data_5a
_audit_creation_date              2017-10-23
_audit_creation_method
;
Olex2 1.2
(compiled 2017.08.10 svn.r3458 for OlexSys, GUI svn.r5381)
;
_publ_contact_author_address      ?
_publ_contact_author_email        ?
_publ_contact_author_id_orcid     ?
_publ_contact_author_name         ''
_publ_contact_author_phone        ?
_publ_section_references
;
Dolomanov, O.V., Bourhis, L.J., Gildea, R.J, Howard, J.A.K. & Puschmann, H.
 (2009), J. Appl. Cryst. 42, 339-341.

Palatinus, L. & Chapuis, G. (2007). J. Appl. Cryst., 40, 786-790;
Palatinus, L. & van der Lee, A. (2008). J. Appl. Cryst. 41, 975-984;
Palatinus, L., Prathapa, S. J. & van Smaalen, S. (2012). J. Appl. Cryst. 45,
 575-580.

Sheldrick, G.M. (2008). Acta Cryst. A64, 112-122.
;
_chemical_name_common             ?
_chemical_name_systematic
;
 ? 
;
_chemical_formula_moiety          'C25 H55 Cr2 I4 O8 Si2, C3 H7'
_chemical_formula_sum             'C28 H62 Cr2 I4 O8 Si2'
_chemical_formula_weight          1194.56
_chemical_melting_point           ?
loop_
  _atom_type_symbol
  _atom_type_description
  _atom_type_scat_dispersion_real
  _atom_type_scat_dispersion_imag
  _atom_type_scat_source
 'C' 'C' 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
 'H' 'H' 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
 'Cr' 'Cr' 0.3209 0.6236 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
 'I' 'I' -0.4742 1.8119 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
 'O' 'O' 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
 'Si' 'Si' 0.0817 0.0704 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_space_group_crystal_system       'triclinic'
_space_group_IT_number            2
_space_group_name_H-M_alt         'P -1'
_space_group_name_Hall            '-P 1'
loop_
  _space_group_symop_id
  _space_group_symop_operation_xyz
 1 'x, y, z'
 2 '-x, -y, -z'

_cell_length_a                    10.0937(14)
_cell_length_b                    11.5433(16)
_cell_length_c                    21.451(3)
_cell_angle_alpha                 79.581(3)
_cell_angle_beta                  89.987(3)
_cell_angle_gamma                 66.108(3)
_cell_volume                      2240.1(5)
_cell_formula_units_Z             2
_cell_measurement_reflns_used     9926
_cell_measurement_temperature     99.95
_cell_measurement_theta_max       25.91
_cell_measurement_theta_min       2.214
_exptl_absorpt_coefficient_mu     3.332
_exptl_absorpt_correction_T_max   0.7453
_exptl_absorpt_correction_T_min   0.6609
_exptl_absorpt_correction_type    multi-scan
_exptl_absorpt_process_details
'SADABS-2016/2 (Bruker,2016/2) was used for absorption correction. wR2(int) was 0.0971 before and 0.0551 after correction. The Ratio of minimum to maximum transmission is 0.8868. The λ/2 correction factor is Not present.'
_exptl_crystal_colour             'clear yellowish red'
_exptl_crystal_colour_lustre      clear
_exptl_crystal_colour_modifier    yellowish
_exptl_crystal_colour_primary     red
_exptl_crystal_density_diffrn     1.771
_exptl_crystal_density_meas       ?
_exptl_crystal_density_method     'not measured'
_exptl_crystal_description        block
_exptl_crystal_F_000              1164
_exptl_crystal_size_max           0.2
_exptl_crystal_size_mid           0.1
_exptl_crystal_size_min           0.1
_exptl_special_details
;
 ? 
;
_diffrn_reflns_av_R_equivalents   0.0453
_diffrn_reflns_av_unetI/netI      0.0407
_diffrn_reflns_limit_h_max        12
_diffrn_reflns_limit_h_min        -12
_diffrn_reflns_limit_k_max        14
_diffrn_reflns_limit_k_min        -14
_diffrn_reflns_limit_l_max        26
_diffrn_reflns_limit_l_min        -26
_diffrn_reflns_number             36768
_diffrn_reflns_theta_full         26.00
_diffrn_reflns_theta_max          26.00
_diffrn_reflns_theta_min          1.94
_diffrn_ambient_temperature       99.95
_diffrn_detector_area_resol_mean  ?
_diffrn_measured_fraction_theta_full 0.984
_diffrn_measured_fraction_theta_max 0.984
_diffrn_measurement_device_type   'Bruker APEX-II CCD'
_diffrn_measurement_method        'φ and ω scans'
_diffrn_radiation_monochromator   graphite
_diffrn_radiation_type            MoK\a
_diffrn_radiation_wavelength      0.71073
_diffrn_source                    'fine-focus sealed tube'
_diffrn_standards_number          0
_reflns_number_gt                 7200
_reflns_number_total              8677
_reflns_threshold_expression      >2sigma(I)
_computing_cell_refinement        'SAINT v8.37A (Bruker, 2015)'
_computing_data_collection        ?
_computing_data_reduction         'SAINT v8.37A (Bruker, 2015)'
_computing_molecular_graphics     'Olex2 (Dolomanov et al., 2009)'
_computing_publication_material   'Olex2 (Dolomanov et al., 2009)'
_computing_structure_refinement   'XL (Sheldrick, 2008)'
_computing_structure_solution
;
Superflip (Palatinus & Chapuis, 2007;Palatinus & van der Lee, 2008;
Palatinus et al., 2012)
;
_refine_diff_density_max          3.707
_refine_diff_density_min          -2.161
_refine_diff_density_rms          0.270
_refine_ls_extinction_coef        ?
_refine_ls_extinction_method      none
_refine_ls_goodness_of_fit_ref    1.069
_refine_ls_hydrogen_treatment     constr
_refine_ls_matrix_type            full
_refine_ls_number_parameters      425
_refine_ls_number_reflns          8677
_refine_ls_number_restraints      0
_refine_ls_R_factor_all           0.0784
_refine_ls_R_factor_gt            0.0654
_refine_ls_restrained_S_all       1.069
_refine_ls_shift/su_max           0.000
_refine_ls_shift/su_mean          0.000
_refine_ls_structure_factor_coef  Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.1154P)²+22.5890P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme       calc
_refine_ls_wR_factor_gt           0.1821
_refine_ls_wR_factor_ref          0.1941
_refine_special_details
'Disordered n-hexane in lattice, modelled with PART refinement. Crystal twinning left large Q peaks.'
_olex2_refinement_description
;
1. Fixed Uiso
 At 1.2 times of:
  All C(H) groups, All C(H,H) groups, All C(H,H,H,H) groups
 At 1.5 times of:
  All C(H,H,H) groups, All C(H,H,H,H,H,H) groups
2. Others
 Sof(H4AC)=Sof(H4AD)=Sof(C5AB)=Sof(H5AC)=Sof(H5AD)=Sof(H6AD)=Sof(H6AE)=
 Sof(H6AF)=1-FVAR(1)
 Sof(H4AA)=Sof(H4AB)=Sof(C5AA)=Sof(H5AA)=Sof(H5AB)=Sof(H6AA)=Sof(H6AB)=
 Sof(H6AC)=FVAR(1)
3.a Ternary CH refined with riding coordinates:
 C1(H1)
3.b Secondary CH2 refined with riding coordinates:
 C4AA(H4AA,H4AB), C4AA(H4AC,H4AD), C5AA(H5AA,H5AB), C5AB(H5AC,H5AD)
3.c Me refined with riding coordinates:
 C6AA(H6AA,H6AB,H6AC), C6AA(H6AD,H6AE,H6AF)
3.d Idealised Me refined as rotating group:
 C3(H3A,H3B,H3C), C4(H4A,H4B,H4C), C5(H5A,H5B,H5C), C7(H7A,H7B,H7C), C8(H8A,
 H8B,H8C), C9(H9A,H9B,H9C), C11(H11A,H11B,H11C), C12(H12A,H12B,H12C), C13(H13A,
 H13B,H13C), C15(H15A,H15B,H15C), C16(H16A,H16B,H16C), C17(H17A,H17B,H17C),
 C19(H19A,H19B,H19C), C20(H20A,H20B,H20C), C21(H21A,H21B,H21C), C23(H23A,H23B,
 H23C), C24(H24A,H24B,H24C), C25(H25A,H25B,H25C)
;
_atom_sites_solution_hydrogens    geom
_atom_sites_solution_primary      iterative
_atom_sites_solution_secondary    difmap
loop_
  _atom_site_label
  _atom_site_type_symbol
  _atom_site_fract_x
  _atom_site_fract_y
  _atom_site_fract_z
  _atom_site_U_iso_or_equiv
  _atom_site_adp_type
  _atom_site_occupancy
  _atom_site_calc_flag
  _atom_site_disorder_assembly
  _atom_site_disorder_group
  _atom_site_refinement_flags_posn
 I1 I -0.11548(6) 0.18330(5) 0.33763(3) 0.02205(17) Uani 1 d . . .
 I2 I 0.52449(7) -0.18082(6) 0.14413(3) 0.03270(19) Uani 1 d . . .
 I3 I 0.07961(10) -0.11920(7) 0.08956(4) 0.0482(2) Uani 1 d . . .
 I4 I 0.05059(7) -0.16789(6) 0.25488(3) 0.03186(19) Uani 1 d . . .
 Cr1 Cr 0.13565(13) 0.03852(12) 0.29731(6) 0.0131(3) Uani 1 d . . .
 Cr2 Cr 0.27446(14) -0.02451(13) 0.17841(6) 0.0181(3) Uani 1 d . . .
 Si1 Si 0.4127(2) -0.1602(2) 0.33473(10) 0.0125(4) Uani 1 d . . .
 Si2 Si 0.0616(2) 0.2276(2) 0.14222(11) 0.0164(4) Uani 1 d . . .
 O1 O 0.3311(6) -0.0679(5) 0.2677(3) 0.0146(11) Uani 1 d . . .
 O2 O 0.2774(5) -0.0818(5) 0.3776(2) 0.0114(10) Uani 1 d . . .
 O3 O 0.5633(6) -0.1580(6) 0.3542(3) 0.0179(12) Uani 1 d . . .
 O4 O 0.4284(6) -0.3056(5) 0.3444(3) 0.0208(12) Uani 1 d . . .
 O5 O 0.1010(6) 0.1142(5) 0.2045(3) 0.0192(12) Uani 1 d . . .
 O6 O 0.2032(6) 0.1418(6) 0.1048(3) 0.0190(12) Uani 1 d . . .
 O7 O -0.0828(6) 0.2559(6) 0.0993(3) 0.0250(13) Uani 1 d . . .
 O8 O 0.0616(7) 0.3613(6) 0.1512(3) 0.0263(14) Uani 1 d . . .
 C1 C 0.1881(11) -0.1582(9) 0.1795(5) 0.031(2) Uani 1 d . . .
 H1 H 0.2712 -0.2451 0.1846 0.037 Uiso 1 calc . . R
 C2 C 0.2619(8) -0.1188(8) 0.4462(4) 0.0172(16) Uani 1 d . . .
 C3 C 0.1599(10) -0.1878(10) 0.4508(5) 0.028(2) Uani 1 d . . .
 H3A H 0.0623 -0.1262 0.4326 0.042 Uiso 1 calc . . GR
 H3B H 0.1558 -0.2230 0.4955 0.042 Uiso 1 calc . . GR
 H3C H 0.1963 -0.2583 0.4272 0.042 Uiso 1 calc . . GR
 C4 C 0.1973(10) 0.0060(9) 0.4709(4) 0.028(2) Uani 1 d . . .
 H4A H 0.2678 0.0448 0.4694 0.042 Uiso 1 calc . . GR
 H4B H 0.1738 -0.0122 0.5149 0.042 Uiso 1 calc . . GR
 H4C H 0.1086 0.0662 0.4445 0.042 Uiso 1 calc . . GR
 C5 C 0.4104(9) -0.2055(9) 0.4811(4) 0.0257(19) Uani 1 d . . .
 H5A H 0.4532 -0.2846 0.4639 0.039 Uiso 1 calc . . GR
 H5B H 0.3992 -0.2279 0.5265 0.039 Uiso 1 calc . . GR
 H5C H 0.4742 -0.1598 0.4754 0.039 Uiso 1 calc . . GR
 C6 C 0.6269(9) -0.0640(9) 0.3458(4) 0.0238(18) Uani 1 d . . .
 C7 C 0.5373(11) 0.0482(9) 0.3755(5) 0.032(2) Uani 1 d . . .
 H7A H 0.4378 0.0885 0.3553 0.048 Uiso 1 calc . . GR
 H7B H 0.5799 0.1117 0.3696 0.048 Uiso 1 calc . . GR
 H7C H 0.5356 0.0175 0.4211 0.048 Uiso 1 calc . . GR
 C8 C 0.6349(10) -0.0195(10) 0.2761(4) 0.028(2) Uani 1 d . . .
 H8A H 0.6939 -0.0940 0.2576 0.043 Uiso 1 calc . . GR
 H8B H 0.6793 0.0427 0.2706 0.043 Uiso 1 calc . . GR
 H8C H 0.5367 0.0217 0.2546 0.043 Uiso 1 calc . . GR
 C9 C 0.7788(10) -0.1370(10) 0.3789(5) 0.030(2) Uani 1 d . . .
 H9A H 0.7732 -0.1803 0.4219 0.045 Uiso 1 calc . . GR
 H9B H 0.8229 -0.0762 0.3814 0.045 Uiso 1 calc . . GR
 H9C H 0.8383 -0.2016 0.3548 0.045 Uiso 1 calc . . GR
 C10 C 0.5389(10) -0.4317(8) 0.3393(5) 0.0247(19) Uani 1 d . . .
 C11 C 0.4787(12) -0.4779(11) 0.2891(6) 0.047(3) Uani 1 d . . .
 H11A H 0.3860 -0.4801 0.3012 0.070 Uiso 1 calc . . GR
 H11B H 0.5478 -0.5649 0.2856 0.070 Uiso 1 calc . . GR
 H11C H 0.4633 -0.4187 0.2482 0.070 Uiso 1 calc . . GR
 C12 C 0.6789(11) -0.4238(10) 0.3191(6) 0.043(3) Uani 1 d . . .
 H12A H 0.6607 -0.3665 0.2773 0.064 Uiso 1 calc . . GR
 H12B H 0.7510 -0.5103 0.3165 0.064 Uiso 1 calc . . GR
 H12C H 0.7159 -0.3896 0.3503 0.064 Uiso 1 calc . . GR
 C13 C 0.5628(15) -0.5176(11) 0.4029(6) 0.054(4) Uani 1 d . . .
 H13A H 0.6169 -0.4939 0.4324 0.080 Uiso 1 calc . . GR
 H13B H 0.6186 -0.6077 0.3991 0.080 Uiso 1 calc . . GR
 H13C H 0.4687 -0.5079 0.4189 0.080 Uiso 1 calc . . GR
 C14 C 0.2519(10) 0.1826(10) 0.0411(4) 0.027(2) Uani 1 d . . .
 C15 C 0.3935(11) 0.1924(11) 0.0553(5) 0.035(2) Uani 1 d . . .
 H15A H 0.3739 0.2680 0.0745 0.053 Uiso 1 calc . . GR
 H15B H 0.4400 0.2014 0.0157 0.053 Uiso 1 calc . . GR
 H15C H 0.4581 0.1141 0.0849 0.053 Uiso 1 calc . . GR
 C16 C 0.2723(12) 0.0779(11) 0.0043(4) 0.036(2) Uani 1 d . . .
 H16A H 0.3450 -0.0046 0.0278 0.053 Uiso 1 calc . . GR
 H16B H 0.3054 0.0994 -0.0374 0.053 Uiso 1 calc . . GR
 H16C H 0.1797 0.0709 -0.0014 0.053 Uiso 1 calc . . GR
 C17 C 0.1384(11) 0.3111(11) 0.0074(5) 0.037(2) Uani 1 d . . .
 H17A H 0.0462 0.3038 0.0012 0.056 Uiso 1 calc . . GR
 H17B H 0.1701 0.3368 -0.0340 0.056 Uiso 1 calc . . GR
 H17C H 0.1253 0.3765 0.0332 0.056 Uiso 1 calc . . GR
 C18 C 0.1338(11) 0.4083(9) 0.1917(5) 0.029(2) Uani 1 d . . .
 C19 C 0.1733(15) 0.5073(13) 0.1487(6) 0.049(3) Uani 1 d . . .
 H19A H 0.2497 0.4635 0.1222 0.074 Uiso 1 calc . . GR
 H19B H 0.2084 0.5523 0.1747 0.074 Uiso 1 calc . . GR
 H19C H 0.0872 0.5701 0.1214 0.074 Uiso 1 calc . . GR
 C20 C 0.0313(12) 0.4676(10) 0.2403(5) 0.036(2) Uani 1 d . . .
 H20A H -0.0667 0.5191 0.2194 0.054 Uiso 1 calc . . GR
 H20B H 0.0653 0.5232 0.2588 0.054 Uiso 1 calc . . GR
 H20C H 0.0292 0.3987 0.2739 0.054 Uiso 1 calc . . GR
 C21 C 0.2704(12) 0.2993(10) 0.2266(5) 0.037(2) Uani 1 d . . .
 H21A H 0.2437 0.2396 0.2570 0.055 Uiso 1 calc . . GR
 H21B H 0.3242 0.3350 0.2494 0.055 Uiso 1 calc . . GR
 H21C H 0.3314 0.2528 0.1959 0.055 Uiso 1 calc . . GR
 C22 C -0.2367(10) 0.3104(9) 0.1067(5) 0.029(2) Uani 1 d . . .
 C23 C -0.3105(13) 0.3610(18) 0.0406(6) 0.068(5) Uani 1 d . . .
 H23A H -0.2791 0.4261 0.0182 0.101 Uiso 1 calc . . GR
 H23B H -0.4161 0.4002 0.0429 0.101 Uiso 1 calc . . GR
 H23C H -0.2845 0.2896 0.0177 0.101 Uiso 1 calc . . GR
 C24 C -0.2747(13) 0.4183(14) 0.1439(7) 0.058(4) Uani 1 d . . .
 H24A H -0.2313 0.3820 0.1877 0.087 Uiso 1 calc . . GR
 H24B H -0.3806 0.4620 0.1440 0.087 Uiso 1 calc . . GR
 H24C H -0.2368 0.4807 0.1238 0.087 Uiso 1 calc . . GR
 C25 C -0.2734(13) 0.2047(14) 0.1446(7) 0.056(4) Uani 1 d . . .
 H25A H -0.2459 0.1325 0.1222 0.084 Uiso 1 calc . . GR
 H25B H -0.3781 0.2387 0.1494 0.084 Uiso 1 calc . . GR
 H25C H -0.2201 0.1744 0.1867 0.084 Uiso 1 calc . . GR
 C4AA C 0.0607(16) 0.4703(16) 0.4833(7) 0.067(4) Uani 1 d . . .
 H4AA H 0.1424 0.4193 0.5161 0.080 Uiso 0.66(4) calc A 1 R
 H4AB H 0.0833 0.5413 0.4598 0.080 Uiso 0.66(4) calc A 1 R
 H4AC H 0.1375 0.4710 0.5117 0.080 Uiso 0.34(4) calc A 2 R
 H4AD H 0.0696 0.3802 0.4943 0.080 Uiso 0.34(4) calc A 2 R
 C5AA C 0.071(2) 0.3886(18) 0.4395(8) 0.046(6) Uani 0.66(4) d A 1 .
 H5AA H -0.0106 0.4361 0.4062 0.055 Uiso 0.66(4) calc A 1 R
 H5AB H 0.0562 0.3126 0.4624 0.055 Uiso 0.66(4) calc A 1 R
 C5AB C 0.126(6) 0.464(5) 0.431(2) 0.067(15) Uani 0.34(4) d A 2 .
 H5AC H 0.1941 0.5051 0.4344 0.080 Uiso 0.34(4) calc A 2 R
 H5AD H 0.0505 0.5216 0.3968 0.080 Uiso 0.34(4) calc A 2 R
 C6AA C 0.2106(16) 0.3403(14) 0.4072(7) 0.061(4) Uani 1 d . . .
 H6AA H 0.1887 0.3644 0.3610 0.092 Uiso 0.66(4) calc A 1 R
 H6AB H 0.2598 0.2460 0.4199 0.092 Uiso 0.66(4) calc A 1 R
 H6AC H 0.2740 0.3792 0.4199 0.092 Uiso 0.66(4) calc A 1 R
 H6AD H 0.2021 0.3589 0.3606 0.092 Uiso 0.34(4) calc A 2 R
 H6AE H 0.1712 0.2765 0.4228 0.092 Uiso 0.34(4) calc A 2 R
 H6AF H 0.3132 0.3058 0.4228 0.092 Uiso 0.34(4) calc A 2 R


_geom_special_details
;
 All esds (except the esd in the dihedral angle between two l.s. planes) 
 are estimated using the full covariance matrix.  The cell esds are taken 
 into account individually in the estimation of esds in distances, angles 
 and torsion angles; correlations between esds in cell parameters are only 
 used when they are defined by crystal symmetry.  An approximate (isotropic) 
 treatment of cell esds is used for estimating esds involving l.s. planes. 
;
loop_
  _geom_bond_atom_site_label_1
  _geom_bond_atom_site_label_2
  _geom_bond_distance
  _geom_bond_site_symmetry_2
  _geom_bond_publ_flag
 I1 Cr1 2.6565(13) . ?
 I2 Cr2 2.6374(14) . ?
 I3 C1 2.100(10) . ?
 I4 C1 2.148(10) . ?
 Cr1 Cr2 2.9735(18) . ?
 Cr1 Si1 2.805(2) . ?
 Cr1 O1 2.031(5) . ?
 Cr1 O2 2.114(5) . ?
 Cr1 O5 1.992(6) . ?
 Cr2 Si2 2.794(3) . ?
 Cr2 O1 1.915(6) . ?
 Cr2 O5 1.999(5) . ?
 Cr2 O6 2.116(6) . ?
 Cr2 C1 2.054(10) . ?
 Si1 O1 1.618(6) . ?
 Si1 O2 1.682(5) . ?
 Si1 O3 1.588(6) . ?
 Si1 O4 1.595(6) . ?
 Si2 O5 1.614(6) . ?
 Si2 O6 1.675(6) . ?
 Si2 O7 1.608(6) . ?
 Si2 O8 1.590(6) . ?
 O2 C2 1.482(9) . ?
 O3 C6 1.454(10) . ?
 O4 C10 1.455(9) . ?
 O6 C14 1.513(10) . ?
 O7 C22 1.442(11) . ?
 O8 C18 1.440(11) . ?
 C2 C3 1.530(12) . ?
 C2 C4 1.516(12) . ?
 C2 C5 1.525(11) . ?
 C6 C7 1.500(13) . ?
 C6 C8 1.503(13) . ?
 C6 C9 1.518(12) . ?
 C10 C11 1.510(15) . ?
 C10 C12 1.511(14) . ?
 C10 C13 1.489(14) . ?
 C14 C15 1.513(13) . ?
 C14 C16 1.507(14) . ?
 C14 C17 1.507(13) . ?
 C18 C19 1.518(15) . ?
 C18 C20 1.519(14) . ?
 C18 C21 1.516(14) . ?
 C22 C23 1.502(15) . ?
 C22 C24 1.519(16) . ?
 C22 C25 1.515(16) . ?
 C4AA C4AA 1.41(3) 2_566 ?
 C4AA C5AA 1.42(2) . ?
 C4AA C5AB 1.29(4) . ?
 C5AA C6AA 1.51(2) . ?
 C5AB C6AA 1.52(5) . ?

loop_
  _geom_angle_atom_site_label_1
  _geom_angle_atom_site_label_2
  _geom_angle_atom_site_label_3
  _geom_angle
  _geom_angle_site_symmetry_1
  _geom_angle_site_symmetry_3
  _geom_angle_publ_flag
 I1 Cr1 Cr2 141.26(6) . . ?
 I1 Cr1 Si1 144.91(7) . . ?
 Si1 Cr1 Cr2 73.52(6) . . ?
 O1 Cr1 I1 177.77(17) . . ?
 O1 Cr1 Cr2 39.65(16) . . ?
 O1 Cr1 Si1 34.63(16) . . ?
 O1 Cr1 O2 71.1(2) . . ?
 O2 Cr1 I1 108.28(14) . . ?
 O2 Cr1 Cr2 110.23(14) . . ?
 O2 Cr1 Si1 36.71(14) . . ?
 O5 Cr1 I1 100.58(16) . . ?
 O5 Cr1 Cr2 41.94(16) . . ?
 O5 Cr1 Si1 114.47(17) . . ?
 O5 Cr1 O1 79.8(2) . . ?
 O5 Cr1 O2 150.5(2) . . ?
 I2 Cr2 Cr1 138.62(6) . . ?
 I2 Cr2 Si2 140.56(7) . . ?
 Si2 Cr2 Cr1 75.34(6) . . ?
 O1 Cr2 I2 96.24(16) . . ?
 O1 Cr2 Cr1 42.58(16) . . ?
 O1 Cr2 Si2 111.78(17) . . ?
 O1 Cr2 O5 82.5(2) . . ?
 O1 Cr2 O6 137.7(2) . . ?
 O1 Cr2 C1 95.8(3) . . ?
 O5 Cr2 I2 170.40(19) . . ?
 O5 Cr2 Cr1 41.75(17) . . ?
 O5 Cr2 Si2 34.57(17) . . ?
 O5 Cr2 O6 71.3(2) . . ?
 O5 Cr2 C1 97.7(3) . . ?
 O6 Cr2 I2 104.23(16) . . ?
 O6 Cr2 Cr1 110.90(16) . . ?
 O6 Cr2 Si2 36.73(16) . . ?
 C1 Cr2 I2 91.8(3) . . ?
 C1 Cr2 Cr1 89.4(3) . . ?
 C1 Cr2 Si2 111.4(3) . . ?
 C1 Cr2 O6 119.6(3) . . ?
 O1 Si1 Cr1 45.51(19) . . ?
 O1 Si1 O2 93.9(3) . . ?
 O2 Si1 Cr1 48.71(18) . . ?
 O3 Si1 Cr1 131.9(2) . . ?
 O3 Si1 O1 115.4(3) . . ?
 O3 Si1 O2 113.2(3) . . ?
 O3 Si1 O4 110.2(3) . . ?
 O4 Si1 Cr1 117.7(2) . . ?
 O4 Si1 O1 115.5(3) . . ?
 O4 Si1 O2 107.4(3) . . ?
 O5 Si2 Cr2 44.7(2) . . ?
 O5 Si2 O6 93.7(3) . . ?
 O6 Si2 Cr2 49.1(2) . . ?
 O7 Si2 Cr2 120.3(3) . . ?
 O7 Si2 O5 115.5(3) . . ?
 O7 Si2 O6 106.8(3) . . ?
 O8 Si2 Cr2 130.5(3) . . ?
 O8 Si2 O5 117.6(3) . . ?
 O8 Si2 O6 113.2(3) . . ?
 O8 Si2 O7 108.9(3) . . ?
 Cr2 O1 Cr1 97.8(2) . . ?
 Si1 O1 Cr1 99.9(3) . . ?
 Si1 O1 Cr2 156.7(3) . . ?
 Si1 O2 Cr1 94.6(2) . . ?
 C2 O2 Cr1 135.7(4) . . ?
 C2 O2 Si1 127.8(5) . . ?
 C6 O3 Si1 136.8(5) . . ?
 C10 O4 Si1 138.0(5) . . ?
 Cr1 O5 Cr2 96.3(2) . . ?
 Si2 O5 Cr1 155.9(4) . . ?
 Si2 O5 Cr2 100.7(3) . . ?
 Si2 O6 Cr2 94.2(3) . . ?
 C14 O6 Cr2 137.1(5) . . ?
 C14 O6 Si2 128.7(5) . . ?
 C22 O7 Si2 135.5(6) . . ?
 C18 O8 Si2 138.7(6) . . ?
 I3 C1 I4 111.9(5) . . ?
 Cr2 C1 I3 107.3(4) . . ?
 Cr2 C1 I4 115.1(4) . . ?
 O2 C2 C3 106.8(6) . . ?
 O2 C2 C4 106.3(7) . . ?
 O2 C2 C5 110.1(6) . . ?
 C4 C2 C3 111.9(7) . . ?
 C4 C2 C5 109.8(7) . . ?
 C5 C2 C3 111.7(7) . . ?
 O3 C6 C7 109.6(7) . . ?
 O3 C6 C8 109.7(7) . . ?
 O3 C6 C9 104.8(7) . . ?
 C7 C6 C8 110.7(8) . . ?
 C7 C6 C9 111.7(8) . . ?
 C8 C6 C9 110.2(7) . . ?
 O4 C10 C11 106.5(7) . . ?
 O4 C10 C12 111.7(7) . . ?
 O4 C10 C13 107.0(8) . . ?
 C11 C10 C12 109.0(9) . . ?
 C13 C10 C11 111.7(10) . . ?
 C13 C10 C12 110.8(9) . . ?
 O6 C14 C15 106.0(7) . . ?
 C16 C14 O6 106.3(7) . . ?
 C16 C14 C15 112.1(8) . . ?
 C17 C14 O6 109.8(7) . . ?
 C17 C14 C15 111.0(9) . . ?
 C17 C14 C16 111.4(9) . . ?
 O8 C18 C19 106.5(8) . . ?
 O8 C18 C20 108.9(8) . . ?
 O8 C18 C21 111.0(7) . . ?
 C19 C18 C20 111.8(9) . . ?
 C21 C18 C19 109.8(9) . . ?
 C21 C18 C20 108.8(9) . . ?
 O7 C22 C23 106.0(8) . . ?
 O7 C22 C24 110.0(8) . . ?
 O7 C22 C25 107.8(8) . . ?
 C23 C22 C24 111.0(11) . . ?
 C23 C22 C25 113.6(11) . . ?
 C25 C22 C24 108.3(10) . . ?
 C4AA C4AA C5AA 126(2) 2_566 . ?
 C5AB C4AA C4AA 150(3) . 2_566 ?
 C5AB C4AA C5AA 52(2) . . ?
 C4AA C5AA C6AA 116.8(17) . . ?
 C4AA C5AB C6AA 125(4) . . ?
 C5AA C6AA C5AB 46.5(18) . . ?

_olex2_submission_special_instructions 'No special instructions were received'
