The Reaction of [Cp*RhCl2]2,
Aniline, and a Terminal Alkyne: Formation of Cyclometalated Rhodium(III)
Complexes

Leong, Weng Kee

The Reaction of [Cp*RhCl₂]₂, Aniline, and a Terminal Alkyne: Formation of Cyclometalated Rhodium(III) Complexes

Posted on 2016-02-20 - 17:39

The reaction of [Cp*RhCl₂]₂ with an aniline (R′NH₂) and a terminal alkyne (RCCH) afforded the N-containing cyclometalated rhodium complexes Cp*Rh(Cl)[N(R′)C(CH₂R)CHCR] via a hydroamination and a 1,2-insertion of an alkyne. A reaction pathway has been proposed on the basis of deuterium labeling experiments and computational studies.

CITE THIS COLLECTION

Kumaran, Elumalai; Leong, Weng Kee (2016). The Reaction of [Cp*RhCl₂]₂, Aniline, and a Terminal Alkyne: Formation of Cyclometalated Rhodium(III) Complexes. ACS Publications. Collection. https://doi.org/10.1021/om300387q

https://doi.org/10.1021/om300387q

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