Three-Dimensional
Magnesiophilic Scaffolds for Reduced
Passivation toward High-Rate Mg Metal Anodes in a Noncorrosive Electrolyte
Posted on 2020-06-12 - 14:39
Magnesium
ion batteries are a promising alternative of the lithium
counterpart; however, the poorly ion-conductive passivation layer
on Mg metal makes plating/stripping difficult. In addition to the
generally recognized chemical passivation, the interphase is dynamically
degraded by electrochemical side reactions. Especially under high
current densities, the interphase thickens, exacerbating the electrode
degradation. Herein, we adopt 3D Mg3Bi2 scaffolds
for Mg metal, of which the high surface area reduces the effective
current density to avoid continuous electrolyte decomposition and
the good Mg affinity homogenizes nucleation. The greatly alleviated
passivation layer could serve as a stable solid/electrolyte interface
instead. The symmetric cell delivers a low overpotential of 0.21 and
0.50 V at a current density of 0.1 and 4 mA cm–2, respectively, and a superior cycling performance over 300 cycles
at 0.5 mA cm–2 in a noncorrosive conventional electrolyte.
This work proves that the control of dynamic passivation can enable
high-power density Mg metal anodes.
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Wan, Bingxin; Dou, Huanglin; Zhao, Xiaoli; Wang, Jiahe; Zhao, Wanyu; Guo, Min; et al. (2020). Three-Dimensional
Magnesiophilic Scaffolds for Reduced
Passivation toward High-Rate Mg Metal Anodes in a Noncorrosive Electrolyte. ACS Publications. Collection. https://doi.org/10.1021/acsami.0c07213