data_mx7337b-173k
_audit_creation_date               2018-07-30
_audit_creation_method
;
Olex2 1.2
(compiled 2018.05.29 svn.r3508 for OlexSys, GUI svn.r5506)
;
_shelx_SHELXL_version_number       '2016/6'
_audit_contact_author_address      ?
_audit_contact_author_email        ?
_audit_contact_author_name         ''
_audit_contact_author_phone        ?
_publ_contact_author_id_orcid      ?
_publ_section_references
;
Dolomanov, O.V., Bourhis, L.J., Gildea, R.J, Howard, J.A.K. & Puschmann, H.
 (2009), J. Appl. Cryst. 42, 339-341.

Sheldrick, G.M. (2015). Acta Cryst. A71, 3-8.

Sheldrick, G.M. (2015). Acta Cryst. C71, 3-8.
;
_chemical_name_common              ?
_chemical_name_systematic          ?
_chemical_formula_moiety           'C27 H19 F2 N O2 Pt'
_chemical_formula_sum              'C27 H19 F2 N O2 Pt'
_chemical_formula_weight           622.52
_chemical_melting_point            ?
loop_
  _atom_type_symbol
  _atom_type_description
  _atom_type_scat_dispersion_real
  _atom_type_scat_dispersion_imag
  _atom_type_scat_source
 'C' 'C' 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
 'H' 'H' 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
 'F' 'F' 0.0171 0.0103 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
 'N' 'N' 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
 'O' 'O' 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
 'Pt' 'Pt' -1.7033 8.3905
 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_shelx_space_group_comment
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
_space_group_crystal_system        'triclinic'
_space_group_IT_number             2
_space_group_name_H-M_alt          'P -1'
_space_group_name_Hall             '-P 1'
loop_
  _space_group_symop_operation_xyz
 'x, y, z'
 '-x, -y, -z'

_cell_length_a                     9.3111(2)
_cell_length_b                     10.2403(2)
_cell_length_c                     12.4557(3)
_cell_angle_alpha                  76.428(2)
_cell_angle_beta                   84.596(2)
_cell_angle_gamma                  69.771(2)
_cell_volume                       1083.15(4)
_cell_formula_units_Z              2
_cell_measurement_reflns_used      10672
_cell_measurement_temperature      173(2)
_cell_measurement_theta_max        27.5300
_cell_measurement_theta_min        2.1350
_shelx_estimated_absorpt_T_max     0.804
_shelx_estimated_absorpt_T_min     0.343
_exptl_absorpt_coefficient_mu      6.520
_exptl_absorpt_correction_T_max    1.00000
_exptl_absorpt_correction_T_min    0.50912
_exptl_absorpt_correction_type     multi-scan
_exptl_absorpt_process_details
;
CrysAlisPro 1.171.39.9d (Rigaku Oxford Diffrction, 2015)
Empirical absorption correction using spherical harmonics,
 implemented in SCALE3 ABSPACK scaling algorithm.
;

_exptl_absorpt_special_details     ?
_exptl_crystal_colour              yellow
_exptl_crystal_density_diffrn      1.909
_exptl_crystal_density_meas        ?
_exptl_crystal_density_method      ?
_exptl_crystal_description         plate
_exptl_crystal_F_000               600
_exptl_crystal_size_max            0.209
_exptl_crystal_size_mid            0.114
_exptl_crystal_size_min            0.035
_exptl_transmission_factor_max     ?
_exptl_transmission_factor_min     ?
_diffrn_reflns_av_R_equivalents    0.0325
_diffrn_reflns_av_unetI/netI       0.0304
_diffrn_reflns_Laue_measured_fraction_full  1.000
_diffrn_reflns_Laue_measured_fraction_max  0.999
_diffrn_reflns_limit_h_max         12
_diffrn_reflns_limit_h_min         -12
_diffrn_reflns_limit_k_max         13
_diffrn_reflns_limit_k_min         -12
_diffrn_reflns_limit_l_max         16
_diffrn_reflns_limit_l_min         -16
_diffrn_reflns_number              14284
_diffrn_reflns_point_group_measured_fraction_full  1.000
_diffrn_reflns_point_group_measured_fraction_max  0.999
_diffrn_reflns_theta_full          25.242
_diffrn_reflns_theta_max           27.485
_diffrn_reflns_theta_min           1.682
_diffrn_ambient_temperature        173.15
_diffrn_detector_area_resol_mean   ?
_diffrn_measured_fraction_theta_full  1.000
_diffrn_measured_fraction_theta_max  0.999
_diffrn_measurement_device_type    'MM007-HF CCD(Saturn 724+)' 
_diffrn_measurement_method        'ω scans at fixed χ = 45°' 
_diffrn_radiation_monochromator   Confocal 
_diffrn_radiation_type            MoK\a
_diffrn_radiation_wavelength      0.71073
_diffrn_source                    'Rotating Anode'
_reflns_Friedel_coverage           0.000
_reflns_Friedel_fraction_full      .
_reflns_Friedel_fraction_max       .
_reflns_number_gt                  4712
_reflns_number_total               4964
_reflns_special_details
;
 Reflections were merged by SHELXL according to the crystal
 class for the calculation of statistics and refinement.
 
 _reflns_Friedel_fraction is defined as the number of unique
 Friedel pairs measured divided by the number that would be
 possible theoretically, ignoring centric projections and
 systematic absences.
;
_reflns_threshold_expression       'I > 2σ(I)'
_computing_cell_refinement         'CrysAlisPro 1.171.39.9d (Rigaku OD, 2015)'
_computing_data_collection        'CrystalClear (Rigaku Inc., 2007)'
_computing_data_reduction         'CrysAlisPro 1.171.39.9d (Rigaku OD, 2015)'
_computing_molecular_graphics     'Olex2 (Dolomanov et al., 2009)'
_computing_publication_material   'CIFTAB (Sheldrick, 2014)'
_computing_structure_refinement    'ShelXL (Sheldrick, 2015)'
_computing_structure_solution      'ShelXT (Sheldrick, 2015)'
_refine_diff_density_max           1.075
_refine_diff_density_min           -0.753
_refine_diff_density_rms           0.114
_refine_ls_extinction_coef         .
_refine_ls_extinction_method       none
_refine_ls_goodness_of_fit_ref     1.058
_refine_ls_hydrogen_treatment      constr
_refine_ls_matrix_type             full
_refine_ls_number_parameters       299
_refine_ls_number_reflns           4964
_refine_ls_number_restraints       0
_refine_ls_R_factor_all            0.0237
_refine_ls_R_factor_gt             0.0218
_refine_ls_restrained_S_all        1.058
_refine_ls_shift/su_max            0.001
_refine_ls_shift/su_mean           0.000
_refine_ls_structure_factor_coef   Fsqd
_refine_ls_weighting_details      
 'w=1/[σ²(Fo²)+(0.0268P)²+0.1131P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme        calc
_refine_ls_wR_factor_gt            0.0492
_refine_ls_wR_factor_ref           0.0502
_refine_special_details            ?
_olex2_refinement_description
;
1. Fixed Uiso
 At 1.2 times of:
  All C(H) groups
 At 1.5 times of:
  All C(H,H,H) groups
2.a Aromatic/amide H refined with riding coordinates:
 C2(H2), C3(H3), C4(H4), C5(H5), C6(H6), C8(H8), C11(H11), C12(H12), C13(H13),
 C14(H14), C15(H15), C17(H17), C19(H19), C23(H23), C24(H24), C26(H26)
2.b Idealised Me refined as rotating group:
 C27(H27A,H27B,H27C)
;
_atom_sites_solution_hydrogens     geom
_atom_sites_solution_primary       dual
_atom_sites_solution_secondary     ?
loop_
  _atom_site_label
  _atom_site_type_symbol
  _atom_site_fract_x
  _atom_site_fract_y
  _atom_site_fract_z
  _atom_site_U_iso_or_equiv
  _atom_site_adp_type
  _atom_site_occupancy
  _atom_site_site_symmetry_order
  _atom_site_calc_flag
  _atom_site_refinement_flags_posn
  _atom_site_refinement_flags_adp
  _atom_site_refinement_flags_occupancy
  _atom_site_disorder_assembly
  _atom_site_disorder_group
 Pt1 Pt 0.79420(2) 0.23702(2) 0.47272(2) 0.02605(5) Uani 1 1 d . . . . .
 F1 F 0.9097(2) 0.2383(2) 0.04204(16) 0.0547(5) Uani 1 1 d . . . . .
 F2 F 1.3277(2) 0.0878(2) 0.27542(18) 0.0520(5) Uani 1 1 d . . . . .
 O1 O 0.5945(2) 0.3116(2) 0.39444(16) 0.0287(4) Uani 1 1 d . . . . .
 O2 O 0.6848(2) 0.2473(2) 0.62357(17) 0.0309(4) Uani 1 1 d . . . . .
 N1 N 1.0013(3) 0.1655(3) 0.5385(2) 0.0289(5) Uani 1 1 d . . . . .
 C1 C 0.3320(3) 0.4166(3) 0.3608(2) 0.0266(6) Uani 1 1 d . . . . .
 C2 C 0.3641(3) 0.4489(3) 0.2483(2) 0.0315(6) Uani 1 1 d . . . . .
 H2 H 0.467530 0.427422 0.223290 0.038 Uiso 1 1 calc R . . . .
 C3 C 0.2474(4) 0.5119(4) 0.1724(3) 0.0379(7) Uani 1 1 d . . . . .
 H3 H 0.271019 0.536128 0.095984 0.045 Uiso 1 1 calc R . . . .
 C4 C 0.0967(4) 0.5396(3) 0.2075(3) 0.0390(7) Uani 1 1 d . . . . .
 H4 H 0.016379 0.582379 0.155417 0.047 Uiso 1 1 calc R . . . .
 C5 C 0.0637(3) 0.5049(3) 0.3180(3) 0.0386(7) Uani 1 1 d . . . . .
 H5 H -0.039818 0.521722 0.341905 0.046 Uiso 1 1 calc R . . . .
 C6 C 0.1790(3) 0.4457(3) 0.3952(3) 0.0325(7) Uani 1 1 d . . . . .
 H6 H 0.154102 0.424797 0.471638 0.039 Uiso 1 1 calc R . . . .
 C7 C 0.4613(3) 0.3546(3) 0.4404(2) 0.0244(6) Uani 1 1 d . . . . .
 C8 C 0.4315(3) 0.3507(3) 0.5533(2) 0.0274(6) Uani 1 1 d . . . . .
 H8 H 0.327428 0.388573 0.575012 0.033 Uiso 1 1 calc R . . . .
 C9 C 0.5402(3) 0.2962(3) 0.6375(2) 0.0275(6) Uani 1 1 d . . . . .
 C10 C 0.4883(3) 0.2930(3) 0.7550(2) 0.0288(6) Uani 1 1 d . . . . .
 C11 C 0.3522(3) 0.3888(3) 0.7855(2) 0.0315(6) Uani 1 1 d . . . . .
 H11 H 0.285604 0.457195 0.730216 0.038 Uiso 1 1 calc R . . . .
 C12 C 0.3130(4) 0.3849(4) 0.8966(3) 0.0381(7) Uani 1 1 d . . . . .
 H12 H 0.220920 0.451705 0.916953 0.046 Uiso 1 1 calc R . . . .
 C13 C 0.4078(4) 0.2842(4) 0.9768(3) 0.0465(8) Uani 1 1 d . . . . .
 H13 H 0.380295 0.279940 1.052654 0.056 Uiso 1 1 calc R . . . .
 C14 C 0.5427(5) 0.1898(4) 0.9467(3) 0.0554(10) Uani 1 1 d . . . . .
 H14 H 0.608349 0.120466 1.002066 0.067 Uiso 1 1 calc R . . . .
 C15 C 0.5833(4) 0.1948(4) 0.8372(3) 0.0434(8) Uani 1 1 d . . . . .
 H15 H 0.677728 0.130114 0.817767 0.052 Uiso 1 1 calc R . . . .
 C16 C 0.9158(3) 0.2129(3) 0.3368(3) 0.0285(6) Uani 1 1 d . . . . .
 C17 C 0.8621(3) 0.2396(3) 0.2305(3) 0.0340(7) Uani 1 1 d . . . . .
 H17 H 0.755206 0.275836 0.217024 0.041 Uiso 1 1 calc R . . . .
 C18 C 0.9642(4) 0.2133(3) 0.1460(3) 0.0384(7) Uani 1 1 d . . . . .
 C19 C 1.1205(4) 0.1624(4) 0.1577(3) 0.0431(8) Uani 1 1 d . . . . .
 H19 H 1.188205 0.145854 0.096611 0.052 Uiso 1 1 calc R . . . .
 C20 C 1.1740(3) 0.1365(3) 0.2634(3) 0.0368(7) Uani 1 1 d . . . . .
 C21 C 1.0774(3) 0.1583(3) 0.3538(3) 0.0311(6) Uani 1 1 d . . . . .
 C22 C 1.1234(3) 0.1322(3) 0.4685(3) 0.0308(6) Uani 1 1 d . . . . .
 C23 C 1.2704(3) 0.0804(3) 0.5098(3) 0.0387(7) Uani 1 1 d . . . . .
 H23 H 1.356232 0.055166 0.461847 0.046 Uiso 1 1 calc R . . . .
 C24 C 1.2919(4) 0.0655(4) 0.6210(3) 0.0405(8) Uani 1 1 d . . . . .
 H24 H 1.392814 0.031000 0.648854 0.049 Uiso 1 1 calc R . . . .
 C25 C 1.1670(4) 0.1005(3) 0.6924(3) 0.0365(7) Uani 1 1 d . . . . .
 C26 C 1.0233(3) 0.1503(3) 0.6465(3) 0.0333(7) Uani 1 1 d . . . . .
 H26 H 0.936159 0.174842 0.693503 0.040 Uiso 1 1 calc R . . . .
 C27 C 1.1848(4) 0.0844(4) 0.8139(3) 0.0473(9) Uani 1 1 d . . . . .
 H27A H 1.226451 -0.017020 0.848979 0.071 Uiso 1 1 calc GR . . . .
 H27B H 1.084793 0.127054 0.847145 0.071 Uiso 1 1 calc GR . . . .
 H27C H 1.254868 0.132718 0.824952 0.071 Uiso 1 1 calc GR . . . .


_geom_special_details
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;
loop_
  _geom_bond_atom_site_label_1
  _geom_bond_atom_site_label_2
  _geom_bond_distance
  _geom_bond_site_symmetry_2
  _geom_bond_publ_flag
 Pt1 O1 2.0003(19) . ?
 Pt1 O2 2.059(2) . ?
 Pt1 N1 1.991(2) . ?
 Pt1 C16 1.962(3) . ?
 F1 C18 1.371(4) . ?
 F2 C20 1.354(3) . ?
 O1 C7 1.291(3) . ?
 O2 C9 1.274(3) . ?
 N1 C22 1.361(4) . ?
 N1 C26 1.345(4) . ?
 C1 C2 1.391(4) . ?
 C1 C6 1.398(4) . ?
 C1 C7 1.496(4) . ?
 C2 H2 0.9500 . ?
 C2 C3 1.383(4) . ?
 C3 H3 0.9500 . ?
 C3 C4 1.382(4) . ?
 C4 H4 0.9500 . ?
 C4 C5 1.372(5) . ?
 C5 H5 0.9500 . ?
 C5 C6 1.384(4) . ?
 C6 H6 0.9500 . ?
 C7 C8 1.401(4) . ?
 C8 H8 0.9500 . ?
 C8 C9 1.404(4) . ?
 C9 C10 1.494(4) . ?
 C10 C11 1.392(4) . ?
 C10 C15 1.384(4) . ?
 C11 H11 0.9500 . ?
 C11 C12 1.392(4) . ?
 C12 H12 0.9500 . ?
 C12 C13 1.377(5) . ?
 C13 H13 0.9500 . ?
 C13 C14 1.377(5) . ?
 C14 H14 0.9500 . ?
 C14 C15 1.374(5) . ?
 C15 H15 0.9500 . ?
 C16 C17 1.393(4) . ?
 C16 C21 1.430(4) . ?
 C17 H17 0.9500 . ?
 C17 C18 1.360(4) . ?
 C18 C19 1.375(5) . ?
 C19 H19 0.9500 . ?
 C19 C20 1.386(5) . ?
 C20 C21 1.383(4) . ?
 C21 C22 1.467(4) . ?
 C22 C23 1.387(4) . ?
 C23 H23 0.9500 . ?
 C23 C24 1.383(5) . ?
 C24 H24 0.9500 . ?
 C24 C25 1.392(5) . ?
 C25 C26 1.383(4) . ?
 C25 C27 1.503(5) . ?
 C26 H26 0.9500 . ?
 C27 H27A 0.9800 . ?
 C27 H27B 0.9800 . ?
 C27 H27C 0.9800 . ?

loop_
  _geom_angle_atom_site_label_1
  _geom_angle_atom_site_label_2
  _geom_angle_atom_site_label_3
  _geom_angle
  _geom_angle_site_symmetry_1
  _geom_angle_site_symmetry_3
  _geom_angle_publ_flag
 O1 Pt1 O2 91.62(8) . . ?
 N1 Pt1 O1 175.27(8) . . ?
 N1 Pt1 O2 93.00(9) . . ?
 C16 Pt1 O1 93.51(10) . . ?
 C16 Pt1 O2 174.38(9) . . ?
 C16 Pt1 N1 81.91(11) . . ?
 C7 O1 Pt1 125.19(18) . . ?
 C9 O2 Pt1 124.76(19) . . ?
 C22 N1 Pt1 116.9(2) . . ?
 C26 N1 Pt1 122.9(2) . . ?
 C26 N1 C22 120.2(3) . . ?
 C2 C1 C6 118.4(3) . . ?
 C2 C1 C7 119.1(3) . . ?
 C6 C1 C7 122.4(3) . . ?
 C1 C2 H2 119.6 . . ?
 C3 C2 C1 120.9(3) . . ?
 C3 C2 H2 119.6 . . ?
 C2 C3 H3 120.0 . . ?
 C4 C3 C2 120.1(3) . . ?
 C4 C3 H3 120.0 . . ?
 C3 C4 H4 120.2 . . ?
 C5 C4 C3 119.5(3) . . ?
 C5 C4 H4 120.2 . . ?
 C4 C5 H5 119.5 . . ?
 C4 C5 C6 121.0(3) . . ?
 C6 C5 H5 119.5 . . ?
 C1 C6 H6 120.0 . . ?
 C5 C6 C1 120.0(3) . . ?
 C5 C6 H6 120.0 . . ?
 O1 C7 C1 113.9(2) . . ?
 O1 C7 C8 126.2(3) . . ?
 C8 C7 C1 119.9(2) . . ?
 C7 C8 H8 116.8 . . ?
 C7 C8 C9 126.4(3) . . ?
 C9 C8 H8 116.8 . . ?
 O2 C9 C8 125.6(3) . . ?
 O2 C9 C10 114.8(3) . . ?
 C8 C9 C10 119.6(3) . . ?
 C11 C10 C9 122.9(3) . . ?
 C15 C10 C9 118.4(3) . . ?
 C15 C10 C11 118.6(3) . . ?
 C10 C11 H11 119.8 . . ?
 C10 C11 C12 120.4(3) . . ?
 C12 C11 H11 119.8 . . ?
 C11 C12 H12 120.0 . . ?
 C13 C12 C11 120.0(3) . . ?
 C13 C12 H12 120.0 . . ?
 C12 C13 H13 120.2 . . ?
 C12 C13 C14 119.7(3) . . ?
 C14 C13 H13 120.2 . . ?
 C13 C14 H14 119.7 . . ?
 C15 C14 C13 120.6(3) . . ?
 C15 C14 H14 119.7 . . ?
 C10 C15 H15 119.6 . . ?
 C14 C15 C10 120.7(3) . . ?
 C14 C15 H15 119.6 . . ?
 C17 C16 Pt1 127.5(2) . . ?
 C17 C16 C21 118.7(3) . . ?
 C21 C16 Pt1 113.7(2) . . ?
 C16 C17 H17 120.3 . . ?
 C18 C17 C16 119.3(3) . . ?
 C18 C17 H17 120.3 . . ?
 F1 C18 C19 117.1(3) . . ?
 C17 C18 F1 118.7(3) . . ?
 C17 C18 C19 124.2(3) . . ?
 C18 C19 H19 121.8 . . ?
 C18 C19 C20 116.5(3) . . ?
 C20 C19 H19 121.8 . . ?
 F2 C20 C19 116.8(3) . . ?
 F2 C20 C21 120.5(3) . . ?
 C21 C20 C19 122.7(3) . . ?
 C16 C21 C22 114.9(3) . . ?
 C20 C21 C16 118.5(3) . . ?
 C20 C21 C22 126.6(3) . . ?
 N1 C22 C21 112.5(3) . . ?
 N1 C22 C23 119.5(3) . . ?
 C23 C22 C21 128.0(3) . . ?
 C22 C23 H23 120.0 . . ?
 C24 C23 C22 119.9(3) . . ?
 C24 C23 H23 120.0 . . ?
 C23 C24 H24 119.7 . . ?
 C23 C24 C25 120.6(3) . . ?
 C25 C24 H24 119.7 . . ?
 C24 C25 C27 122.5(3) . . ?
 C26 C25 C24 116.8(3) . . ?
 C26 C25 C27 120.7(3) . . ?
 N1 C26 C25 123.0(3) . . ?
 N1 C26 H26 118.5 . . ?
 C25 C26 H26 118.5 . . ?
 C25 C27 H27A 109.5 . . ?
 C25 C27 H27B 109.5 . . ?
 C25 C27 H27C 109.5 . . ?
 H27A C27 H27B 109.5 . . ?
 H27A C27 H27C 109.5 . . ?
 H27B C27 H27C 109.5 . . ?

loop_
  _geom_torsion_atom_site_label_1
  _geom_torsion_atom_site_label_2
  _geom_torsion_atom_site_label_3
  _geom_torsion_atom_site_label_4
  _geom_torsion
  _geom_torsion_site_symmetry_1
  _geom_torsion_site_symmetry_2
  _geom_torsion_site_symmetry_3
  _geom_torsion_site_symmetry_4
  _geom_torsion_publ_flag
 Pt1 O1 C7 C1 175.03(17) . . . . ?
 Pt1 O1 C7 C8 -3.3(4) . . . . ?
 Pt1 O2 C9 C8 0.3(4) . . . . ?
 Pt1 O2 C9 C10 -179.70(18) . . . . ?
 Pt1 N1 C22 C21 0.9(3) . . . . ?
 Pt1 N1 C22 C23 -179.3(2) . . . . ?
 Pt1 N1 C26 C25 180.0(2) . . . . ?
 Pt1 C16 C17 C18 -178.4(2) . . . . ?
 Pt1 C16 C21 C20 179.7(2) . . . . ?
 Pt1 C16 C21 C22 -0.9(3) . . . . ?
 F1 C18 C19 C20 -179.5(3) . . . . ?
 F2 C20 C21 C16 178.6(3) . . . . ?
 F2 C20 C21 C22 -0.8(5) . . . . ?
 O1 C7 C8 C9 -1.7(5) . . . . ?
 O2 C9 C10 C11 152.5(3) . . . . ?
 O2 C9 C10 C15 -24.3(4) . . . . ?
 N1 C22 C23 C24 -1.2(5) . . . . ?
 C1 C2 C3 C4 -2.0(5) . . . . ?
 C1 C7 C8 C9 -179.9(3) . . . . ?
 C2 C1 C6 C5 0.2(4) . . . . ?
 C2 C1 C7 O1 -12.6(4) . . . . ?
 C2 C1 C7 C8 165.9(3) . . . . ?
 C2 C3 C4 C5 0.3(5) . . . . ?
 C3 C4 C5 C6 1.6(5) . . . . ?
 C4 C5 C6 C1 -1.8(5) . . . . ?
 C6 C1 C2 C3 1.7(4) . . . . ?
 C6 C1 C7 O1 168.4(3) . . . . ?
 C6 C1 C7 C8 -13.1(4) . . . . ?
 C7 C1 C2 C3 -177.3(3) . . . . ?
 C7 C1 C6 C5 179.1(3) . . . . ?
 C7 C8 C9 O2 3.3(5) . . . . ?
 C7 C8 C9 C10 -176.7(3) . . . . ?
 C8 C9 C10 C11 -27.4(4) . . . . ?
 C8 C9 C10 C15 155.8(3) . . . . ?
 C9 C10 C11 C12 -177.0(3) . . . . ?
 C9 C10 C15 C14 178.4(3) . . . . ?
 C10 C11 C12 C13 -1.2(5) . . . . ?
 C11 C10 C15 C14 1.4(5) . . . . ?
 C11 C12 C13 C14 1.4(6) . . . . ?
 C12 C13 C14 C15 -0.2(6) . . . . ?
 C13 C14 C15 C10 -1.2(6) . . . . ?
 C15 C10 C11 C12 -0.2(5) . . . . ?
 C16 C17 C18 F1 179.2(3) . . . . ?
 C16 C17 C18 C19 -0.7(5) . . . . ?
 C16 C21 C22 N1 0.0(4) . . . . ?
 C16 C21 C22 C23 -179.8(3) . . . . ?
 C17 C16 C21 C20 1.1(4) . . . . ?
 C17 C16 C21 C22 -179.4(3) . . . . ?
 C17 C18 C19 C20 0.4(6) . . . . ?
 C18 C19 C20 F2 -179.3(3) . . . . ?
 C18 C19 C20 C21 0.7(5) . . . . ?
 C19 C20 C21 C16 -1.5(5) . . . . ?
 C19 C20 C21 C22 179.1(3) . . . . ?
 C20 C21 C22 N1 179.4(3) . . . . ?
 C20 C21 C22 C23 -0.4(5) . . . . ?
 C21 C16 C17 C18 -0.1(5) . . . . ?
 C21 C22 C23 C24 178.6(3) . . . . ?
 C22 N1 C26 C25 -0.4(4) . . . . ?
 C22 C23 C24 C25 0.7(5) . . . . ?
 C23 C24 C25 C26 -0.1(5) . . . . ?
 C23 C24 C25 C27 179.2(3) . . . . ?
 C24 C25 C26 N1 -0.1(5) . . . . ?
 C26 N1 C22 C21 -178.8(3) . . . . ?
 C26 N1 C22 C23 1.0(4) . . . . ?
 C27 C25 C26 N1 -179.4(3) . . . . ?

_olex2_submission_special_instructions  'No special instructions were received'
