Synthesis of Four Illudalane Sesquiterpenes Utilizing
a One-Pot Diels–Alder/Oxidative Aromatization Sequence
Posted on 2019-08-23 - 11:06
The concise, divergent
total syntheses of four illudalane sesquiterpenes
using an indanone as the key intermediate are reported. The key elements
in these total syntheses, which involve only four to six operational
steps, consist of a Suzuki cross-coupling and a one-pot Diels–Alder/oxidative
aromatization reaction.
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Xun, Miao-Miao; Bai, Yunli; Wang, Yanhong; Hu, Zhiyong; Fu, Kai; Ma, Wenbing; et al. (2019). Synthesis of Four Illudalane Sesquiterpenes Utilizing
a One-Pot Diels–Alder/Oxidative Aromatization Sequence. ACS Publications. Collection. https://doi.org/10.1021/acs.orglett.9b02511
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AUTHORS (7)
MX
Miao-Miao Xun
YB
Yunli Bai
YW
Yanhong Wang
ZH
Zhiyong Hu
KF
Kai Fu
WM
Wenbing Ma
CY
Changchun Yuan