The [1,5]-Brook Rearrangement:  An Initial Application in Anion Relay Chemistry

Kim, Dae-Shik

The [1,5]-Brook Rearrangement: An Initial Application in Anion Relay Chemistry

Posted on 2006-09-27 - 00:00

The [1,5]-Brook rearrangement proceeds efficiently in a series of hydroxyl dithiane substrates with sodium and potassium bases; less effective are lithium bases. That the mode of silyl migration is intramolecular was demonstrated by a crossover experiment. Finally, the tricomponent anion relay chemistry (ARC) coupling tactic was demonstrated employing the [1,5]-Brook rearrangement.

CITE THIS COLLECTION

Smith, Amos B.; Xian, Ming; Kim, Won-Suk; Kim, Dae-Shik (2016). The [1,5]-Brook Rearrangement: An Initial Application in Anion Relay Chemistry. ACS Publications. Collection. https://doi.org/10.1021/ja065033e

https://doi.org/10.1021/ja065033e

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