Trifluoromethylthiolation-Based Bifunctionalization
of Diazocarbonyl Compounds by Rhodium Catalysis

Szabó, Kálmán J.

Trifluoromethylthiolation-Based Bifunctionalization of Diazocarbonyl Compounds by Rhodium Catalysis

Version 3 2018-08-17, 08:14

Version 2 2017-08-30, 19:50

Version 1 2017-08-16, 21:09

Posted on 2018-08-17 - 08:14

A new Rh-catalyzed, three-component reaction for the oxytrifluoromethylthiolation of α-diazoketones was developed. The SCF₃ functionality was introduced using a stable dibenzenesulfonimide reagent under mild conditions. Alcohols, acetals, and ethers were used as the alkoxy sources. Cyclic ethers underwent a trifunctionalization reaction through the introduction of SCF₃, OR, and N(SO₂Ph)₂ substituents in a single step.

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Lübcke, Marvin; Yuan, Weiming; Szabó, Kálmán J. (2017). Trifluoromethylthiolation-Based Bifunctionalization of Diazocarbonyl Compounds by Rhodium Catalysis. ACS Publications. Collection. https://doi.org/10.1021/acs.orglett.7b02139

https://doi.org/10.1021/acs.orglett.7b02139

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