 
C34 C36 H36 119.5 . . ? 
C9 C36 H36 119.5 . . ? 
C72 C37 C18 119.1(8) . . ? 
C72 C37 H37 120.4 . . ? 
C18 C37 H37 120.4 . . ? 
C55 C38 C4 119.3(7) . . ? 
C55 C38 H38 120.4 . . ? 
C4 C38 H38 120.4 . . ? 
C79 C39 N4 123.7(9) . . ? 
C79 C39 C33 124.0(8) . . ? 
N4 C39 C33 110.7(9) . . ? 
C48 C40 C23 120.3(6) . . ? 
C48 C40 H40 119.8 . . ? 
C23 C40 H40 119.8 . . ? 
C58 C41 C4 120.5(8) . . ? 
C58 C41 H41 119.8 . . ? 
C4 C41 H41 119.8 . . ? 
C11 C42 C62 121.4(7) . . ? 
C11 C42 H42 119.3 . . ? 
C62 C42 H42 119.3 . . ? 
C48 C43 C14 120.8(7) . . ? 
C48 C43 H43 119.6 . . ? 
C14 C43 H43 119.6 . . ? 
C108 C44 N8 124.3(10) . . ? 
C108 C44 C26 124.8(8) . . ? 
N8 C44 C26 108.7(9) . . ? 
C18 C45 C75 120.2(8) . . ? 
C18 C45 H45 119.9 . . ? 
C75 C45 H45 119.9 . . ? 
C29 C46 C73 122.0(7) . . ? 
C29 C46 H46 119.0 . . ? 
C73 C46 H46 119.0 . . ? 
C52 C47 C25 119.3(8) . . ? 
C52 C47 H47 120.4 . . ? 
C25 C47 H47 120.4 . . ? 
C40 C48 C43 120.1(6) . . ? 
C40 C48 H48 119.9 . . ? 
C43 C48 H48 119.9 . . ? 
C16 C49 C57 118.5(8) . . ? 
C16 C49 H49 120.8 . . ? 
C57 C49 H49 120.8 . . ? 
C96 C50 C17 119.9(8) . . ? 
C96 C50 H50 120.0 . . ? 
C17 C50 H50 120.0 . . ? 
C76 C51 C8 120.0(8) . . ? 
C76 C51 H51 120.0 . . ? 
C8 C51 H51 120.0 . . ? 
C86 C52 C47 121.5(8) . . ? 
C86 C52 H52 119.2 . . ? 
C47 C52 H52 119.2 . . ? 
C101 C53 C21 120.3(8) . . ? 
C101 C53 H53 119.9 . . ? 
C21 C53 H53 119.9 . . ? 
C13 C54 C86 119.9(8) . . ? 
C13 C54 H54 120.0 . . ? 
C86 C54 H54 120.0 . . ? 
C66 C55 C38 120.9(8) . . ? 
C66 C55 H55 119.5 . . ? 
C38 C55 H55 119.5 . . ? 
C16 C56 C81 119.9(8) . . ? 
C16 C56 H56 120.1 . . ? 
C81 C56 H56 120.1 . . ? 
C70 C57 C49 120.8(8) . . ? 
C70 C57 H57 119.6 . . ? 
C49 C57 H57 119.6 . . ? 
C66 C58 C41 120.6(8) . . ? 
C66 C58 H58 119.7 . . ? 
C41 C58 H58 119.7 . . ? 
C78 C59 C95 119.8(8) . . ? 
C78 C59 H59 120.1 . . ? 
C95 C59 H59 120.1 . . ? 
C107 C60 C5 119.6(8) . . ? 
C107 C60 H60 120.2 . . ? 
C5 C60 H60 120.2 . . ? 
C90 C61 N1 116.5(8) . . ? 
C90 C61 H61A 108.2 . . ? 
N1 C61 H61A 108.2 . . ? 
C90 C61 H61B 108.2 . . ? 
N1 C61 H61B 108.2 . . ? 
H61A C61 H61B 107.3 . . ? 
C99 C62 C42 120.2(8) . . ? 
C99 C62 H62 119.9 . . ? 
C42 C62 H62 119.9 . . ? 
C15 C63 C98 121.6(9) . . ? 
C15 C63 H63 119.2 . . ? 
C98 C63 H63 119.2 . . ? 
C73 C64 C89 120.2(7) . . ? 
C73 C64 H64 119.9 . . ? 
C89 C64 H64 119.9 . . ? 
C72 C65 C75 120.5(7) . . ? 
C72 C65 H65 119.8 . . ? 
C75 C65 H65 119.8 . . ? 
C58 C66 C55 119.9(7) . . ? 
C58 C66 H66 120.1 . . ? 
C55 C66 H66 120.1 . . ? 
C32 C67 C95 121.4(9) . . ? 
C32 C67 H67 119.3 . . ? 
C95 C67 H67 119.3 . . ? 
C102 C68 C15 121.3(10) . . ? 
C102 C68 H68 119.3 . . ? 
C15 C68 H68 119.3 . . ? 
C32 C69 C78 120.5(8) . . ? 
C32 C69 H69 119.7 . . ? 
C78 C69 H69 119.7 . . ? 
C57 C70 C81 120.5(8) . . ? 
C57 C70 H70 119.8 . . ? 
C81 C70 H70 119.8 . . ? 
C111 C71 C28 118.8(12) . . ? 
C111 C71 H71 120.6 . . ? 
C28 C71 H71 120.6 . . ? 
C65 C72 C37 121.0(8) . . ? 
C65 C72 H72 119.5 . . ? 
C37 C72 H72 119.5 . . ? 
C64 C73 C46 119.0(7) . . ? 
C64 C73 H73 120.5 . . ? 
C46 C73 H73 120.5 . . ? 
C22 C74 C103 120.1(9) . . ? 
C22 C74 H74 120.0 . . ? 
C103 C74 H74 120.0 . . ? 
C65 C75 C45 119.7(8) . . ? 
C65 C75 H75 120.1 . . ? 
C45 C75 H75 120.1 . . ? 
C51 C76 C103 120.5(9) . . ? 
C51 C76 H76 119.7 . . ? 
C103 C76 H76 119.7 . . ? 
C113 C77 C17 121.1(8) . . ? 
C113 C77 H77 119.4 . . ? 
C17 C77 H77 119.4 . . ? 
C59 C78 C69 120.3(9) . . ? 
C59 C78 H78 119.9 . . ? 
C69 C78 H78 119.9 . . ? 
C39 C79 C110 116.2(12) . . ? 
C39 C79 H79 121.9 . . ? 
C110 C79 H79 121.9 . . ? 
C35 C80 C109 119.8(9) . . ? 
C35 C80 H80 120.1 . . ? 
C109 C80 H80 120.1 . . ? 
C70 C81 C56 119.3(9) . . ? 
C70 C81 H81 120.4 . . ? 
C56 C81 H81 120.4 . . ? 
N6 C82 C97 123.5(11) . . ? 
N6 C82 H82 118.3 . . ? 
C97 C82 H82 118.3 . . ? 
C84 C83 C20 117.5(10) . . ? 
C84 C83 H83 121.2 . . ? 
C20 C83 H83 121.2 . . ? 
C97 C84 C83 118.5(8) . . ? 
C97 C84 H84 120.7 . . ? 
C83 C84 H84 120.7 . . ? 
C104 C85 N4 121.0(11) . . ? 
C104 C85 H85 119.5 . . ? 
N4 C85 H85 119.5 . . ? 
C52 C86 C54 119.6(8) . . ? 
C52 C86 H86 120.2 . . ? 
C54 C86 H86 120.2 . . ? 
C98 C87 C102 122.2(8) . . ? 
C98 C87 H87 118.9 . . ? 
C102 C87 H87 118.9 . . ? 
C89 C88 C29 119.9(8) . . ? 
C89 C88 H88 120.0 . . ? 
C29 C88 H88 120.0 . . ? 
C64 C89 C88 120.6(9) . . ? 
C64 C89 H89 119.7 . . ? 
C88 C89 H89 119.7 . . ? 
C91 C90 N2 120.0(5) . . ? 
C91 C90 C61 124.1(6) . . ? 
N2 C90 C61 115.7(7) . . ? 
C90 C91 C92 120.0 . . ? 
C90 C91 H91 120.0 . . ? 
C92 C91 H91 120.0 . . ? 
C93 C92 C91 120.0 . . ? 
C93 C92 H92 120.0 . . ? 
C91 C92 H92 120.0 . . ? 
C92 C93 C94 120.0 . . ? 
C92 C93 H93 120.0 . . ? 
C94 C93 H93 120.0 . . ? 
N2 C94 C93 120.0(5) . . ? 
N2 C94 H94 120.0 . . ? 
C93 C94 H94 120.0 . . ? 
C67 C95 C59 119.5(9) . . ? 
C67 C95 H95 120.2 . . ? 
C59 C95 H95 120.2 . . ? 
C105 C96 C50 119.7(8) . . ? 
C105 C96 H96 120.1 . . ? 
C50 C96 H96 120.1 . . ? 
C84 C97 C82 119.5(9) . . ? 
C84 C97 H97 120.3 . . ? 
C82 C97 H97 120.3 . . ? 
C87 C98 C63 118.2(10) . . ? 
C87 C98 H98 120.9 . . ? 
C63 C98 H98 120.9 . . ? 
C62 C99 C116 118.9(8) . . ? 
C62 C99 H99 120.6 . . ? 
C116 C99 H99 120.6 . . ? 
C118 C100 C28 121.4(14) . . ? 
C118 C100 H100 119.3 . . ? 
C28 C100 H100 119.3 . . ? 
C53 C101 C107 120.4(8) . . ? 
C53 C101 H101 119.8 . . ? 
C107 C101 H101 119.8 . . ? 
C68 C102 C87 117.8(11) . . ? 
C68 C102 H102 121.1 . . ? 
C87 C102 H102 121.1 . . ? 
C76 C103 C74 119.4(8) . . ? 
C76 C103 H103 120.3 . . ? 
C74 C103 H103 120.3 . . ? 
C110 C104 C85 119.4(10) . . ? 
C110 C104 H104 120.3 . . ? 
C85 C104 H104 120.3 . . ? 
C96 C105 C113 121.2(9) . . ? 
C96 C105 H105 119.4 . . ? 
C113 C105 H105 119.4 . . ? 
C3 C106 C117 122.1(10) . . ? 
C3 C106 H106 119.0 . . ? 
C117 C106 H106 119.0 . . ? 
C60 C107 C101 119.7(9) . . ? 
C60 C107 H107 120.2 . . ? 
C101 C107 H107 120.2 . . ? 
C44 C108 C119 120.5(13) . . ? 
C44 C108 H108 119.8 . . ? 
C119 C108 H108 119.8 . . ? 
C117 C109 C80 119.5(8) . . ? 
C117 C109 H109 120.3 . . ? 
C80 C109 H109 120.3 . . ? 
C104 C110 C79 123.0(13) . . ? 
C104 C110 H110 118.5 . . ? 
C79 C110 H110 118.5 . . ? 
C71 C111 C115 116.5(14) . . ? 
C71 C111 H111 121.7 . . ? 
C115 C111 H111 121.7 . . ? 
C11 C112 C116 120.2(9) . . ? 
C11 C112 H112 119.9 . . ? 
C116 C112 H112 119.9 . . ? 
C105 C113 C77 119.3(9) . . ? 
C105 C113 H113 120.3 . . ? 
C77 C113 H113 120.3 . . ? 
N8 C114 C120 120.0(12) . . ? 
N8 C114 H114 120.0 . . ? 
C120 C114 H114 120.0 . . ? 
C118 C115 C111 126.5(12) . . ? 
C118 C115 H115 116.8 . . ? 
C111 C115 H115 116.8 . . ? 
C99 C116 C112 121.2(9) . . ? 
C99 C116 H116 119.4 . . ? 
C112 C116 H116 119.4 . . ? 
C109 C117 C106 119.9(11) . . ? 
C109 C117 H117 120.1 . . ? 
C106 C117 H117 120.1 . . ? 
C115 C118 C100 115.6(14) . . ? 
C115 C118 H118 122.2 . . ? 
C100 C118 H118 122.2 . . ? 
C120 C119 C108 117.8(15) . . ? 
C120 C119 H119 121.1 . . ? 
C108 C119 H119 121.1 . . ? 
C119 C120 C114 121.4(14) . . ? 
C119 C120 H120 119.3 . . ? 
C114 C120 H120 119.3 . . ? 
C61 N1 P1 119.6(5) . . ? 
C61 N1 P2 120.6(5) . . ? 
P1 N1 P2 115.6(3) . . ? 
C94 N2 C90 120.0(8) . . ? 
C33 N3 P4 120.7(5) . . ? 
C33 N3 P3 119.0(5) . . ? 
P4 N3 P3 115.3(3) . . ? 
C85 N4 C39 115.6(10) . . ? 
C27 N5 P5 118.8(4) . . ? 
C27 N5 P6 120.2(5) . . ? 
P5 N5 P6 115.2(3) . . ? 
C20 N6 C82 116.5(7) . . ? 
C26 N7 P8 122.1(4) . . ? 
C26 N7 P7 122.8(4) . . ? 
P8 N7 P7 114.9(3) . . ? 
C114 N8 C44 114.4(11) . . ? 
N1 P1 C4 105.6(3) . . ? 
N1 P1 C5 108.8(3) . . ? 
C4 P1 C5 104.3(3) . . ? 
N1 P1 Au1 109.52(18) . . ? 
C4 P1 Au1 111.7(2) . . ? 
C5 P1 Au1 116.2(2) . . ? 
N1 P2 C32 106.3(3) . . ? 
N1 P2 C6 104.3(3) . . ? 
C32 P2 C6 103.2(3) . . ? 
N1 P2 Au2 114.9(2) . . ? 
C32 P2 Au2 113.3(3) . . ? 
C6 P2 Au2 113.8(2) . . ? 
N3 P3 C3 103.6(3) . . ? 
N3 P3 C13 106.6(3) . . ? 
C3 P3 C13 105.9(3) . . ? 
N3 P3 Au3 110.59(19) . . ? 
C3 P3 Au3 120.2(2) . . ? 
C13 P3 Au3 109.2(2) . . ? 
N3 P4 C29 108.1(3) . . ? 
N3 P4 C11 105.7(3) . . ? 
C29 P4 C11 107.9(3) . . ? 
N3 P4 Au4 109.69(19) . . ? 
C29 P4 Au4 114.2(2) . . ? 
C11 P4 Au4 110.9(2) . . ? 
N5 P5 C18 106.5(3) . . ? 
N5 P5 C2 110.3(3) . . ? 
C18 P5 C2 102.6(3) . . ? 
N5 P5 Au5 110.26(19) . . ? 
C18 P5 Au5 112.5(2) . . ? 
C2 P5 Au5 114.2(2) . . ? 
N5 P6 C15 105.0(3) . . ? 
N5 P6 C1 105.1(3) . . ? 
C15 P6 C1 102.5(3) . . ? 
N5 P6 Au6 114.03(18) . . ? 
C15 P6 Au6 116.5(3) . . ? 
C1 P6 Au6 112.4(2) . . ? 
N7 P7 C8 105.5(3) . . ? 
N7 P7 C16 107.2(3) . . ? 
C8 P7 C16 104.0(3) . . ? 
N7 P7 Au7 106.71(18) . . ? 
C8 P7 Au7 118.4(2) . . ? 
C16 P7 Au7 114.2(2) . . ? 
N7 P8 C17 109.6(3) . . ? 
N7 P8 C28 107.4(3) . . ? 
C17 P8 C28 105.0(4) . . ? 
N7 P8 Au8 111.83(18) . . ? 
C17 P8 Au8 111.9(2) . . ? 
C28 P8 Au8 110.7(3) . . ? 
F2' P9 F6 91.7(17) . . ? 
F2' P9 F4 152.1(19) . . ? 
F6 P9 F4 87.8(14) . . ? 
F2' P9 F3' 120(2) . . ? 
F6 P9 F3' 86.1(10) . . ? 
F4 P9 F3' 32.4(17) . . ? 
F2' P9 F2 26.2(18) . . ? 
F6 P9 F2 87.2(9) . . ? 
F4 P9 F2 174.6(15) . . ? 
F3' P9 F2 145(2) . . ? 
F2' P9 F1 123(2) . . ? 
F6 P9 F1 76(2) . . ? 
F4 P9 F1 84(2) . . ? 
F3' P9 F1 115(3) . . ? 
F2 P9 F1 97(2) . . ? 
F2' P9 F4' 140(2) . . ? 
F6 P9 F4' 120.1(13) . . ? 
F4 P9 F4' 59.7(14) . . ? 
F3' P9 F4' 87.8(16) . . ? 
F2 P9 F4' 124.9(16) . . ? 
F1 P9 F4' 54(2) . . ? 
F2' P9 F1' 80.0(17) . . ? 
F6 P9 F1' 98.3(13) . . ? 
F4 P9 F1' 127.6(14) . . ? 
F3' P9 F1' 159.8(19) . . ? 
F2 P9 F1' 55.3(12) . . ? 
F1 P9 F1' 48.6(18) . . ? 
F4' P9 F1' 72.9(16) . . ? 
F2' P9 F3 66.8(16) . . ? 
F6 P9 F3 86.8(8) . . ? 
F4 P9 F3 85.3(11) . . ? 
F3' P9 F3 52.9(17) . . ? 
F2 P9 F3 92.3(14) . . ? 
F1 P9 F3 160(2) . . ? 
F4' P9 F3 132.2(10) . . ? 
F1' P9 F3 146.6(10) . . ? 
F2' P9 F5 80.7(16) . . ? 
F6 P9 F5 168.5(9) . . ? 
F4 P9 F5 94.9(14) . . ? 
F3' P9 F5 90.2(13) . . ? 
F2 P9 F5 89.6(10) . . ? 
F1 P9 F5 116(2) . . ? 
F4' P9 F5 70.5(11) . . ? 
F1' P9 F5 88.9(11) . . ? 
F3 P9 F5 82.3(7) . . ? 
F13 P10 F13 180.0(5) 3_665 . ? 
F13 P10 F15 90.1(4) 3_665 . ? 
F13 P10 F15 89.9(4) . . ? 
F13 P10 F15 89.9(4) 3_665 3_665 ? 
F13 P10 F15 90.1(4) . 3_665 ? 
F15 P10 F15 180.0(5) . 3_665 ? 
F13 P10 F14 89.3(4) 3_665 . ? 
F13 P10 F14 90.7(4) . . ? 
F15 P10 F14 89.4(4) . . ? 
F15 P10 F14 90.6(4) 3_665 . ? 
F13 P10 F14 90.7(4) 3_665 3_665 ? 
F13 P10 F14 89.3(4) . 3_665 ? 
F15 P10 F14 90.6(4) . 3_665 ? 
F15 P10 F14 89.4(4) 3_665 3_665 ? 
F14 P10 F14 180.0(8) . 3_665 ? 
F10 P11 F12 88.4(12) . . ? 
F10 P11 F7 92.1(8) . . ? 
F12 P11 F7 87.3(7) . . ? 
F10 P11 F8 173.3(13) . . ? 
F12 P11 F8 84.9(10) . . ? 
F7 P11 F8 87.4(6) . . ? 
F10 P11 F11 91.6(13) . . ? 
F12 P11 F11 176.1(8) . . ? 
F7 P11 F11 88.8(7) . . ? 
F8 P11 F11 95.0(11) . . ? 
F10 P11 F9 89.4(8) . . ? 
F12 P11 F9 90.8(7) . . ? 
F7 P11 F9 177.6(8) . . ? 
F8 P11 F9 90.9(7) . . ? 
F11 P11 F9 93.1(7) . . ? 
Au9 S1 Au8 92.51(5) . . ? 
Au9 S1 Au1 110.98(6) . . ? 
Au8 S1 Au1 83.81(4) . . ? 
Au10 S2 Au2 90.62(5) . . ? 
Au10 S2 Au3 102.28(5) . . ? 
Au2 S2 Au3 87.41(6) . . ? 
Au9 S3 Au5 111.85(6) . . ? 
Au9 S3 Au4 95.48(5) . . ? 
Au5 S3 Au4 83.35(4) . . ? 
Au10 S4 Au6 90.75(5) . . ? 
Au10 S4 Au7 105.51(5) . . ? 
Au6 S4 Au7 86.28(6) . . ? 
N9 C122 C121 151(3) . . ? 
C124 C123 H12D 109.5 . . ? 
C124 C123 H12E 109.5 . . ? 
H12D C123 H12E 109.5 . . ? 
C124 C123 H12F 109.5 . . ? 
H12D C123 H12F 109.5 . . ? 
H12E C123 H12F 109.5 . . ? 
N10 C124 C123 176(4) . . ? 
 
_diffrn_measured_fraction_theta_max    0.979 
_diffrn_reflns_theta_full              26.00 
_diffrn_measured_fraction_theta_full   0.979 
_refine_diff_density_max    1.574 
_refine_diff_density_min   -2.305 
_refine_diff_density_rms    0.165 
