Toughening of Biodegradable Poly(3-hydroxybutyrate-co-3-hydroxyvalerate)/Poly(ε-caprolactone) Blends by In Situ
Reactive Compatibilization
Posted on 2020-06-16 - 11:42
Reactive
extrusion of poly(3-hydroxybutyrate-co-3-hydroxyvalerate)/poly(ε-caprolactone)
(PHBV/PCL) blends was performed in the presence of cross-linker 1,3,5-tri-2-propenyl-1,3,5-triazine-2,4,6(1H,3H,5H)-trione (TAIC)
and peroxide. The compatibility between the two biodegradable polymers
was significantly improved only when TAIC and peroxide work together,
as evidenced by the decreased PCL particle size and blurred interfacial
gap between the PHBV and PCL. The mechanical, thermal, morphological,
and rheological properties of the compatibilized blends were studied
and compared to the blends without TAIC and peroxide. At the optimal
TAIC content (1 phr), the elongation at break of the compatibilized
blends was 380% that of the PHBV/PCL blend without any additives and
700% that of neat PHBV. The improved interfacial compatibility, decreased
PCL particle size, and uniform PHBV crystals are all factors that
contribute to improving the toughness of the blend. Through Fourier
transform infrared (FTIR) and rheological studies, the reaction mechanism
is discussed. The study shows that PHBV and PCL are cross-linked by
TAIC, resulting in the formation of a PHBV–PCL co-polymer,
which improves the compatibility of the blend. The biodegradable polymer
blends with high crystallinity and improved toughness prepared in
this study are proposed to be used in sustainable packaging or other
applications.
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Zytner, Peter; Wu, Feng; Misra, Manjusri; Mohanty, Amar K. (2020). Toughening of Biodegradable Poly(3-hydroxybutyrate-co-3-hydroxyvalerate)/Poly(ε-caprolactone) Blends by In Situ
Reactive Compatibilization. ACS Publications. Collection. https://doi.org/10.1021/acsomega.9b04379