Ring Enlargement of Cyclic Acetals and
Ketals:  A Way to Seven-Membered
Nucleoside Phostones

Rosenberg, Ivan

Ring Enlargement of Cyclic Acetals and Ketals: A Way to Seven-Membered Nucleoside Phostones

Posted on 2007-12-20 - 00:00

Novel seven-membered nucleoside phostones were prepared by the reaction of chlorodiethyl phosphite with 3‘,5‘-acetals or ketals derived from xylo-dT. A mechanism for the ring enlargement was proposed, and support for it was provided by ab initio calculations.

CITE THIS COLLECTION

Páv, Ondřej; Barvík, Ivan; Buděšínský, Miloš; Masojídková, Milena; Rosenberg, Ivan (2016). Ring Enlargement of Cyclic Acetals and Ketals: A Way to Seven-Membered Nucleoside Phostones. ACS Publications. Collection. https://doi.org/10.1021/ol7023899

https://doi.org/10.1021/ol7023899

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