Synthesis and Structural Characterization of a Cyclen-Derived
Molecular Cage
Posted on 2015-12-04 - 00:00
Reaction of a tetrafunctionalized
cyclen derivative containing
four aldehyde groups with an appropriate diamine followed by reduction
and demetalation highly efficiently affords a bis(cyclen)-derived
molecular cage. Potentiometric investigations show that this compound
forms dimetallic complexes with copper(II), with the two metal ions
selectively coordinated to the cyclen units. X-ray crystallography
indicates that these complexes could give rise to new cascade complexes
after incorporation of anions between the metal centers.
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Ganß, Alexander; Belda, Raquel; Pitarch, Javier; Goddard, Richard; García-España, Enrique; Kubik, Stefan (2016). Synthesis and Structural Characterization of a Cyclen-Derived
Molecular Cage. ACS Publications. Collection. https://doi.org/10.1021/acs.orglett.5b03027