Triazabicyclodecene: An Effective Isotope
Exchange Catalyst in CDCl3
Posted on 2007-06-22 - 00:00
We describe the first effective H/D exchange reaction with
acidic substrates in CDCl3 at room temperature. The particularly mild reaction conditions involved (solvent, base,
and temperature) allow the chemoselective deuteration of
ketones over esters. An NMR study was conducted with the
aim of rationalizing the results obtained in the presence of
TBD as catalyst.
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Sabot, Cyrille; Kumar, Kanduluru Ananda; Antheaume, Cyril; Mioskowski, Charles (2016). Triazabicyclodecene: An Effective Isotope
Exchange Catalyst in CDCl3. ACS Publications. Collection. https://doi.org/10.1021/jo070307h
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AUTHORS (4)
- CSCyrille SabotKKKanduluru Ananda KumarCACyril AntheaumeCMCharles Mioskowski
