Thermoresponsive Supramolecular Hydrogels with High
Fracture Toughness
Posted on 2018-09-14 - 13:22
Supramolecular
hydrogels formed from random copolymers of N-isopropylacrylamide
(NIPAM) and 2-(N-ethylperfluorooctanesulfonamido)ethyl
acrylate (FOSA) exhibit a volume phase transition due to a lower critical
solution temperature (LCST). The LCST can be tuned between 32 and
5 °C by incorporating up to 14 mol % FOSA in the copolymer. The
tensile modulus and strength of the hydrogels increased above the
LCST as a consequence of an increase in the effective cross-link density
due to the phase separation of water from the hydrogel. Below the
LCST, the hydrogels exhibited extraordinary fracture toughness and
crack blunting capability. Fracture energies of ∼8000 J/m2 were achieved, which is comparable or greater than that
of cartilage and what has been previously achieved with synthetic
supramolecular hydrogels. These gels exhibited large hysteresis behavior,
though unlike tough double network hydrogels, the NIPAM/FOSA hydrogels
can fully recover their dimensions (i.e., no permanent set) and properties
after tensile deformations as high as 400% strain. Although the recovery
of the macroscopic dimensions is relatively quick, the recovery of
the microstructure requires times on the order of hours. The excellent
energy dissipation behavior and recovery of the hydrogel is due to
the reversible nature of the hydrophobic bonds and their aggregation
into core–shell nanodomains, ∼6 nm in diameter. Under
stress, the hydrophobic FOSA bonds break and the FOSA groups can rearrange
either within the nanodomain or pull out of the nanodomain to dissipate
energy. The bonds, however, reform when the stress is removed and
the nanostructure heals. The hydrogels also exhibit stress-softening
behavior (Mullins effect) as a consequence of the
kinetics of the reversible structure and properties recovery following
a deformation.
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Wang, Fei; Weiss, R. A. (2018). Thermoresponsive Supramolecular Hydrogels with High
Fracture Toughness. ACS Publications. Collection. https://doi.org/10.1021/acs.macromol.8b00490
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AUTHORS (2)
FW
Fei Wang
RW
R. A. Weiss
KEYWORDS
Thermoresponsive Supramolecular HydrogelsFOSA bondsnetwork hydrogelsLCSTNIPAMcrack blunting capabilityFracture energiesFOSA groupsmacroscopic dimensionsproperties recoverysupramolecular hydrogelsphase separationnanostructure healshysteresis behaviorsolution temperatureHigh Fracture Toughness Supramolecular hydrogelsvolume phase transitionenergy dissipation behaviorMullins effectexhibit stress-softening behaviorcross-link densityfracture toughness