[3 + 2] Cycloaddition Reaction of in Situ Formed Azaoxyallyl
Cations with Aldehydes: An Approach to Oxazolidin-4-ones
Version 2 2016-09-12, 20:23
Version 1 2016-08-27, 12:13
Posted on 2016-08-29 - 00:00
A novel [3 + 2] cycloaddition reaction
between in situ formed azaoxyallyl
cations and aldehydes has been developed. This concise method allows
the rapid formation of a number of oxazolidin-4-ones in high yields
with good functional group tolerance at room temperature. Further
transformation and late-stage modifications of drug molecules could
also be achieved in good yields, highlighting the potential utility
of the reaction.
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Zhang, Kaifan; Yang, Chi; Yao, Hequan; Lin, Aijun (2016). [3 + 2] Cycloaddition Reaction of in Situ Formed Azaoxyallyl
Cations with Aldehydes: An Approach to Oxazolidin-4-ones. ACS Publications. Collection. https://doi.org/10.1021/acs.orglett.6b02254
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AUTHORS (4)
KZ
Kaifan Zhang
CY
Chi Yang
HY
Hequan Yao
AL
Aijun Lin