Ru-Catalyzed Dehydrogenative Silylation of POSS-Silanols
with Hydrosilanes: Its Introduction to One-Pot Synthesis

Hreczycho, Grzegorz

Ru-Catalyzed Dehydrogenative Silylation of POSS-Silanols with Hydrosilanes: Its Introduction to One-Pot Synthesis

Posted on 2019-01-10 - 21:04

A commercially available and stable ruthenium dodecacarbonyl catalyst (Ru₃(CO)₁₂) allows very efficient and convenient access to functionalized silsesquioxanes (SQs) containing siloxane moiety (Si–O–Si) via dehydrogenative coupling of POSS-silanols with hydrosilanes. With the aid of SiH-containing silsesquioxanes, an unprecedented one-pot procedure has been revealed, and the usefulness of this approach was demonstrated by the synthesis of various derivatives via O-silylation, as well as CC and CN hydrosilylation.

CITE THIS COLLECTION

DataCite

3 Biotech

3D Printing in Medicine

3D Research

3D-Printed Materials and Systems

4OR

AAPG Bulletin

AAPS Open

AAPS PharmSciTech

Abhandlungen aus dem Mathematischen Seminar der Universität Hamburg

ABI Technik (German)

Academic Medicine

Academic Pediatrics

Academic Psychiatry

Academic Questions

Academy of Management Discoveries

Academy of Management Journal

Academy of Management Learning and Education

Academy of Management Perspectives

Academy of Management Proceedings

Academy of Management Review

Kaźmierczak, Joanna; Kuciński, Krzysztof; Lewandowski, Dariusz; Hreczycho, Grzegorz (2019). Ru-Catalyzed Dehydrogenative Silylation of POSS-Silanols with Hydrosilanes: Its Introduction to One-Pot Synthesis. ACS Publications. Collection. https://doi.org/10.1021/acs.inorgchem.8b02645

https://doi.org/10.1021/acs.inorgchem.8b02645

or

Select your citation style and then place your mouse over the citation text to select it.