Tuning Solvent Quality Induces Morphological Phase
Transitions in Miktoarm Star Polymer Films
Version 2 2020-07-27, 17:19
Version 1 2020-07-24, 13:34
Posted on 2020-07-27 - 17:19
The
ordering and kinetics of self-assembly of miktoarm star polymers
of the form (An)k–C–(Bn)k in solution and confined between two surfaces are
investigated using a coarse-grained molecular dynamics simulation,
with the ultimate goal of developing predictive capabilities for these
systems. By systematically changing the relative solvent-block interaction
for one block, combined with the effect of confining substrate on
one side and vapor on the other side, we observed a number of interesting
morphologies for an inherently lamellar miktoarm star polymers in
the absence of solvent. Furthermore, we also found that in solution
the self-assembly kinetics of miktoarm star polymers into cylindrical
and lamellar morphologies is completely different from the self-assembly
kinetics of linear block copolymers. The findings from the present
study can be used to tailor the film morphology of miktoarm star polymers,
playing a leading role in guiding the experimentalists for designing
this class of materials for different types of applications.
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Workineh, Zerihun G.; Pellicane, Giuseppe; Tsige, Mesfin (2020). Tuning Solvent Quality Induces Morphological Phase
Transitions in Miktoarm Star Polymer Films. ACS Publications. Collection. https://doi.org/10.1021/acs.macromol.0c00770
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AUTHORS (3)
ZW
Zerihun G. Workineh
GP
Giuseppe Pellicane
MT
Mesfin Tsige