Trapping CS22– and S32– between Two Ytterbium Formamidinates
Posted on 2019-01-19 - 18:29
Treatment
of [YbII(DippForm)2(thf)n] (n = 2 (1aYb), n = 1 (1bYb); DippForm = N,N′-bis(2,6-diisopropylphenyl)formamidinate), with either excess CS2 or S8 gives [YbIII2(DippForm)4(CS2)] (3) and [YbIII2(DippForm)4(S2)0.5/(S3)0.5] (4) respectively. 3 is a new addition to an exclusive class of compounds containing
the CS22− dianion, and 4 is the first crystallographically characterized example of a rare-earth
trisulfide complex.
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Werner, Daniel; Deacon, Glen B.; Junk, Peter C. (2019). Trapping CS22– and S32– between Two Ytterbium Formamidinates. ACS Publications. Collection. https://doi.org/10.1021/acs.inorgchem.8b02820
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AUTHORS (3)
DW
Daniel Werner
GD
Glen B. Deacon
PJ
Peter C. Junk