Triaryl-Boron Functionalized Dinuclear Platinum Complexes
Linked by Photoisomerizable Bpe Ligand: Luminescence and Isomerism
Posted on 2017-10-12 - 14:24
We
report herein a series of triarylboron-functionalized Pt(II) dinuclear
complexes using a photoactive bis(4-pyridyl)ethylene (bpe) bridging
unit. The new Pt(II) complexes display phosphorescence at both room
temperature and 77 K. Depending on the conditions under which crystals
of the complexes were grown, either the cis- or trans-isomers could be obtained. The trans and cis isomers were found to undergo light-induced
isomerization in solution with the trans isomer being
the dominant species.
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Wang, Nan; Hu, Mingfeng; Mellerup, Soren K.; Wang, Xiang; Sauriol, Françoise; Peng, Tai; et al. (2017). Triaryl-Boron Functionalized Dinuclear Platinum Complexes
Linked by Photoisomerizable Bpe Ligand: Luminescence and Isomerism. ACS Publications. Collection. https://doi.org/10.1021/acs.inorgchem.7b01535
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AUTHORS (7)
NW
Nan Wang
MH
Mingfeng Hu
SM
Soren K. Mellerup
XW
Xiang Wang
FS
Françoise Sauriol
TP
Tai Peng
SW
Suning Wang