Cine-Substitutions at Five-Membered
Hetarenes Enabled by Sulfonium Salts
Posted on 2020-07-08 - 22:03
We report a nucleophilic
substitution reaction of five-membered
hetarylsulfonium salts that results in a change of the substitution
pattern on the arene. The products of these cine-substitutions
are hard to access synthetically otherwise. The sulfonium salts that
serve as starting materials are generated by a highly site-selective
C–H functionalization reaction.
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Berger, Florian; Alvarez, Eva Maria; Frank, Nils; Bohdan, Kostiantyn; Kondratiuk, Mykhailo; Torkowski, Luca; et al. (2020). Cine-Substitutions at Five-Membered
Hetarenes Enabled by Sulfonium Salts. ACS Publications. Collection. https://doi.org/10.1021/acs.orglett.0c02067
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AUTHORS (9)
FB
Florian Berger
EA
Eva Maria Alvarez
NF
Nils Frank
KB
Kostiantyn Bohdan
MK
Mykhailo Kondratiuk
LT
Luca Torkowski
PE
Pascal S. Engl
JB
Joana Barletta
TR
Tobias Ritter