Silylative Carbocyclization of
Allenyl-carbonyl Units with Et3SiH
Catalyzed by Rhodium:
Cis-Stereoselective Synthesis of
Homoallylic Cycloalkanols†
Posted on 2003-07-08 - 00:00
A new procedure for the synthesis of cis-2-triethylsilylvinyl-cyclopentanols and -cyclohexanols from allenyl-aldehydes and -ketones with Et3SiH through rhodium-catalyzed silylative carbocyclization is described. The use of Rh(acac)(CO)2 (1 mol %) to promote the reaction results in
a mild and convenient protocol for the three-component assembly.
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Kang, Suk-Ku; Hong, Young-Taek; Lee, Joon-Hwan; Kim, Won-Yeol; Lee, Inhee; Yu, Chan-Mo (2016). Silylative Carbocyclization of
Allenyl-carbonyl Units with Et3SiH
Catalyzed by Rhodium:
Cis-Stereoselective Synthesis of
Homoallylic Cycloalkanols†. ACS Publications. Collection. https://doi.org/10.1021/ol034787k
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AUTHORS (6)
- SKSuk-Ku KangYHYoung-Taek HongJLJoon-Hwan LeeWKWon-Yeol KimILInhee LeeCYChan-Mo Yu
