Understanding and Interrupting the Fischer Azaindolization
Reaction
Posted on 2017-10-12 - 12:05
Experimental
and computational studies pertaining to the Fischer
azaindolization reaction are reported. These studies explain why pyridylhydrazines
are poorly reactive in Fischer indolization reactions, in addition
to the origin of hydrazine substituent effects. Additionally, an interrupted
variant of Fischer azaindolization methodology is disclosed, which
provides a synthetic entryway into fused azaindoline scaffolds.
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Simmons, Bryan J.; Hoffmann, Marie; Champagne, Pier Alexandre; Picazo, Elias; Yamakawa, Katsuya; Morrill, Lucas A.; et al. (2017). Understanding and Interrupting the Fischer Azaindolization
Reaction. ACS Publications. Collection. https://doi.org/10.1021/jacs.7b07518
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AUTHORS (8)
BS
Bryan J. Simmons
MH
Marie Hoffmann
PC
Pier Alexandre Champagne
EP
Elias Picazo
KY
Katsuya Yamakawa
LM
Lucas A. Morrill
KH
K. N. Houk
NG
Neil K. Garg