Stimuli-Responsive
Aggregation-Induced Delayed Fluorescence Emitters Featuring the Asymmetric
D–A Structure with a Novel Diarylketone Acceptor Toward Efficient
OLEDs with Negligible Efficiency Roll-Off
Posted on 2020-06-22 - 16:34
Multifunctional
luminescent materials with aggregation-induced delayed fluorescence
(AIDF) are capable of suppressing concentration-caused emission quenching
and exciton annihilation when used as organic light-emitting diode
(OLED) emitters. In this contribution, three stimuli-responsive AIDF
luminogens, pipd-BZ-PXZ, pipd-BZ-PTZ,
and pipd-BZ-DMAC, featuring a D–A asymmetric
framework based on a fused N-heterocycle diarylketone acceptor (imid-azo[1,2-a]pyridin-2-yl(phenyl)methanone pipd) are
designed and synthesized. Interestingly, pipd-BZ-PTZ
forms two different kinds of crystals (G-crystal and O-crystal) with
distinct intermolecular interactions between pipd moieties. The G-crystal with a looser packing mode presents significant
morphology-dependent stimuli-responsive behavior with a shifted emission
wavelength of 56 nm. Generated by a strong intramolecular charge transfer
effect, pipd-BZ-PXZ and pipd-BZ-PTZ
exhibit orange to red emission in solution and neat films. Both nondoped
and doped devices are fabricated for comparison. Nondoped devices
present moderate performance with external quantum efficiencies and
current efficiency that reach 7.04% and 19.86 cd A–1, respectively, and the corresponding efficiency roll off at 1000
cd m–2 is as small as 2.3%, which is among the best
records of AIDF-OLEDs with an emission wavelength over 570 nm. Doped
devices show better performance with corresponding efficiencies of
up to 55.41 cd A–1 and 15.77%.
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Yang, Zhiwen; Zhan, Yingying; Qiu, Zhipeng; Zeng, Jiajie; Guo, Jingjing; Hu, Sheng; et al. (2020). Stimuli-Responsive
Aggregation-Induced Delayed Fluorescence Emitters Featuring the Asymmetric
D–A Structure with a Novel Diarylketone Acceptor Toward Efficient
OLEDs with Negligible Efficiency Roll-Off. ACS Publications. Collection. https://doi.org/10.1021/acsami.0c07612
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AUTHORS (11)
ZY
Zhiwen Yang
YZ
Yingying Zhan
ZQ
Zhipeng Qiu
JZ
Jiajie Zeng
JG
Jingjing Guo
SH
Sheng Hu
ZZ
Zujin Zhao
XL
Xianwei Li
SJ
Shaomin Ji
YH
Yanping Huo
SS
Shi-jian Su
KEYWORDS
stimuli-responsive AIDF luminogensBZ-DMACAIDF-OLEDFluorescence Emitters FeaturingNovel Diarylketone AcceptorNegligible Efficiency Roll-Off MultifunctionalOLEDBZ-PTZefficiencyintramolecular charge transfer effectemission wavelengthN-heterocycle diarylketone acceptorBZ-PXZconcentration-caused emission quenchingpipdDoped devices showmorphology-dependent stimuli-responsive behavior