Systematic Tuning of the Optical Properties of Discrete
Complexes of EuII in Solution Using Counterions and Solvents
Posted on 2020-07-03 - 13:03
We describe a systematic study of
the influence of halides and
solvents on the optical properties of EuII-containing complexes
in solution starting from well-defined crystalline precursors. Anionic
halides, chloride and bromide, blue-shift the spectroscopic properties
of EuII, whereas neutral ligands, methanol and acetonitrile,
cause a red shift. This system provides evidence that EuII has a stronger affinity for chloride, and to some extent bromide,
relative to acetonitrile but not methanol. We also describe a simple
procedure using an ion-exchange resin for the exchange of iodide counterions
to hexafluorophosphate. These findings are a step toward designing
ligands that can tune the optical properties of EuII-containing
complexes for solution-based applications.
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Basal, Lina A.; Kajjam, Aravind B.; Bailey, Matthew D.; Allen, Matthew J. (2020). Systematic Tuning of the Optical Properties of Discrete
Complexes of EuII in Solution Using Counterions and Solvents. ACS Publications. Collection. https://doi.org/10.1021/acs.inorgchem.0c01516
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AUTHORS (4)
LB
Lina A. Basal
AK
Aravind B. Kajjam
MB
Matthew D. Bailey
MA
Matthew J. Allen