data_mjl18335_0m
_audit_creation_date               2018-07-17
_audit_creation_method
;
Olex2 1.2
(compiled 2018.05.29 svn.r3508 for OlexSys, GUI svn.r5506)
;
_shelx_SHELXL_version_number       '2016/6'
_audit_contact_author_address      ?
_audit_contact_author_email        ?
_audit_contact_author_name         ''
_audit_contact_author_phone        ?
_publ_contact_author_id_orcid      ?
_publ_section_references
;
Dolomanov, O.V., Bourhis, L.J., Gildea, R.J, Howard, J.A.K. & Puschmann, H.
 (2009), J. Appl. Cryst. 42, 339-341.

Sheldrick, G.M. (2015). Acta Cryst. A71, 3-8.

Sheldrick, G.M. (2015). Acta Cryst. C71, 3-8.
;
_chemical_name_common              ?
_chemical_name_systematic          ?
_chemical_formula_moiety           'C12 H16 Cl2 Co N2 O'
_chemical_formula_sum              'C12.50 H16 Cl2 Co N1.50 O'
_chemical_formula_weight           333.10
_chemical_absolute_configuration   rmad
_chemical_melting_point            ?
loop_
  _atom_type_symbol
  _atom_type_description
  _atom_type_scat_dispersion_real
  _atom_type_scat_dispersion_imag
  _atom_type_scat_source
 'C' 'C' 0.0148 0.0070 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
 'H' 'H' 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
 'Cl' 'Cl' 0.3294 0.5404 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
 'Co' 'Co' -0.6671 2.8827
 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
 'N' 'N' 0.0253 0.0136 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
 'O' 'O' 0.0412 0.0250 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_shelx_space_group_comment
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
_space_group_crystal_system        'triclinic'
_space_group_IT_number             1
_space_group_name_H-M_alt          'P 1'
_space_group_name_Hall             'P 1'
loop_
  _space_group_symop_operation_xyz
 'x, y, z'

_cell_length_a                     8.5586(2)
_cell_length_b                     8.9303(2)
_cell_length_c                     9.6822(2)
_cell_angle_alpha                  76.7230(10)
_cell_angle_beta                   86.7030(10)
_cell_angle_gamma                  85.1260(10)
_cell_volume                       717.08(3)
_cell_formula_units_Z              2
_cell_measurement_reflns_used      5347
_cell_measurement_temperature      170(2)
_cell_measurement_theta_max        54.955
_cell_measurement_theta_min        5.314
_shelx_estimated_absorpt_T_max     0.672
_shelx_estimated_absorpt_T_min     0.357
_exptl_absorpt_coefficient_mu      8.648
_exptl_absorpt_correction_T_max    0.7508
_exptl_absorpt_correction_T_min    0.4694
_exptl_absorpt_correction_type     multi-scan
_exptl_absorpt_process_details    
 'SADABS-2016/2 (Bruker,2016/2) was used for absorption correction. wR2(int) was 0.1028 before and 0.0629 after correction. The Ratio of minimum to maximum transmission is 0.6252. The λ/2 correction factor is Not present.'
_exptl_absorpt_special_details     ?
_exptl_crystal_colour              'blue'
_exptl_crystal_density_diffrn      1.543
_exptl_crystal_density_meas        ?
_exptl_crystal_density_method      ?
_exptl_crystal_description         'block'
_exptl_crystal_F_000               341
_exptl_crystal_size_max            0.15
_exptl_crystal_size_mid            0.1
_exptl_crystal_size_min            0.05
_exptl_transmission_factor_max     ?
_exptl_transmission_factor_min     ?
_diffrn_reflns_av_R_equivalents    0.0408
_diffrn_reflns_av_unetI/netI       0.0560
_diffrn_reflns_Laue_measured_fraction_full  0.994
_diffrn_reflns_Laue_measured_fraction_max  0.992
_diffrn_reflns_limit_h_max         10
_diffrn_reflns_limit_h_min         -10
_diffrn_reflns_limit_k_max         10
_diffrn_reflns_limit_k_min         -8
_diffrn_reflns_limit_l_max         11
_diffrn_reflns_limit_l_min         -11
_diffrn_reflns_number              7632
_diffrn_reflns_point_group_measured_fraction_full  0.634
_diffrn_reflns_point_group_measured_fraction_max  0.631
_diffrn_reflns_theta_full          53.594
_diffrn_reflns_theta_max           54.929
_diffrn_reflns_theta_min           5.312
_diffrn_ambient_temperature        169.99
_diffrn_detector_area_resol_mean   ?
_diffrn_measured_fraction_theta_full  0.994
_diffrn_measured_fraction_theta_max  0.992
_diffrn_measurement_device_type    'Bruker D8 Venture'
_diffrn_measurement_method         'φ and ω scans'
_diffrn_radiation_type             GaK\a
_diffrn_radiation_wavelength       1.34139
_diffrn_source                     ?
_diffrn_standards_number           0
_reflns_Friedel_coverage           0.273
_reflns_Friedel_fraction_full      0.273
_reflns_Friedel_fraction_max       0.271
_reflns_number_gt                  3195
_reflns_number_total               3459
_reflns_special_details
;
 Reflections were merged by SHELXL according to the crystal
 class for the calculation of statistics and refinement.
 
 _reflns_Friedel_fraction is defined as the number of unique
 Friedel pairs measured divided by the number that would be
 possible theoretically, ignoring centric projections and
 systematic absences.
;
_reflns_threshold_expression       'I > 2σ(I)'
_computing_cell_refinement         'SAINT v8.37A (Bruker, 2015)'
_computing_data_collection         ?
_computing_data_reduction          'SAINT v8.37A (Bruker, 2015)'
_computing_molecular_graphics      'Olex2 (Dolomanov et al., 2009)'
_computing_publication_material    'Olex2 (Dolomanov et al., 2009)'
_computing_structure_refinement    'ShelXL (Sheldrick, 2015)'
_computing_structure_solution      'ShelXT (Sheldrick, 2015)'
_refine_diff_density_max           0.313
_refine_diff_density_min           -1.052
_refine_diff_density_rms           0.091
_refine_ls_abs_structure_details
;
 Classical Flack method preferred over Parsons because s.u. lower.
;
_refine_ls_abs_structure_Flack     0.011(7)
_refine_ls_extinction_coef         .
_refine_ls_extinction_method       none
_refine_ls_goodness_of_fit_ref     0.810
_refine_ls_hydrogen_treatment      constr
_refine_ls_matrix_type             full
_refine_ls_number_parameters       331
_refine_ls_number_reflns           3459
_refine_ls_number_restraints       3
_refine_ls_R_factor_all            0.0408
_refine_ls_R_factor_gt             0.0369
_refine_ls_restrained_S_all        0.809
_refine_ls_shift/su_max            0.000
_refine_ls_shift/su_mean           0.000
_refine_ls_structure_factor_coef   Fsqd
_refine_ls_weighting_details      
 'w=1/[σ²(Fo²)+(0.1000P)²] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme        calc
_refine_ls_wR_factor_gt            0.0995
_refine_ls_wR_factor_ref           0.1050
_refine_special_details            ?
_olex2_refinement_description
;
1. Fixed Uiso
 At 1.2 times of:
  All C(H) groups, All C(H,H) groups
 At 1.5 times of:
  All C(H,H,H) groups
2.a Ternary CH refined with riding coordinates:
 C9(H9), C10(H10), C21(H21), C22(H22)
2.b Secondary CH2 refined with riding coordinates:
 C8(H8A,H8B), C20(H20A,H20B)
2.c Aromatic/amide H refined with riding coordinates:
 C3(H3), C4(H4), C5(H5), C15(H15), C16(H16), C17(H17)
2.d Idealised Me refined as rotating group:
 C1(H1A,H1B,H1C), C11(H11A,H11B,H11C), C12(H12A,H12B,H12C), C13(H13A,H13B,
 H13C), C23(H23A,H23B,H23C), C24(H24B,H24A,H24C)
;
_atom_sites_solution_hydrogens     geom
_atom_sites_solution_primary       dual
_atom_sites_solution_secondary     ?
loop_
  _atom_site_label
  _atom_site_type_symbol
  _atom_site_fract_x
  _atom_site_fract_y
  _atom_site_fract_z
  _atom_site_U_iso_or_equiv
  _atom_site_adp_type
  _atom_site_occupancy
  _atom_site_site_symmetry_order
  _atom_site_calc_flag
  _atom_site_refinement_flags_posn
  _atom_site_refinement_flags_adp
  _atom_site_refinement_flags_occupancy
  _atom_site_disorder_assembly
  _atom_site_disorder_group
 Co1 Co 0.66737(7) 0.68885(7) 0.78374(7) 0.0174(2) Uani 1 1 d . . . . .
 Cl1 Cl 0.78471(17) 0.65474(17) 0.98722(15) 0.0291(3) Uani 1 1 d . . . . .
 Cl2 Cl 0.76636(17) 0.86002(15) 0.59950(15) 0.0275(3) Uani 1 1 d . . . . .
 O1 O 0.2354(5) 0.5772(5) 0.7209(5) 0.0269(10) Uani 1 1 d . . . . .
 N1 N 0.4311(6) 0.6837(5) 0.7983(5) 0.0213(11) Uani 1 1 d . . . . .
 N2 N 0.6498(5) 0.4901(6) 0.7084(5) 0.0199(10) Uani 1 1 d . . . . .
 C1 C 0.9301(7) 0.4243(7) 0.6869(7) 0.0280(14) Uani 1 1 d . . . . .
 H1A H 0.941237 0.533309 0.642704 0.042 Uiso 1 1 calc GR . . . .
 H1B H 1.000958 0.359839 0.637623 0.042 Uiso 1 1 calc GR . . . .
 H1C H 0.956677 0.403730 0.786998 0.042 Uiso 1 1 calc GR . . . .
 C2 C 0.7639(7) 0.3874(7) 0.6770(6) 0.0212(12) Uani 1 1 d . . . . .
 C3 C 0.7251(8) 0.2549(7) 0.6368(6) 0.0248(13) Uani 1 1 d . . . . .
 H3 H 0.805747 0.182428 0.616231 0.030 Uiso 1 1 calc R . . . .
 C4 C 0.5710(8) 0.2297(7) 0.6271(6) 0.0255(13) Uani 1 1 d . . . . .
 H4 H 0.544442 0.138894 0.601266 0.031 Uiso 1 1 calc R . . . .
 C5 C 0.4534(8) 0.3374(7) 0.6551(6) 0.0239(13) Uani 1 1 d . . . . .
 H5 H 0.345843 0.324353 0.645768 0.029 Uiso 1 1 calc R . . . .
 C6 C 0.4990(7) 0.4619(7) 0.6964(6) 0.0191(11) Uani 1 1 d . . . . .
 C7 C 0.3872(6) 0.5806(7) 0.7399(6) 0.0183(12) Uani 1 1 d . . . . .
 C8 C 0.1603(8) 0.7147(9) 0.7651(9) 0.0349(17) Uani 1 1 d . . . . .
 H8A H 0.064536 0.688993 0.825334 0.042 Uiso 1 1 calc R . . . .
 H8B H 0.131993 0.797718 0.681512 0.042 Uiso 1 1 calc R . . . .
 C9 C 0.2855(6) 0.7633(6) 0.8492(6) 0.0237(11) Uani 1 1 d . . . . .
 H9 H 0.266174 0.715908 0.952208 0.028 Uiso 1 1 calc R . . . .
 C10 C 0.2912(7) 0.9362(7) 0.8321(7) 0.0250(13) Uani 1 1 d . . . . .
 H10 H 0.320008 0.982803 0.730697 0.030 Uiso 1 1 calc R . . . .
 C11 C 0.4146(8) 0.9703(7) 0.9250(7) 0.0337(13) Uani 1 1 d . . . . .
 H11A H 0.416660 1.082166 0.912620 0.051 Uiso 1 1 calc GR . . . .
 H11B H 0.517763 0.927117 0.897658 0.051 Uiso 1 1 calc GR . . . .
 H11C H 0.389053 0.923598 1.024759 0.051 Uiso 1 1 calc GR . . . .
 C12 C 0.1311(9) 1.0060(9) 0.8680(10) 0.0465(19) Uani 1 1 d . . . . .
 H12A H 0.094485 0.950991 0.962286 0.070 Uiso 1 1 calc GR . . . .
 H12B H 0.057045 0.997234 0.797209 0.070 Uiso 1 1 calc GR . . . .
 H12C H 0.137962 1.115067 0.867713 0.070 Uiso 1 1 calc GR . . . .
 Co2 Co 0.32362(7) 0.33379(7) 0.25932(7) 0.0182(2) Uani 1 1 d . . . . .
 Cl3 Cl 0.21231(15) 0.17411(14) 0.44494(15) 0.0248(3) Uani 1 1 d . . . . .
 Cl4 Cl 0.22344(19) 0.35305(19) 0.04943(17) 0.0351(4) Uani 1 1 d . . . . .
 O2 O 0.7571(5) 0.4490(5) 0.3176(5) 0.0234(9) Uani 1 1 d . . . . .
 N3 N 0.5592(6) 0.3225(5) 0.2715(5) 0.0190(10) Uani 1 1 d . . . . .
 N4 N 0.3441(6) 0.5500(5) 0.3035(5) 0.0200(10) Uani 1 1 d . . . . .
 C13 C 0.0668(7) 0.6249(8) 0.3055(9) 0.0347(16) Uani 1 1 d . . . . .
 H13A H 0.049177 0.633687 0.204773 0.052 Uiso 1 1 calc GR . . . .
 H13B H -0.005005 0.699745 0.341642 0.052 Uiso 1 1 calc GR . . . .
 H13C H 0.047740 0.520335 0.359029 0.052 Uiso 1 1 calc GR . . . .
 C14 C 0.2327(7) 0.6566(7) 0.3226(7) 0.0247(13) Uani 1 1 d . . . . .
 C15 C 0.2692(8) 0.7932(7) 0.3587(7) 0.0277(14) Uani 1 1 d . . . . .
 H15 H 0.188431 0.869566 0.370706 0.033 Uiso 1 1 calc R . . . .
 C16 C 0.4240(8) 0.8147(7) 0.3765(8) 0.0312(14) Uani 1 1 d . . . . .
 H16 H 0.449918 0.904401 0.404616 0.037 Uiso 1 1 calc R . . . .
 C17 C 0.5414(7) 0.7056(7) 0.3536(7) 0.0260(13) Uani 1 1 d . . . . .
 H17 H 0.648681 0.719903 0.362815 0.031 Uiso 1 1 calc R . . . .
 C18 C 0.4970(7) 0.5743(6) 0.3165(6) 0.0194(12) Uani 1 1 d . . . . .
 C19 C 0.6068(7) 0.4452(7) 0.2979(6) 0.0202(13) Uani 1 1 d . . . . .
 C20 C 0.8339(7) 0.3101(7) 0.2782(7) 0.0238(13) Uani 1 1 d . . . . .
 H20A H 0.911909 0.257496 0.348282 0.029 Uiso 1 1 calc R . . . .
 H20B H 0.886642 0.336016 0.182904 0.029 Uiso 1 1 calc R . . . .
 C21 C 0.6955(6) 0.2087(6) 0.2788(6) 0.0196(10) Uani 1 1 d . . . . .
 H21 H 0.689925 0.133448 0.372711 0.024 Uiso 1 1 calc R . . . .
 C22 C 0.7041(7) 0.1192(7) 0.1619(6) 0.0229(12) Uani 1 1 d . . . . .
 H22 H 0.607843 0.060647 0.173502 0.027 Uiso 1 1 calc R . . . .
 C23 C 0.8449(9) 0.0010(8) 0.1832(8) 0.0387(17) Uani 1 1 d . . . . .
 H23A H 0.941872 0.054584 0.166517 0.058 Uiso 1 1 calc GR . . . .
 H23B H 0.842602 -0.065842 0.116082 0.058 Uiso 1 1 calc GR . . . .
 H23C H 0.840741 -0.061622 0.280520 0.058 Uiso 1 1 calc GR . . . .
 C24 C 0.7064(8) 0.2211(7) 0.0121(6) 0.0355(14) Uani 1 1 d . . . . .
 H24B H 0.706049 0.156553 -0.057205 0.053 Uiso 1 1 calc GR . . . .
 H24A H 0.801174 0.278068 -0.003991 0.053 Uiso 1 1 calc GR . . . .
 H24C H 0.613386 0.294195 0.001162 0.053 Uiso 1 1 calc GR . . . .


_geom_special_details
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;
loop_
  _geom_bond_atom_site_label_1
  _geom_bond_atom_site_label_2
  _geom_bond_distance
  _geom_bond_site_symmetry_2
  _geom_bond_publ_flag
 Co1 Cl1 2.2097(15) . ?
 Co1 Cl2 2.2428(15) . ?
 Co1 N1 2.022(5) . ?
 Co1 N2 2.087(5) . ?
 O1 C7 1.326(7) . ?
 O1 C8 1.476(8) . ?
 N1 C7 1.277(7) . ?
 N1 C9 1.497(7) . ?
 N2 C2 1.352(8) . ?
 N2 C6 1.353(8) . ?
 C1 H1A 0.9800 . ?
 C1 H1B 0.9800 . ?
 C1 H1C 0.9800 . ?
 C1 C2 1.501(8) . ?
 C2 C3 1.398(8) . ?
 C3 H3 0.9500 . ?
 C3 C4 1.369(9) . ?
 C4 H4 0.9500 . ?
 C4 C5 1.391(9) . ?
 C5 H5 0.9500 . ?
 C5 C6 1.358(8) . ?
 C6 C7 1.484(8) . ?
 C8 H8A 0.9900 . ?
 C8 H8B 0.9900 . ?
 C8 C9 1.530(9) . ?
 C9 H9 1.0000 . ?
 C9 C10 1.519(8) . ?
 C10 H10 1.0000 . ?
 C10 C11 1.519(8) . ?
 C10 C12 1.512(9) . ?
 C11 H11A 0.9800 . ?
 C11 H11B 0.9800 . ?
 C11 H11C 0.9800 . ?
 C12 H12A 0.9800 . ?
 C12 H12B 0.9800 . ?
 C12 H12C 0.9800 . ?
 Co2 Cl3 2.2423(15) . ?
 Co2 Cl4 2.2157(16) . ?
 Co2 N3 2.019(5) . ?
 Co2 N4 2.095(5) . ?
 O2 C19 1.316(7) . ?
 O2 C20 1.472(7) . ?
 N3 C19 1.284(7) . ?
 N3 C21 1.475(6) . ?
 N4 C14 1.325(8) . ?
 N4 C18 1.361(7) . ?
 C13 H13A 0.9800 . ?
 C13 H13B 0.9800 . ?
 C13 H13C 0.9800 . ?
 C13 C14 1.496(9) . ?
 C14 C15 1.408(9) . ?
 C15 H15 0.9500 . ?
 C15 C16 1.381(9) . ?
 C16 H16 0.9500 . ?
 C16 C17 1.384(9) . ?
 C17 H17 0.9500 . ?
 C17 C18 1.390(8) . ?
 C18 C19 1.461(8) . ?
 C20 H20A 0.9900 . ?
 C20 H20B 0.9900 . ?
 C20 C21 1.550(8) . ?
 C21 H21 1.0000 . ?
 C21 C22 1.524(8) . ?
 C22 H22 1.0000 . ?
 C22 C23 1.523(9) . ?
 C22 C24 1.525(7) . ?
 C23 H23A 0.9800 . ?
 C23 H23B 0.9800 . ?
 C23 H23C 0.9800 . ?
 C24 H24B 0.9800 . ?
 C24 H24A 0.9800 . ?
 C24 H24C 0.9800 . ?

loop_
  _geom_angle_atom_site_label_1
  _geom_angle_atom_site_label_2
  _geom_angle_atom_site_label_3
  _geom_angle
  _geom_angle_site_symmetry_1
  _geom_angle_site_symmetry_3
  _geom_angle_publ_flag
 Cl1 Co1 Cl2 116.50(6) . . ?
 N1 Co1 Cl1 115.75(15) . . ?
 N1 Co1 Cl2 116.43(15) . . ?
 N1 Co1 N2 81.53(19) . . ?
 N2 Co1 Cl1 115.78(14) . . ?
 N2 Co1 Cl2 105.30(15) . . ?
 C7 O1 C8 105.0(4) . . ?
 C7 N1 Co1 110.9(4) . . ?
 C7 N1 C9 106.9(5) . . ?
 C9 N1 Co1 142.1(4) . . ?
 C2 N2 Co1 129.8(4) . . ?
 C6 N2 Co1 112.2(4) . . ?
 C6 N2 C2 117.9(5) . . ?
 H1A C1 H1B 109.5 . . ?
 H1A C1 H1C 109.5 . . ?
 H1B C1 H1C 109.5 . . ?
 C2 C1 H1A 109.5 . . ?
 C2 C1 H1B 109.5 . . ?
 C2 C1 H1C 109.5 . . ?
 N2 C2 C1 116.7(5) . . ?
 N2 C2 C3 120.4(5) . . ?
 C3 C2 C1 122.9(5) . . ?
 C2 C3 H3 120.0 . . ?
 C4 C3 C2 120.0(6) . . ?
 C4 C3 H3 120.0 . . ?
 C3 C4 H4 120.1 . . ?
 C3 C4 C5 119.8(5) . . ?
 C5 C4 H4 120.1 . . ?
 C4 C5 H5 121.4 . . ?
 C6 C5 C4 117.2(6) . . ?
 C6 C5 H5 121.4 . . ?
 N2 C6 C5 124.7(5) . . ?
 N2 C6 C7 111.8(5) . . ?
 C5 C6 C7 123.5(5) . . ?
 O1 C7 C6 118.9(5) . . ?
 N1 C7 O1 118.6(5) . . ?
 N1 C7 C6 122.5(5) . . ?
 O1 C8 H8A 110.9 . . ?
 O1 C8 H8B 110.9 . . ?
 O1 C8 C9 104.1(5) . . ?
 H8A C8 H8B 109.0 . . ?
 C9 C8 H8A 110.9 . . ?
 C9 C8 H8B 110.9 . . ?
 N1 C9 C8 101.4(4) . . ?
 N1 C9 H9 108.3 . . ?
 N1 C9 C10 114.9(4) . . ?
 C8 C9 H9 108.3 . . ?
 C10 C9 C8 115.3(5) . . ?
 C10 C9 H9 108.3 . . ?
 C9 C10 H10 108.5 . . ?
 C11 C10 C9 110.6(5) . . ?
 C11 C10 H10 108.5 . . ?
 C12 C10 C9 109.7(5) . . ?
 C12 C10 H10 108.5 . . ?
 C12 C10 C11 111.0(6) . . ?
 C10 C11 H11A 109.5 . . ?
 C10 C11 H11B 109.5 . . ?
 C10 C11 H11C 109.5 . . ?
 H11A C11 H11B 109.5 . . ?
 H11A C11 H11C 109.5 . . ?
 H11B C11 H11C 109.5 . . ?
 C10 C12 H12A 109.5 . . ?
 C10 C12 H12B 109.5 . . ?
 C10 C12 H12C 109.5 . . ?
 H12A C12 H12B 109.5 . . ?
 H12A C12 H12C 109.5 . . ?
 H12B C12 H12C 109.5 . . ?
 Cl4 Co2 Cl3 116.69(6) . . ?
 N3 Co2 Cl3 111.78(15) . . ?
 N3 Co2 Cl4 118.55(15) . . ?
 N3 Co2 N4 81.40(19) . . ?
 N4 Co2 Cl3 110.92(14) . . ?
 N4 Co2 Cl4 112.18(14) . . ?
 C19 O2 C20 105.5(4) . . ?
 C19 N3 Co2 112.2(4) . . ?
 C19 N3 C21 107.6(5) . . ?
 C21 N3 Co2 139.5(4) . . ?
 C14 N4 Co2 129.4(4) . . ?
 C14 N4 C18 119.4(5) . . ?
 C18 N4 Co2 111.2(4) . . ?
 H13A C13 H13B 109.5 . . ?
 H13A C13 H13C 109.5 . . ?
 H13B C13 H13C 109.5 . . ?
 C14 C13 H13A 109.5 . . ?
 C14 C13 H13B 109.5 . . ?
 C14 C13 H13C 109.5 . . ?
 N4 C14 C13 117.2(5) . . ?
 N4 C14 C15 121.2(5) . . ?
 C15 C14 C13 121.5(5) . . ?
 C14 C15 H15 120.5 . . ?
 C16 C15 C14 119.0(5) . . ?
 C16 C15 H15 120.5 . . ?
 C15 C16 H16 120.0 . . ?
 C15 C16 C17 120.1(5) . . ?
 C17 C16 H16 120.0 . . ?
 C16 C17 H17 121.1 . . ?
 C16 C17 C18 117.8(6) . . ?
 C18 C17 H17 121.1 . . ?
 N4 C18 C17 122.4(5) . . ?
 N4 C18 C19 113.6(5) . . ?
 C17 C18 C19 123.8(5) . . ?
 O2 C19 C18 119.8(5) . . ?
 N3 C19 O2 118.4(5) . . ?
 N3 C19 C18 121.6(5) . . ?
 O2 C20 H20A 111.1 . . ?
 O2 C20 H20B 111.1 . . ?
 O2 C20 C21 103.2(4) . . ?
 H20A C20 H20B 109.1 . . ?
 C21 C20 H20A 111.1 . . ?
 C21 C20 H20B 111.1 . . ?
 N3 C21 C20 101.8(4) . . ?
 N3 C21 H21 108.4 . . ?
 N3 C21 C22 113.8(4) . . ?
 C20 C21 H21 108.4 . . ?
 C22 C21 C20 115.5(5) . . ?
 C22 C21 H21 108.4 . . ?
 C21 C22 H22 107.3 . . ?
 C21 C22 C23 109.4(5) . . ?
 C21 C22 C24 113.9(5) . . ?
 C23 C22 H22 107.3 . . ?
 C24 C22 H22 107.3 . . ?
 C24 C22 C23 111.5(5) . . ?
 C22 C23 H23A 109.5 . . ?
 C22 C23 H23B 109.5 . . ?
 C22 C23 H23C 109.5 . . ?
 H23A C23 H23B 109.5 . . ?
 H23A C23 H23C 109.5 . . ?
 H23B C23 H23C 109.5 . . ?
 C22 C24 H24B 109.5 . . ?
 C22 C24 H24A 109.5 . . ?
 C22 C24 H24C 109.5 . . ?
 H24B C24 H24A 109.5 . . ?
 H24B C24 H24C 109.5 . . ?
 H24A C24 H24C 109.5 . . ?

_olex2_submission_special_instructions  'No special instructions were received'
