Synthesis and Structure of Organoantimony(III) Compounds Containing Antimony−Selenium and −Tellurium Terminal Bonds
Posted on 2008-12-08 - 00:00
The reactions of the organoantimony(I) compound Sb4Ar4 (where Ar is the N,C,N chelating ligand C6H3-2,6-(CH2NMe2)2) with elemental Se and Te give the unprecedented monomeric compounds ArSbE (E = Se, Te) with the terminal Sb−E bond being retained both in solution and in the solid state.
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Dostál, Libor; Jambor, Roman; Růžička, Aleš; Lyčka, Antonín; Brus, Jiří; Proft, Frank de (2016). Synthesis and Structure of Organoantimony(III) Compounds Containing Antimony−Selenium and −Tellurium Terminal Bonds. ACS Publications. Collection. https://doi.org/10.1021/om800945g