The Inheritance Angle: A Determinant for the Number
of Members in the Substituted Cucurbit[n]uril Family
Posted on 2017-07-21 - 20:19
Two
new glycoluril diethers have been prepared, bearing strained
cyclobutene and cyclobutane rings at the fused junction of the two
imidazolidinone rings. The wide angle of the concave face of the cyclobutano
derivative enabled the synthesis of cyclobutanocucurbit[5–8]uril,
the largest member being the most significant achievement. A limited
binding affinity study compared the new substituted family to classical
cucurbit[5–8]uril. Surprisingly lower affinities were found,
except for cyclobutanocucurbit[6]uril, which
was 3.3-fold higher.
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Zhao, Yi; Mandadapu, Vijaybabu; Iranmanesh, Hasti; Beves, Jonathon E.; Day, Anthony I. (2017). The Inheritance Angle: A Determinant for the Number
of Members in the Substituted Cucurbit[n]uril Family. ACS Publications. Collection. https://doi.org/10.1021/acs.orglett.7b01786
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AUTHORS (5)
YZ
Yi Zhao
VM
Vijaybabu Mandadapu
HI
Hasti Iranmanesh
JB
Jonathon E. Beves
AD
Anthony I. Day